CN1261089A - Non-toxic adhesive for building and decoration - Google Patents

Non-toxic adhesive for building and decoration Download PDF

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Publication number
CN1261089A
CN1261089A CN 00103079 CN00103079A CN1261089A CN 1261089 A CN1261089 A CN 1261089A CN 00103079 CN00103079 CN 00103079 CN 00103079 A CN00103079 A CN 00103079A CN 1261089 A CN1261089 A CN 1261089A
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CN
China
Prior art keywords
weight parts
finishing
building
sulfonated polystyrene
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 00103079
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Chinese (zh)
Inventor
张洪志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HAISEN INDUSTRIAL TRADE Co BEIJING
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HAISEN INDUSTRIAL TRADE Co BEIJING
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HAISEN INDUSTRIAL TRADE Co BEIJING filed Critical HAISEN INDUSTRIAL TRADE Co BEIJING
Priority to CN 00103079 priority Critical patent/CN1261089A/en
Publication of CN1261089A publication Critical patent/CN1261089A/en
Pending legal-status Critical Current

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  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A non-toxic adhesive for building and decoration is prepared from non-toxic solvent, resin and filler in weight ratio of 100 : (20-200) : (0-100), and features high adhesion, quick drying, high early viscosity, good water-proof nature, no poison and no pollution in its production. It is used for adhering bricks, tiles, floor, wall plate, door, window and furniture.

Description

Building and finishing avirulent adhesion agent
The invention relates to a kind of building and the finishing stick with glue agent, more particularly stick with glue agent about a kind of reality nontoxic building and finishing.
Along with the raising of people's living standard, also more and more higher for the requirement of buildings.But buildings inner and outer wall plastering and the block finishing material of stickup etc. still adopt traditional technology at present, promptly add water with cement and come sticking construction.Not only speed of application is slow for traditional technology, technical requirements is high, and the wall face big area is plastered in being difficult to avoid hollowing and crack problem, and the hollowing of wall face sticking block shape material comes off and leakage problems in also being difficult to eliminate.In order to satisfy stability and the intensity between the building slab, multiple building adhesive has appearred at present, but the unit elongation deficiency that these tackiness agents have, cause that cracking leaks, be mixed with in the formula for raw stock that has and have toxic pharmaceutical chemicals, give and make, use and brought great inconvenience, further, also do not meet the environmental requirement of advocating in the present worldwide.
The purpose of this invention is to provide a kind of applied widely, the cost cost is low, bonding strength is high, water-fast, building that the high-low temperature resistant effect is strong and finishing nontoxic pollution-free tackiness agent.
These and other objects of the present invention will and be described and further set forth and explanation by following detailed description.
In the present invention, building and finishing are used avirulent adhesion agent, comprise innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 20~200: 0~100.
Further, building of the present invention and finishing are used avirulent adhesion agent, comprise innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 30~150: 1~50.
Be preferably, building of the present invention and finishing are used avirulent adhesion agent, comprise innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 50~150: 1~10.
In the present invention, described innoxious solvent comprises vinyl acetic monomer, N-BUTYL ACETATE, kautschin, dibutyl phthalate, white gasoline, can use wherein a kind ofly separately, also can use its mixture; Described resin comprises polystyrene, sulfonated polystyrene ionizable metal salt polymkeric substance, rosin, styrene butadiene-acrylonitrile copolymer (ABS), ethylene-vinyl acetate copolymer, polyester, can use wherein a kind ofly separately, also can use its mixture; Described filler comprises gypsum, talcum powder, titanium dioxide, zinc oxide, Magnesium Silicate q-agent, can use wherein a kind ofly separately, also can use its mixture; Described sulfonated polystyrene ionizable metal salt polymkeric substance comprises sulfonated polystyrene sodium salt, sulfonated polystyrene zinc salt, sulfonated polystyrene lithium salts, sulfonated polystyrene sylvite, sulfonated polystyrene calcium salt, can use wherein a kind ofly separately, also can use its mixture.
Compared with prior art, product of the present invention has the bonding strength height, fast does, initial viscosity is high, water-fast, to advantages such as environment are nontoxic, can be mixed in the sand-cement slurry as buildings interface processing and bonding silicates and multiple porous, micropore building and ornament materials, have ten parts of ideal effects.
In the present invention, if necessary, also can use other additive, filler or composition improving agent (concrete kind example can be consulted professional book), these additives, filler or composition improving agent can be conventional the uses, also can need and add according to certain.
In the present invention, above-mentioned compound can be buied in market, or directly obtains from relevant factory, more particularly, can use life waste material, and is as waste polystyrene foam plastic etc., more favourable for the protection environment like this.
Product of the present invention can prepare according to a conventional method, comprise that character according to various compositions is dissolved or steps such as fusion, stirring, mixing, those skilled in the art need not spend creative work according to oneself expertise and can prepare, further, can be with reference to Chinese patent CN-94111941,96120237,96195018 etc.
Below further specify the present invention by specific embodiment, but embodiment only be used for the explanation, can not limit the scope of the invention.
In the present invention, if not refer in particular to, all parts, amount are the weight unit based on gross weight, and all raw materials all can be buied from market.
Example 1: following ingredients is dissolved or fused with ordinary method according to character, mix then promptly to get to build and fit up and stick with glue agent, bonding strength 4.11MPa during product normal temperature, 7 days bonding strength 3.51MPa of normal temperature bubble, 7 days bonding strength 4.01MPa of 100 ℃ of oven dry.
98 kilograms of vinyl acetic monomers, 2 kilograms of kautschins, the polystyrene 105 kg,
4 kilograms of rosin, 5 kilograms of sulfonated polystyrene sodium salts, 1 kilogram in gypsum, 1 kilogram of titanium dioxide.
Example 2: following ingredients is dissolved or fused with ordinary method according to character, mix then promptly to get to build and fit up and stick with glue agent.Bonding strength 2.31MPa during product normal temperature, 7 days bonding strength 2.1MPa of normal temperature bubble, 7 days bonding strength 2.01MPa of 100 ℃ of oven dry.
98 kilograms of vinyl acetic monomers, 1 kilogram of kautschin, 10 kilograms in zinc oxide,
80 kilograms of polystyrene, 1 kilogram of N-BUTYL ACETATE, 5 kilograms in gypsum,
10 kilograms of Magnesium Silicate q-agents, 1 kilogram of sulfonated polystyrene zinc salt.
Example 3: following ingredients is dissolved or fused with ordinary method according to character, mix then promptly to get to build and fit up and stick with glue agent.Bonding strength 3.1MPa during product normal temperature, 7 days bonding strength 2.71MPa of normal temperature bubble, 7 days bonding strength 3.13MPa of 100 ℃ of oven dry.
90 kilograms of vinyl acetic monomers, 2 kilograms of kautschins, 10 kilograms in zinc oxide,
80 kilograms of polystyrene, 5 kilograms of N-BUTYL ACETATEs, 20 kilograms of Magnesium Silicate q-agents, 3 kilograms of sulfonated polystyrene zinc salts, 3 kilograms of dibutyl phthalates.
Example 4: following ingredients is dissolved or fused with ordinary method according to character, mix then promptly to get to build and fit up and stick with glue agent.Bonding strength 4.10MPa during product normal temperature, 7 days bonding strength 3.31MPa of normal temperature bubble, 7 days bonding strength 4.01MPa of 100 ℃ of oven dry.
95 kilograms of vinyl acetic monomers, 3 kilograms of N-BUTYL ACETATEs, 2 kilograms of kautschins,
90 kilograms of polystyrene, 5 kilograms of titanium dioxides, 5 kilograms of rosin,
5 kilograms of sulfonated polystyrene zinc salts.
Example 5: following ingredients is dissolved or fused with ordinary method according to character, mix then promptly to get to build and fit up and stick with glue agent.Bonding strength 5.10MPa during product normal temperature, 7 days bonding strength 3.31MPa of normal temperature bubble, 7 days bonding strength 4.92MPa of 100 ℃ of oven dry.
90 kilograms of vinyl acetic monomers, 3 kilograms of rosin, 95 kilograms of polystyrene,
5 kilograms of sulfonated polystyrene zinc salts, 5 kilograms of ethylene-vinyl acetate copolymers,
3 kilograms of titanium dioxides.

Claims (10)

1, a kind of building and finishing are used avirulent adhesion agent, it is characterized in that comprising innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 20~200: 0~100.
2, building as claimed in claim 1 and finishing are used avirulent adhesion agent, it is characterized in that comprising innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 30~150: 1~50.
3, building as claimed in claim 1 and finishing are used avirulent adhesion agent, it is characterized in that comprising innoxious solvent, resin and filler, and wherein the weight ratio of innoxious solvent and resin and filler is 100: 50~150: 1~10.
4, as described building of claim 1~3 and finishing avirulent adhesion agent, it is characterized in that described innoxious solvent comprises vinyl acetic monomer, N-BUTYL ACETATE, kautschin, dibutyl phthalate, white gasoline, can use wherein a kind ofly separately, also can use its mixture.
5, as described building of claim 1~3 and finishing avirulent adhesion agent, it is characterized in that described resin comprises polystyrene, sulfonated polystyrene ionizable metal salt polymkeric substance, rosin, styrene butadiene-acrylonitrile copolymer (ABS), ethylene-vinyl acetate copolymer, polyester, can use wherein a kind ofly separately, also can use its mixture.
6, use avirulent adhesion agent as described building of claim 1~3 and finishing, it is characterized in that described filler comprises gypsum, talcum powder, titanium dioxide, zinc oxide, Magnesium Silicate q-agent, can use wherein a kind ofly separately, also can use its mixture.
7, building as claimed in claim 5 and finishing avirulent adhesion agent, it is characterized in that described sulfonated polystyrene ionizable metal salt polymkeric substance comprises sulfonated polystyrene sodium salt, sulfonated polystyrene zinc salt, sulfonated polystyrene lithium salts, sulfonated polystyrene sylvite, sulfonated polystyrene calcium salt, can use wherein a kind ofly separately, also can use its mixture.
8, use avirulent adhesion agent as described building of claim 1~3 and finishing, it is characterized in that comprising:
Vinyl acetic monomer 98 weight parts, kautschin 2 weight parts,
Polystyrene 105 weight parts, rosin 4 weight parts,
Sulfonated polystyrene sodium salt 5 weight parts, gypsum 1 weight part,
Titanium dioxide 1 weight part.
9, use avirulent adhesion agent as described building of claim 1~3 and finishing, it is characterized in that comprising:
Vinyl acetic monomer 98 weight parts, kautschin 1 weight part,
Polystyrene 80 weight parts, N-BUTYL ACETATE 1 weight part,
Sulfonated polystyrene zinc salt 1 weight part, gypsum 5 weight parts,
Magnesium Silicate q-agent 10 weight parts, zinc oxide 10 weight parts.
10, use avirulent adhesion agent as described building of claim 1~3 and finishing, it is characterized in that comprising:
Vinyl acetic monomer 90 weight parts, kautschin 2 weight parts,
Polystyrene 80 weight parts, N-BUTYL ACETATE 5 weight parts,
Sulfonated polystyrene zinc salt 3 weight parts, Magnesium Silicate q-agent 20 weight parts,
Dibutyl phthalate 3 weight parts, zinc oxide 10 weight parts.
CN 00103079 2000-02-28 2000-02-28 Non-toxic adhesive for building and decoration Pending CN1261089A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 00103079 CN1261089A (en) 2000-02-28 2000-02-28 Non-toxic adhesive for building and decoration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 00103079 CN1261089A (en) 2000-02-28 2000-02-28 Non-toxic adhesive for building and decoration

Publications (1)

Publication Number Publication Date
CN1261089A true CN1261089A (en) 2000-07-26

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CN (1) CN1261089A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6528122B2 (en) * 2001-08-02 2003-03-04 Mattel, Inc. Terpene/co-solvent adhesive or paint coating composition for toy articles
CN103059776A (en) * 2012-12-29 2013-04-24 宁波鼎程胶粘剂有限公司 PS-ABS (polystyrene-acrylonitrile butadiene styrene) solvent type adhesive
CN103484040A (en) * 2013-09-22 2014-01-01 抚顺哥俩好化学有限公司 Environment-friendly nail-free glue for construction and preparation method thereof
US10869814B2 (en) 2015-08-28 2020-12-22 Maybom (UK) Limited Nipple and nipple assembly

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6528122B2 (en) * 2001-08-02 2003-03-04 Mattel, Inc. Terpene/co-solvent adhesive or paint coating composition for toy articles
US6838537B2 (en) * 2001-08-02 2005-01-04 Mattel, Inc. Terpene/co-solvent adhesive or paint coating composition for toy articles
CN103059776A (en) * 2012-12-29 2013-04-24 宁波鼎程胶粘剂有限公司 PS-ABS (polystyrene-acrylonitrile butadiene styrene) solvent type adhesive
CN103059776B (en) * 2012-12-29 2015-12-09 宁波鼎程胶粘剂有限公司 PS-ABS solvent-based adhesive
CN103484040A (en) * 2013-09-22 2014-01-01 抚顺哥俩好化学有限公司 Environment-friendly nail-free glue for construction and preparation method thereof
CN103484040B (en) * 2013-09-22 2016-04-06 哥俩好新材料股份有限公司 A kind of Environment-friendlynail-free nail-free glue for construction and preparation method thereof
US10869814B2 (en) 2015-08-28 2020-12-22 Maybom (UK) Limited Nipple and nipple assembly

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