A kind of energy storage luminescent ceramics coating and preparation method thereof
Technical field
The present invention is belonging to field of new, relates to the preparation of a kind of energy storage luminescent ceramics coating, is particularly applicable in traffic
Safety devices field, such as bus platform, station, subway station etc..
Background technology
Along with the development of China Transportation Industry, traffic safety facilities is also required that stricter.Environment-friendly and energy-efficient product
Become the important need of social development.
In recent years, the development of ceramic coating is applied in multiple fields, and it is wear-resisting, high temperature resistant, high intensity, super thin
The advantages such as water can to a certain degree replace traditional enamel product.The autonomous characteristics of luminescence of energy-accumulating luminous powder is transported in traffic the most
Defeated field many aspects are applied, and it has obtained fully agreeing of all circles from main light emission, environmental protection and energy saving, the performance such as pollution-free
Fixed.The most do not occur that the plurality of advantages with ceramic coating simultaneously can also be from the product of main light emission, literary composition
Offering and also have no report in patent, this characteristic can play a significant role in the underground installations such as subway station, has city widely
Field prospect.
Summary of the invention
It is an object of the invention to: a kind of energy storage luminescent ceramics coating of exploitation so that it is there is the characteristic of ceramic coating simultaneously,
There is again the autonomous illumination effect of energy-conserving and environment-protective.And it is simple with manufacture craft to meet production, it is suitable for the need of large-scale production
Will be with the requirement of client.
To achieve these goals, the present invention provides following technical scheme:
A kind of energy storage luminescent ceramics coating, is formed, including the raw material of following weight portion by three component configurations:
Component A:
B component:
Component C
Energy-accumulating luminous powder 50-90 part
Solvent 0-50 part.
Preferably, described colloidal silica is 1-30% with the concentration of nano alumina sol, and particle diameter is 20-
60nm。
Preferably, described filler is one or more combinations in quartz, mica powder, talcum powder, kaolin, titanium dioxide
Form.
Preferably, described catalyst is acid-base modifier, in glacial acetic acid, formic acid, acetic acid, stearic acid, oleic acid
Plant or multiple combination.
Preferably, described organic siliconresin is in methoxyl group trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane
One or more through modified resin.
Preferably, described binding agent is methyl methacrylate, butyl acrylate, acrylonitrile emulsion, organosilicone elastic
One or more in body, vinegar the third adhesive mix.
Preferably, described auxiliary agent include in dispersant, levelling agent, wetting agent, defoamer one or more combination and
Becoming, described organic solvent is that one or more in ethanol, methyl alcohol, acetone, ethyl acetate, ethylene glycol mix, described
Solvent be that one or more in running water, deionized water, ethanol, acetone mix.
Preferably, described energy-accumulating luminous powder is long afterglow class luminescent powder, in aluminate serial, silicate series
Kind or multiple be composited.
Preferably, the preparation method of described energy storage luminescent ceramics coating, when specifically comprising the following steps that preparation the most respectively by A,
B, component C configure, and are then uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally by (A+B): C=1:0.1-1:0.8 weight
Amount ratio adds C, cures 4-6h with 20-150r/min speed scroll on twin-roll machine, forms product.
Preferably, the construction method of described energy storage luminescent ceramics coating, specifically comprise the following steps that
A. paint is joined
It is uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally by (A+B): C=1:0.1-1:0.8 weight ratio adds C,
On twin-roll machine, the speed scroll with 20~150r/m cures 4~6h;
B. the surface of workpiece processes
Workpiece, after oil removing, carries out blasting treatment, removes the rusty stain on surface, spot;The workpiece of blasting treatment is before applying
5~10min are preheated at the environment of 50~60 DEG C;
C. construct
Take gas or airless spraying, or electrostatic spraying mode is by energy storage luminescent ceramics spray painting to workpiece;
D. solidify
Under the conditions of 150~220 DEG C, solidify 10~30min.
The profitable effect of the present invention is:
1, the energy storage luminescent ceramics coating of preparation has high temperature resistant, wear-resisting, super-hydrophobic, high intensity, noninflammability, is suitable for many necks
Territory is applied;
2, the energy storage luminescent ceramics coating of preparation can be from main light emission, energy-conserving and environment-protective.
3, production technology is simple, without complicated procedures of forming, produces constant product quality, has a good application prospect.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described:
Embodiment 1
A kind of energy storage luminescent ceramics coating, it is characterised in that formed by three components configurations, former including following weight portion
Material:
Component A:
B component:
Component C
50 parts of energy-accumulating luminous powder
Solvent 1 part.
Embodiment 2
A kind of energy storage luminescent ceramics coating, it is characterised in that formed by three components configurations, former including following weight portion
Material:
Component A:
B component:
Component C
70 parts of energy-accumulating luminous powder
Solvent 20 parts.
Embodiment 3
A kind of energy storage luminescent ceramics coating, it is characterised in that formed by three components configurations, former including following weight portion
Material:
Component A:
B component:
Component C
90 parts of energy-accumulating luminous powder
Solvent 50 parts.
Wherein, in embodiment 1-3:
Described colloidal silica is 1-30% with the concentration of nano alumina sol, and particle diameter is 20-60nm.
Described filler is that one or more in quartz, mica powder, talcum powder, kaolin, titanium dioxide combine.
Described catalyst is acid-base modifier, for one or more in glacial acetic acid, formic acid, acetic acid, stearic acid, oleic acid
Combination.
Described organic siliconresin is the one in methoxyl group trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane
Or it is multiple through modified resin.
Described binding agent is methyl methacrylate, butyl acrylate, acrylonitrile emulsion, elastomer silicone, vinegar third
One or more in adhesive mix.
Described auxiliary agent includes that one or more in dispersant, levelling agent, wetting agent, defoamer combine, described
Organic solvent be that one or more in ethanol, methyl alcohol, acetone, ethyl acetate, ethylene glycol mix, described solvent is
One or more in running water, deionized water, ethanol, acetone mix.
Described energy-accumulating luminous powder is long afterglow class luminescent powder, for the one in aluminate serial, silicate series or many
Plant and be composited.
Embodiment 4
The preparation method of the energy storage luminescent ceramics coating in embodiment 1-3, when specifically comprising the following steps that preparation the most respectively by A,
B, component C configure, and are then uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally by (A+B): C=1:0.1-1:0.8 weight
Amount ratio adds C, cures 4-6h with 20-150r/min speed scroll on twin-roll machine, forms product.
Embodiment 5
The construction method of the energy storage luminescent ceramics coating in embodiment 1-3, specifically comprises the following steps that
A. paint is joined
It is uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally by (A+B): C=1:0.1-1:0.8 weight ratio adds C,
On twin-roll machine, the speed scroll with 20~150r/m cures 4~6h;
B. the surface of workpiece processes
Workpiece, after oil removing, carries out blasting treatment, removes the rusty stain on surface, spot;The workpiece of blasting treatment is before applying
5~10min are preheated at the environment of 50~60 DEG C;
C. construct
Take gas or airless spraying, or electrostatic spraying mode is by energy storage luminescent ceramics spray painting to workpiece;
D. solidify
Under the conditions of 150~220 DEG C, solidify 10~30min.
Embodiment 6
There is the luminescent properties of excellence in order to better illustrate this energy storage luminescent ceramics coating, by the energy-accumulating luminous pottery of preparation
Porcelain coating is coated on steel plate and tests, and test result is as shown in table 1.
The twilight sunset test of table 1 reflex reflection energy-accumulating luminous paint