GB2155944A - Powder compositions for producing tile adhesives and grouts - Google Patents

Powder compositions for producing tile adhesives and grouts Download PDF

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Publication number
GB2155944A
GB2155944A GB08505058A GB8505058A GB2155944A GB 2155944 A GB2155944 A GB 2155944A GB 08505058 A GB08505058 A GB 08505058A GB 8505058 A GB8505058 A GB 8505058A GB 2155944 A GB2155944 A GB 2155944A
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GB
United Kingdom
Prior art keywords
composition
powder
polymer
ether
cellulose ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08505058A
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GB2155944B (en
GB8505058D0 (en
Inventor
Peter James Jones
Frank Vaughan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BUILDING ADHESIVES Ltd
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BUILDING ADHESIVES Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB848406959A external-priority patent/GB8406959D0/en
Application filed by BUILDING ADHESIVES Ltd filed Critical BUILDING ADHESIVES Ltd
Priority to GB08505058A priority Critical patent/GB2155944B/en
Publication of GB8505058D0 publication Critical patent/GB8505058D0/en
Publication of GB2155944A publication Critical patent/GB2155944A/en
Application granted granted Critical
Publication of GB2155944B publication Critical patent/GB2155944B/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34—Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/28—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/28—Polysaccharides or derivatives thereof
    • C04B26/285—Cellulose or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • C04B2111/00672—Pointing or jointing materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The powder compositions comprise water soluble polymer and inorganic filler and can be used as or in powder adhesives, ready mixed adhesives and two part adhesives as well as grouting preparations. The water soluble polymer may be a natural, synthetic or semi-synthetic polymer.

Description

SPECIFICATION Powder compositions Description This invention concerns powder compositions suitable for adhesives and grout preparations.
With most ceramic tile adhesives fixing of the tiles to a substrate is more or less permanent, removal of tiles being very difficult. In fact if a change of tiling is desired removal of the old tiles tends to damage the substrate, which then has to be made good before retiling. Furthermore, if some tiles do fall off or become loose it is difficult to remove the old adhesive which is necessary before the tiles can be refixed.
There exists, therefore, a need for an adhesive for fixing ceramic tiles that is strong enough to hold the tiles in place for as long as desired but from which tiles can be removed without damage and which can itself be readily removed.
It has now been found that certain powder mixes can be used to produce such an adhesive. It has further been found that these powder mixes can be modified to produce relatively permanent adhesives and also grout preparations.
In these powder mixes, the essential ingredients, are believed to be water soluble polymer, as binder, and a filler, preferably an inorganic filler.
The water-soluble polymer used as a binder may be semi-synthetic, such as a cellulose derivative or a starch derivative. Examples of suitable cellulose derivatives are simple ethers, such as methyl cellulose ether, ethyl cellulose ether, hydroxy ethyl cellulose ether, hydroxy methyl cellulose ether and hydroxy propyl cellulose ether, and mixed ethers, such as ethyl hydroxy ethyl cellulose ether, ethyl methyl cellulose ether and hydroxy propyl methyl cellulose ether. Examples of suitable starch derivates are starch acetates, hydroxy ethyl starch and carboxymethyl starch.
The water soluble polymer may be a synthetic polymer, such as polyacrylic acids, polyacrylate, polyacrylamide, polyvinyl, alcohol, polyvinyl-methoxy acetate, polyvinyl methyl ether and polycarboxylic acid.
The water-soluble polymer may alternatively be a natural polymer or a derivative thereof, a polysaccharide or a protein. Examples of suitable natural polymers are galactommannans, such as locust bean gum and guargum. A suitable polysaccharide is microbial polysaccharide, such as Xanthan gum, starch and dextrine. Suitable proteins are casein, gelatin, animal hide and algenates.
The filler can be any mineral powder such as gypsum, calcium carbonates, silica sand, silica flour and clays. Examples of suitable calcium carbonates are limestone, whiting and marble. The fillers may be used singly or as blends of two or more types.
The powder mixes of the invention may be reinforced by the addition of redispersable powders, for example, polyvinyl acetate hompolymer, polyvinyl acetate copolymers, such as vinyl acetate/ethylene copolymer and vinyl acetate/vinyl versatate copolymer.
Other optional ingredients of the powder mixes of the invention include rheological modifying agents, such as fumed silica, cellulose, kaolin and attapulgite, bulking agents such as expanded unmilled perlite, coalescing solvents and plasticisers which may be required to improve the film forming properties of the polymer, dispersing agents or surfactants to improve and stabilise dispersion of the powder in water, preservatives to protect the adhesive during storage and fungicides to protect the adhesive film in use.
Other ingredients may be included to modify the powder mixes according to its intended use and also to modify its performance.
The powder mixes of the invention are believed to be suitable for a variety of uses. Firstly by mixing the powder with water, an adhesive suitable for fixing a variety of wall and floor coverings to a variety of substrates can be produced. The wall and floor coverings may be ceramic tiles suitable for wall or floor covering, mosaics such as of the paper-faced or mesh-backed types, plastic tiles, cork tiles, wood blocks, marble cladding, brick slips, terrazzos, favioures and slate tiles. Most sound, stable surfaces provide a suitable substrate and examples are cementitous backgrounds, wall boards, plaster, metal, wood, vinyl, existing glazed tiled surfaces and even brickwork. An advantageous feature of the adhesives of the invention is that they contain no hydraulic components, such as cement, which makes them particularly useful on gypsum plaster substrates.It should be noted that the use of adhesives containing cement on gypsum plaster substrates is not recommended in BS 5385 Part 1 1976.
The adhesive can be used in any traditional method of tile or the like fixing, such as by thin- or thickbed techniques, including application by notched trowels or solid-bed spreaders, or by buttering. Alternatively, the adhesive can be applied by being pumped onto the wall or floor surfaces. Another alternative could be to precoat the tiles with the adhesive which, when set, can be revived with water for fixing the tiles to a substrate.
(Details of suitable fixing techniques are given in BS 5385).
The powder mixes of the invention can be used to produce adhesives for sale in a ready mixed form.
For ready mixed adhesive preparations the redispersible powder may be replaced by a polymer emulsion, such as of polyvinyl acetate homopolymer emulsion, styrene/acrylate copolymer emulsion or styrene/butadiene rubber emulsion. These ready mixed adhesives may also include organic solvents.
The powder mixes of the invention may also be formulated into two part adhesive preparations, in which one part of the preparation would be the powder mix and the other part could comprise an aqueous solution or dispersion of a natural rubber latex or a styrene/butadiene rubber, an acrylic/styrene copolymer, polyvinyl alcohol or polyvinyl acetate and cellulose.
The adhesion strength of adhesives made from the powder mixes of the invention can be varied by the content of redispersible powder, polymer emulsion or water soluble polymer. With little or no such powder or emulsion, the adhesive is such that tiles can be readily removed from a substrate and the adhesive can be readily removed from the substrate and the tiles say by scraping, possibly with the assistance of wetting with water. The tiles are then reusable and the adhesive may be reconstituted by mixing with water and, optionally, further adhesive powder.
With greater amounts of the redispersible powder, emulsion or water soluble polymer the adhesion strength of the adhesive can be as good as conventional ceramic tile adhesives, i.e. exceeding the requirements of BS 5980.
The adhesion strength of adhesives of the invention can be further or alternatively improved by incorporation in the powder mix of styrene/butadiene rubber, natural rubber latex or acylic polymers or polyvinyl alcohol.
% by weight Water soluble polymer 1 - 50 Inorganic fillers 30 - 80 Redispersible powder or polymer emulsion (30-80% solids) 0-10 Rheoiogical modifying agent 0 - 5 Bulking agent 0-5 Preservative 0-1 Fungicide 0-1 Fillers 0 - 80 Water 0 - 80 For flexibility, say for a movement joint, the adhesive compositions of the invention could include a styrene/n - butyl acrylate copolymer. For a decorative effect suitable pigments could be included and for a pleasant odour, perfumes may be included in the compositions of the invention.
The compositions discussed above are believed not to be particularly suitable for fixing wall coverings subject to very damp conditions, such as externally or in swimming pools or shower cubicles. It may, however, be possible to modify the compositions of the invention to improve water resistance.
Whilst much of the discussion above has been with reference to adhesive preparations, the powder mixes of the invention may be modified so as to be suitable forming preparations that can be used as grouting material or as combined adhesive/grouting material.
This invention will now be further described by means of the following Examples.
Examples Example 1 A powder adhesive composition for mixing with water was prepared by mixing the following ingredients in the amounts stated in parts by weight: Hydroxy propyl methyl cellulose ether viscosity 15,000 cps 15.3 Aliphatic amide and heterocyclic sulphur containing compound mixture 2.0 Expanded unmilled perlite 19.1 China Clay - grade D 95.4 Silica flour-mean particle size 22 > 420.0 To give an adhesive of suitable consistency for fixing ceramic tiles to a substrate the above powder composition was mixed with 450.4 parts by weight of water and left to thicken slighly for about ten minutes. The resultant adhesive was able to fix ceramic tiles to a substrate but the tiles were readily removable. After removal of the tiles, the adhesive could be scraped off both the tiles and the substrate for reuse of the tiles and the adhesive.
Example 2 Another powder adhesive composition for mixing with water was prepared as in Example 1 except that seed gum is used in place of the hydroxy propyl methyl cellulose ether but in the same amount.
This adhesive powder composition when mixed with 450.4 parts by weight of water gave an adhesive of similar properties to the adhesive of Example 1.
Examples 3 and 4 Adhesive powders having greater adhesion than the adhesives of Examples 1 and 2 were prepared from the same basic powder formulations as those of Examples 1 and 2 respectively but with the addition of 20 parts by weight of a vinyl acetate/vinyl versatate copolymer.
For use in fixing tiles, the powder was mixed with 450.4 parts by weight of water.
Examples 5 and 6 Adhesive powders having greater adhesion than the adhesives of Examples 1 and 2 were prepared from the same basic powder formulation as those of Examples 1 and 2 respectively but with the addition of 20 parts by weight of a vinyl acetate/ethylene copolymer.
For use in fixing tiles, the powder was mixed with 450.4 parts by weight of water.
Examples 7 and 8 Ready mixed adhesive compositions for use in fixing ceramic tiles were prepared from the same basic powder formulations as those of Examples 1 and 2 respectively by mixing with 450.4 parts by weight of water and 11 parts by weight of polyvinyl acetate homopolymer emulsion in water (53% solids).
Examples 9 and 10 Ready mixed adhesive compositions for use in fixing ceramic tiles were prepared from the same basic powder formulations as those of Examples 1 and 2 respectively by mixing with 450.4 parts by weight of water and 11 parts by weight of styrene/acrylate copolymer emulsion in water (45% solids).
It will be appreciated that the above exemplified compositions can have their viscosity adjusted by alteration of the amounts of the various ingredients. Furthermore, these formulations could be adjusted so that they could be used as grouting compositions.

Claims (32)

1. A powder composition for producing ceramic tile adhesives or grouts the composition comprising a water soluble polymer, as binder, and a filler or blend of fillers.
2. A composition as claimed in claim 1, wherein the polymer is semi-synthetic.
3. A composition as claimed in claim 2, wherein the polymer is a cellulose derivative or a starch de rivative.
4. A composition as claimed in claim 3, wherein the cellulose derivative is an ether or a mixed ether.
5. A composition as claimed in claim 4, wherein the ether is methyl cellulose ether, ethyl cellulose ether, hydroxyethyl cellulose ether, hydroxymethyl cellulose ether or hydroxy propyl cellulose ether.
6. A composition as claimed in claim 4, wherein the mixed cellulose ether is ethyl hydroxy ethyl cellu lose ether, ethyl methyl cellulose ether or hydroxyl propyl methyl cellulose ether.
7. A composition as claimed in claim 3, wherein the starch derivative is starch acetate, hydroxyethyl starch or carboxymethyl starch.
8. A composition as claimed in claim 1, wherein the water soluble polymer is a synthetic polymer.
9. A composition as claimed in claim 8, wherein the synthetic polymer is polyacrylic acid polyacrylate, polyacrylamide, polyvinyl alcohol, polyvinyl-methoxy acetate, polyvinyl methyl ether or polycarboxylic acid.
10. A composition as claimed in claim 1, wherein the water soluble polymer is a natural polymer or a derivative thereof, a polysaccharide or a protein.
11. A composition as claimed in claim 10, wherein the natural polymer is a galactomannans.
12. A composition as claimed in claim 11, wherein the natural polymer is locust bean gum or guargum.
13. A composition as claimed in claim 10, wherein the polysaccharide is microbial polysaccharide.
14. A composition as claimed in claim 13, wherein the polysaccharide is xanthan gum, starch or dextrine.
15. A composition as claimed in claim 10, wherein the protein is casein, gelatin, animal hide or an algenate.
16. A composition as claimed in any one of claims 1 to 15 wherein the filler is an inorganic filler.
17. A composition as claimed in claim 16, wherein the filler is a mineral powder.
18. A composition as claimed in claim 17, wherein the mineral powder is gypsum, calcium carbonate, silica sand, silica flour or a clay.
19. A composition as claimed in any one of claims 1 to 18, comprising one or more redispersable powders.
20. A composition as claimed in claim 19, wherein the redispersable powders are selected from polyvinyl acetate monopolymer or polyvinyl acetate copolymers.
21. A composition as claimed in claim 20 wherein the polyvinyl acetate copolymer is vinylacetatel ethylene copolymer or vinyl acetate/vinyl versatate copolymer.
22. A composition as claimed in any one of claims 1 to 21 further comprising one or more of rheological modifying agents, bulking agents, coalescing solvents, plasticisers, dispersing agents, surfactants, preservatives and fungicides.
23. A composition as claimed in claim 22, wherein the rheologicai modifying agent is fumed silica, cellulose, kaolin or attapulgite.
24. A composition as claimed in claim 22, wherein the bulking agent is expanded unmilled perlite.
25. A powder composition as claimed in claim 1, having the following ingredients in the stated amount: %by weight Water soluble polymer 1 - 50 Inorganic fillers 30 - 80 Redispersible powder or polymer emulsion (30-80% solids) 0 - 10 Rheological modifying agent 0 - 5 Bulking agent 0-5 Preservative 0-1 Fungicide 0-1 Fillers 0 - 80 Water 0 - 80
26. An adhesive preparation for mixing with water for use comprising a powder composition as claimed in any one of claims 1 to 25.
27. A ready mixed adhesive comprising a powder composition as claimed in any one of claims 1 to 25.
28. A two part adhesive preparation comprising in one part a powder composition as claimed in any one of claims 1 to 25 and in the other part an aqueous solution or dispersion of a natural rubber latex or a styrene/butadiene rubber, an acrylic/styrene copolymer, polyvinyl alcohol or polyvinyl acetate and cellulose.
29. An adhesive preparation as claimed in claims 26, 27 or 28 further comprising a styrene/n-butyl acrylate copolymer.
30. An adhesive preparation as claimed in any one of claims 26 to 29 further comprising a pigment and/or a perfume or blend of perfumes.
31. A powder adhesive preparation as claimed in claim 1 and substantially as hereinbefore described with reference to any one of Examples 1 to 6.
32. A ready mixed adhesive preparation as claimed in claim 27 and substantially as hereinbefore described with reference to any one of Examples 7 to 10.
GB08505058A 1984-03-16 1985-02-27 Powder compositions for producing tile adhesives and grouts Expired GB2155944B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB08505058A GB2155944B (en) 1984-03-16 1985-02-27 Powder compositions for producing tile adhesives and grouts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB848406959A GB8406959D0 (en) 1984-03-16 1984-03-16 Powder compositions
GB08505058A GB2155944B (en) 1984-03-16 1985-02-27 Powder compositions for producing tile adhesives and grouts

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GB8505058D0 GB8505058D0 (en) 1985-03-27
GB2155944A true GB2155944A (en) 1985-10-02
GB2155944B GB2155944B (en) 1988-04-27

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309897A3 (en) * 1987-09-29 1991-05-15 Hoechst Aktiengesellschaft Copolymers of ethylene and methoxy acetic acid vinyl ester and their use as additives for mineral oil distillates
GB2255568A (en) * 1990-10-09 1992-11-11 Wallcoverings International Li Liquid lining material
EP0562199A1 (en) * 1990-11-28 1993-09-29 Rhone-Poulenc Chimie Isolating articles of mineral fibers and process for their production
GB2275476A (en) * 1993-02-23 1994-08-31 Park Jae Hoon Process for laying building materials by employing water-soluble bonding agent
EP1044797A1 (en) * 1999-04-13 2000-10-18 3M Innovative Properties Company Method for mounting ceramic tiles by means of an acrylic foam pressure sensitive adhesive
EP0994170A3 (en) * 1998-10-13 2000-12-20 Evode Limited Lightweight adhesive
WO2003037817A1 (en) * 2001-11-02 2003-05-08 John Thomas Liddy Improved block paving sand
EP0862856B1 (en) * 1997-03-03 2003-06-18 Rohm And Haas Company Pesticide compositions
WO2007141211A1 (en) * 2006-06-08 2007-12-13 Wacker Chemie Ag Tiles coated with polymer dispersions and method for their production
US7332537B2 (en) * 1996-09-04 2008-02-19 Z Corporation Three dimensional printing material system and method
US7550518B2 (en) 2000-04-14 2009-06-23 Z Corporation Methods and compositions for three-dimensional printing of solid objects
US7569273B2 (en) 2003-05-21 2009-08-04 Z Corporation Thermoplastic powder material system for appearance models from 3D printing systems
US7795349B2 (en) 1999-11-05 2010-09-14 Z Corporation Material systems and methods of three-dimensional printing
US7905951B2 (en) 2006-12-08 2011-03-15 Z Corporation Three dimensional printing material system and method using peroxide cure
US7968626B2 (en) 2007-02-22 2011-06-28 Z Corporation Three dimensional printing material system and method using plasticizer-assisted sintering
WO2012007529A3 (en) * 2010-07-16 2012-04-12 Parexlanko Redispersible dry composition of polymer finishes or other products for the construction
US8167999B2 (en) 2007-01-10 2012-05-01 3D Systems, Inc. Three-dimensional printing material system with improved color, article performance, and ease of use
DK178740B1 (en) * 2014-12-23 2016-12-19 Papiruld Danmark As Hitherto unknown sealants
WO2024101996A1 (en) * 2022-11-11 2024-05-16 Coöperatie Koninklijke Avebe U.A. Starch-based tile adhesive

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Publication number Priority date Publication date Assignee Title
CN116496047B (en) * 2023-04-28 2024-03-26 清远市楼固环保建材有限公司 Double-component ceramic tile interface treating agent and application thereof

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Publication number Priority date Publication date Assignee Title
GB821457A (en) * 1956-09-03 1959-10-07 Borden Co Blood glue
GB892633A (en) * 1958-08-26 1962-03-28 Commw Engiring Company Improvements in or relating to adhesives
GB946960A (en) * 1961-08-12 1964-01-15 Richards Tiles Ltd Improvements relating to the fixing of ceramic tiles on walls or other structural elements
GB1030018A (en) * 1962-10-30 1966-05-18 Monsanto Co Dry cements
GB1060085A (en) * 1963-02-20 1967-02-22 Tintex Corp Method of adhering dentures and compositions therefor
GB1137603A (en) * 1966-02-18 1968-12-27 Nat Starch Chem Corp Dry tape joint cement
GB1215202A (en) * 1967-01-28 1970-12-09 Shinetsu Chemical Co Adhesive compositions
GB1263860A (en) * 1969-06-06 1972-02-16 Brown & Polson Ltd Powders containing starch
GB1345940A (en) * 1970-11-18 1974-02-06 Staley Mfg Co A E Remoistenable adhesive composition for prepasted wall coverings
GB1435041A (en) * 1973-05-29 1976-05-12 Staley Mfg Co A E Compositions and method for making water resistant short tack adhesives
GB1504520A (en) * 1975-10-31 1978-03-22 Nat Res Dev Poly-(carboxylate) cements
GB2085463A (en) * 1980-10-01 1982-04-28 Building Adhesives Ltd Grout preparations
GB2093856A (en) * 1981-02-28 1982-09-08 Building Adhesives Ltd Adhesive compositions

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB821457A (en) * 1956-09-03 1959-10-07 Borden Co Blood glue
GB892633A (en) * 1958-08-26 1962-03-28 Commw Engiring Company Improvements in or relating to adhesives
GB946960A (en) * 1961-08-12 1964-01-15 Richards Tiles Ltd Improvements relating to the fixing of ceramic tiles on walls or other structural elements
GB1030018A (en) * 1962-10-30 1966-05-18 Monsanto Co Dry cements
GB1060085A (en) * 1963-02-20 1967-02-22 Tintex Corp Method of adhering dentures and compositions therefor
GB1137603A (en) * 1966-02-18 1968-12-27 Nat Starch Chem Corp Dry tape joint cement
GB1215202A (en) * 1967-01-28 1970-12-09 Shinetsu Chemical Co Adhesive compositions
GB1263860A (en) * 1969-06-06 1972-02-16 Brown & Polson Ltd Powders containing starch
GB1345940A (en) * 1970-11-18 1974-02-06 Staley Mfg Co A E Remoistenable adhesive composition for prepasted wall coverings
GB1435041A (en) * 1973-05-29 1976-05-12 Staley Mfg Co A E Compositions and method for making water resistant short tack adhesives
GB1504520A (en) * 1975-10-31 1978-03-22 Nat Res Dev Poly-(carboxylate) cements
GB2085463A (en) * 1980-10-01 1982-04-28 Building Adhesives Ltd Grout preparations
GB2093856A (en) * 1981-02-28 1982-09-08 Building Adhesives Ltd Adhesive compositions

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309897A3 (en) * 1987-09-29 1991-05-15 Hoechst Aktiengesellschaft Copolymers of ethylene and methoxy acetic acid vinyl ester and their use as additives for mineral oil distillates
GB2255568A (en) * 1990-10-09 1992-11-11 Wallcoverings International Li Liquid lining material
EP0562199A1 (en) * 1990-11-28 1993-09-29 Rhone-Poulenc Chimie Isolating articles of mineral fibers and process for their production
GB2275476A (en) * 1993-02-23 1994-08-31 Park Jae Hoon Process for laying building materials by employing water-soluble bonding agent
US7332537B2 (en) * 1996-09-04 2008-02-19 Z Corporation Three dimensional printing material system and method
EP0862856B1 (en) * 1997-03-03 2003-06-18 Rohm And Haas Company Pesticide compositions
EP0994170A3 (en) * 1998-10-13 2000-12-20 Evode Limited Lightweight adhesive
EP1044797A1 (en) * 1999-04-13 2000-10-18 3M Innovative Properties Company Method for mounting ceramic tiles by means of an acrylic foam pressure sensitive adhesive
US7795349B2 (en) 1999-11-05 2010-09-14 Z Corporation Material systems and methods of three-dimensional printing
US7550518B2 (en) 2000-04-14 2009-06-23 Z Corporation Methods and compositions for three-dimensional printing of solid objects
WO2003037817A1 (en) * 2001-11-02 2003-05-08 John Thomas Liddy Improved block paving sand
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GB2155944B (en) 1988-04-27
GB8505058D0 (en) 1985-03-27

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