CN108342170A - Aqueous, environmental protective glue for tile, preparation method and applications - Google Patents
Aqueous, environmental protective glue for tile, preparation method and applications Download PDFInfo
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- CN108342170A CN108342170A CN201810256421.9A CN201810256421A CN108342170A CN 108342170 A CN108342170 A CN 108342170A CN 201810256421 A CN201810256421 A CN 201810256421A CN 108342170 A CN108342170 A CN 108342170A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to adhesive areas, specifically, providing a kind of aqueous, environmental protective glue for tile, preparation method and applications.The aqueous, environmental protective glue for tile includes each component of following mass fraction：0.5 1 parts of 30 60 parts of styrene-acrylic emulsion, 5 15 parts of kaolin, 10 25 parts of barium sulfate, native 15 parts recessed, 5 15 parts of talcum powder, 5 15 parts of calcium carbonate, 0.5 2 parts of dispersant, 38 parts of coalescents and wetting agent.Above-mentioned aqueous, environmental protective glue for tile is grouped as by groups such as the styrene-acrylic emulsion of certain content, kaolin, barium sulfate, recessed soil, talcum powder and calcium carbonate, the mating reaction of each component is given full play to, so that aqueous, environmental protective glue for tile has excellent caking property and water resistance, loosening, hollowing, the ceramic tile to fall off or paving ceramic tile can be repaired using the aqueous, environmental protective glue for tile, improves service life and the safety of ceramic tile.
Description
Technical field
The present invention relates to adhesive areas, in particular to a kind of aqueous, environmental protective glue for tile, preparation method and its answer
With.
Background technology
Ceramic tile is also known as ceramic tile, is metal oxide and half-metal oxide with fire resisting, via grinding, mixing, suppresses, applies
Glaze, sintering process, and the porcelain or stone matter etc. of a kind of acid and alkali-resistance formed, building or ornament materials.Ceramic tile can be divided by purposes
For exterior wall tile, internal wall brick, floor tile, square brick, industrial brick etc..Currently, there are mainly two types of the methods of paving ceramic tile：1, using ceramic tile
Adhesive paving；2, coordinate paving using cement and generic interface agent.Interfacial agents and cement paste or sand are used for second
The laying method of slurry cooperation has the following problems：(1) adhesion strength is low, and hollowing peeling phenomenon is serious；(2) most of interfacial agents are deposited
Durability it is poor, it is not water-fast, not weather-proof, there is a possibility that the shortcomings of serious aging, using this method paving ceramic tile, there is tight
The hidden danger of weight.
More extensive using glue for tile paving ceramic tile application, glue for tile is specifically applied to paste the back side process of ceramic tile,
Suitable for low water absorption, the stone material that quality is fine and close, surface is smooth, ceramic tile can be effectively improved and bond ground (such as metope, ground
Deng) between adhesion strength, the problems such as solving common hollowing in tile paste, fall off.Although however existing glue for tile exists
Good bond effect can be realized in a short time, but is susceptible to the phenomenon that falling off after the long-term use of ceramic tile, shorten ceramic tile
Service life reduces the safety in utilization of ceramic tile.
In view of this, special propose the present invention.
Invention content
The first object of the present invention is to provide a kind of aqueous, environmental protective glue for tile, which gives full play to
The mating reaction of each component has excellent caking property and water resistance, uses ceramic tile after the aqueous, environmental protective glue for tile paving ceramic tile
It is less prone to the phenomenon that falling off, the service life and safety in utilization of ceramic tile are improved.
The second object of the present invention is to provide a kind of preparation method of aqueous, environmental protective glue for tile, and this method is simple for process,
The each component of formula ratio need to be only uniformly mixed, be suitble to industrialization large-scale production, and low production cost, production process
In it is non-toxic and tasteless, obtained aqueous, environmental protective glue for tile have excellent caking property and weatherability.
The third object of the present invention is to provide a kind of above-mentioned aqueous, environmental protective glue for tile and loosens in tile laying or ceramic tile, is empty
Application in drum, the repairing that falls off, above-mentioned aqueous, environmental protective glue for tile is fitted into the plastic tube with Jiao Zui applied to tile laying or
In ceramic tile repairing, construction is simple is convenient.
In order to realize that the above-mentioned purpose of the present invention, spy use following technical scheme：
In a first aspect, the present invention provides a kind of aqueous, environmental protective glue for tile, include each component of following mass fraction：Phenylpropyl alcohol
30-60 parts of lotion, 10-25 parts of barium sulfate, recessed 1-5 parts of soil, 5-15 parts of talcum powder, 5-15 parts of calcium carbonate, is divided 5-15 parts of kaolin
0.5-1 parts of 0.5-2 parts of powder, 3-8 parts of coalescents and wetting agent.
As further preferred technical solution, include each component of following mass fraction：35-60 parts of styrene-acrylic emulsion, height
Soil 5-10 parts of ridge, 15-25 parts of barium sulfate, recessed 1-4 parts of soil, 5-13 parts of talcum powder, 5-13 parts of calcium carbonate, 0.5-1.5 parts of dispersant,
0.5-0.8 parts of 3-6 parts of coalescents and wetting agent.
As further preferred technical solution, include each component of following mass fraction：35-55 parts of styrene-acrylic emulsion, height
Soil 7-10 parts of ridge, 15-20 parts of barium sulfate, recessed 2-4 parts of soil, 7-13 parts of talcum powder, 7-13 parts of calcium carbonate, 0.8-1.5 parts of dispersant,
0.6-0.8 parts of 4-6 parts of coalescents and wetting agent.
As further preferred technical solution, the components also include antifoaming agent 0.5-1 mass parts.
As further preferred technical solution, the components also include pure-acrylic emulsion or acrylate and vinyl acetate emulsion 10-25 mass parts.
As further preferred technical solution, include each component of following mass fraction：It is 30-45 parts of styrene-acrylic emulsion, pure
Acrylic emulsion or 10-25 parts of acrylate and vinyl acetate emulsion, 5-15 parts of kaolin, 10-25 parts of barium sulfate, recessed 1-3 parts of soil, 5-15 parts of talcum powder, carbon
0.5-1 parts of sour calcium 5-10 parts, 0.5-2 parts of dispersant, 3-8 parts of coalescents and wetting agent.
Further include 0.5-2 parts of other auxiliary agents as further preferred technical solution, other described auxiliary agents include enhancing
At least one of agent, preservative, mould inhibitor or hydrophober.
Second aspect, the present invention provides a kind of above-mentioned aqueous, environmental protective glue for tile preparation methods, include the following steps：It will match
The each component just measured is uniformly mixed.
As further preferred technical solution, include the following steps：(a) styrene-acrylic emulsion and dispersant is uniform
Latex A；
(b) latex A is uniformly mixed to obtain lotion B with kaolin and recessed soil；
(c) lotion B is uniformly mixed to obtain lotion C with barium sulfate, talcum powder and calcium carbonate successively；
(d) lotion C is uniformly mixed to obtain the aqueous, environmental protective glue for tile with coalescents and wetting agent.
The third aspect, the present invention provides a kind of above-mentioned aqueous, environmental protective glue for tile answering in tile laying or ceramic tile repairing
With.
Compared with prior art, beneficial effects of the present invention are：
Aqueous, environmental protective glue for tile provided by the invention is by the styrene-acrylic emulsion of certain content, kaolin, barium sulfate, recessed soil, cunning
The groups such as mountain flour and calcium carbonate are grouped as, and have given full play to the mating reaction of each component so that aqueous, environmental protective glue for tile has excellent
Caking property and water resistance, be less prone to the phenomenon that falling off using ceramic tile after the aqueous, environmental protective glue for tile paving ceramic tile, ceramic tile
Service life and safety in utilization are improved.
In addition, the aqueous, environmental protective glue for tile construction is simple, construction environment is clean, and metope, ground can be bonded with ceramic tile,
Thickness can be ignored with respect to tile thickness, thus surface is very smooth when repairing loosening, hollowing, falling off ceramic tile, while ceramic tile
Rupture can also repair on wall.
The preparation method that the present invention provides aqueous, environmental protective glue for tile is simple for process, need to only mix each component of formula ratio equal
It is even, it is suitble to industrialization large-scale production, and low production cost, obtained aqueous, environmental protective glue for tile that there is excellent bonding
Property and water resistance.
Above-mentioned aqueous, environmental protective glue for tile is applied in tile laying or ceramic tile repairing, ceramic tile is not easily to fall off, can extend
The service life and safety in utilization of ceramic tile.
Specific implementation mode
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.
In a first aspect, provide a kind of aqueous, environmental protective glue for tile in some embodiments, including following mass fraction is each
Component：30-60 parts of styrene-acrylic emulsion, 5-15 parts of kaolin, 10-25 parts of barium sulfate, recessed 1-5 parts of soil, 5-15 parts of talcum powder, calcium carbonate
0.5-1 parts of 5-15 parts, 0.5-2 parts of dispersant, 3-8 parts of coalescents and wetting agent.
Styrene-acrylic emulsion (styrene-acrylate emulsion) is obtained through emulsion copolymerization by styrene and acrylate monomer,
With good adhesive force, glued membrane is transparent, and water-fast, oil resistant, heat-resisting, ageing-resistant performance is good.Styrene-acrylic emulsion is milky white liquid, band
Blue light, solid content 40~50%, 500~3000mPas of viscosity, pH value 8~9.In the present invention, according to the mass fraction, phenylpropyl alcohol
The typical but non-limiting content of lotion be 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts,
40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55
Part, 56 parts, 57 parts, 58 parts, 59 parts or 60 parts.
Kaolin is a kind of nonmetallic minerals, is a kind of clay and clay rock based on kaolinite race clay mineral；Cause
White and fine and smooth, also known as white clouds are native.Kaolin has chemical inertness, high covering power, ideal mobile performance, cost
Low feature.In addition, kaolin also has good suspendability and dispersion performance, it is used as filler.In the present invention, by mass parts
Number meter, the typical but non-limiting content of kaolin are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts
Or 15 parts.
Barium sulfate is white or linen crystalline powder, and chemical inertness is strong, and stability is good, and acid and alkali-resistance, density is big, hardness
Moderate, proportion is high, and high whiteness has higher fillibility and rheological characteristic.In the present invention, according to the mass fraction, barium sulfate it is typical but
Unrestricted content be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts,
22 parts, 23 parts, 24 parts or 25 parts.
Recessed soil is the abbreviation of attapulgite clay, is a kind of rare nonmetal mineral resource, it is a kind of layer of chain structure
The clay mineral of zeopan containing Shuifu County.Studies have shown that attapulgite clay can be applied to building materials, chemical industry, machinery, military project, core work
The multiple fields such as industry, weaving, environmental protection, papermaking, medicine, food, have " thousand with soil, ten thousand soil king " good reputation.Recessed soil has good
Good thickening property, suspension, thixotropy, levelability, weatherability and the feature of environmental protection.In the present invention, according to the mass fraction, recessed soil is typical
But unrestricted content is 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
Talcum powder main component is aqueous magnesium silicate, has lubricity, helps stream, is fire resistance, acid-resisting, insulating properties, molten
Point height, the chemically excellent Wuli-Shili-Renli system approach such as torpescence, covering power good, softness, good luster, strong adsorption force, Neng Gouzeng
Add resistance to acid and alkali, heat resistance and the fire protecting performance of aqueous, environmental protective glue for tile.In the present invention, according to the mass fraction, talcum powder is typical
But unrestricted content is 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts.
Calcium carbonate has good compatibility with sizing material, can accelerate the cross-linking reaction of glue, substantially improve the thixotropy of system,
Enhance dimensional stability, improves the mechanical performance of glue, and additive amount is big, reach filling and reinforcement double action, meanwhile, it can make
Sizing material surface-brightening is fine and smooth.In the present invention, according to the mass fraction, the typical but non-limiting content of calcium carbonate be 5 parts, 6 parts, 7
Part, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts.
Dispersant be it is a kind of in the molecule while there is the interfacial agents of two kinds of opposite natures of lipophile and hydrophily, can
Those are poorly soluble inorganic, organic pigment solid and liquid particles in liquid for uniform dispersion, while can also prevent particle
Sedimentation and cohesion, form the amphipathic reagent stabilized needed for suspension.Dispersant can reduce remaining component and complete dispersion process institute
The time needed and energy, stablize disperseed dispersion, and modified particle surface nature adjusts the motility of particle.The present invention
In, according to the mass fraction, the typical but non-limiting content of dispersant be 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1
Part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts.
Coalescents are also known as coalescing aid, can promote high-molecular compound Plastic Flow and flexible deformation, improve cohesiveness
Can, the substance that can be formed a film within the scope of wide construction temperature.General lotion has film-forming temperature, when environment temperature is less than lotion
Lotion is not easy to form a film when film-forming temperature, and coalescents can improve emulsion film forming mechanism, helps to form a film.Coalescents are waved after film forming
Hair, does not interfere with the characteristic of film.In the present invention, according to the mass fraction, the typical but non-limiting content of coalescents is 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts or 8 parts.
Wetting agent can make solid material be more easy to be soaked in water, and by reducing its surface tension or interfacial tension, allow the water to open up
It is opened on solid material surface, or penetrates its surface, and solid material is soaked, increase the mixing of solid component and remaining component
Uniformity.In the present invention, according to the mass fraction, the typical but non-limiting content of wetting agent be 0.5 part, 0.6 part, 0.7 part,
0.8 part, 0.9 part or 1 part.
Above-mentioned aqueous, environmental protective glue for tile is by the styrene-acrylic emulsion of certain content, kaolin, barium sulfate, recessed soil, talcum powder and carbon
The groups such as sour calcium are grouped as, and have given full play to the mating reaction of each component so that aqueous, environmental protective glue for tile has excellent caking property
And water resistance, it is less prone to the phenomenon that falling off, the service life of ceramic tile using ceramic tile after the aqueous, environmental protective glue for tile paving ceramic tile
It is improved with safety in utilization.
In addition, the aqueous, environmental protective glue for tile construction is simple, construction environment is clean, and metope, ground can be bonded with ceramic tile,
Thickness can be ignored with respect to tile thickness, thus surface is very smooth when repairing loosening, hollowing, falling off ceramic tile, while ceramic tile
Rupture can also repair on wall.
In a preferred embodiment, include each component of following mass fraction：35-60 parts of styrene-acrylic emulsion, kaolinite
5-10 parts native, 15-25 parts of barium sulfate, recessed 1-4 parts of soil, 5-13 parts of talcum powder, 5-13 parts of calcium carbonate, 0.5-1.5 parts of dispersant, at
0.5-0.8 parts of 3-6 parts of film auxiliary agent and wetting agent.
In a preferred embodiment, include each component of following mass fraction：35-55 parts of styrene-acrylic emulsion, kaolinite
7-10 parts native, 15-20 parts of barium sulfate, recessed 2-4 parts of soil, 7-13 parts of talcum powder, 7-13 parts of calcium carbonate, 0.8-1.5 parts of dispersant, at
0.6-0.8 parts of 4-6 parts of film auxiliary agent and wetting agent.
Above-mentioned optimization formula has further considered the characteristic of each component, can improve the mating reaction between each component, obtain
The caking property of the aqueous, environmental protective glue for tile arrived is stronger, water resistance is more preferable.
In a preferred embodiment, the components also include antifoaming agent 0.5-1 mass parts.
Antifoaming agent is the industrial additive for referring to reduce surface tension, foam is inhibited to generate.If aqueous, environmental protective ceramic tile
There are a large amount of bubbles in glue, can seriously affect the product quality of aqueous, environmental protective glue for tile, and viscosity reduces, and be easy to cause ceramic tile sky
Drum.Above-mentioned antifoaming agent includes but not limited to organosiloxane, polyethers, silicon and ether grafting, amine-containing, imines or amides.By quality
Number meter, typical but non-limiting above-mentioned antifoaming agent is 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part or 1 part.
Preferably, the aqueous, environmental protective glue for tile includes each component of following mass fraction：30-60 parts of styrene-acrylic emulsion, height
Soil 10-15 parts of ridge, 10-25 parts of barium sulfate, recessed 2-5 parts of soil, 5-15 parts of talcum powder, 5-15 parts of calcium carbonate, 0.5-2 parts of dispersant,
0.5-1 parts of 3-8 parts of coalescents, 0.5-1 parts of antifoaming agent and wetting agent.
In a preferred embodiment, the components also include pure-acrylic emulsion or acrylate and vinyl acetate emulsion 10-25 mass parts.
Pure-acrylic emulsion is transparent or milky white slightly lurid thick liquid, color according to different producer's manufacture crafts not
Same and different, grain size is thin, high glaze, excellent acid resistance, alkali resistance, excellent anti-after tack, and impermeability is good, low-temperature flexibility
Property good, Weatherproof ageing-resistant have excellent performance, have wide applicability.The constituent component of pure-acrylic emulsion：A variety of acrylic acid, methyl-prop
Olefin(e) acid, methyl methacrylate, esters of acrylic acid and functional aid are polynary poly-, newborn made of being copolymerized by optimize technique
Liquid.
It is aqueous high molecular tree made of the copolymerization of main function monomer that acrylate and vinyl acetate emulsion, which is with vinyl acetate and butyl acrylate,
Fat；Grain size is thin, gloss is high, no APEO (alkyl phenol polyoxyethylene ether class compound), formaldehydeless, health environment-friendly, has splendid resistance to
Aqueous, hardness is big, scrubbing resistance, and film-forming temperature is lower than styrene-acrylic emulsion, can reduce aqueous, environmental protective glue for tile suitably less plus coalescents
Cost.
According to the mass fraction, the content of above-mentioned pure-acrylic emulsion or acrylate and vinyl acetate emulsion is typical but non-limiting each independently is
10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts or
25 parts.
In a preferred embodiment, include each component of following mass fraction：30-45 parts of styrene-acrylic emulsion, pure third
Lotion or 10-25 parts of acrylate and vinyl acetate emulsion, 5-15 parts of kaolin, 10-25 parts of barium sulfate, recessed 1-3 parts of soil, 5-15 parts of talcum powder, carbonic acid
0.5-1 parts of 5-10 parts of calcium, 0.5-2 parts of dispersant, 3-8 parts of coalescents and wetting agent.Aqueous ring in this preferred embodiment
It protects the pure-acrylic emulsion for further comprising certain content in glue for tile or acrylate and vinyl acetate emulsion with remaining each component to coordinate, can further enhance
The water resistance and ageing-resistant performance of aqueous, environmental protective glue for tile.
In a preferred embodiment, further include 0.5-2 parts of other auxiliary agents, other described auxiliary agents include reinforcing agent,
At least one of preservative, mould inhibitor or hydrophober.According to the mass fraction, the typical but non-limiting content of other auxiliary agents is
0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts,
1.8 parts, 1.9 parts or 2 parts.Aqueous, environmental protective glue for tile can be improved by increasing reinforcing agent, preservative, mould inhibitor or hydrophober
Adhesion strength or mould proof water proofing property extend the service life of aqueous, environmental protective glue for tile, enhance its safety in utilization.
It should be noted that the present invention aqueous, environmental protective glue for tile in each component can be used it is commercially available, also can be voluntarily
It is prepared, prepares raw material and method using existing.
Second aspect provides a kind of above-mentioned aqueous, environmental protective glue for tile preparation method in some embodiments, including following
Step：The each component of formula ratio is uniformly mixed.The preparation method of above-mentioned aqueous, environmental protective glue for tile is simple for process, only need by
The each component of formula ratio is uniformly mixed, and is suitble to industrialization large-scale production, and low production cost, obtained aqueous, environmental protective
Glue for tile has excellent caking property and water resistance.
In a preferred embodiment, include the following steps：(a) styrene-acrylic emulsion and dispersant is newbornly uniform
Liquid A；
(b) latex A is uniformly mixed to obtain lotion B with kaolin and recessed soil；
(c) lotion B is uniformly mixed to obtain lotion C with barium sulfate, talcum powder and calcium carbonate successively；
(d) lotion C is uniformly mixed to obtain the aqueous, environmental protective glue for tile with coalescents and wetting agent.
Each component is uniformly mixed in such a way that substep mixes and obtains aqueous, environmental protective glue for tile, energy by this preferred embodiment
Each component is enough set to be easier to be uniformly mixed, incorporation time is short, and the performance of obtained aqueous, environmental protective glue for tile is more preferable.
Preferably, when containing pure-acrylic emulsion or acrylate and vinyl acetate emulsion in component, by styrene-acrylic emulsion, pure-acrylic emulsion in step (a)
Or acrylate and vinyl acetate emulsion and dispersant it is uniform latex A.Preferably, when containing other auxiliary agents in component, lotion in step (d)
C is uniformly mixed to obtain the aqueous, environmental protective glue for tile with coalescents, wetting agent and other auxiliary agents.
The third aspect provides a kind of above-mentioned aqueous, environmental protective glue for tile and is repaiied in tile laying or ceramic tile in some embodiments
The application of bowl spares.Above-mentioned aqueous, environmental protective glue for tile is applied in tile laying or ceramic tile repairing, ceramic tile is not easily to fall off, Neng Gouyan
The service life and safety in utilization of long ceramic tile.
Optionally, construction and application method：The above aqueous, environmental protective glue for tile is fitted into in the Packaging Bottle for facilitating mouth, is constructed
When, material is directly extruded into the ceramic tile back side (plastic squeeze is got on four side gluings or periphery, center ready), ceramic tile is then shifted onto metope or ground
Face (metope or ground have to smooth, cannot there is dust), metope generally pastes two layers or more, is connected with adhesive tape, because
Glue is done solid work want 24 hours after, initial stage fitting only by aqueous, environmental protective glue for tile itself bonding force and ceramic tile and brick face between glue
Close other adsorption capacities of glue.
With reference to embodiment and comparative example, the present invention will be further described in detail.
Embodiment 1
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：30 parts of styrene-acrylic emulsion, 5 parts of kaolin, sulphur
0.5 part of 10 parts of sour barium, native 1 part recessed, 5 parts of talcum powder, 5 parts of calcium carbonate, 0.5 part of dispersant, 3 parts of coalescents and wetting agent are prevented
0.2 part of rotten agent, 0.2 part of mould inhibitor.
Embodiment 2
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：60 parts of styrene-acrylic emulsion, 15 parts of kaolin,
1 part of 25 parts of barium sulfate, native 5 parts recessed, 15 parts of talcum powder, 15 parts of calcium carbonate, 2 parts of dispersant, 8 parts of coalescents and wetting agent are prevented
0.2 part of rotten agent, 0.2 part of mould inhibitor.
Embodiment 3
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：33 parts of styrene-acrylic emulsion, 7 parts of kaolin, sulphur
0.6 part of 15 parts of sour barium, native 2 parts recessed, 7 parts of talcum powder, 7 parts of calcium carbonate, 0.8 part of dispersant, 4 parts of coalescents and wetting agent are prevented
0.2 part of rotten agent, 0.2 part of mould inhibitor.
Embodiment 4
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：55 parts of styrene-acrylic emulsion, 10 parts of kaolin,
20 parts of barium sulfate, native 4 parts recessed, 13 parts of talcum powder, 13 parts of calcium carbonate, 1.5 parts of dispersant, 6 parts of coalescents and wetting agent 0.8
Part, 0.2 part of preservative, 0.2 part of mould inhibitor.
Embodiment 5
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：45 parts of styrene-acrylic emulsion, 8 parts of kaolin, sulphur
0.7 part of 18 parts of sour barium, native 3 parts recessed, 10 parts of talcum powder, 10 parts of calcium carbonate, 1 part of dispersant, 5 parts of coalescents and wetting agent are prevented
0.2 part of rotten agent, 0.2 part of mould inhibitor.
Embodiment 6
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：45 parts of styrene-acrylic emulsion, 8 parts of kaolin, sulphur
18 parts of sour barium, native 3 parts recessed, 10 parts of talcum powder, 10 parts of calcium carbonate, 1 part of dispersant, 5 parts of coalescents, 0.7 part of wetting agent and disappear
0.8 part of infusion, 0.2 part of preservative, 0.2 part of mould inhibitor.
As different from Example 5, antifoaming agent is increased in the present embodiment.
Embodiment 7
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：45 parts of styrene-acrylic emulsion, pure-acrylic emulsion 20
Part, 8 parts of kaolin, 18 parts of barium sulfate, native 3 parts recessed, 10 parts of talcum powder, 10 parts of calcium carbonate, 1 part of dispersant, 5 parts of coalescents and
0.7 part of wetting agent, 0.2 part of preservative, 0.2 part of mould inhibitor.
As different from Example 5, pure-acrylic emulsion is increased in the present embodiment.
Embodiment 8
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：45 parts of styrene-acrylic emulsion, acrylate and vinyl acetate emulsion 20
Part, 8 parts of kaolin, 18 parts of barium sulfate, native 3 parts recessed, 10 parts of talcum powder, 10 parts of calcium carbonate, 1 part of dispersant, 5 parts of coalescents and
0.7 part of wetting agent, 0.2 part of preservative, 0.2 part of mould inhibitor.
As different from Example 5, acrylate and vinyl acetate emulsion is increased in the present embodiment.
Embodiment 9
A kind of aqueous, environmental protective glue for tile, includes each component of following mass fraction：45 parts of styrene-acrylic emulsion, 8 parts of kaolin, sulphur
18 parts of sour barium, native 3 parts recessed, 10 parts of talcum powder, 10 parts of calcium carbonate, 1 part of dispersant, 5 parts of coalescents, 0.7 part of wetting agent and increasing
Strong 1 part of agent, 0.2 part of preservative, 0.2 part of mould inhibitor.
As different from Example 5, reinforcing agent is increased in the present embodiment.
Embodiment 10
A kind of aqueous, environmental protective glue for tile, identical as the constituent component of embodiment 1, preparation method includes the following steps：(a)
By styrene-acrylic emulsion and dispersant it is uniform latex A；
(b) latex A is uniformly mixed to obtain lotion B with kaolin and recessed soil；
(c) lotion B is uniformly mixed to obtain lotion C with barium sulfate, talcum powder and calcium carbonate successively；
(d) lotion C is uniformly mixed to obtain the aqueous, environmental protective glue for tile with coalescents and wetting agent.
Aqueous, environmental protective glue for tile is prepared using identical preparation method in embodiment 10 in embodiment 2-9.
Comparative example 1
A kind of glue for tile includes each component of following mass fraction：30 parts of styrene-acrylic emulsion, 5 parts of kaolin, native 1 part recessed, cunning
0.5 part of 5 parts of mountain flour, 5 parts of calcium carbonate, 0.5 part of dispersant, 3 parts of coalescents and wetting agent, 0.2 part of preservative, mould inhibitor 0.2
Part.
As different from Example 1, not barium sulfate-containing in this comparative example.
Comparative example 2
A kind of glue for tile includes each component of following mass fraction：28 parts of styrene-acrylic emulsion, 20 parts of kaolin, barium sulfate 8
Part, native 0.5 part recessed, 20 parts of talcum powder, 3 parts of calcium carbonate, 3 parts of dispersant, 2 parts of coalescents and 3 parts of wetting agent, preservative 0.2
Part, 0.2 part of mould inhibitor.
As different from Example 1, in this comparative example the content of each component not in the range of not inventing provided.
Performance test
By the glue for tile in embodiment 1-10 and comparative example 1-3 according to national building material industry standard JC/T 547-2005《Pottery
Porcelain Wall or floor tile adhesive》Regulation test glue for tile performance, the results are shown in Table 1.
The different glue for tile service check results of table 1
By the performance test results of table 1 it is found that the stretching gluing original intensity of aqueous, environmental protective glue for tile, leaching in embodiment 1-10
The stretching adhesive strength after stretching adhesive strength, heat ageing after water, the stretching adhesive strength after Frozen-thawed cycled and cool set 20min
It stretches adhesive strength and is above comparative example 1-3, skidding distance is below comparative example 1-3, thus illustrates provided by the invention aqueous
The adhesivity of environment protection tile glue is good, and remains to keep higher adhesive strength after long-term use, good weatherability, it is not easily to fall off or
Sliding.
Further analysis shows that the stretching gluing original intensity of embodiment 6-9 is above embodiment 5, illustrate to increase in component
Antifoaming agent, pure-acrylic emulsion, acrylate and vinyl acetate emulsion or reinforcing agent can further increase the glueability of aqueous, environmental protective glue for tile.Embodiment
10 stretching adhesive strength is higher than embodiment 5, illustrates to be conducive to further increase using currently preferred preparation method aqueous
The performance of environment protection tile glue.
Although illustrate and describing the present invention with specific embodiment, it will be appreciated that without departing substantially from the present invention's
Many other change and modification can be made in the case of spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.
Claims (10)
1. a kind of aqueous, environmental protective glue for tile, which is characterized in that include each component of following mass fraction：30-60 parts of styrene-acrylic emulsion,
5-15 parts of kaolin, 10-25 parts of barium sulfate, recessed 1-5 parts of soil, 5-15 parts of talcum powder, 5-15 parts of calcium carbonate, 0.5-2 parts of dispersant,
0.5-1 parts of 3-8 parts of coalescents and wetting agent.
2. aqueous, environmental protective glue for tile according to claim 1, which is characterized in that include each component of following mass fraction：
35-60 parts of styrene-acrylic emulsion, 5-10 parts of kaolin, 15-25 parts of barium sulfate, recessed 1-4 parts of soil, 5-13 parts of talcum powder, calcium carbonate 5-13
Part, 0.5-1.5 parts of dispersant, 3-6 parts of coalescents and 0.5-0.8 parts of wetting agent.
3. aqueous, environmental protective glue for tile according to claim 1, which is characterized in that include each component of following mass fraction：
35-55 parts of styrene-acrylic emulsion, 7-10 parts of kaolin, 15-20 parts of barium sulfate, recessed 2-4 parts of soil, 7-13 parts of talcum powder, calcium carbonate 7-13
Part, 0.8-1.5 parts of dispersant, 4-6 parts of coalescents and 0.6-0.8 parts of wetting agent.
4. aqueous, environmental protective glue for tile according to claim 1, which is characterized in that the components also include antifoaming agent 0.5-1
Mass parts.
5. aqueous, environmental protective glue for tile according to claim 1, which is characterized in that the components also include pure-acrylic emulsion or vinegar
Acrylic emulsion 10-25 mass parts.
6. aqueous, environmental protective glue for tile according to claim 5, which is characterized in that include each component of following mass fraction：
10-25 parts of 30-45 parts of styrene-acrylic emulsion, pure-acrylic emulsion or acrylate and vinyl acetate emulsion, 5-15 parts of kaolin, 10-25 parts of barium sulfate, recessed soil 1-3
Part, 5-15 parts of talcum powder, 5-10 parts of calcium carbonate, 0.5-2 parts of dispersant, 3-8 parts of coalescents and 0.5-1 parts of wetting agent.
7. according to claim 1-6 any one of them aqueous, environmental protective glues for tile, which is characterized in that further include other auxiliary agents 0.5-
2 parts, other described auxiliary agents include at least one of reinforcing agent, preservative, mould inhibitor or hydrophober.
8. claim 1-7 any one of them aqueous, environmental protective glue for tile preparation methods, which is characterized in that include the following steps：
The each component of formula ratio is uniformly mixed.
9. the preparation method of aqueous, environmental protective glue for tile according to claim 8, which is characterized in that include the following steps：(a)
By styrene-acrylic emulsion and dispersant it is uniform latex A；
(b) latex A is uniformly mixed to obtain lotion B with kaolin and recessed soil；
(c) lotion B is uniformly mixed to obtain lotion C with barium sulfate, talcum powder and calcium carbonate successively；
(d) lotion C is uniformly mixed to obtain the aqueous, environmental protective glue for tile with coalescents and wetting agent.
10. application of the claim 1-7 any one of them aqueous, environmental protective glues for tile in tile laying or ceramic tile repairing.
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| CN201810256421.9A CN108342170B (en) | 2018-03-26 | 2018-03-26 | Water-based environment-friendly ceramic tile adhesive, preparation method and application thereof |
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| CN201810256421.9A CN108342170B (en) | 2018-03-26 | 2018-03-26 | Water-based environment-friendly ceramic tile adhesive, preparation method and application thereof |
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| CN109868955A (en) * | 2019-03-26 | 2019-06-11 | 青岛光辉彩饰有限公司 | The construction method of wall is used for after various plane materiels and cellular board are compound |
| CN111925694A (en) * | 2020-08-19 | 2020-11-13 | 武汉德邦仕建材有限公司 | Energy-saving powerful type repairing glue for tile stone system |
| CN111978891A (en) * | 2020-08-31 | 2020-11-24 | 惠州市固硕宝建材有限公司 | Small-particle-size large-plate brick binder and preparation method thereof |
| CN114605942A (en) * | 2022-01-14 | 2022-06-10 | 湖北碱克新材料有限公司 | Single-component tile back adhesive with super-weather resistance and preparation method thereof |
| CN114958251A (en) * | 2022-04-06 | 2022-08-30 | 杭州乐可适新材料科技有限公司 | Ceramic tile anti-cracking film and preparation method and application thereof |
| WO2023144538A1 (en) * | 2022-01-27 | 2023-08-03 | TopHat Industries Limited | Facade material |
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| CN114958251A (en) * | 2022-04-06 | 2022-08-30 | 杭州乐可适新材料科技有限公司 | Ceramic tile anti-cracking film and preparation method and application thereof |
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|---|---|
| CN108342170B (en) | 2020-12-15 |
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