CN106118456B - Anti-slip agent for ceramic tiles and preparation method and application thereof - Google Patents

Anti-slip agent for ceramic tiles and preparation method and application thereof Download PDF

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Publication number
CN106118456B
CN106118456B CN201610442790.8A CN201610442790A CN106118456B CN 106118456 B CN106118456 B CN 106118456B CN 201610442790 A CN201610442790 A CN 201610442790A CN 106118456 B CN106118456 B CN 106118456B
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component
preparation
ceramic tile
ceramic tiles
ceramic
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CN106118456A (en
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张中明
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Guangdong Nade New Materials Co ltd
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Guangdong Nade New Materials Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092—Polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/14—Anti-slip materials; Abrasives
    • C09K3/149—Antislip compositions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses an anti-slip agent for ceramic tiles and a preparation method and application thereof, wherein the anti-slip agent for the ceramic tiles is composed of a component A and a component B, wherein the component A comprises the following components in percentage by weight: 5 to 50 percent of organic or inorganic acid, 0.1 to 1 percent of dispersion stabilizer and the balance of water, wherein the component B comprises the following components in percentage by weight: 0.5-50% of silicone oil, 0.5-10% of silane coupling agent, 0.1-1% of dispersion stabilizer, 0.1-1% of emulsifier and the balance of water. The anti-slip agent for the ceramic tiles is used for anti-slip treatment of the surfaces of the ceramic tiles, has good anti-slip and anti-fouling effects, and simplifies the anti-slip treatment process of the surfaces of the ceramic tiles.

Description

A kind of ceramic tile antilubricant and its preparation method and application
Technical field
The invention belongs to ceramic tile surface processing technology fields, and in particular to a kind of ceramic tile antilubricant and preparation method thereof and Using.
Background technique
As the improvement of people's living standards, ceramic tile has come into huge numbers of families, in the ever-expanding process of its application range In, also there are some urgent problems to be solved, such as：Water smoothness Tai Gaoyi skidding etc. is met on surface, so exploitation meets masses The anti-skidding brick product of demand becomes mainstream.
Existing Antiskid ceramic tile be by being provided with fold striped or sags and crests in ceramic tile surface, with increase floor tile face with The frictional force of human body sole or sole prevents from skidding and fall down.This mode is more demanding to processing method, increases ceramic tile processing Difficulty.It has had already appeared at present using the super clean bright Ceramic Tiles of acid corrosion and has prepared skid-proof ceramic tile, but obtained by this method Anti-skid brick anti-fouling effect is poor, and the discharge of acid solution in process, causes and is affected to environment, causes environment Pollution.
Summary of the invention
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of ceramic tile antilubricant, the antilubricants For carrying out anti-skidding processing, good anti-skidding and anti-fouling effect to ceramic tile surface, while simplifying the anti-skidding treatment process of ceramic tile surface.
Another object of the present invention is to provide a kind of preparation methods of ceramic tile antilubricant, are obtained by the preparation method A kind of ceramic tile antilubricant.
Third object of the present invention is to provide ceramic tile antilubricant of the present invention super clean bright polishing Ceramic Tiles Application in surface anti-skid treatment.
To solve the above problems, the technical solution adopted in the present invention is as follows：
A kind of ceramic tile antilubricant, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Organic or inorganic acid 5%-50%,
Dispersion stabilizer 0.1%-1%,
Water surplus；
B component includes following component by weight percentage：
Silicone oil 0.5%-50%,
Silane coupling agent 0.5%~10%,
Dispersion stabilizer 0.1%~1%,
Emulsifier 0.1-1%
Water surplus.
As further embodiment, silane coupling agent of the present invention is selected from sodium methyl silicate, methyl trimethoxy oxygroup silicon One or more of alkane, methyltriethoxysilane and methyl triacetoxysilane.
As further embodiment, dispersion stabilizer of the present invention is amine ether type monomer or copolymerization, is selected from Ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, isomerous tridecanol polyoxyethylene ether, nonylphenol polyoxyethylene ether, Diethanol amine, triethanolamine, acrylic acid-acrylamide copolymer, polyoxyethylene ether one or more.
As further embodiment, organic/inorganic acid of the present invention be selected from chromic acid, boric acid, phosphoric acid, hydrochloric acid, sulfuric acid, One or more of oxalic acid, acetic acid.
As further embodiment, silicone oil of the present invention be selected from methyl-silicone oil, methylhydroxy silicone oil, amido silicon oil, One or more of linear silicone oils, modified silicon oil, silicon oil of low hydrogen content, high containing hydrogen silicone oil.
As further embodiment, the mass ratio of component A and B component of the present invention is 1:(1-3).
A kind of preparation method of ceramic tile antilubricant, the preparation method include the following steps：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Application of the ceramic tile antilubricant of the present invention in the anti-skidding processing of ceramic brick surface of super clean bright polishing, wherein The mass ratio of component A and B component is 1:(1-3).
Compared with prior art, the beneficial effects of the present invention are：
1. ceramic tile of the present invention with antilubricant for carrying out anti-skidding processing to ceramic tile surface, both with it is anti-skidding and antifouling Effect, while simplifying the anti-skidding treatment process of ceramic tile surface；
2. ceramic tile of the present invention in antilubricant component A and B component independently pack, when in use according to one Fixed ratio mixing, can be used for the anti-skidding processing of ceramic brick surface of super clean bright polishing.
Invention is further described in detail With reference to embodiment.
Specific embodiment
Ceramic tile antilubricant of the present invention, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Organic or inorganic acid 5%-50%,
Dispersion stabilizer 0.1%-1%,
Water surplus；
B component includes following component by weight percentage：
Silicone oil 0.5%-50%,
Silane coupling agent 0.5%~10%,
Dispersion stabilizer 0.1%~1%,
Emulsifier 0.1-1%
Water surplus.
As further embodiment, silane coupling agent of the present invention is selected from sodium methyl silicate, methyl trimethoxy oxygroup silicon One or more of alkane, methyltriethoxysilane and methyl triacetoxysilane.
As further embodiment, dispersion stabilizer of the present invention is amine ether type monomer or copolymerization, is selected from Ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, isomerous tridecanol polyoxyethylene ether, nonylphenol polyoxyethylene ether, Diethanol amine, triethanolamine, acrylic acid-acrylamide copolymer, polyoxyethylene ether one or more.
As further embodiment, organic/inorganic acid of the present invention be selected from chromic acid, boric acid, phosphoric acid, hydrochloric acid, sulfuric acid, One or more of oxalic acid, acetic acid.Consider cost with it is environmental-friendly, in the present invention, it is preferred to organic/inorganic acid be Oxalic acid or acetic acid.
In the present invention, the silicone oil in B component has good chemical stability, insulating properties and hydrophobic performance good, and has There is lesser surface tension.As further embodiment, silicone oil of the present invention be selected from methyl-silicone oil, methylhydroxy silicone oil, One or more of amido silicon oil, linear silicone oils, modified silicon oil, silicon oil of low hydrogen content, high containing hydrogen silicone oil.
As further embodiment, the mass ratio of component A and B component of the present invention is 1:(1-3).
A kind of preparation method of ceramic tile antilubricant, the preparation method include the following steps：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Application of the ceramic tile antilubricant of the present invention in the anti-skidding processing of ceramic brick surface of super clean bright polishing, wherein The mass ratio of component A and B component is 1:(1-3).In the process of surface treatment of Ceramic Tiles, first using component A to ceramic watch Face carries out anti-skidding processing, is handled again using B component later, and Ceramic Tiles is made to have anti-fouling effect.
It is specific embodiment of the present invention below, in the following embodiments, used raw material, reagent can pass through purchase Buyer's formula obtains.Embodiment 1
A kind of ceramic tile antilubricant, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Oxalic acid 50%
Diethanol amine 1%
Water surplus；
B component includes following component by weight percentage：
Methyl-silicone oil 0.5%
1% emulsifier 0.1% of methyltrimethoxysilane
Water surplus.
Preparation method is as follows：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Embodiment 2
A kind of ceramic tile antilubricant, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Acetic acid 49%
Butyl glycol ether 1%
Water surplus；
B component includes following component by weight percentage：
Methyl-silicone oil 45%
Methyltrimethoxysilane 5%
Polyoxyethylene ether 0.1%
Emulsifier 1%
Water surplus；
Preparation method is as follows：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Embodiment 3
A kind of ceramic tile antilubricant, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Sulfuric acid 5%
Triethanolamine 1%
Water surplus；
B component includes following component by weight percentage：
Amido silicon oil 25%
Methyltrimethoxysilane 5%
Triethanolamine 1%
Emulsifier 1%
Water surplus；
Preparation method is as follows：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Embodiment 4
A kind of ceramic tile antilubricant, is made of component A and B component, wherein
Component A includes following component by weight percentage：
Phosphoric acid 25%
Triethanolamine 0.5%
Water surplus；
B component includes following component by weight percentage：
50 parts of amido silicon oil
Methyltrimethoxysilane 10%
Triethanolamine 0.1%
Emulsifier 0.1%
Water surplus；
Preparation method is as follows：
1) preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2) preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3) obtained component A and B component are independently packed.
Application Example 1
The Ceramic Tiles Jing Guo super clean bright polishing are handled with antilubricant using ceramic tile described in embodiment 1, use A first Component carries out anti-skidding processing to ceramic brick surface, is then shown with B component Ceramic Tiles to carry out antifouling process；Wherein component A and B The mass ratio of component is 1:1.
Application Example 2
The Ceramic Tiles Jing Guo super clean bright polishing are handled with antilubricant using ceramic tile described in embodiment 1, first by A Component and B component mixing, then Ceramic Tiles are shown to carry out antifouling process；Wherein the mass ratio of component A and B component is 1:2.
Application Example 3
The Ceramic Tiles Jing Guo super clean bright polishing are handled with antilubricant using ceramic tile described in embodiment 1, first by A Component and B component mixing, then Ceramic Tiles are shown to carry out antifouling process；Wherein the mass ratio of component A and B component is 1:3.
The antiskid effect and anti-fouling effect of Application Example 1-3 treated Ceramic Tiles are shown in Table 1.
Table 1
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (3)

1. a kind of ceramic tile antilubricant, which is characterized in that it is made of component A and B component, wherein
Component A includes following component by weight percentage：
Oxalic acid 50%
Diethanol amine 1%
Water surplus；
B component includes following component by weight percentage：
Methyl-silicone oil 0.5%
Methyltrimethoxysilane 1%
Emulsifier 0.1%
Water surplus;
The mass ratio of component A and B component is 1:1.
2. a kind of preparation method of ceramic tile antilubricant as described in claim 1, which is characterized in that the preparation method include with Lower step：
1）The preparation of component A：Each ingredient in component A is proportionally mixed, is stirred evenly to get component A；
2）The preparation of B component proportionally mixes each ingredient in B component, stirs evenly to get B component；
3）Obtained component A and B component are independently packed.
3. application of the ceramic tile antilubricant as described in claim 1 in the anti-skidding processing of ceramic brick surface of super clean bright polishing, It is characterized in that, wherein the mass ratio of component A and B component is 1:1.
CN201610442790.8A 2016-06-17 2016-06-17 Anti-slip agent for ceramic tiles and preparation method and application thereof Active CN106118456B (en)

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Application Number Priority Date Filing Date Title
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CN106118456B true CN106118456B (en) 2018-11-27

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107476528A (en) * 2017-06-09 2017-12-15 信益陶瓷(中国)有限公司 A kind of super clean bright on-slip brick and its manufacture method
CN107325788A (en) * 2017-06-13 2017-11-07 上海世卿防滑防护科技有限公司 A kind of preparation method of floor tile antilubricant
CN107201161A (en) * 2017-06-28 2017-09-26 安徽爱弥儿环境科技有限公司 A kind of anti-skid intensifier for smooth brick masonry surface and preparation method thereof
CN107325790B (en) * 2017-07-28 2019-05-10 河北畅步地面防滑工程技术有限公司 A kind of preparation method of floor tile antilubricant
CN107880848A (en) * 2017-10-25 2018-04-06 刘彦麟 A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method
CN109251058A (en) * 2018-09-28 2019-01-22 佛山市善益科技有限公司 A kind of ceramic tile antilubricant and preparation method thereof
CN109437972A (en) * 2018-10-29 2019-03-08 李登科 On-slip agent and preparation method thereof
CN109705811B (en) * 2018-12-20 2021-06-04 上海地宝防滑防护科技有限公司 Safe environment-friendly stain-resistant anti-slip agent and preparation method thereof
CN111944485A (en) * 2020-09-14 2020-11-17 安徽双虹化工科技有限公司 Ceramic tile surface anti-slip agent and preparation method thereof
CN112063299A (en) * 2020-09-27 2020-12-11 广东粤固建材科技有限公司 Ceramic tile antifouling agent and preparation method thereof
CN113004868A (en) * 2021-02-26 2021-06-22 郝士军 Anti-slip agent and preparation method thereof
CN113636870A (en) * 2021-07-13 2021-11-12 广东富强陶瓷有限公司 Production process of antibacterial wear-resistant anti-skid glazed ceramic tile

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CN1075976A (en) * 1993-03-19 1993-09-08 张梧 Slipproofing agent
CN1699289A (en) * 2005-05-10 2005-11-23 山东师范大学 Anti-skid intensifier for smooth brick masonry surface and method for preparing same
CN104419376A (en) * 2013-08-30 2015-03-18 如皋市启润运动用品有限公司 Anti-lubricant for indoor sports floor

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Publication number Priority date Publication date Assignee Title
FR2832724B1 (en) * 2001-08-07 2004-02-06 Christian Kowalski ANTI-SLIP FOR SLIDING DEVICE SUCH AS A SURF

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075976A (en) * 1993-03-19 1993-09-08 张梧 Slipproofing agent
CN1699289A (en) * 2005-05-10 2005-11-23 山东师范大学 Anti-skid intensifier for smooth brick masonry surface and method for preparing same
CN104419376A (en) * 2013-08-30 2015-03-18 如皋市启润运动用品有限公司 Anti-lubricant for indoor sports floor

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Address after: 526000 No.7 Fenggang Road, high tech Zone, Zhaoqing City, Guangdong Province

Patentee after: GUANGDONG NADE NEW MATERIALS Co.,Ltd.

Address before: 528000 Shishan muyuan, Nanhai District, Foshan City, Guangdong Province:Jin Zigang) 528000 Shishan muyuan, Nanhai District, Foshan City, Guangdong Province

Patentee before: GUANGDONG NADE NEW MATERIALS Co.,Ltd.

CP02 Change in the address of a patent holder