WO2014183257A1 - Toning method of ceramic coating - Google Patents

Toning method of ceramic coating Download PDF

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Publication number
WO2014183257A1
WO2014183257A1 PCT/CN2013/075578 CN2013075578W WO2014183257A1 WO 2014183257 A1 WO2014183257 A1 WO 2014183257A1 CN 2013075578 W CN2013075578 W CN 2013075578W WO 2014183257 A1 WO2014183257 A1 WO 2014183257A1
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WIPO (PCT)
Prior art keywords
slurry
pigment
acid
ceramic coating
siloxane
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PCT/CN2013/075578
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French (fr)
Chinese (zh)
Inventor
李力锋
谢桂军
张蕾
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上海宜瓷龙新材料科技有限公司
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Priority to PCT/CN2013/075578 priority Critical patent/WO2014183257A1/en
Publication of WO2014183257A1 publication Critical patent/WO2014183257A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances

Definitions

  • This invention relates to the field of ceramic coatings and, more particularly, to a method of sizing ceramic coatings.
  • the coloring of the paint is generally directly grinding the pigment into a color paste together with the film-forming substance, and coloring with a color paste during the coloring, the coloring of the ceramic coating is more troublesome, because the paint can be used after being matured (reacted). Toning, otherwise the color will be different, but the coloring can not be done in one time. It takes several times to reach the desired color, so that the color period of the ceramic coating is longer, because the paint is matured once. ⁇ 16 hours, it takes a few days to adjust a color, which is very troublesome.
  • An object of the present invention is to overcome the deficiencies of the prior art and to provide a method of sizing a ceramic coating.
  • a method for coloring ceramic coatings is composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is matured, and then the pigment slurry is added for coloring to obtain ceramic coatings of various colors.
  • the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1: 1 to 5: 1 to 10, preferably 1: 3: 5.
  • the pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
  • the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
  • the aging process comprises the steps of: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:50 ⁇ 200; mixing uniformly to obtain a mixture of the acid and the siloxane, and then the acid and the siloxane.
  • the mixture is added to the filler slurry and mixed uniformly.
  • the volume ratio of the mixture of acid and siloxane to the slurry is 1:1 ⁇ 5; placed on a roller frame at 25 ° C, 120 ⁇ 140 rpm for 8 to 16 hours. It can be used afterwards; the unused filling slurry can be placed in the refrigerator for refrigerating and can be used for 3 to 7 days.
  • the acid is one or a mixture of formic acid or acetic acid
  • the volume ratio of the acid to the siloxane is 1:100;
  • the volume ratio of the mixture of acid and siloxane and the filler slurry is 1:3;
  • the siloxane is one or a mixture of methyltrimethoxysilane and methyltriethoxysilane.
  • the coloring method after adding the color paste is to first grind a filler slurry with a film-forming substance, and the filler
  • the pulp has no coloring ability, and then it is ground with water and solvent (but many pigment pastes, because most colors are adjusted with a variety of single color pastes).
  • Pigment paste when the color is used, the filler slurry is matured, and then the pigment paste is added. To do the coloring, you only need to adjust the proportion of the pigment slurry to achieve the color requirement.
  • the pigment paste does not need to be matured, so it is not necessary to mature the color paste many times as before, so that the color cycle is greatly shortened. of.
  • Example J A specific embodiment of the coloring method of a ceramic coating of the present invention is provided below.
  • Example J A specific embodiment of the coloring method of a ceramic coating of the present invention is provided below.
  • a method of coloring a ceramic coating the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
  • the volume ratio of the filler slurry to the pigment slurry is 1:3.
  • the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:2:2.
  • the pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
  • the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
  • the aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is
  • the roller frame can be used after being aged for 15 to 16 hours at 25 ° C and 120 to 140 rpm.
  • the acid is a mixture of two of formic acid or acetic acid
  • the siloxane is a mixture of methyltrimethoxysilane and methyltriethoxysilane.
  • the entire coloring time is 18 hours.
  • a method of coloring a ceramic coating the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
  • the volume ratio of the filler slurry to the pigment slurry is 1:6.
  • the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:3:5.
  • the pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
  • the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
  • the aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:100; mixing uniformly to obtain a mixture of the acid and the siloxane, and then mixing the acid and the siloxane Adding the filler slurry and mixing evenly, the volume ratio of the mixture of acid and siloxane to the filler slurry is 1:3; it can be used on the roller frame at 25 ° C, 120 ⁇ 140 rpm for 8 ⁇ 16 hours. .
  • the acid is formic acid
  • the siloxane is methyltrimethoxysilane.
  • a method of coloring a ceramic coating the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
  • the volume ratio of the filler slurry to the pigment slurry is 1:8.
  • the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1: 5:10.
  • the pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
  • the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
  • the aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:200; mixing uniformly to obtain a mixture of the acid and the siloxane, and then mixing the acid and the siloxane Adding the filler slurry and mixing evenly, the volume ratio of the mixture of acid and siloxane to the filler slurry is 1:5; it can be used on the roller frame at 25 ° C, 120 ⁇ 140 rpm for 8 ⁇ 16 hours. .
  • the acid is acetic acid
  • the siloxane is methyltriethoxysilane.
  • a method of coloring a ceramic coating the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry and the pigment slurry are simultaneously aged and then toned to obtain ceramic coatings of various colors.
  • the volume ratio of the filler slurry to the pigment slurry is 1:6.
  • the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:3:5.
  • the pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
  • the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is: 100 parts of silica sol
  • the acid is formic acid
  • the siloxane is methyltrimethoxysilane.
  • the overall toning time was 32 hours, which took a lot of time and was less efficient than in Example 2.

Abstract

A toning method of a ceramic coating. The ceramic coating comprises filler slurry and pigment slurry. The filler slurry is cured, and the pigment slurry is added to tone so as to obtain ceramic coatings in different colors. The pigment slurry comprises water, isopropanol and a pigment. The filler slurry comprises silica sol, whisker silicon, mica powder, kaolin, alumina fiber and the like. A color requirement can be met by just adjusting a proportion of the pigment slurry. The pigment slurry does not need to be cured. Therefore, a color can be toned without curing color slurry for many times as before, a toning period is greatly shortened, and production efficiency is improved.

Description

一种陶瓷涂料的调色方法  Method for coloring ceramic coating
【技术领域】 [Technical Field]
本发明涉及陶瓷涂料技术领域，具体地说，是一种陶瓷涂料的调色方 法。 说  This invention relates to the field of ceramic coatings and, more particularly, to a method of sizing ceramic coatings. Say
【背景技术】 书 BACKGROUND OF THE INVENTION
涂料的调色一般是将颜料与成膜物质一起直接研磨成色浆，调色的时 候用色浆来调色， 陶瓷涂料的调色就更麻烦， 因为涂料要熟化好 （反应) 以后才能用来调色， 否则颜色会有差异， 但是调色不是一次就能完成的， 要反复几次才可以达到要求的颜色，这样一来陶瓷涂料调色的周期就比较 长， 因为涂料熟化一次时间要 8〜16小时，这样调一种颜色就要好几天的 时间， 非常麻烦。  The coloring of the paint is generally directly grinding the pigment into a color paste together with the film-forming substance, and coloring with a color paste during the coloring, the coloring of the ceramic coating is more troublesome, because the paint can be used after being matured (reacted). Toning, otherwise the color will be different, but the coloring can not be done in one time. It takes several times to reach the desired color, so that the color period of the ceramic coating is longer, because the paint is matured once. ~16 hours, it takes a few days to adjust a color, which is very troublesome.
【发明内容】 [Summary of the Invention]
本发明的目的在于克服现有技术的不足，提供一种陶瓷涂料的调色方 法。  SUMMARY OF THE INVENTION An object of the present invention is to overcome the deficiencies of the prior art and to provide a method of sizing a ceramic coating.
本发明的目的是通过以下技术方案来实现的：  The object of the present invention is achieved by the following technical solutions:
一种陶瓷涂料的调色方法，陶瓷涂料为填料浆和颜料浆组成，其特征 在于， 将填料浆进行熟化， 然后加入颜料浆进行调色， 得到各种不同颜色 的陶瓷涂料。 所述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 为 1 : 1〜5： 1〜10， 优选为 1 : 3： 5。 A method for coloring ceramic coatings, the ceramic coating is composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is matured, and then the pigment slurry is added for coloring to obtain ceramic coatings of various colors. The pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1: 1 to 5: 1 to 10, preferably 1: 3: 5.
所述的颜料由多种颜料组成， 因为颜色为多种单一颜料调配出来，颜 料为市售的各种颜料。  The pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
所述的填料浆为硅溶胶， 晶须硅，云母粉，高岭土，氧化铝纤维组成， 其中， 原料的质量份数为：  The filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
硅溶胶 100份  Silica sol 100 parts
晶须硅 10〜20份  Whisker silicon 10~20 parts
云母粉 5〜10份  Mica powder 5~10 parts
高岭土 1〜5份  Kaolin 1~5 parts
氧化铝纤维 1〜30份  Alumina fiber 1~30 parts
所述的熟化， 其工艺为： 将酸加入硅氧垸中， 酸和硅氧垸的体积比为 1： 50〜200； 混合均匀得到酸和硅氧垸的混合物， 然后将酸和硅氧垸的 混合物加入填料浆混合均匀， 酸和硅氧垸的混合物和填料浆的体积比为 1： 1〜5； 放到滚架上在 25 °C下， 120〜140转 /分熟化 8〜16小时后即可 使用； 使用不完的填料浆可以放入冰箱冷藏， 可以使用 3〜7天。  The aging process comprises the steps of: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:50~200; mixing uniformly to obtain a mixture of the acid and the siloxane, and then the acid and the siloxane. The mixture is added to the filler slurry and mixed uniformly. The volume ratio of the mixture of acid and siloxane to the slurry is 1:1~5; placed on a roller frame at 25 ° C, 120~140 rpm for 8 to 16 hours. It can be used afterwards; the unused filling slurry can be placed in the refrigerator for refrigerating and can be used for 3 to 7 days.
所述的酸为甲酸或者乙酸中的一种或者二种混合；  The acid is one or a mixture of formic acid or acetic acid;
所述的酸和硅氧垸的体积比为 1 : 100；  The volume ratio of the acid to the siloxane is 1:100;
所述的酸和硅氧垸的混合物和填料浆的体积比为 1 : 3；  The volume ratio of the mixture of acid and siloxane and the filler slurry is 1:3;
所述的硅氧垸为甲基三甲氧基硅垸，甲基三乙氧基硅垸中的一种或者 二种混合。  The siloxane is one or a mixture of methyltrimethoxysilane and methyltriethoxysilane.
与现有技术相比， 本发明的积极效果是：  Compared with the prior art, the positive effects of the present invention are:
采用后添加色浆的调色方法是先用成膜物质研磨一份填料浆， 填料 浆是没有着色能力的， 然后再用水和溶剂研磨（而是很多颜料浆， 因为多 数颜色是用很多种单色浆调出来的） 颜料浆， 调色的时候熟化好填料浆， 然后加入颜料浆进行调色， 只需调整颜料浆的比例就可以达到颜色的要 求，颜料浆是不需要熟化的，所以就不需要像之前那样熟化很多次色浆进 行调色了， 这样调色周期会大大缩短的。 The coloring method after adding the color paste is to first grind a filler slurry with a film-forming substance, and the filler The pulp has no coloring ability, and then it is ground with water and solvent (but many pigment pastes, because most colors are adjusted with a variety of single color pastes). Pigment paste, when the color is used, the filler slurry is matured, and then the pigment paste is added. To do the coloring, you only need to adjust the proportion of the pigment slurry to achieve the color requirement. The pigment paste does not need to be matured, so it is not necessary to mature the color paste many times as before, so that the color cycle is greatly shortened. of.
【具体实施方式】 【detailed description】
以下提供本发明一种陶瓷涂料的调色方法的具体实施方式。 实施例 J  A specific embodiment of the coloring method of a ceramic coating of the present invention is provided below. Example J
一种陶瓷涂料的调色方法，陶瓷涂料为填料浆和颜料浆组成，其特征 在于， 将填料浆进行熟化， 然后加入颜料浆进行调色， 得到各种不同颜色 的陶瓷涂料。  A method of coloring a ceramic coating, the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
所述的填料浆和颜料浆的体积比为 1 : 3。  The volume ratio of the filler slurry to the pigment slurry is 1:3.
所述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 为 1 : 2： 2。  The pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:2:2.
所述的颜料由多种颜料组成， 因为颜色为多种单一颜料调配出来，颜 料为市售的各种颜料。  The pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
所述的填料浆为硅溶胶， 晶须硅，云母粉，高岭土，氧化铝纤维组成， 其中， 原料的质量份数为：  The filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
硅溶胶 100份  Silica sol 100 parts
晶须硅 10份  Whisker silicon 10 parts
云母粉 5份 高岭土 1份 Mica powder 5 parts 1 part of kaolin
氧化铝纤维 1份  Alumina fiber 1 part
所述的熟化， 其工艺为： 将酸加入硅氧垸中， 酸和硅氧垸的体积比为 The aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is
1： 50； 混合均匀得到酸和硅氧垸的混合物， 然后将酸和硅氧垸的混合物 加入填料浆混合均匀， 酸和硅氧垸的混合物和填料浆的体积比为 1 : 1 ; 放到滚架上在 25°C下， 120〜140转 /分熟化 8〜16小时后即可使用。 1: 50; mixing to obtain a mixture of acid and siloxane, then adding a mixture of acid and siloxane to the slurry, and mixing the mixture of acid and siloxane with a volume ratio of 1:1; The roller frame can be used after being aged for 15 to 16 hours at 25 ° C and 120 to 140 rpm.
所述的酸为甲酸或者乙酸中的二种混合；  The acid is a mixture of two of formic acid or acetic acid;
所述的硅氧垸为甲基三甲氧基硅垸， 甲基三乙氧基硅垸的二种混合。 整个调色时间为 18小时。 实施例 2  The siloxane is a mixture of methyltrimethoxysilane and methyltriethoxysilane. The entire coloring time is 18 hours. Example 2
一种陶瓷涂料的调色方法，陶瓷涂料为填料浆和颜料浆组成，其特征 在于， 将填料浆进行熟化， 然后加入颜料浆进行调色， 得到各种不同颜色 的陶瓷涂料。  A method of coloring a ceramic coating, the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
所述的填料浆和颜料浆的体积比为 1 : 6。  The volume ratio of the filler slurry to the pigment slurry is 1:6.
所述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 为 1 : 3： 5。  The pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:3:5.
所述的颜料由多种颜料组成， 因为颜色为多种单一颜料调配出来，颜 料为市售的各种颜料。  The pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
所述的填料浆为硅溶胶， 晶须硅，云母粉，高岭土，氧化铝纤维组成， 其中， 原料的质量份数为：  The filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
硅溶胶 100份  Silica sol 100 parts
晶须硅 15份 云母粉 7份 Whisker silicon 15 parts Mica powder 7 parts
高岭土 3份  Kaolin 3 parts
氧化铝纤维 15份  Alumina fiber 15 parts
所述的熟化， 其工艺为： 将酸加入硅氧垸中， 酸和硅氧垸的体积比为 1： 100； 混合均匀得到酸和硅氧垸的混合物， 然后将酸和硅氧垸的混合物 加入填料浆混合均匀， 酸和硅氧垸的混合物和填料浆的体积比为 1 : 3 ; 放到滚架上在 25°C下， 120〜140转 /分熟化 8〜16小时后即可使用。  The aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:100; mixing uniformly to obtain a mixture of the acid and the siloxane, and then mixing the acid and the siloxane Adding the filler slurry and mixing evenly, the volume ratio of the mixture of acid and siloxane to the filler slurry is 1:3; it can be used on the roller frame at 25 ° C, 120~140 rpm for 8~16 hours. .
所述的酸为甲酸；  The acid is formic acid;
所述的硅氧垸为甲基三甲氧基硅垸。  The siloxane is methyltrimethoxysilane.
整个调色时间为 20小时。 实施例 3  The entire coloring time is 20 hours. Example 3
一种陶瓷涂料的调色方法，陶瓷涂料为填料浆和颜料浆组成，其特征 在于， 将填料浆进行熟化， 然后加入颜料浆进行调色， 得到各种不同颜色 的陶瓷涂料。  A method of coloring a ceramic coating, the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then a pigment slurry is added for coloring to obtain ceramic coatings of various colors.
所述的填料浆和颜料浆的体积比为 1 : 8。  The volume ratio of the filler slurry to the pigment slurry is 1:8.
所述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 为 1 : 5： 10。  The pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1: 5:10.
所述的颜料由多种颜料组成， 因为颜色为多种单一颜料调配出来，颜 料为市售的各种颜料。  The pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
所述的填料浆为硅溶胶， 晶须硅，云母粉，高岭土，氧化铝纤维组成， 其中， 原料的质量份数为：  The filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is:
硅溶胶 100份 晶须硅 20份 100 parts of silica sol 20 parts of whisker silicon
云母粉 10份  Mica powder 10 parts
高岭土 5份  Kaolin 5 parts
氧化铝纤维 30份  Alumina fiber 30 parts
所述的熟化， 其工艺为： 将酸加入硅氧垸中， 酸和硅氧垸的体积比为 1： 200； 混合均匀得到酸和硅氧垸的混合物， 然后将酸和硅氧垸的混合 物加入填料浆混合均匀， 酸和硅氧垸的混合物和填料浆的体积比为 1 : 5； 放到滚架上在 25 °C下， 120〜140转 /分熟化 8〜16小时后即可使用。  The aging process is as follows: adding an acid to the siloxane, the volume ratio of the acid to the siloxane is 1:200; mixing uniformly to obtain a mixture of the acid and the siloxane, and then mixing the acid and the siloxane Adding the filler slurry and mixing evenly, the volume ratio of the mixture of acid and siloxane to the filler slurry is 1:5; it can be used on the roller frame at 25 ° C, 120~140 rpm for 8~16 hours. .
所述的酸为乙酸；  The acid is acetic acid;
所述的硅氧垸为甲基三乙氧基硅垸。  The siloxane is methyltriethoxysilane.
整个调色时间为 20小时。 对比例 J  The entire coloring time is 20 hours. Comparative example J
一种陶瓷涂料的调色方法， 陶瓷涂料为填料浆和颜料浆组成， 其特 征在于， 将填料浆和颜料浆进行同时熟化， 然后进行调色， 得到各种不同 颜色的陶瓷涂料。  A method of coloring a ceramic coating, the ceramic coating being composed of a filler slurry and a pigment slurry, characterized in that the filler slurry and the pigment slurry are simultaneously aged and then toned to obtain ceramic coatings of various colors.
所述的填料浆和颜料浆的体积比为 1 : 6。  The volume ratio of the filler slurry to the pigment slurry is 1:6.
所述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 为 1 : 3： 5。  The pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:3:5.
所述的颜料由多种颜料组成， 因为颜色为多种单一颜料调配出来，颜 料为市售的各种颜料。  The pigment is composed of a plurality of pigments because the color is formulated for a plurality of single pigments, and the pigments are various commercially available pigments.
所述的填料浆为硅溶胶， 晶须硅，云母粉，高岭土，氧化铝纤维组成， 其中， 原料的质量份数为： 硅溶胶 100份 The filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the mass fraction of the raw material is: 100 parts of silica sol
晶须硅 15份  Whisker silicon 15 parts
云母粉 7份  Mica powder 7 parts
高岭土 3份  Kaolin 3 parts
氧化铝纤维 15份  Alumina fiber 15 parts
所述的酸为甲酸； The acid is formic acid;
所述的硅氧垸为甲基三甲氧基硅垸。  The siloxane is methyltrimethoxysilane.
整个调色时间为 32小时， 比实施例 2多花很多时间， 效率较低。 The overall toning time was 32 hours, which took a lot of time and was less efficient than in Example 2.

Claims

权 利 要 求 书 Claim
1. 一种陶瓷涂料的调色方法， 陶瓷涂料为填料浆和颜料浆组成， 其 特征在于， 将填料浆进行熟化， 然后加入颜料浆进行调色， 得到各种不同 颜色的陶瓷涂料。 A method for coloring a ceramic coating, the ceramic coating comprising a filler slurry and a pigment slurry, characterized in that the filler slurry is aged, and then the pigment slurry is added for coloring to obtain ceramic coatings of various colors.
2. 如权利要求 1所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比为 1 : 1〜5： 1〜10。  2. A method of tinting a ceramic coating according to claim 1, wherein the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1: 1~ 5: 1 to 10.
3. 如权利要求 1所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的颜料浆为水， 异丙醇和颜料组成， 水， 异丙醇和颜料的质量比 1 : 3：  3. A method of tinting a ceramic coating according to claim 1, wherein the pigment slurry is composed of water, isopropanol and pigment, and the mass ratio of water, isopropanol and pigment is 1:3:
4. 如权利要求 1所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的填料浆为硅溶胶， 晶须硅， 云母粉， 高岭土，氧化铝纤维组成，其中， 原料的质量份数为： The method for coloring a ceramic coating according to claim 1, wherein the filler slurry is composed of silica sol, whisker silicon, mica powder, kaolin, alumina fiber, wherein the quality of the raw material The number of copies is:
硅溶胶 100份  Silica sol 100 parts
晶须硅 10〜20份  Whisker silicon 10~20 parts
云母粉 5〜10份  Mica powder 5~10 parts
高岭土 1〜5份  Kaolin 1~5 parts
氧化铝纤维 1〜30份。  Alumina fiber 1 to 30 parts.
5. 如权利要求 1所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的熟化，其工艺为：将酸加入硅氧垸中，酸和硅氧垸的体积比为 1 : 50〜 200； 混合均匀得到酸和硅氧垸的混合物， 然后将酸和硅氧垸的混合物加 入填料浆混合均匀， 酸和硅氧垸的混合物和填料浆的体积比为 1 : 1〜5； 放到滚架上在 25°C下， 120〜140转 /分熟化 8〜16小时后即可使用。5. The method of grading a ceramic coating according to claim 1, wherein the aging is carried out by adding an acid to the siloxane, and the volume ratio of the acid to the siloxane is 1: 50~200; mixed uniformly to obtain a mixture of acid and siloxane, and then a mixture of acid and siloxane is added to the filler slurry to mix uniformly, the volume ratio of the mixture of acid and siloxane and the filler slurry is 1: 1~5; Put it on the roller frame and use it at 25 ° C for 120 to 140 rpm for 8 to 16 hours.
6. 如权利要求 5所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的酸为甲酸或者乙酸中的一种或者二种混合。 The method of coloring a ceramic coating according to claim 5, wherein the acid is one or a mixture of formic acid or acetic acid.
7. 如权利要求 5所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的酸和硅氧垸的体积比为 1 : 100。  7. A method of tinting a ceramic coating according to claim 5, wherein the volume ratio of the acid to the siloxane is 1:100.
8. 如权利要求 5所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的酸和硅氧垸的混合物和填料浆的体积比为 1 : 3。  8. A method of tinting a ceramic coating according to claim 5, wherein the volume ratio of the mixture of acid and siloxane to the filler slurry is 1:3.
9. 如权利要求 5所述的一种陶瓷涂料的调色方法， 其特征在于， 所 述的硅氧垸为甲基三甲氧基硅垸，甲基三乙氧基硅垸中的一种或者二种混  The method for coloring a ceramic coating according to claim 5, wherein the siloxane is one of methyltrimethoxysilane and methyltriethoxysilane. Two kinds of mixing
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