CN103484040B - A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof - Google Patents
A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof Download PDFInfo
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- CN103484040B CN103484040B CN201310436009.2A CN201310436009A CN103484040B CN 103484040 B CN103484040 B CN 103484040B CN 201310436009 A CN201310436009 A CN 201310436009A CN 103484040 B CN103484040 B CN 103484040B
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- 239000003292 glue Substances 0.000 title claims abstract description 39
- 238000010276 construction Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 28
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 15
- 239000004902 Softening Agent Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 238000004090 dissolution Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 13
- JUMYIBMBTDDLNG-OJERSXHUSA-N hydron;methyl (2r)-2-phenyl-2-[(2r)-piperidin-2-yl]acetate;chloride Chemical compound Cl.C([C@@H]1[C@H](C(=O)OC)C=2C=CC=CC=2)CCCN1 JUMYIBMBTDDLNG-OJERSXHUSA-N 0.000 claims description 10
- 229940099204 ritalin Drugs 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 230000009969 flowable effect Effects 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 11
- 229920002689 polyvinyl acetate Polymers 0.000 abstract description 6
- 239000012763 reinforcing filler Substances 0.000 abstract description 6
- 239000011347 resin Substances 0.000 abstract description 6
- 229920005989 resin Polymers 0.000 abstract description 6
- 239000013008 thixotropic agent Substances 0.000 abstract description 6
- 230000032683 aging Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to environment-friendly type building glue, particularly a kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof, it comprises following component: polyvinyl acetate resin 12.0 ~ 40.0%; Reinforcing filler 18.0 ~ 40.0%; Solvent 15.0 ~ 40.0%; Thixotropic agent 0.5 ~ 8.0%; Coupling agent 0.1 ~ 3.5%; Softening agent 0.1 ~ 5.0%; Dispersion agent 0.1 ~ 0.5%; Its preparation method: solvent is dropped in high speed agitator, polyvinyl acetate resin is added after starting agitator, stirring 1 ~ 3 is little becomes clear homogeneous liquid up to each material dissolution, add softening agent again, coupling agent, dispersion agent stir, then slowly add reinforcing filler, stir after obtaining the paste mixture that can flow and add thixotropic agent, stir obtained Environment-friendlynail-free nail-free glue for construction.Environmental friendliness of the present invention, easy construction, bonding without nail, bonding strength is high, and ageing-resistant performance is excellent.
Description
Technical field
The invention belongs to environment-friendly adhesive, particularly relate to a kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof.
Background technology
Of the same race and xenogenesis material of construction can be bonded together by architecture adhesion agent preferably, substitutes the techniques such as original nail, riveting, weldering, the saving resource, improve speed of application, reduce construction costs etc. of high degree.In recent years, the increment amplitude of architecture adhesion agent is considerably beyond other products, its range of application also by the application extension such as reinforcing, reinforcement, antidetonation of single existing building to every field such as road, bridge, subway, culvert, tunnel, dykes and dams, even newly-built every High speed railway project also uses construction structure glue bonding in a large number, and along with the progress of technology, tackiness agent changes, as heat-resisting, low temperature resistant, insulation, expediting setting type, environmental type etc. to featuresization.
Along with the demand to decorations personalization, family DIY operation is risen gradually, and building nail-free glue relies on its easy construction, without the bonding advantage attractive in appearance of nail being used widely by people gradually.Chinese Enterprises also develops a few money building nail-free glue product in recent years, but the kind developed also is only limitted to non-environmentfriendly products, containing a large amount of hazardous solvent.The today more and more pursue environmental protection people, aspiring after perfection, exploitation one can improve architectural construction technology, avoids nail and ailhead to expose and the Environment-friendlynail-free nail-free glue for construction that affects construction effect is very important.
Summary of the invention
The present invention is intended to overcome the deficiencies in the prior art part and provides one not containing the objectionable impurities such as formaldehyde and benzene, amount of solvent is few, environmentally friendly, bonding strength is high, easy construction, widely applicable Environment-friendlynail-free nail-free glue for construction and preparation method thereof, thus realize purely and simply to substitute nail, bypass nail and ailhead, allow all buildings, decoration become smooth seamless.
For achieving the above object, the present invention realizes like this.
A kind of Environment-friendlynail-free nail-free glue for construction, with weight, comprises following component:
Polyvinyl acetate resin 12.0 ~ 40.0%;
Reinforcing filler 20.0 ~ 40.0%;
Solvent 15.0 ~ 40.0%;
Thixotropic agent 0.5 ~ 8.0%;
Coupling agent 0.1 ~ 3.5%.
As a kind of preferred version, the weight percentage of softening agent of the present invention and dispersion agent is followed successively by: 0.1 ~ 5.0% and 0.1 ~ 0.5%.
Further, polyvinyl acetate resin of the present invention is one or more the mixture in polyvinyl acetate (PVA), vinyl acetate between to for plastic and ethylene copolymer, vinyl acetate between to for plastic and butyl acrylate copolymer, vinyl acetate between to for plastic and acrylic copolymer, vinyl acetate between to for plastic-butyl acrylate-acrylic acid copolymer.
Further, reinforcing filler of the present invention is one or more the mixture in water-ground limestone, activated Calcium carbonate, nano-calcium carbonate, silicon powder, potter's clay, talcum powder and kaolin.
Further, solvent of the present invention is one or more the mixture in ritalin, vinyl acetic monomer, N-BUTYL ACETATE, methyl alcohol, ethanol, 6# solvent oil, hexanaphthene.
Further, thixotropic agent of the present invention is one or more the mixture in aerosil, precipitated silica, inorganic bentonite, organobentonite, hydrogenated castor oil.
Further, coupling agent of the present invention is one or more the mixture in silane coupling agent, titanate coupling agent, titanium complex.
Further, silane coupling agent of the present invention is one or more the mixture in KH-550, KH-560, KH570, KH-580, KH-590, KH-792, KH-602, KH171.
The preparation method of above-mentioned Environment-friendlynail-free nail-free glue for construction, can implement as follows:
A, solvent is dropped in high speed agitator, start agitator;
B, add polyvinyl acetate resin, stir 1 ~ 3 and littlely becomes clear homogeneous liquid up to each material dissolution;
C, add softening agent, coupling agent, dispersion agent, stir;
D, slowly add reinforcing filler, stir the obtained paste mixture that can flow;
E, add thixotropic agent, stir obtained Environment-friendlynail-free nail-free glue for construction.
The present invention has following features.
In a, the present invention's formula, solvent is few, solvent environmentally safe, to human body fanout free region, belongs to environment-friendly adhesive product.Screening formulation ritalin is used to be then Diamond Search discharge product as solvent.
B, preparation manipulation technique of the present invention are simple, and product storage stability is good.
C, building nail-free glue of the present invention have thixotropic property, and applying glue facilitates and glue can not trickle along facade.
D, the present invention have superpower cementability and intensity, have good ageing-resistant performance simultaneously.
E, purely and simply can substitute nail, bypass nail and ailhead, allow all building decorations become smooth seamless.
Embodiment
Below in conjunction with embodiment, the invention will be further described.These embodiments are only for the object of illustration, and protection scope of the present invention does not limit to illustration category.
The present invention take polyvinyl acetate resin as base-material, and coordinate the obtained Environment-friendlynail-free nail-free glue for construction such as thixotropic agent, coupling agent, reinforcing filler, its bonding strength is high, and applying glue is convenient, can substitute nail completely.
embodiment 1.
A kind of Environment-friendlynail-free nail-free glue for construction, its component and concrete proportioning are formed:
Polyvinyl acetate (PVA) 105.0g;
Ritalin 105.0g;
Water-ground limestone 75.0g
Dioctyl phthalate (DOP) 5.3g;
Coupling agent KH-5503.3g;
Precipitated silica 24.8g.
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, ritalin is dropped in high speed agitator, start agitator;
B, add polyvinyl acetate (PVA), stir 2.5 and littlely becomes clear homogeneous liquid up to each material dissolution;
C, add softening agent, coupling agent KH-550 stirs 15 minutes to evenly;
D, slowly add water-ground limestone, stir 1 hour obtained homogeneous flowable paste mixture;
E, add precipitated silica, stir obtained Environment-friendlynail-free nail-free glue for construction.
embodiment 2.
A kind of Environment-friendlynail-free nail-free glue for construction, its component and concrete proportioning are formed:
Polyvinyl acetate (PVA) 120.0g;
Methyl alcohol 60.0g;
Vinyl acetic monomer 60.0g;
Kaolin 120.0g
Softening agent Benzoflex9883.6g;
Silok7781.0g
Coupling agent kh-570 4.0g;
Aerosil 8.0g;
Inorganic bentonite 20.0g.
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, methyl alcohol, vinyl acetic monomer to be dropped in high speed agitator, start agitator;
B, add polyvinyl acetate (PVA), stir 2 and littlely becomes clear homogeneous liquid up to each material dissolution;
C, add softening agent, dispersion agent, coupling agent kh-570 stir 15 minutes to evenly;
D, slowly add kaolin, stir 1.5 hours obtained homogeneous flowable paste mixtures;
E, add inorganic bentonite, aerosil, stir obtained Environment-friendlynail-free nail-free glue for construction.
embodiment 3.
A kind of Environment-friendlynail-free nail-free glue for construction, its component and concrete proportioning are formed:
Vinyl acetate between to for plastic-butyl acrylate copolymer 115.0g;
Ritalin 115.0g
Kaolin 105.0g;
Coupling agent KH-5503.3g;
Organobentonite 6.0g
Precipitated silica 6.0g.
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, be that the vinyl acetate between to for plastic of 9:1 and butyl acrylate copolymer-1 in ritalin make vinyl acetate between to for plastic-butyl acrylate copolymer solution for 2 hours by ratio;
B, vinyl acetate between to for plastic-butyl acrylate copolymer solution is proceeded in high speed agitator;
C, coupling agent KH-550 is joined in agitator, stir 15 minutes to evenly;
D, slowly add kaolin, high-speed stirring 1.5 hours obtained homogeneous flowable paste mixtures;
E, add organobentonite, precipitated silica, stir obtained Environment-friendlynail-free nail-free glue for construction.
experimental example.
Get the environment-friendly type building nail-free glue obtained by 50g embodiment 1-3 respectively, select the standard rubber plywood of 100*25*4.5mm, according to each bonding 40 groups of test specimens of the method for AS2329-1999, carry out unaged, burin-in process.Test tensile shear strength is as shown in table 1.
Table 1.
Shown by table 1 test data, nail-free glue obtained by the present invention meets the requirement of industry standard AS2329-1999 completely, there is very high intensity and the ageing resistance of excellence, especially adopt high as the building nail-free glue product strength that base-material is obtained by polymerization vinyl acetate between to for plastic-butyl acrylate copolymer solution, snappiness good.
Be understandably, above about specific descriptions of the present invention, the technical scheme described by the embodiment of the present invention is only not limited to for illustration of the present invention, those of ordinary skill in the art is to be understood that, still can modify to the present invention or equivalent replacement, to reach identical technique effect; Needs are used, all within protection scope of the present invention as long as meet.
Claims (3)
1. an Environment-friendlynail-free nail-free glue for construction, is characterized in that, with weight, comprises following component:
Polyvinyl acetate (PVA) 105.0g;
Ritalin 105.0g;
Water-ground limestone 75.0g
Dioctyl phthalate (DOP) 5.3g;
Coupling agent KH-5503.3g;
Precipitated silica 24.8g;
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, ritalin is dropped in high speed agitator, start agitator;
B, add polyvinyl acetate (PVA), stir 2.5 and littlely becomes clear homogeneous liquid up to each material dissolution;
C, add softening agent, coupling agent KH-550 stirs 15 minutes to evenly;
D, slowly add water-ground limestone, stir 1 hour obtained homogeneous flowable paste mixture;
E, add precipitated silica, stir obtained Environment-friendlynail-free nail-free glue for construction.
2. an Environment-friendlynail-free nail-free glue for construction, is characterized in that, with weight, comprises following component:
Polyvinyl acetate (PVA) 120.0g;
Methyl alcohol 60.0g;
Vinyl acetic monomer 60.0g;
Kaolin 120.0g
Softening agent Benzoflex9883.6g;
Silok7781.0g
Coupling agent kh-570 4.0g;
Aerosil 8.0g;
Inorganic bentonite 20.0g;
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, methyl alcohol, vinyl acetic monomer to be dropped in high speed agitator, start agitator;
B, add polyvinyl acetate (PVA), stir 2 and littlely becomes clear homogeneous liquid up to each material dissolution;
C, add softening agent, dispersion agent, coupling agent kh-570 stir 15 minutes to evenly;
D, slowly add kaolin, stir 1.5 hours obtained homogeneous flowable paste mixtures;
E, add inorganic bentonite, aerosil, stir obtained Environment-friendlynail-free nail-free glue for construction.
3. an Environment-friendlynail-free nail-free glue for construction, is characterized in that, with weight, comprises following component:
Vinyl acetate between to for plastic-butyl acrylate copolymer 115.0g;
Ritalin 115.0g
Kaolin 105.0g;
Coupling agent KH-5503.3g;
Organobentonite 6.0g
Precipitated silica 6.0g;
The preparation process of above-mentioned Vinyl Acetate Copolymer type Environment-friendlynail-free nail-free glue for construction is as follows:
A, be that the vinyl acetate between to for plastic of 9:1 and butyl acrylate copolymer-1 in ritalin make vinyl acetate between to for plastic-butyl acrylate copolymer solution for 2 hours by ratio;
B, vinyl acetate between to for plastic-butyl acrylate copolymer solution is proceeded in high speed agitator;
C, coupling agent KH-550 is joined in agitator, stir 15 minutes to evenly;
D, slowly add kaolin, high-speed stirring 1.5 hours obtained homogeneous flowable paste mixtures;
E, add organobentonite, precipitated silica, stir obtained Environment-friendlynail-free nail-free glue for construction.
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| CN201310436009.2A CN103484040B (en) | 2013-09-22 | 2013-09-22 | A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof |
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| CN201310436009.2A CN103484040B (en) | 2013-09-22 | 2013-09-22 | A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof |
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| CN103484040A CN103484040A (en) | 2014-01-01 |
| CN103484040B true CN103484040B (en) | 2016-04-06 |
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| CN104845537A (en) * | 2015-05-13 | 2015-08-19 | 钱万标 | Environment-friendly building adhesive |
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| CN107189718A (en) * | 2017-07-07 | 2017-09-22 | 滁州隆扬农业科技有限公司 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
| CN111040664A (en) * | 2019-11-27 | 2020-04-21 | 广东东方一哥新材料股份有限公司 | Environment-friendly chlorine-free nail-free glue and preparation method thereof |
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| CN103484040A (en) | 2014-01-01 |
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