CN108676522A - Novel vitrified brick gum - Google Patents

Novel vitrified brick gum Download PDF

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Publication number
CN108676522A
CN108676522A CN201810594293.9A CN201810594293A CN108676522A CN 108676522 A CN108676522 A CN 108676522A CN 201810594293 A CN201810594293 A CN 201810594293A CN 108676522 A CN108676522 A CN 108676522A
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CN
China
Prior art keywords
vitrified brick
brick gum
sand
powder
adhesive
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Pending
Application number
CN201810594293.9A
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Chinese (zh)
Inventor
刘晓辰
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Individual
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Individual
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Priority to CN201810594293.9A priority Critical patent/CN108676522A/en
Publication of CN108676522A publication Critical patent/CN108676522A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00Adhesives based on homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02Homopolymers or copolymers of hydrocarbons
    • C09J125/04Homopolymers or copolymers of styrene
    • C09J125/08Copolymers of styrene
    • C09J125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses novel vitrified brick gum, raw material components number meters by weight, it is characterised in that:The vitrified brick gum is grouped as by single group, includes each component of following weight:Lotion 240kg, sand 700kg, adhesive 10kg, preservative 1.5kg 2kg, antifoaming agent 1.5kg 2kg, sodium acetate solution 1kg 2kg, thickener 2kg close 1 4kg of powder, 1 1.5kg of auxiliary agent, white carbon 2kg 3kg, nano powder solution 1.5kg 2kg.The novel vitrified brick gum; it can accelerate cured speed in the construction process; improve the veneer speed of vitrified tile; to improve whole construction efficiency; and its material used is all ep-type material; it is economic and practical; it is at low cost; it will not pollute; have the function of antibacterial, optimization air and ageing-resistant; healthy hidden danger will not be caused to constructor, it is stronger relative to traditional vitrified brick gum bonding effect and adhesive force, the phenomenon that solving after vitrified tile is pasted and be susceptible to hollowing, fall off.

Description

Novel vitrified brick gum
Technical field
The present invention relates to building material field, specially novel vitrified brick gum.
Background technology
Vitrified tile is being commonly called as polished brick in porcelain character, is that a kind of light made of polishing is passed through on the surface of all-body tile green body Brick belongs to one kind of all-body tile, because its low hardness of water absorption rate is also relatively high, it is not easy to have cut, so Develop into the mainstream of indoor decoration, needs to use the vitrified tile back of the body for be bonded with metope, ground in the construction process Glue, vitrified brick gum are to be specifically applied to wet combining glass by polymer emulsion material and the compound two-component product of inorganic silicate The back side process for changing brick is also applied for the back side process of low water absorption, quality densification, the smooth stone material and other brick materials in surface. There are certain drawbacks in existing vitrified brick gum, making material is of high cost in use, not economic and practical enough, making material at This is low, and bonding effect is poor, after a period of use, the phenomenon that hollowing, fall off easily occurs, and needs after gluing etc. Five hours or so gum could realize solidification, could carry out down one of working procedure, reduce construction efficiency, and existing The material of vitrified brick gum is not environmentally friendly enough, if dropping into the positions such as eyes or mouth and nose accidentally can affect, from And certain healthy hidden danger is caused, therefore, it is proposed that novel vitrified brick gum.
Invention content
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides novel vitrified brick gums, can accelerate in the construction process Cured speed improves the veneer speed of vitrified tile, and to improve whole construction efficiency, and its material used is all It is economic and practical for ep-type material, it is at low cost, it will not pollute, have the function of antibacterial, optimization air and ageing-resistant, Healthy hidden danger will not be caused to constructor, it is stronger relative to traditional vitrified brick gum bonding effect and adhesive force, solve glass Change after brick is pasted the phenomenon that being susceptible to hollowing, falling off.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:Novel vitrified brick gum, raw material components Number meter, the vitrified brick gum are grouped as by single group by weight, include each component of following weight:Lotion 240kg, sand 700kg, adhesive 10kg, preservative 1.5kg-2kg, antifoaming agent 1.5kg-2kg, sodium acetate solution 1kg-2kg, thickener 2kg, Close powder 1-4kg, auxiliary agent 1-1.5kg, white carbon 2kg-3kg, nano powder solution 1.5kg-2kg.
Preferably, described adhesive is by acrylate adhesive, adhesive for polyurethane, epoxy resin adhesive, UV gluings Agent is according to proportioning 1:1:1:1 ratio row are composed, and the lotion is by styrene-butadiene emulsion, styrene-acrylic emulsion, three kinds of neoprene latex Emulsion polymerization forms.
Preferably, the styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene latex polymerization temperature control between 40 DEG C -60 DEG C, And neoprene latex is made of zinc oxide, magnesia vulcanization.
Preferably, the nano powder solution is integrated with water by nano-powder forms, and the structure of nano-powder is subtle Particle, and between a diameter of 1-100nm, and the grain shape of nano-powder is spherical structure.
Preferably, the pH value of the sodium acetate solution is 8.7, and the density of the neoprene latex is 1.23g- 1.25g/㎝3, and neoprene latex is milky sheet or block.
Preferably, the epoxy resin adhesive is that water white transparency and band have specific characteristics the thick liquid of smell, the increasing Thick dose is alkaline thickener.
Preferably, the sand includes quartz sand and white sand, and the color of quartz sand is semi-transparent clear shape, and quartzy The face shaping of sand is in more prismatics, and the quartz sand is made of uncemented crushed rocks.
Preferably, the adhesive for polyurethane is mainly by isocyanic acid ammonium, polyalcohol, the polyethers containing alkyl, catalyst and molten Agent forms, and contains organosilicon in the ingredient of the antifoaming agent.
Preferably, include the following steps, step 1:First by three kinds of styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene latex breasts Liquid is according to 1:1:1 proportioning is mixed into the lotion of 240kg, adds the auxiliary agent of 1-1.5kg, the thickener of 2kg, 2kg-3kg The nano powder solution of white carbon, 1.5kg-2kg, pours into agitator and is stirred, until being sufficiently mixed, step 2:After mixing, The sand for first pouring into the 700kg by quartz sand and white sand mixing carries out mixture, then pours into the conjunction powder of 1-4kg, step 3:It is added The sodium acetate solution of 1kg-2kg generates, the defoaming of 1.5kg-2kg due to having bubble when sodium acetate solution generates chemical reaction Agent adds after sodium acetate solution is poured into, and the adhesive of 10kg and the anti-corrosion of 1.5kg-2kg are eventually adding after bubble collapse Agent is stirred five minutes.
(3) advantageous effect
The present invention provides a kind of formulas and preparation method of Paclitaxe sauce, have following advantageous effect:
It can cure rapidly in the construction process, accelerate the veneer speed of vitrified tile, improve construction efficiency, use Material be all ep-type material, healthy hidden danger will not be caused to constructor, will not be polluted, have antibacterial, optimization air It is stronger relative to traditional vitrified brick gum bonding effect and adhesive force with ageing-resistant function, after solving vitrified tile stickup The phenomenon that being susceptible to hollowing, falling off.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
The present invention provides a kind of technical solution:Novel vitrified brick gum, raw material components by weight number meter, vitrified brick gum by Single group is grouped as, and includes each component of following weight:Lotion 240kg, sand 700kg, adhesive 10kg, preservative 1.5kg- 2kg, antifoaming agent 1.5kg-2kg, sodium acetate solution 1kg-2kg, thickener 2kg close powder 1-4kg, auxiliary agent 1-1.5kg, hard charcoal Black 2kg-3kg, nano powder solution 1.5kg-2kg, styrene-butadiene emulsion, styrene-acrylic emulsion, the control of neoprene latex polymerization temperature are 40 Between DEG C -60 DEG C, and neoprene latex is made of zinc oxide, magnesia vulcanization, and nano powder solution is by nano-powder and aqueous fusion It is combined into, and the structure of nano-powder is fine particle, and between a diameter of 1-100nm, and the granulated of nano-powder Shape is spherical structure, and the pH value of sodium acetate solution is 8.7, and the density of neoprene latex is 1.23g-1.25g/ ㎝3, and chlorine Buna lotion is milky sheet or block, and epoxy resin adhesive is that water white transparency and band have specific characteristics the viscous of smell Thick liquid, thickener are alkaline thickener, and sand includes quartz sand and white sand, and the color of quartz sand is semi-transparent clear Shape, and the face shaping of quartz sand is in more prismatics, quartz sand is made of uncemented crushed rocks, and adhesive for polyurethane is main By isocyanic acid ammonium, polyalcohol, the polyethers containing alkyl, catalysts and solvents composition contains organosilicon in the ingredient of antifoaming agent, including Following steps, step 1:First by three kinds of styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene latex lotions according to 1:1:1 proportioning is mixed The lotion for synthesizing 240kg adds the auxiliary agent of 1-1.5kg, the thickener of 2kg, the white carbon of 2kg-3kg, 1.5kg-2kg and receives Rice flour solution, pours into agitator and is stirred, until being sufficiently mixed, step 2:After mixing, first pour by quartz sand and white sand The sand of mixed 700kg carries out mixture, then pours into the conjunction powder of 1-4kg, step 3:The sodium acetate that 1kg-2kg is added is molten Liquid is generated due to having bubble when sodium acetate solution generates chemical reaction, and the antifoaming agent of 1.5kg-2kg falls in sodium acetate solution It is added after entering, the preservative of adhesive and 1.5kg-2kg that 10kg is eventually adding after bubble collapse stirs five minutes i.e. It can.
In conclusion the novel vitrified brick gum, includes the following steps, step 1:First by styrene-butadiene emulsion, phenylpropyl alcohol breast Three kinds of liquid, neoprene latex lotions are according to 1:1:1 proportioning is mixed into the lotion of 240kg, add 1-1.5kg auxiliary agent, The nano powder solution of the thickener of 2kg, the white carbon of 2kg-3kg, 1.5kg-2kg, pours into agitator and is stirred, until filling Divide mixing, step 2:After mixing, the sand for first pouring into the 700kg by quartz sand and white sand mixing carries out mixture, then pours into 1- The conjunction powder of 4kg, step 3:The sodium acetate solution of 1kg-2kg is added, due to being had when sodium acetate solution generates chemical reaction Bubble generates, and the antifoaming agent of 1.5kg-2kg adds after sodium acetate solution is poured into, and is eventually adding 10kg's after bubble collapse The preservative of adhesive and 1.5kg-2kg stir five minutes.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of novel vitrified brick gum, raw material components number meter by weight, it is characterised in that:The vitrified brick gum is by one pack system Composition, includes each component of following weight:Lotion 240kg, sand 700kg, adhesive 10kg, preservative 1.5kg-2kg, defoaming Agent 1.5kg-2kg, sodium acetate solution 1kg-2kg, thickener 2kg close powder 1-4kg, auxiliary agent 1-1.5kg, white carbon 2kg- 3kg, nano powder solution 1.5kg-2kg.
2. novel vitrified brick gum according to claim 1, it is characterised in that:Described adhesive is by acrylate gluing Agent, adhesive for polyurethane, epoxy resin adhesive, UV adhesives are according to proportioning 1:1:1:1 ratio row are composed, the lotion It is formed by three kinds of styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene latex emulsion polymerizations.
3. novel vitrified brick gum according to claim 2, it is characterised in that:The styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene Rubber latex polymerization temperature controls between 40 DEG C -60 DEG C, and neoprene latex is made of zinc oxide, magnesia vulcanization.
4. novel vitrified brick gum according to claim 1, it is characterised in that:The nano powder solution by nano-powder with Aqueous fusion is combined into, and the structure of nano-powder is fine particle, and between a diameter of 1-100nm, and of nano-powder Particle shape shape is spherical structure.
5. the novel vitrified brick gum according to claim 1-2, it is characterised in that:The pH value of the sodium acetate solution is 8.7, the density of the neoprene latex is 1.23g-1.25g/ ㎝3, and neoprene latex be milky sheet or Block.
6. the novel vitrified brick gum according to claim 1-2, it is characterised in that:The epoxy resin adhesive is colourless Transparent and band has specific characteristics the thick liquid of smell, and the thickener is alkaline thickener.
7. novel vitrified brick gum according to claim 1, it is characterised in that:The sand includes quartz sand and white sand, And the color of quartz sand is semi-transparent clear shape, and the face shaping of quartz sand is in more prismatics, and the quartz sand is by non-glue The crushed rocks composition of knot.
8. the novel vitrified brick gum according to claim 1-2, it is characterised in that:The adhesive for polyurethane is mainly by different Ammonium cyanate, polyalcohol, the polyethers containing alkyl, catalysts and solvents form, and contain organosilicon in the ingredient of the antifoaming agent.
9. the concocting method of the novel vitrified brick gum according to claim 1-8, includes the following steps, it is characterised in that: Step 1:First by three kinds of styrene-butadiene emulsion, styrene-acrylic emulsion, neoprene latex lotions according to 1:1:1 proportioning is mixed into 240kg Lotion, add the nano powder solution of the auxiliary agent of 1-1.5kg, the thickener of 2kg, the white carbon of 2kg-3kg, 1.5kg-2kg, It pours into agitator and is stirred, until being sufficiently mixed, step 2:After mixing, first pour by quartz sand and white sand mixing The sand of 700kg carries out mixture, then pours into the conjunction powder of 1-4kg, step 3:The sodium acetate solution of 1kg-2kg is added, due to vinegar Acid sodium solution has bubble generation when generating chemical reaction, the antifoaming agent of 1.5kg-2kg adds after sodium acetate solution is poured into, The preservative of adhesive and 1.5kg-2kg that 10kg is eventually adding after bubble collapse stirs five minutes.
CN201810594293.9A 2018-06-11 2018-06-11 Novel vitrified brick gum Pending CN108676522A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810594293.9A CN108676522A (en) 2018-06-11 2018-06-11 Novel vitrified brick gum

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Application Number Priority Date Filing Date Title
CN201810594293.9A CN108676522A (en) 2018-06-11 2018-06-11 Novel vitrified brick gum

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CN108676522A true CN108676522A (en) 2018-10-19

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109708938A (en) * 2019-01-08 2019-05-03 同济大学 A kind of artificial transparent rock and preparation method thereof based on shadowless glue and tekite sand
CN113233905A (en) * 2021-05-24 2021-08-10 重庆唯美陶瓷有限公司 Preparation method of ceramic tile and ceramic tile

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8901220B2 (en) * 2010-03-05 2014-12-02 Basf Se Styrene-butadiene-based binders and methods of preparing and using same
CN105969308A (en) * 2016-06-27 2016-09-28 浙江共创建材科技有限公司 Eco-friendlyceramic tilegum for vitrified tiles
CN106497473A (en) * 2016-10-21 2017-03-15 湖北碱克新材料有限公司 A kind of environment protection type single-component vitrified brick gum and preparation method thereof
CN106916554A (en) * 2017-04-28 2017-07-04 湖北碱克新材料有限公司 A kind of one pack system vitrified brick gum

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8901220B2 (en) * 2010-03-05 2014-12-02 Basf Se Styrene-butadiene-based binders and methods of preparing and using same
CN105969308A (en) * 2016-06-27 2016-09-28 浙江共创建材科技有限公司 Eco-friendlyceramic tilegum for vitrified tiles
CN106497473A (en) * 2016-10-21 2017-03-15 湖北碱克新材料有限公司 A kind of environment protection type single-component vitrified brick gum and preparation method thereof
CN106916554A (en) * 2017-04-28 2017-07-04 湖北碱克新材料有限公司 A kind of one pack system vitrified brick gum

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109708938A (en) * 2019-01-08 2019-05-03 同济大学 A kind of artificial transparent rock and preparation method thereof based on shadowless glue and tekite sand
CN109708938B (en) * 2019-01-08 2021-11-09 同济大学 Artificial transparent rock based on shadowless glue and fused quartz sand and preparation method thereof
CN113233905A (en) * 2021-05-24 2021-08-10 重庆唯美陶瓷有限公司 Preparation method of ceramic tile and ceramic tile

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Application publication date: 20181019

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