CN108977125A - A kind of strength cross-linking type ceramic tile gum - Google Patents
A kind of strength cross-linking type ceramic tile gum Download PDFInfo
- Publication number
- CN108977125A CN108977125A CN201810916512.0A CN201810916512A CN108977125A CN 108977125 A CN108977125 A CN 108977125A CN 201810916512 A CN201810916512 A CN 201810916512A CN 108977125 A CN108977125 A CN 108977125A
- Authority
- CN
- China
- Prior art keywords
- component
- ceramic tile
- emulsion
- parts
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Road Paving Structures (AREA)
Abstract
The present invention provides a kind of strength cross-linking type ceramic tile gums, by weight, including following component: 40-70 parts of polymer emulsion, 15-30 parts of aqueous epoxy resin emulsion, 1-3 parts of preservative, 1-5 parts of defoaming agent, 0.2-1 parts of thickener, 5-10 parts of aqueous epoxy resin curing agent, 15-30 parts of water.Strength cross-linking type ceramic tile gum of the invention need to cooperate cement-based adhesive/cement mortar to use, before tile laying, it needs first in one layer of gum of ceramic tile back side roller coating, it hangs to its dry tack free, then paving is carried out with cement-based adhesive/cement mortar, it is easy for construction, greatly improve the adhesion strength between ceramic tile and cement-based material, there is splendid water resistance and heat-resistant aging again simultaneously, the problem of avoiding ceramic tile hollowing, flake, fall off.
Description
Technical field
The invention belongs to gum technical fields, more particularly, to a kind of strength cross-linking type ceramic tile gum.
Background technique
With the raising of people's daily life quality, ceramic tile quality used in decorations is also correspondingly improved, originally
Vitrified tile for floor file face also all applies to metope paving now.Since vitrified tile hardly absorbs water, and size compares
Greatly, therefore vitrified tile is used for metope and is difficult paving, is mainly manifested in and serious hollowing occurs, phenomena such as falling off, fall brick.Strength is crosslinked
Type ceramic tile gum is specifically applied to the back side process of wet combining ceramic tile, is also applied for the stone that low water absorption, quality are fine and close, surface is smooth
Material, can effectively improve the adhesion strength between ceramic tile and binding material, solve hollowing common in ceramic tile wet combining, fall off etc. to ask
Topic.
One-component emulsion-type ceramic tile gum adhesive strength in the prior art is low, and water resistance and heat-resistant aging are poor, and general
The two-component ceramic tile gum construction of logical cement mortar cooperation polymer emulsion is not convenient, ceramic tile and cement-based material and base's wall
The adhesion strength in face is urgently further promoted.
Summary of the invention
In view of this, the problem to be solved in the present invention is to propose a kind of strength cross-linking type ceramic tile gum, it is able to solve above-mentioned
Problem.
In order to achieve the above objectives, the technical scheme of the present invention is realized as follows:
A kind of strength cross-linking type ceramic tile gum, according to the mass fraction, including following component:
Component A:
B component:
5-10 parts of aqueous epoxy resin curing agent
15-30 parts of water
It needs for component A and B component to be mixed and stirred for uniformly before use.
Preferably, the polymer emulsion in the component A is styrene-acrylate emulsion, acrylic acid ester emulsion, butylbenzene
Lotion, carboxylic styrene butadiene latex, s-B-S latex, polyvinyl acetate emulsion, polychloroprene latex, vinyl acetate-
One or more of ethylene copolymer emulsion, NBR latex.
Preferably, the polymer emulsion in the component A is styrene-acrylate emulsion, acrylic acid ester emulsion, poly-vinegar
One or more of sour vac emulsion, styrene-butadiene emulsion, vinyl acetate-ethylene copolymer emulsion.
Preferably, the aqueous epoxy resin emulsion in the component A is by diglycidyl ether type epoxy resin, glycidol
One or more of ester type epoxy resin, glycidyl amine type epoxy resin are prepared by physical method or chemical modification method
Non-ion aqueous epoxy resin latex.
Preferably, the aqueous epoxy resin curing agent in the B component is aliphatic polyamine class, alicyclic polyamine class and changes
The non-ionic lotion of property polyamines class.
Including following component preferably, according to the mass fraction:
Component A:
B component:
5 parts of aqueous epoxy resin curing agent
17.5 parts of water
It needs for component A and B component to be mixed and stirred for uniformly before use.
Action principle are as follows: the bi-component ceramic tile gum, the wherein water of the aqueous epoxy resin curing agent of B component and component A
Property epoxy resin latex can crosslink reaction, form network polymers, the polymer emulsion molecule and above-mentioned ring of component A
Oxygen --- curing agent cross-linking system, which interts mutually, forms entirety, and solidification effect more preferably, greatly improves ceramic tile and cement-based material
Between adhesion strength.
The advantages and positive effects of the present invention are: strength cross-linking type ceramic tile gum of the invention need to cooperate cement base rubber
Stick/cement mortar uses, and before tile laying, needs to hang to its dry tack free, so first in one layer of gum of ceramic tile back side roller coating
Paving is carried out with cement-based adhesive/cement mortar afterwards, it is easy for construction, it greatly improves viscous between ceramic tile and cement-based material
Knotting strength, while there is splendid water resistance and heat-resistant aging again, the problem of avoiding ceramic tile hollowing, flake, fall off.
Specific embodiment
In addition to being defined, technical term used in following embodiment has and the invention one of ordinary skill in the art
The identical meanings being commonly understood by.Test reagent used in following embodiment is unless otherwise specified conventional reagent；It is described
Experimental method is unless otherwise specified conventional method.
Below with reference to examples and drawings come the present invention will be described in detail create.
Embodiment 1:
A kind of strength cross-linking type ceramic tile gum, according to the mass fraction, including following component:
Component A:
B component:
3.3 parts of aqueous epoxy resin curing agent
18.5 parts of water
Above-mentioned gum component A and B component are mixed, stirred evenly with electronic stirring tool, standard brick (ceramics are painted on
Brick: the AIa class for meeting GB/T4100-2015 appendix A requirement squeezes Ceramic Tiles and [is measured with boiling method, water absorption rate 0.1%-
0.5%], surface size is (50 ± 1) mm* (50 ± 1) mm, the adhesive surface that thickness (5 ± 2) mm has non-glazing smooth) back side, it dries in the air
It sets for 24 hours, (C1 grades, reference: 1) standard requirements of JC/T547-2017 are shown in Table after it is completely dried, then with cement-based adhesive
Carry out tile paste experiment.
The technical requirements of 1 cement-based adhesive of table (C1)
Tensile bond strength is conserved and is tested according to the method that JC/T 547-2017 is required, as a result such as following table.
Embodiment 2:
A kind of strength cross-linking type ceramic tile gum, according to the mass fraction, including following component:
Component A:
B component:
5 parts of aqueous epoxy resin curing agent
17.5 parts of water
Above-mentioned gum component A and B component are mixed, stirred evenly with electronic stirring tool, standard brick (ceramics are painted on
Brick: the AIa class for meeting GB/T4100-2015 appendix A requirement squeezes Ceramic Tiles and [is measured with boiling method, water absorption rate 0.1%-
0.5%], surface size is (50 ± 1) mm* (50 ± 1) mm, the adhesive surface that thickness (5 ± 2) mm has non-glazing smooth) back side, it dries in the air
It sets for 24 hours, (C1 grades, reference: 1) standard requirements of JC/T547-2017 are shown in Table after it is completely dried, then with cement-based adhesive
Carry out tile paste experiment.
The technical requirements of 1 cement-based adhesive of table (C1)
Tensile bond strength is conserved and is tested according to the method that JC/T 547-2017 is required, the result is as follows:
Comparative example 1:
Directly with cement-based adhesive, (C1 grades, reference: the standard requirements of JC/T547-2017 are shown in Table 1) progress standard brick
(Ceramic Tiles: the AIa class for meeting GB/T4100-2015 appendix A requirement squeezes Ceramic Tiles and [is measured with boiling method, water absorption rate is
0.1%-0.5%], surface size is (50 ± 1) mm* (50 ± 1) mm, the adhesive surface that thickness (5 ± 2) mm has non-glazing smooth)
Experiment is pasted, is conserved and tested tensile bond strength according to the method that JC/T547-2017 is required, the result is as follows:
Conclusion: being not used the strength cross-linking type ceramic tile gum of this case, directly uses cement-based adhesive, eventually passes through test,
Indices are lower than embodiment 1 or embodiment 2.
Comparative example 2:
Commercially available pressure sensitive adhesive class gum is painted on standard brick and (Ceramic Tiles: meets the AIa of GB/T4100-2015 appendix A requirement
Class squeezes Ceramic Tiles [being measured with boiling method, water absorption rate 0.1%-0.5%], and surface size is (50 ± 1) mm* (50 ± 1) mm,
The adhesive surface that thickness (5 ± 2) mm has non-glazing smooth) back side, it hangs for 24 hours, after it is completely dried, then uses cement-based adhesive
(C1 grades of references: the standard requirements of JC/T547-2017 are shown in Table 1) progress tile paste experiment, according to JC/T 547-2017 requirement
Method conserved and tested tensile bond strength, the result is as follows:
Conclusion: commercially available pressure sensitive adhesive class gum is used, eventually passes through test, indices are than embodiment 1 or embodiment 2
It is low.
The foregoing is merely the preferred embodiments of the invention, are not intended to limit the invention creation, all at this
Within the spirit and principle of innovation and creation, any modification, equivalent replacement, improvement and so on should be included in the invention
Protection scope within.
Claims (6)
1. a kind of strength cross-linking type ceramic tile gum, it is characterised in that: according to the mass fraction, including following component:
Component A:
B component:
5-10 parts of aqueous epoxy resin curing agent
15-30 parts of water
It needs for component A and B component to be mixed and stirred for uniformly before use.
2. strength cross-linking type ceramic tile gum according to claim 1, it is characterised in that: the polymer cream in the component A
Liquid is styrene-acrylate emulsion, acrylic acid ester emulsion, styrene-butadiene emulsion, carboxylic styrene butadiene latex, styrene-butadiene-benzene second
One of alkene latex, polyvinyl acetate emulsion, polychloroprene latex, vinyl acetate-ethylene copolymer emulsion, NBR latex are several
Kind.
3. strength cross-linking type ceramic tile gum according to claim 1, it is characterised in that: the polymer cream in the component A
Liquid, using styrene-acrylate emulsion, acrylic acid ester emulsion, polyvinyl acetate emulsion, styrene-butadiene emulsion, vinyl acetate-
One or more of ethylene copolymer emulsion.
4. strength cross-linking type ceramic tile gum according to claim 1, it is characterised in that: the water-base epoxy in the component A
Resin emulsion is by diglycidyl ether type epoxy resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin
The non-ion aqueous epoxy resin latex that is prepared by physical method or chemical modification method of one or more.
5. strength cross-linking type ceramic tile gum according to claim 1, it is characterised in that: the water-base epoxy in the B component
Resin curing agent is the non-ion aqueous resin or non-ionic of aliphatic polyamine class, alicyclic polyamine class and modified polyamine class
Lotion.
6. strength cross-linking type ceramic tile gum according to claim 1, it is characterised in that: according to the mass fraction, including it is as follows
Component:
Component A:
B component:
5 parts of aqueous epoxy resin curing agent
17.5 parts of water
It needs for component A and B component to be mixed and stirred for uniformly before use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810916512.0A CN108977125A (en) | 2018-08-13 | 2018-08-13 | A kind of strength cross-linking type ceramic tile gum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810916512.0A CN108977125A (en) | 2018-08-13 | 2018-08-13 | A kind of strength cross-linking type ceramic tile gum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108977125A true CN108977125A (en) | 2018-12-11 |
Family
ID=64553144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810916512.0A Pending CN108977125A (en) | 2018-08-13 | 2018-08-13 | A kind of strength cross-linking type ceramic tile gum |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108977125A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109650775A (en) * | 2019-01-18 | 2019-04-19 | 武汉科技大学 | A kind of preparation method of the high-strength ceramic tile gum for high-temperature region |
| CN109825235A (en) * | 2019-01-21 | 2019-05-31 | 株洲加美乐素建材有限公司 | A kind of waterproof roll cement base adhesive aqua and preparation method thereof |
| CN111154410A (en) * | 2019-12-23 | 2020-05-15 | 广东东方一哥新材料股份有限公司 | Air-permeable hollowing-proof ceramic tile back glue and preparation method thereof |
| CN111732921A (en) * | 2020-06-09 | 2020-10-02 | 武汉天成旭邦新型建材有限公司 | Vitrified tile back adhesive and preparation method thereof |
| CN112063338A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Anticorrosive joint filling material for ceramic tiles and preparation method thereof |
| CN112625605A (en) * | 2020-12-15 | 2021-04-09 | 广东博智林机器人有限公司 | Double-component ceramic tile adhesive |
| CN113234418A (en) * | 2021-05-27 | 2021-08-10 | 河南伯高节能科技有限公司 | Tile back glue and preparation method thereof |
| CN114262588A (en) * | 2021-12-06 | 2022-04-01 | 上海保立佳新材料有限公司 | Ceramic tile hollowing glue, raw material composition thereof, and preparation method and application thereof |
| CN114562082A (en) * | 2022-03-09 | 2022-05-31 | 孙龙海 | Water permeability resin coating anti-drop all-ceramic tile |
| CN114907792A (en) * | 2022-07-04 | 2022-08-16 | 广州瓷添乐装饰材料有限公司 | Preparation method of large-plate ceramic tile back glue emulsion |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318076A (en) * | 2016-08-29 | 2017-01-11 | 东方雨虹民用建材有限责任公司 | Tiling mate and construction method thereof |
| CN106497473A (en) * | 2016-10-21 | 2017-03-15 | 湖北碱克新材料有限公司 | A kind of environment protection type single-component vitrified brick gum and preparation method thereof |
| CN106916554A (en) * | 2017-04-28 | 2017-07-04 | 湖北碱克新材料有限公司 | A kind of one pack system vitrified brick gum |
-
2018
- 2018-08-13 CN CN201810916512.0A patent/CN108977125A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318076A (en) * | 2016-08-29 | 2017-01-11 | 东方雨虹民用建材有限责任公司 | Tiling mate and construction method thereof |
| CN106497473A (en) * | 2016-10-21 | 2017-03-15 | 湖北碱克新材料有限公司 | A kind of environment protection type single-component vitrified brick gum and preparation method thereof |
| CN106916554A (en) * | 2017-04-28 | 2017-07-04 | 湖北碱克新材料有限公司 | A kind of one pack system vitrified brick gum |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109650775A (en) * | 2019-01-18 | 2019-04-19 | 武汉科技大学 | A kind of preparation method of the high-strength ceramic tile gum for high-temperature region |
| CN109825235A (en) * | 2019-01-21 | 2019-05-31 | 株洲加美乐素建材有限公司 | A kind of waterproof roll cement base adhesive aqua and preparation method thereof |
| CN111154410A (en) * | 2019-12-23 | 2020-05-15 | 广东东方一哥新材料股份有限公司 | Air-permeable hollowing-proof ceramic tile back glue and preparation method thereof |
| CN111732921A (en) * | 2020-06-09 | 2020-10-02 | 武汉天成旭邦新型建材有限公司 | Vitrified tile back adhesive and preparation method thereof |
| CN111732921B (en) * | 2020-06-09 | 2022-03-04 | 武汉天成旭邦新型建材有限公司 | Vitrified tile back adhesive and preparation method thereof |
| CN112063338A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Anticorrosive joint filling material for ceramic tiles and preparation method thereof |
| CN112625605A (en) * | 2020-12-15 | 2021-04-09 | 广东博智林机器人有限公司 | Double-component ceramic tile adhesive |
| CN113234418A (en) * | 2021-05-27 | 2021-08-10 | 河南伯高节能科技有限公司 | Tile back glue and preparation method thereof |
| CN114262588A (en) * | 2021-12-06 | 2022-04-01 | 上海保立佳新材料有限公司 | Ceramic tile hollowing glue, raw material composition thereof, and preparation method and application thereof |
| CN114262588B (en) * | 2021-12-06 | 2023-03-17 | 上海保立佳新材料有限公司 | Ceramic tile hollowing glue, raw material composition thereof, and preparation method and application thereof |
| CN114562082A (en) * | 2022-03-09 | 2022-05-31 | 孙龙海 | Water permeability resin coating anti-drop all-ceramic tile |
| CN114907792A (en) * | 2022-07-04 | 2022-08-16 | 广州瓷添乐装饰材料有限公司 | Preparation method of large-plate ceramic tile back glue emulsion |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108977125A (en) | A kind of strength cross-linking type ceramic tile gum | |
| CN109181595B (en) | Tile back glue and preparation method and use method thereof | |
| JP5109555B2 (en) | Waterproofing composition | |
| JPH1095922A (en) | Aqueous emulsion composition and its production | |
| CN108585684A (en) | A kind of cement base Ceramic Tiles adhesive | |
| CN104402367B (en) | Without the high-strength ceramic tile adhesive of the accumulation of salt in the surface soil | |
| CN105777009A (en) | Gum for vetrified bricks, preparation method for gum and construction method | |
| CN106497473B (en) | A kind of environment protection type single-component vitrified brick gum and preparation method thereof | |
| CN108947430A (en) | A kind of slow setting hard features waterproof mortar and preparation method thereof fastly | |
| CN106318076B (en) | A kind of patch block companion and its construction method | |
| CN110804406A (en) | Paste ceramic tile back glue and preparation method and use method thereof | |
| CN107417197B (en) | Exposed wear-resistant polymer cement waterproof slurry and preparation method thereof | |
| KR101010854B1 (en) | Highly efficient two-component tile adhesive with combined waterproof properties | |
| KR101105122B1 (en) | Loess tile adhesive with vinyl water | |
| CN108640620A (en) | Glue for tile and preparation method thereof | |
| JP2004262748A (en) | Polymer cement composition for waterproofing | |
| EP3247687B1 (en) | Use of levelling compound | |
| JP2009097210A (en) | Film waterproofing method | |
| CN104531010A (en) | Adhesive paste, and preparation method and application thereof | |
| JP4093179B2 (en) | Rooftop exterior insulation waterproofing method | |
| CN107556570B (en) | Dibutylbenzene redispersible emulsion powder and preparation method thereof | |
| CN105542684A (en) | Waterproof coil system capable of being constructed on humid and uneven base course | |
| CN106381103B (en) | Water polyacrylic acid adhesive and preparation method thereof | |
| CN106630877A (en) | Alkaline-slag-based inorganic adhesive for bonding carbon fiber sheets | |
| JP6159213B2 (en) | Polymer cement composition for adhesion of tarpaulin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20191120 Address after: 300381 No. 508 Hongqi South Road, Nankai District Sports Center, Tianjin Applicant after: Tianjin Construction Material Science Research Institute Co., Ltd. Address before: 300381 Jinbao Expressway South, Shuangkou Town, Beichen District, Tianjin (in Hongguang Brick Factory) Applicant before: TIANJIN KEYUAN NEW BUILDING MATERIAL CO., LTD. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181211 |