JPH0425587A - Adhesive for interior material - Google Patents
Adhesive for interior materialInfo
- Publication number
- JPH0425587A JPH0425587A JP13198490A JP13198490A JPH0425587A JP H0425587 A JPH0425587 A JP H0425587A JP 13198490 A JP13198490 A JP 13198490A JP 13198490 A JP13198490 A JP 13198490A JP H0425587 A JPH0425587 A JP H0425587A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- attapulgite
- binder
- synthetic resin
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 30
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 30
- 239000000463 material Substances 0.000 title claims description 7
- 239000011230 binding agent Substances 0.000 claims abstract description 19
- 229960000892 attapulgite Drugs 0.000 claims abstract description 15
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 9
- 239000000057 synthetic resin Substances 0.000 claims abstract description 9
- 239000011256 inorganic filler Substances 0.000 claims abstract description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000203 mixture Substances 0.000 abstract description 8
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- 239000006185 dispersion Substances 0.000 abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract description 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- -1 methanol or ethanol Chemical compound 0.000 description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000010425 asbestos Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 229910052895 riebeckite Inorganic materials 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- QSLLXQPOVJSDAY-UHFFFAOYSA-L dipotassium;tetradecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCCCOP([O-])([O-])=O QSLLXQPOVJSDAY-UHFFFAOYSA-L 0.000 description 1
- LEHZBQJZYMFYMK-UHFFFAOYSA-L disodium;hexadecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCOP([O-])([O-])=O LEHZBQJZYMFYMK-UHFFFAOYSA-L 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- PFMVLFSAAABWQD-UHFFFAOYSA-M potassium;octadecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O PFMVLFSAAABWQD-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- QAEVVAMQWJMMGX-UHFFFAOYSA-M sodium;didodecyl phosphate Chemical compound [Na+].CCCCCCCCCCCCOP([O-])(=O)OCCCCCCCCCCCC QAEVVAMQWJMMGX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本願発明は内装材、とくに床材の施工に適した接着剤に
関し、塗布作業性が良く、貯蔵安定性の良い接着剤を提
供する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to an adhesive suitable for the construction of interior materials, particularly flooring materials, and provides an adhesive that has good application workability and good storage stability.
（従来技術と問題点） ３゜ ２ 。(Conventional technology and problems) 3゜ 2.
一般に酢酸ビニル樹脂系溶剤型接着剤はポリ酢酸ビニル
もしくは共重合体をバインダーとし、メタノール等の極
性有機溶剤、充填剤、その他の補助材料を配合して用途
に応した接着剤を製造している。Vinyl acetate resin-based solvent-based adhesives generally use polyvinyl acetate or a copolymer as a binder, and are mixed with polar organic solvents such as methanol, fillers, and other auxiliary materials to produce adhesives tailored to the application. .
しかしながら、接着剤の初期粘着力と接着強度の高いも
のを得ようとバインダー成分を増加させた配合にすれば
、塗布作業性が低下して所謂刷毛さばきが重くなる欠点
を生じた。However, when the binder component is increased in order to obtain an adhesive with high initial adhesion and adhesive strength, the coating workability is reduced and so-called brush handling becomes difficult.
また逆に刷毛さばきを軽くして塗布作業性を向上させる
ために、溶剤及び充填剤の種類や量を選択すると初期粘
着力や接着強度が低下した。On the other hand, when the type and amount of solvent and filler were selected in order to lighten brush strokes and improve coating workability, the initial adhesive force and adhesive strength decreased.
このように接着剤の物性が接着剤の各成分の相互作用に
起因していることから、従来の溶剤型接着剤で接着性と
塗布作業性の両者において共に優わたものは入手困霞で
あった。As the physical properties of adhesives are caused by the interaction of the adhesive's components, it is difficult to find conventional solvent-based adhesives that are superior in both adhesion and application workability. Ta.
この様な観点から石綿の極短繊維もしくはその粉末（以
下単に石綿という）がそれ自身アルカリ性を有すること
、並びにチクソトロピ−性を示すことから、充填剤とし
て最近多用されているが、石綿は労働安全衛生法で有害
な鉱物性粉塵に指定されており、製造時に作業環境上重
大な問題となり、石綿に代えて他の無害な充填剤を使用
しうる溶剤型接着剤の開発が強く望まれていた。From this point of view, asbestos ultrashort fibers or its powder (hereinafter simply referred to as asbestos) has been frequently used as a filler recently because it has alkalinity itself and exhibits thixotropic properties. It is designated as harmful mineral dust under the Sanitation Act, which poses a serious problem in the working environment during manufacturing, and there was a strong desire to develop a solvent-based adhesive that could use other harmless fillers in place of asbestos. .
（問題点を解決する手段）
本願発明は、上記問題点を解消した発明で、合成樹脂バ
インダーとアタパルジャイトと、無機充填剤と前記合成
樹脂バインダーが溶解する溶剤とからなり、弱アルカリ
性であることを特徴とする内装材用接着剤、をその要旨
とする。(Means for Solving the Problems) The present invention solves the above problems, and is composed of a synthetic resin binder, attapulgite, an inorganic filler, and a solvent in which the synthetic resin binder is dissolved, and is weakly alkaline. The gist of this product is an adhesive for interior materials that is characterized by its characteristics.
本発明に使用するバインダーは酢酸ビニル系ポリマーが
望ましく、とくに酢ビホモポリマーと酢ビ−アクリルコ
ポリマーの混合物や酢ビーベオパメタノールペーストが
好適である。The binder used in the present invention is preferably a vinyl acetate polymer, particularly a mixture of a vinyl acetate homopolymer and a vinyl acetate-acrylic copolymer or a vinyl acetate beopamethanol paste.
本願発明においては接着剤中にアタパルジャイトを合成
樹脂バインダー１００重量部に対し好ましくは５〜５０
重量部、さらに好ましくはｌＯ〜２５重量部配合爪部。In the present invention, preferably 5 to 50 parts of attapulgite is added to the adhesive based on 100 parts by weight of the synthetic resin binder.
Parts by weight, more preferably 10 to 25 parts by weight compounded nail part.
アタパルジャイトの純粋な組成は（○Ｈ）２Ｍ ｇ５”
Ｓ ｉＢ○２ｏ ・４Ｈ２０で示されるが、結晶水を
含む場合やこの化学式中Ｍｇ の−部がＡρ やＦｅ、
その他の金属に置換されたものも含まれる。The pure composition of attapulgite is (○H)2M g5”
It is represented by S iB○2o 4H20, but in cases where water of crystallization is included or the - part of Mg in this chemical formula is Aρ, Fe,
It also includes those substituted with other metals.
アタパルジャイトは長さ１μｍ、
巾０．０１μｍ程度の針状体の集合体である構成を有す
る。Attapulgite has a structure that is an aggregate of needle-like bodies with a length of about 1 μm and a width of about 0.01 μm.
接着剤組成物中にアタパルジャイトが配合されると針状
体の束が分散され、不規則な格子を作り、液体を取り込
んで粘度を上げる。When attapulgite is incorporated into an adhesive composition, bundles of needles are dispersed, creating an irregular lattice that traps liquid and increases viscosity.
アタパルジャイトの主な性質としては下記の２つがあげ
られる。The following two main properties of attapulgite are listed below.
■天然の状態で非常に吸収性・吸着性が大きい。■Highly absorbent and adsorbent in its natural state.
■アタパルジャイトの懸濁液はどのような濃度でも揺変
性があり、せん断力が増すにつれて急に流動性が増す。■A suspension of attapulgite exhibits thixotropy at any concentration, and its fluidity increases rapidly as the shear force increases.
アタパルジャイト添加量がバインダーに対し５重量部未
満であると、本願発明の効果が少なく、また５０重量部
を越すと塗布作業性が低下する。If the amount of attapulgite added is less than 5 parts by weight based on the binder, the effect of the present invention will be small, and if it exceeds 50 parts by weight, coating workability will decrease.
アタパルジャイト以外の充填剤としては、炭酸カルシウ
ム、タルク、クレー、ケイソウ士等、従来公知の物質を
使用でき、これらは労働安全衛生法上、無害な物質であ
り、石綿のような有害な物質は用いる必要がない。As fillers other than attapulgite, conventionally known substances such as calcium carbonate, talc, clay, and diatomite can be used.These are harmless substances according to the Industrial Safety and Health Act, but harmful substances such as asbestos cannot be used. There's no need.
これら充填剤は必要に応じて１種もしくは２種以上使用
でき、使用する場合には、例えばバインダー樹脂１００
部に対して通常約２０〜４００部、好ましくは約５０〜
２５０部配合される。These fillers can be used alone or in combination as required. When used, for example, binder resin 100%
Usually about 20 to 400 parts, preferably about 50 to 400 parts
250 parts are mixed.
本願に使用する溶剤としては、メタノール、エタノール
等の低級アルコールが望ましいが、この他合成樹脂バイ
ンダーが溶解されれば、どんな溶剤でもよい。The solvent used in this application is preferably a lower alcohol such as methanol or ethanol, but any other solvent may be used as long as it dissolves the synthetic resin binder.
さらに可使時間を延長するために界面活性剤をバインダ
ー１００重量部に対し０．７〜１．５部添加するのが望
ましい。Furthermore, in order to extend the pot life, it is desirable to add 0.7 to 1.5 parts of a surfactant to 100 parts by weight of the binder.
これらの界面活性剤としては、その具体例として
（１）ポリオキシエチレンラウリルエーテル、ポリオキ
シエチレンセチルエーテル、ポリオキシプロピレンセチ
ルエーテル等（ＩＩ）ソルビタンモノラウレート、ソル
ビタンモノパルミテート、ソルビタンモノステアレート
等（ｍ）ポリオキシエチレンモノラウレート、ポリオキ
シエチレンモノステアレート、ポリオキシプロピレンモ
ノラウレート等、（ｒＶ）ソジウムラウリルサルフェー
ト、ラウリルアルコール硫酸エステルトリエタノールア
ミン塩。Specific examples of these surfactants include (1) polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxypropylene cetyl ether, etc. (II) sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate. (m) Polyoxyethylene monolaurate, polyoxyethylene monostearate, polyoxypropylene monolaurate, etc. (rV) Sodium lauryl sulfate, lauryl alcohol sulfate triethanolamine salt.
カリウムステアリルサルフェート等、（Ｖ）ミリスチル
フォスフェートカリウム塩、ジラウリルフォスフェート
ソジュウム塩、パルミチルフォスフェートソジュウム塩
等、を挙げることができる。Examples include potassium stearyl sulfate, (V) myristyl phosphate potassium salt, dilauryl phosphate sodium salt, palmityl phosphate sodium salt, and the like.
上記界面活性剤を本願接着剤組成物においてバインダー
樹脂の０．１〜５重量％、さらに望ましくは０．５〜１
．５重量％を添加することにより、さらに可使時間を延
長して、床用等の接着剤として使い易くすることができ
る。The above surfactant is contained in the adhesive composition of the present invention in an amount of 0.1 to 5% by weight, more preferably 0.5 to 1% by weight based on the binder resin.
．． By adding 5% by weight, the pot life can be further extended, making it easier to use as an adhesive for floors, etc.
本願接着剤はアタパルジャイトを単に接着剤中に含有さ
せるだけで、ＰＨを７〜８．５の弱アルカリ性に調整す
ることができる。The pH of the adhesive of the present invention can be adjusted to a weak alkaline value of 7 to 8.5 simply by incorporating attapulgite into the adhesive.
調整さｔた接着剤組成物中にはバインダー１００重量部
に対しｏ、２−″ｏ、３部アルカリ増粘剤が添加されて
もよい。To 100 parts by weight of binder, 3 parts of alkaline thickener may be added to the prepared adhesive composition.
これらアルカリ増粘剤としては、例えばプライマルＡＳ
Ｅ−６０（アクリル酸とアクリル酸エステルとの共重合
体であって、アクリル酸含量４０〜４５重量％のものの
エマルジョン、固形分に対し約０．１重量％の架橋性モ
ノマーを含有する架橋タイプ）、プライマルＡＳＥ−７
５（アクリル酸含量３０〜４０重量％のアクリル酸とア
クリル酸エステルとの共重合体非架橋タイプエマルジョ
ン）、プライマルＡＳＥ−９５，１０８（アクリル酸と
アクリル酸エステルとの共重合体（アクリル酸とアクリ
ル酸エステルとの共重合体（アクリル酸含量６０〜７０
％のエマルジョン）（以上アメリカ、ローム・アンド・
ハース社製）等のカルボキシル化樹脂エマルジョンが例
示できる。Examples of these alkaline thickeners include Primal AS
E-60 (a copolymer of acrylic acid and acrylic ester, emulsion with acrylic acid content of 40 to 45% by weight, crosslinked type containing about 0.1% by weight of crosslinking monomer based on solid content) ), Primal ASE-7
5 (non-crosslinked emulsion of copolymer of acrylic acid and acrylic ester with an acrylic acid content of 30 to 40% by weight), Primal ASE-95,108 (copolymer of acrylic acid and acrylic ester (non-crosslinked emulsion of acrylic acid and acrylic ester)), Copolymer with acrylic acid ester (acrylic acid content 60-70
% emulsion) (over America, Rohm &
Examples include carboxylated resin emulsions such as those manufactured by Haas Corporation.
（発明の効果）
■良好な接着力とともに適当なチクソトロピー性も得ら
れ、刷毛さばきも良好であった。(Effects of the Invention) - Good adhesion and appropriate thixotropy were obtained, and the brush handling was also good.
■オープンタイムが長く取れるので、塗布作業性も良か
った。■Since the open time is long, the application workability was also good.
■アスベストを添加しなくても良好な性能が得られ、環
境安全上良好であった。■ Good performance was obtained even without the addition of asbestos, and the product was environmentally safe.
■分散安定性が良く、貯蔵性が良好であった。■Dispersion stability was good and storage stability was good.
■接着剤ＰＨが弱アルカリ性なので、とくにモルタル下
地上に塗布する時、好適であった。■Since the adhesive pH is weakly alkaline, it is particularly suitable for application onto mortar bases.
（実施例）
実施例１、実施例２
第１表の配合組成の接着剤を製造し、ｐｖｃ床タイルを
貼着施工した。(Example) Example 1, Example 2 An adhesive having the composition shown in Table 1 was manufactured, and PVC floor tiles were adhered to the adhesive.
結果を第２表に示す。The results are shown in Table 2.
比較例１、比較例２ 第１表の配合組成の接着剤を製造し、 同様床タイルを施工した。Comparative example 1, comparative example 2 Producing an adhesive having the composition shown in Table 1, Similar floor tiles were installed.
結果を第２表に示す。The results are shown in Table 2.
実施例
（×１）酢酸ビニルーベオパ型
（×２）ポリオキシエチレンモノラウレートを添加この
結果、アタパルジャイトを配合した実施例１〜実施例３
とも、接着力、塗布作業性、チクソトロピー性、分散安
定性、環境安全性のすべてにおいて満足させる性能が得
られた。Example (x1) Vinyl acetate rubber type (x2) Addition of polyoxyethylene monolaurate As a result, attapulgite was blended Examples 1 to 3
In both cases, satisfactory performance was obtained in all aspects of adhesive strength, coating workability, thixotropy, dispersion stability, and environmental safety.
一方、比較例２は塗布作業性が悪く、貯蔵時の分散安定
性も悪かった。On the other hand, Comparative Example 2 had poor coating workability and poor dispersion stability during storage.
比較例１はアスベストを使用しているので、環境安全上
好ましくなかった。Since Comparative Example 1 used asbestos, it was not preferable in terms of environmental safety.
以上that's all
Claims (1)
剤と前期合成樹脂バインダーが溶 解する溶剤とからなり、弱アルカリ性であ ることを特徴とする内装材用接着剤。 ２、アタパルジャイトをバインダー１００重量部に対し
て５〜５０重量部含有することを 特徴とする請求項１の接着剤。 ３、合成樹脂バインダーに界面活性剤が添加された請求
項１の内装材用接着剤。[Claims] 1. An adhesive for interior materials comprising a synthetic resin binder, attapulgite, an inorganic filler, and a solvent in which the synthetic resin binder is dissolved, and is weakly alkaline. 2. The adhesive according to claim 1, which contains 5 to 50 parts by weight of attapulgite based on 100 parts by weight of the binder. 3. The adhesive for interior materials according to claim 1, wherein a surfactant is added to the synthetic resin binder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13198490A JPH0425587A (en) | 1990-05-22 | 1990-05-22 | Adhesive for interior material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13198490A JPH0425587A (en) | 1990-05-22 | 1990-05-22 | Adhesive for interior material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0425587A true JPH0425587A (en) | 1992-01-29 |
Family
ID=15070837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13198490A Pending JPH0425587A (en) | 1990-05-22 | 1990-05-22 | Adhesive for interior material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0425587A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973730A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing attapulgite soft clay |
| CN103484040A (en) * | 2013-09-22 | 2014-01-01 | 抚顺哥俩好化学有限公司 | Environment-friendly nail-free glue for construction and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57190047A (en) * | 1981-05-18 | 1982-11-22 | Takeda Chem Ind Ltd | Stabilized aqueous suspension |
| JPS6178884A (en) * | 1984-09-27 | 1986-04-22 | Toyota Central Res & Dev Lab Inc | Anticorrosive adhesive |
| JPS6243474A (en) * | 1985-08-21 | 1987-02-25 | Sumikurosu Kogyo Kk | Water-insensitive pressure-sensitive adhesive |
-
1990
- 1990-05-22 JP JP13198490A patent/JPH0425587A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57190047A (en) * | 1981-05-18 | 1982-11-22 | Takeda Chem Ind Ltd | Stabilized aqueous suspension |
| JPS6178884A (en) * | 1984-09-27 | 1986-04-22 | Toyota Central Res & Dev Lab Inc | Anticorrosive adhesive |
| JPS6243474A (en) * | 1985-08-21 | 1987-02-25 | Sumikurosu Kogyo Kk | Water-insensitive pressure-sensitive adhesive |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973730A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Method for producing attapulgite soft clay |
| CN103484040A (en) * | 2013-09-22 | 2014-01-01 | 抚顺哥俩好化学有限公司 | Environment-friendly nail-free glue for construction and preparation method thereof |
| CN103484040B (en) * | 2013-09-22 | 2016-04-06 | 哥俩好新材料股份有限公司 | A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4225496A (en) | Acrylic latex cove base cement | |
| US4654388A (en) | Latex adhesives for floor laying | |
| JP5009469B2 (en) | Secondary adhesives based on aqueous polymer dispersions | |
| JPS58152074A (en) | Adhesive composition for ceramic tile | |
| US5349009A (en) | Water-based construction adhesive mastic | |
| WO2013141170A1 (en) | Chloroprene rubber-based polymer latex composition and use thereof | |
| CN110050022B (en) | Water-based compositions having low surface tack | |
| US3639653A (en) | Protective coating for metal and wood surfaces | |
| JPH0425587A (en) | Adhesive for interior material | |
| JPS60124675A (en) | Aqueous adhesive composition | |
| JP2567727B2 (en) | Adhesive for flooring | |
| JP2000109777A (en) | One-component aqueous adhesive composition | |
| JP2646305B2 (en) | Base emulsion for adhesives | |
| KR20030015565A (en) | Water soluble tile adhesive agent | |
| JP2564089B2 (en) | Aqueous emulsion type adhesive composition | |
| JPH0832865B2 (en) | Breathable water-based adhesive composition | |
| US2536375A (en) | Grouting material | |
| JP6143396B1 (en) | Adhesive composition for flooring and method for producing adhesive composition for flooring | |
| US2335104A (en) | Latex adhesive | |
| KR20100027078A (en) | Environmentally, friendly water-based acrylic adhesives used in the binding of wooden floors and method thereof | |
| JP2005281626A (en) | Inorganic-organic composite type aqueous adhesive composition | |
| JP4850483B2 (en) | Polymer emulsion composition for coating | |
| JPH0747722B2 (en) | Curing agent for epoxy adhesive and epoxy adhesive | |
| JP2859472B2 (en) | Solvent adhesive | |
| JPH04220484A (en) | Adhesive |