CN107189718A - A kind of environmentally friendly nail-free glue for building and preparation method thereof - Google Patents
A kind of environmentally friendly nail-free glue for building and preparation method thereof Download PDFInfo
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- CN107189718A CN107189718A CN201710548984.0A CN201710548984A CN107189718A CN 107189718 A CN107189718 A CN 107189718A CN 201710548984 A CN201710548984 A CN 201710548984A CN 107189718 A CN107189718 A CN 107189718A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses one kind environmentally friendly nail-free glue for building, include the raw material of following parts by weight：20 30 parts of polyvinyl alcohol, 15 25 parts of polyvinyl acetate, 8 12 parts of methyl acetate, 10 12 parts of filler, 23 parts of defoamer, 13 parts of coupling agent, 10 18 parts of plant gum powder, 46 parts of nano silicon, 13 parts of nano zine oxide, 0.5 1.5 parts of nano titanium oxide, 0.2 0.6 parts of preservative, 79 parts of inorganic tackifier, 24 parts of neopelex.The present invention environmentally friendly nail-free glue for building, its adhesive strength is high, and ageing-resistant performance is good, with water resistance, be difficult that good mouldy, asepsis environment-protecting, formaldehydeless, colorless and odorless, denseness, period of storage length, water-retaining property be good, low temperature not gel the characteristics of；The raw material components of the present invention are safe and reliable simultaneously, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, with higher practical value and good application prospect.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of environmentally friendly nail-free glue for building and preparation method thereof.
Background technology
Of the same race and xenogenesis construction material can be preferably bonded together by architecture adhesion agent, substitute the works such as original nail, riveting, weldering
Skill, high degree saves resource, improves speed of application, reduction construction costs etc..In recent years, the increment of architecture adhesion agent
Amplitude considerably beyond other products, its application also by the application extensions such as the reinforcing, reinforcement, antidetonation of single existing building to
The every field such as road, bridge, subway, culvert, tunnel, dykes and dams, or even newly-built every High speed railway project are also largely used
Building structure glue sticking, and with advances in technology, adhesive changes to featuresization, such as heat-resisting, low temperature resistant, insulation,
Expediting setting type, environmental type etc..
On the one hand in order to reach environment protecting, the building adhesive that synthesis is gradually replaced using natural plant is occurred in that,
Such as guar gum and sesbania gum.Natural plant generally requires etherification modified or non-ionic hydroxypropyl changes using cationic
Property after, its caking property and water solubility can just be greatly improved, but its water resistance is poor, if be chronically exposed in air easily by
Tide, corrosion, and easily come off, there is crack, had a strong impact on construction quality.
On the other hand with the demand personalized to decorations, family DIY operations are gradually risen, building nail-free glue with
Advantage attractive in appearance is bonded by means of its easy construction, without nail gradually widely to be used by people.Chinese Enterprises are also developed in recent years
Several moneys building nail-free glue products, but the kind developed also is only limitted to non-environmental protection product, contain a large amount of hazardous solvents.In people
The today for increasingly pursue environmental protection, aspiring after perfection, exploitation one kind can improve architectural construction technology, it is to avoid nail and ailhead are exposed
And influence the Environment-friendlynail-free nail-free glue for construction of construction effect to be very important.
The content of the invention
For the defect of prior art, it is an object of the invention to provide one kind environmentally friendly nail-free glue for building, the ring for building
Nail-free glue is protected, its adhesive strength is high, and ageing-resistant performance is good, with water resistance, is difficult mouldy, asepsis environment-protecting, formaldehydeless, colourless nothing
Taste, denseness are good, period of storage length, water-retaining property are good, low temperature not gel the characteristics of；The raw material components of the present invention are safe and reliable simultaneously,
It is environmentally safe, and raw material is easy to get, cost is relatively low, and technique is concise, with higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that：
The invention provides one kind environmentally friendly nail-free glue for building, include the raw material of following parts by weight：
20-30 parts of polyvinyl alcohol, 15-25 parts of polyvinyl acetate, 8-12 parts of methyl acetate, 10-12 parts of filler, defoamer 2-3
Part, 1-3 parts of coupling agent, 10-18 parts of plant gum powder, 4-6 parts of nano silicon, 1-3 parts of nano zine oxide, nano titanium oxide
0.5-1.5 parts, 0.2-0.6 parts of preservative, 7-9 parts of inorganic tackifier, 2-4 parts of neopelex.
Preferably, the environmentally friendly nail-free glue for building includes the raw material of following parts by weight：
25 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 10 parts of methyl acetate, 11 parts of filler, 2.5 parts of defoamer, coupling agent 2
Part, 14 parts of plant gum powder, 5 parts of nano silicon, 2 parts of nano zine oxide, 1 part of nano titanium oxide, 0.4 part of preservative, nothing
8 parts of machine tackifier, 3 parts of neopelex.
Preferably, the filler is that titanium dioxide, carbon black, silica flour compare 2 according to weight:1:The mixture of 1 composition.
Preferably, the defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio
1:1:The mixture of 2 compositions.
Preferably, the preservative is sodium benzoate and Kathon CG according to weight ratio 2:The mixture of 3 compositions.
Preferably, the preparation method of the plant gum powder is：By weight 2:After 1 removes the peel konjaku and potato cleaning,
It is pulverized and mixed, adds appropriate water and decocted 20-30 minutes under 1-2 atmospheric pressure, is obtained gains are spray-dried
Rubber powder.
Preferably, the inorganic tackifier is that waterglass, aluminium hydroxide or zinc oxide compare 1 according to weight:2:0.5 composition
Mixture.
The present invention also provides a kind of preparation method of environmentally friendly nail-free glue for building, comprises the following steps：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 300-400 r/min, stirs 25-35 minutes, obtains mixture A；
Step 3, adds the deionized water of 10-16 times of polyvinyl alcohol and its weight, is then heated up to 90-98 in a kettle.
DEG C boil 30-50 minutes, be completely dissolved polyvinyl alcohol, it is cold to go to 50-60 DEG C, add polyvinyl acetate, methyl acetate,
Defoamer, plant gum powder, inorganic tackifier, insulated and stirred 40-60 minutes, speed of agitator 300-400r/min, then it is cooled to 30-
40 DEG C, the mixture A, neopelex, preservative of step 2 preparation are sequentially added, continues insulated and stirred 1-2 hours,
Speed of agitator 400-600r/min, it is naturally cold go after produce the present invention environmentally friendly nail-free glue for building.
Preferably, the preparation process of the environmentally friendly nail-free glue for building is：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 350r/min, stirs 30 minutes, obtains mixture A；
Step 3, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle.
40 minutes, polyvinyl alcohol is completely dissolved, is cooled to 55 DEG C, add polyvinyl acetate, methyl acetate, defoamer, plant
Rubber powder, inorganic tackifier, insulated and stirred 50 minutes, speed of agitator 350r/min, then it is cooled to 35 DEG C, sequentially add step 2 system
Standby mixture A, neopelex, preservative, continue insulated and stirred 1.5 hours, and speed of agitator 500r/min is natural
It is cold go after produce the present invention environmentally friendly nail-free glue for building.
Compared with prior art, the present invention has following beneficial effect：
（1）A kind of plant gum powder of environmentally friendly nail-free glue addition for building of the present invention is mainly that konjaku and potato are poly- by extracting
Obtained after conjunction, on the one hand its can effectively reduce polyvinyl alcohol usage amount it is nontoxic, it is formaldehydeless pollution, harmless, ring
Guaranteed cost is good, and both another aspect konjaku and potato plant polyose and content of starch are higher, and it is prepared with polyvinyl alcohol
Nail-free glue bond effect it is good, anti-slipping property is excellent, and performance is stable.
（2）Nano silicon, nano zine oxide, the nano-silica of a kind of environmentally friendly nail-free glue addition for building of the present invention
Change titanium, a few person's compound actions there can be thixotropic property, and applying glue is convenient and glue will not trickle along facade, can be complete
Nail is substituted entirely entirely, nail and ailhead is bypassed, allows building decoration to become smooth seamless, while also having preferable antimycotic antiseptic
Effect.
（3）A kind of ceramic tile of the present invention bonds the filler that agent is added, predominantly titanium dioxide, carbon black, quartz with high-efficiency environment friendly
Powder, its granularity is smaller, can be effectively crosslinked with other materials, form fine and close paste elastomer, do not invaded by thermal expansion, freezing up
Evil, so that preparing nail-free glue reaches excellent weatherability, the pollutant that on the other hand filler of addition can be in absorption air,
The effect of preferable purification air is reached.
（4）A kind of preservative of environmentally friendly nail-free glue addition for building of the present invention, can play anti-corrosion work to whole product
With, increase its preservation time, and preservative selects the preservative of food-grade, uses whole product more safe and environment-friendly；
The inorganic tackifier of addition is mainly the mixture of waterglass, aluminium hydroxide or zinc oxide, and both, which act synergistically, causes what is prepared
Nail-free glue sag resistance can be greatly improved with adhesive property.
（5）A kind of environmentally friendly nail-free glue for building of the present invention, its adhesive strength height, ageing-resistant performance is good, with water resistance,
Be difficult that good mouldy, asepsis environment-protecting, formaldehydeless, colorless and odorless, denseness, period of storage length, water-retaining property be good, the spy of low temperature not gel
Point；The raw material components of the present invention are safe and reliable simultaneously, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, tool
There are higher practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown
So, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of environmentally friendly nail-free glue for building of the present embodiment, includes the raw material of following parts by weight：
20 parts of polyvinyl alcohol, 15 parts of polyvinyl acetate, 8 parts of methyl acetate, 10 parts of filler, 2 parts of defoamer, 1 part of coupling agent, plant
10 parts of thing rubber powder, 4 parts of nano silicon, 1 part of nano zine oxide, 0.5 part of nano titanium oxide, 0.2 part of preservative, inorganic increasing
7 parts of stick, 2 parts of neopelex.
Filler in the present embodiment is titanium dioxide, carbon black, silica flour compare 2 according to weight:1:The mixture of 1 composition.
Defoamer in the present embodiment is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio
1:1:The mixture of 2 compositions.
Preservative in the present embodiment is sodium benzoate and Kathon CG according to weight ratio 2:The mixture of 3 compositions.
The preparation method of plant gum powder in the present embodiment is：By weight 2:After 1 removes the peel konjaku and potato cleaning,
It is pulverized and mixed, adds appropriate water and decoct at 1 atmosphere pressure 30 minutes, obtains rubber powder by gains are spray-dried.
Inorganic tackifier in the present embodiment compares 1 for waterglass, aluminium hydroxide or zinc oxide according to weight:2:0.5 composition
Mixture.
A kind of preparation method of environmentally friendly nail-free glue for building of the present embodiment, comprises the following steps：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 300r/min, stirs 25 minutes, obtains mixture A；
Step 3, adds the deionized water of 10 times of polyvinyl alcohol and its weight, is then heated up to 90 DEG C and boils in a kettle.
30 minutes, polyvinyl alcohol is completely dissolved, is cooled to 50 DEG C, add polyvinyl acetate, methyl acetate, defoamer, plant
Rubber powder, inorganic tackifier, insulated and stirred 40 minutes, speed of agitator 300r/min, then it is cooled to 30-40 DEG C, sequentially add step
The two mixture A prepared, neopelex, preservative, continue insulated and stirred 1 hour, speed of agitator 400r/min, from
So it is cold go after produce the present invention environmentally friendly nail-free glue for building.
Embodiment 2.
A kind of environmentally friendly nail-free glue for building of the present embodiment, includes the raw material of following parts by weight：
30 parts of polyvinyl alcohol, 25 parts of polyvinyl acetate, 12 parts of methyl acetate, 12 parts of filler, 3 parts of defoamer, 3 parts of coupling agent,
It is 18 parts of plant gum powder, 6 parts of nano silicon, 3 parts of nano zine oxide, 1.5 parts of nano titanium oxide, 0.6 part of preservative, inorganic
9 parts of tackifier, 4 parts of neopelex.
Filler in the present embodiment is titanium dioxide, carbon black, silica flour compare 2 according to weight:1:The mixture of 1 composition.
Defoamer in the present embodiment is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio
1:1:The mixture of 2 compositions.
Preservative in the present embodiment is sodium benzoate and Kathon CG according to weight ratio 2:The mixture of 3 compositions.
The preparation method of plant gum powder in the present embodiment is：By weight 2:After 1 removes the peel konjaku and potato cleaning,
It is pulverized and mixed, adds appropriate water and decocted 20 minutes under 2 atmospheric pressure, obtains rubber powder by gains are spray-dried.
Inorganic tackifier in the present embodiment compares 1 for waterglass, aluminium hydroxide or zinc oxide according to weight:2:0.5 composition
Mixture.
A kind of preparation method of environmentally friendly nail-free glue for building of the present embodiment, comprises the following steps：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 400 r/min, stirs 35 minutes, obtains mixture A；
Step 3, adds the deionized water of 16 times of polyvinyl alcohol and its weight, is then heated up to 98 DEG C and boils in a kettle.
50 minutes, polyvinyl alcohol is completely dissolved, is cooled to 60 DEG C, add polyvinyl acetate, methyl acetate, defoamer, plant
Rubber powder, inorganic tackifier, insulated and stirred 60 minutes, speed of agitator 400r/min, then it is cooled to 40 DEG C, sequentially add step 2 system
Standby mixture A, neopelex, preservative, continue insulated and stirred 2 hours, speed of agitator 600r/min, naturally cold
The environmentally friendly nail-free glue for building of the present invention is produced after going.
Embodiment 3.
A kind of environmentally friendly nail-free glue for building of the present embodiment, includes the raw material of following parts by weight：
25 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 10 parts of methyl acetate, 11 parts of filler, 2.5 parts of defoamer, coupling agent 2
Part, 14 parts of plant gum powder, 5 parts of nano silicon, 2 parts of nano zine oxide, 1 part of nano titanium oxide, 0.4 part of preservative, nothing
8 parts of machine tackifier, 3 parts of neopelex.
Filler in the present embodiment is titanium dioxide, carbon black, silica flour compare 2 according to weight:1:The mixture of 1 composition.
Defoamer in the present embodiment is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio
1:1:The mixture of 2 compositions.
Preservative in the present embodiment is sodium benzoate and Kathon CG according to weight ratio 2:The mixture of 3 compositions.
The preparation method of plant gum powder in the present embodiment is：By weight 2:After 1 removes the peel konjaku and potato cleaning,
It is pulverized and mixed, adds appropriate water and decocted 25 minutes under 1.5 atmospheric pressure, obtains glue by gains are spray-dried
Powder.
Inorganic tackifier in the present embodiment compares 1 for waterglass, aluminium hydroxide or zinc oxide according to weight:2:0.5 composition
Mixture.
A kind of preparation method of environmentally friendly nail-free glue for building of the present embodiment, comprises the following steps：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 350r/min, stirs 30 minutes, obtains mixture A；
Step 3, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle.
40 minutes, polyvinyl alcohol is completely dissolved, is cooled to 55 DEG C, add polyvinyl acetate, methyl acetate, defoamer, plant
Rubber powder, inorganic tackifier, insulated and stirred 50 minutes, speed of agitator 350r/min, then it is cooled to 35 DEG C, sequentially add step 2 system
Standby mixture A, neopelex, preservative, continue insulated and stirred 1.5 hours, and speed of agitator 500r/min is natural
It is cold go after produce the present invention environmentally friendly nail-free glue for building.
The performance test results of environmentally friendly nail-free glue for building prepared by various embodiments above are as follows：
| The strong MPa of tensile shear before aging | Strong MPa is sheared in aging after-drawing | |
| Embodiment 1 | 1.98 | 1.56 |
| Embodiment 2 | 1.90 | 1.62 |
| Embodiment 3 | 1.94 | 1.52 |
| Standard requirement | 1.25 | 0.98 |
A kind of environmentally friendly nail-free glue for building of the present invention, its adhesive strength is high, and ageing-resistant performance is good, with water resistance, is difficult hair
Mould, asepsis environment-protecting, formaldehydeless, colorless and odorless, denseness are good, period of storage length, water-retaining property are good, low temperature not gel the characteristics of；Simultaneously
The raw material components of the present invention are safe and reliable, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, with higher
Practical value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (9)
1. a kind of environmentally friendly nail-free glue for building, it is characterised in that include the raw material of following parts by weight：
20-30 parts of polyvinyl alcohol, 15-25 parts of polyvinyl acetate, 8-12 parts of methyl acetate, 10-12 parts of filler, defoamer 2-3
Part, 1-3 parts of coupling agent, 10-18 parts of plant gum powder, 4-6 parts of nano silicon, 1-3 parts of nano zine oxide, nano titanium oxide
0.5-1.5 parts, 0.2-0.6 parts of preservative, 7-9 parts of inorganic tackifier, 2-4 parts of neopelex.
2. one kind environmentally friendly nail-free glue for building according to claim 1, it is characterised in that the environmentally friendly nail-free glue for building
Include the raw material of following parts by weight：
25 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 10 parts of methyl acetate, 11 parts of filler, 2.5 parts of defoamer, coupling agent 2
Part, 14 parts of plant gum powder, 5 parts of nano silicon, 2 parts of nano zine oxide, 1 part of nano titanium oxide, 0.4 part of preservative, nothing
8 parts of machine tackifier, 3 parts of neopelex.
3. one kind environmentally friendly nail-free glue for building according to claim 1 or 2, it is characterised in that the filler be titanium dioxide,
Carbon black, silica flour compare 2 according to weight:1:The mixture of 1 composition.
4. one kind environmentally friendly nail-free glue for building according to claim 1 or 2, it is characterised in that the defoamer is emulsification
Silicone oil, polypropylene glycerol aether and dimethyl silicone polymer are according to weight ratio 1:1:The mixture of 2 compositions.
5. one kind environmentally friendly nail-free glue for building according to claim 1 or 2, it is characterised in that the preservative is benzene first
Sour sodium and Kathon CG are according to weight ratio 2:The mixture of 3 compositions.
6. one kind environmentally friendly nail-free glue for building according to claim 1 or 2, it is characterised in that the system of the plant gum powder
Preparation Method is：By weight 2:1, by after konjaku and potato cleaning peeling, is pulverized and mixed, adds appropriate water at 1-2
Decocted 20-30 minutes under atmospheric pressure, obtain rubber powder by gains are spray-dried.
7. one kind environmentally friendly nail-free glue for building according to claim 1 or 2, it is characterised in that the inorganic tackifier is
Waterglass, aluminium hydroxide or zinc oxide compare 1 according to weight:2:The mixture of 0.5 composition.
8. a kind of method for preparing environmentally friendly nail-free glue for building as claimed in claim 1 or 2, it is characterised in that including following
Step：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 300-400 r/min, stirs 25-35 minutes, obtains mixture A；
Step 3, adds the deionized water of 10-16 times of polyvinyl alcohol and its weight, is then heated up to 90-98 in a kettle.
DEG C boil 30-50 minutes, be completely dissolved polyvinyl alcohol, be cooled to 50-60 DEG C, add polyvinyl acetate, methyl acetate,
Defoamer, plant gum powder, inorganic tackifier, insulated and stirred 40-60 minutes, speed of agitator 300-400r/min, then it is cooled to 30-
40 DEG C, the mixture A, neopelex, preservative of step 2 preparation are sequentially added, continues insulated and stirred 1-2 hours,
Speed of agitator 400-600r/min, it is naturally cold go after produce the present invention environmentally friendly nail-free glue for building.
9. a kind of preparation method of environmentally friendly nail-free glue for building according to claim 8, it is characterised in that the step
For：
Step one, weigh on request and prepare each component raw material；
Step 2, coupling agent, filler, nano silicon, nano zine oxide, nano titanium oxide are mixed and add high-speed stirred
In machine, rotating speed is 350r/min, stirs 30 minutes, obtains mixture A；
Step 3, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle.
40 minutes, polyvinyl alcohol is completely dissolved, is cooled to 55 DEG C, add polyvinyl acetate, methyl acetate, defoamer, plant
Rubber powder, inorganic tackifier, insulated and stirred 50 minutes, speed of agitator 350r/min, then it is cooled to 35 DEG C, sequentially add step 2 system
Standby mixture A, neopelex, preservative, continue insulated and stirred 1.5 hours, and speed of agitator 500r/min is natural
It is cold go after produce the present invention environmentally friendly nail-free glue for building.
Priority Applications (1)
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| CN201710548984.0A CN107189718A (en) | 2017-07-07 | 2017-07-07 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
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| CN201710548984.0A CN107189718A (en) | 2017-07-07 | 2017-07-07 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
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| CN107189718A true CN107189718A (en) | 2017-09-22 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841267A (en) * | 2017-11-09 | 2018-03-27 | 浙江久而久化学有限公司 | A kind of manufacture method of nail-free glue |
| CN107936856A (en) * | 2017-11-30 | 2018-04-20 | 明光市裕阳新材料有限公司 | A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof |
| CN112625653A (en) * | 2020-12-22 | 2021-04-09 | 北京启航东方印刷有限公司 | Calendar adhesive |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952496A (en) * | 2012-11-26 | 2013-03-06 | 山东泰德新能源有限公司 | Non-toxic adhesive and preparation method thereof |
| CN103484040A (en) * | 2013-09-22 | 2014-01-01 | 抚顺哥俩好化学有限公司 | Environment-friendly nail-free glue for construction and preparation method thereof |
| CN103805093A (en) * | 2014-02-21 | 2014-05-21 | 武汉优邦新材料化工有限公司 | Plant modified environment-friendly building adhesive and preparation method thereof |
| CN104293244A (en) * | 2014-10-27 | 2015-01-21 | 广东三和化工科技有限公司 | Transparent nail-free glue and preparation method thereof |
| CN106010373A (en) * | 2016-08-12 | 2016-10-12 | 哥俩好（辽宁）新材料有限公司 | Novel environmental-protection aqueous nail-free glue and production method thereof |
-
2017
- 2017-07-07 CN CN201710548984.0A patent/CN107189718A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952496A (en) * | 2012-11-26 | 2013-03-06 | 山东泰德新能源有限公司 | Non-toxic adhesive and preparation method thereof |
| CN103484040A (en) * | 2013-09-22 | 2014-01-01 | 抚顺哥俩好化学有限公司 | Environment-friendly nail-free glue for construction and preparation method thereof |
| CN103805093A (en) * | 2014-02-21 | 2014-05-21 | 武汉优邦新材料化工有限公司 | Plant modified environment-friendly building adhesive and preparation method thereof |
| CN104293244A (en) * | 2014-10-27 | 2015-01-21 | 广东三和化工科技有限公司 | Transparent nail-free glue and preparation method thereof |
| CN106010373A (en) * | 2016-08-12 | 2016-10-12 | 哥俩好（辽宁）新材料有限公司 | Novel environmental-protection aqueous nail-free glue and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李红强: "《胶粘原理、技术及引用》", 31 January 2014, 华南理工大学出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841267A (en) * | 2017-11-09 | 2018-03-27 | 浙江久而久化学有限公司 | A kind of manufacture method of nail-free glue |
| CN107841267B (en) * | 2017-11-09 | 2019-11-08 | 浙江久而久化学有限公司 | A kind of manufacturing method of nail-free glue |
| CN107936856A (en) * | 2017-11-30 | 2018-04-20 | 明光市裕阳新材料有限公司 | A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof |
| CN112625653A (en) * | 2020-12-22 | 2021-04-09 | 北京启航东方印刷有限公司 | Calendar adhesive |
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Application publication date: 20170922 |