CN105176329B - A kind of LED UV woodenware transparent repair priming paint and preparation method - Google Patents
A kind of LED UV woodenware transparent repair priming paint and preparation method Download PDFInfo
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- CN105176329B CN105176329B CN201510675143.7A CN201510675143A CN105176329B CN 105176329 B CN105176329 B CN 105176329B CN 201510675143 A CN201510675143 A CN 201510675143A CN 105176329 B CN105176329 B CN 105176329B
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Abstract
A kind of LED UV woodenware transparent repair priming paint and preparation method, the priming paint are made up of the component of following percentage by weight:Epocryl 20~30%;Pure acrylate resin 5~10%;Specific functionality acrylate 8~12%;Monomer 25~30%;Light trigger 8~10%;Anti-settling agent 0.5% 1%;Wetting dispersing agent 0.3 0.5%;Filler 11~20%;Filler is made up of by accounting for described filler the talcum powder and 5 8% transparent powder for accounting for coating gross weight 6 12%;Specific functionality resin is the functional acrylic resin that low energy solidifies;The epoxy acrylic resin is standard Bisphenol-A epoxy acrylate;The pure acrylate resin is the pure acrylate resin of trifunctional;The monomer is propylene glycol diacrylate;The light trigger is 2; 4; 6 trimethyl benzoyl diphenyl base phosphine oxides, have the advantages that efficiently (paint film can be achieved through LED UV ultraviolet lights 3~5 seconds to be fully cured), good low energy curing performance, easy construction, transparency is high, recoatability is good, fillibility is good, grinability is good, the discharge of environmentally friendly VOC free.
Description
Technical field
The present invention relates to LED-UV woodenware transparent repair priming paint.
Background technology
At present at finishing work scene, because the imprudence or other factorses of workmen make already installed woodenware
Gadget surface, which is scratched or encountered, small depression, and field patch recovery, traditional side must just be carried out by such case occur
Method is all to carry out repairing filling using PU paints or PE paints, and the drying varniss time of traditional PU paint PE paints long (needs
Want 5-8 hours paint films to dry, carry out next process), and cause this period workmen to have nothing to do, can only be at which
In wait, so bring many inconveniences to the engineering that works to tight deadlines of scene, be easy for the delay for causing engineering to hand over the phase.
UV paints currently used in the market all have efficiently (can be achieved paint film in 3~5 seconds completely solid through ultraviolet light
Change) the characteristics of, typically all by high-pressure sodium lamp luminous radiation, carry out cross-linking and curing reaction and complete paint film forming.High-pressure sodium lamp
Because power is high (generally 80W/cm), with strong light intensity brightness, can produce ozone when very strong heat radiation and work and
Supporting cooling system is needed, therefore is unpractical in engineering construction onsite application, and the appearance of LED-UV lamps compensate for this
One defect, LED-UV lamps have power low (general portable LED-UV curing be 9~12W) heat radiation is small when working (impinges upon
Workpiece surface just increases by 3 degree or so of temperature, and 20 degree or so of workpiece surface temperature of conventional high-pressure mercury lantern festival increase), ozone free
Produce, availability is high, small volume is easy to maintenance, meet environmental protection and safety requirements.Therefore needing badly can be carried out using LED-UV lamps
The special woodenware transparent repair coating of LED-UV of solidification, to be constructed in engineering site.
The content of the invention
The technical problem to be solved in the present invention is to provide the UV woodenware transparent repair priming paint of LED-UV a kind of, the UV woodenware
Transparent repair priming paint has efficiently (paint film can be achieved within 3~5 seconds through LED-UV ultraviolet lights to be fully cured), low energy solidification
Performance is good, easy construction, transparency is high, recoatability is good, fillibility is good, grinability is good, the advantage of environmentally friendly VOC free discharge.
In order to solve the above-mentioned technical problem, the invention provides a kind of LED-UV woodenware transparent repair priming paint, by as follows
The component composition of percentage by weight:
Epocryl 20~30%;
Pure acrylate resin 5~10%;
Specific functionality acrylate 8~12%;
Monomer 25~30%;
Light trigger 8~10%;
Anti-settling agent 0.5%-1%;
Wetting dispersing agent 0.3-0.5%;
Filler 11~20%;
The filler is by accounting for described filler by accounting for coating gross weight 6-12% talcum powder and 5-8% transparent powder group
Into;
The specific functionality resin is the functional acrylic resin that low energy solidifies;
The epoxy acrylic resin is standard Bisphenol-A epoxy acrylate;
The pure acrylate resin is the pure acrylate resin of trifunctional;
The monomer is propylene glycol diacrylate;
The light trigger is 2,4,6- trimethylbenzoy-dipheny phosphine oxides.
Preferably, the LED-UV woodenware is with the weight percent content of transparent repair priming paint each component:
Epocryl 25~29%;
Pure acrylate resin 5~6%;
Specific functionality acrylate 10~12%;
Monomer 26~30%;
Light trigger 8~10%;
Anti-settling agent 0.5%-0.7%;
Wetting dispersing agent 0.3-0.5%;
Filler 11~20%;
The filler is by accounting for described filler by accounting for coating gross weight 10-12% talcum powder and 6-8% transparent powder group
Into
Preferably, the pure acrylate resin of the trifunctional is Heng Guang companies 1700.
Preferably, the functional acrylic resin of the low energy solidification is the ADDITOL of cyanogen specialization workTM LED 01。
Preferably, the anti-settling agent is aerosil.
Preferably, the wetting dispersing agent is EFKA-4010.
Present invention also offers the above-mentioned LED-UV woodenware preparation method of transparent repair priming paint, comprise the following steps:
Step one, it is slow by propylene oxide successively according to the proportioning under conditions of daylight or ultraviolet light is avoided
Acid ester resin, pure acrylate resin, the functional acrylic resin of low energy solidification, monomer, light trigger, anti-settling agent, profit
Hygroscopic water powder is stirred to well mixed, keeps mixed material temperature to be less than 50 DEG C in whipping process, mixing speed is 500-8000
Rev/min, continue 5 minutes;
Step 2, talcum powder and transparent powder are added according to the proportioning, with 800-1000 revs/min of mixing speed scattered 10
Minute to fineness is less than 60um, so as to obtain the LED-UV woodenware transparent repair priming paint of the present invention.
The special woodenware transparent repair priming paint of LED-UV of the present invention is at engineering construction scene, for decoration woodenware gadget surface
The defects such as the scratch and collision of paint film, are repaired using blade coating or the method brushed, are then sent by LED-UV lamps
Several seconds of ultraviolet light, you can with fully crosslinked film-forming, it is if necessary to repeat to brush, then middle to polish, can
First to brush a LED-UV woodenware transparent repairs priming paint (30~50g/ ㎡), with several seconds of LED-UV light irradiations, consolidate paint film
After change, continue to brush LED-UV woodenware makes paint in several seconds with transparent repair priming paint (30~50g/ ㎡), then with LED-UV light irradiations
After film solidification, then carry out sand milling below, dedusting, the process of upper finish paint.Existed using LED-UV woodenware with transparent repair priming paint
Engineering construction scene has easy construction, and high-efficiency environment friendly, security is good;The properties of product are superior, with low energy curing performance
It is good, fillibility is good, transparency is high, easy polish, can recoat, the advantages of VOC free volatilizees.
Embodiment
Below by embodiment, technical scheme is further described, each embodiment is only as preferred real
Mode is applied to illustrate technical scheme, limitation of the invention is not constituted.
The various components of the present invention use existing commercially available prod.
In following embodiment, the epoxy acrylic resin is standard Bisphenol-A epoxy acrylate, with most of activity
The functional acrylic resin of monomer, modified epoxy acrylate resin and low energy solidification can dissolve each other completely.
The pure acrylate resin is the pure acrylate resin of trifunctional, and it has, and weatherability is good, curing rate is fitted
In, adhesive force is good, adjustable UV resins recoatability advantage, the present invention uses Jiangmen city Heng Guang new materials Co., Ltd
1700 models (hereinafter referred to as " Heng Guang companies 1700 ").
The specific functionality resin is the functional acrylic resin that low energy solidifies, and is that one kind aims at more low energy
The resin of LED-UV photocurings varnish and paint system design, the resin opens a kind of new paragon of improvement surface cure, draws
Enter faster flowing water producing line, be highly suitable for Lower Energy Consumption Curing system, the present invention uses the ADDITOL of cyanogen specialization workTM LED
01。
The monomer is propylene glycol diacrylate (DPGDA), and the monomer has viscosity low, and diluting power is good, solidification speed
The features such as spending fast.
The wetting dispersing agent uses EFKA-4010.
It is 2,4,6- trimethylbenzoy-diphenies phosphine oxide (TPO) that the light trigger, which is,.
The filler is made up of the transparent powder of the talcum powder and 5-8% that account for coating gross weight 6-12%.
Embodiment 1
The UV woodenware transparent repair priming paint that the LED-UV of the present embodiment is special is made up of the component of following percentage by weight:Ring
Oxypropylene acid ester resin 28%, pure acrylate resin 5%, specific functionality resin 12%, monomer 28%, light trigger 8%,
Anti-settling agent 0.50%, wetting dispersing agent 0.50%, talcum powder 10% and transparent powder 8%.
The UV woodenware transparent repair priming paint preparation methods that the LED-UV of the present embodiment is special are as follows:
Step one, it is slow by propylene oxide successively according to said ratio under conditions of daylight or ultraviolet light is avoided
Acid ester resin, pure acrylate resin, the functional acrylic resin of low energy solidification, monomer, light trigger, anti-settling agent, profit
Hygroscopic water powder is stirred to well mixed, keeps mixed material temperature to be less than 50 DEG C in whipping process, mixing speed is 500-8000
Rev/min, continue 5 minutes;
Step 2, talcum powder and transparent powder are added according to the proportioning, with 800-1000 revs/min of mixing speed scattered 10
Minute to fineness is less than 60um, so as to obtain the LED-UV woodenware transparent repair priming paint of the present invention.Service check standard and inspection
Result is surveyed as shown in the corresponding data of embodiment 1 in table one.
Embodiment 2
The UV woodenware transparent repair priming paint that the LED-UV of the present embodiment is special is made up of the component of following percentage by weight:Ring
Oxypropylene acid ester resin 25%, pure acrylate resin 6%, specific functionality acrylate 10%, monomer 30%, light draw
Send out agent 10%, anti-settling agent 0.6%, wetting dispersing agent 0.4%, talcum powder 12% and transparent powder 6%.
According to the said ratio of the present embodiment, the preparation method described in embodiment 1 is repeated, you can obtain the LED- of the present invention
UV woodenware transparent repair priming paint.Service check standard and testing result are as shown in the corresponding data of embodiment 2 in table one.
Embodiment 3
The UV woodenware transparent repair priming paint that the LED-UV of the present embodiment is special is made up of the component of following percentage by weight:Ring
Oxypropylene acid ester resin 29%, pure acrylate resin 6%, specific functionality resin 10%, monomer 26%, light trigger 9%,
Anti-settling agent 0.70%, wetting dispersing agent 0.30%, talcum powder 11%, transparent powder 8%.
According to the said ratio of the present embodiment, the preparation method described in embodiment 1 is repeated, you can obtain the LED- of the present invention
UV woodenware transparent repair priming paint.Service check standard and testing result are as shown in the corresponding data of embodiment 3 in table one.
The special woodenware transparent repair priming paint of LED-UV of the various embodiments described above has properties of product superior, efficiently, low energy
Curing performance is good, and fillibility is good, and transparency is high, easily polishing, can recoat, the advantages of VOC free volatilizees.
Table one
Embodiment described above only expresses embodiments of the present invention, and it describes more specific and detailed, but can not
Therefore the limitation to the scope of the claims of the present invention is interpreted as, as long as the skill obtained using the form of equivalent substitution or equivalent transformation
Art scheme, all should fall within the scope and spirit of the invention.
Claims (3)
1. a kind of LED-UV woodenware transparent repair priming paint, it is characterised in that be made up of the component of following percentage by weight:
Epocryl 20~30%;
Pure acrylate resin 5~10%;
Specific functionality acrylate 8~12%;
Monomer 25~30%;
Light trigger 8~10%;
Anti-settling agent 0.5%-1%;
Wetting dispersing agent 0.3-0.5%;
Filler 11~20%;
Described filler is made up of the transparent powder of the talcum powder and 5-8% that account for coating gross weight 6-12%;
The specific functionality acrylate is the functional acrylic resin that low energy solidifies;
The epoxy acrylic resin is standard Bisphenol-A epoxy acrylic resin;
The pure acrylate resin is the pure acrylate resin of trifunctional;
The monomer is propylene glycol diacrylate;
The light trigger is 2,4,6- trimethylbenzoy-dipheny phosphine oxides;
The functional acrylic resin of the low energy solidification is the ADDITOL of cyanogen specialization workTMLED01;
The anti-settling agent is aerosil;
The wetting dispersing agent is EFKA-4010.
2. LED-UV woodenware transparent repair priming paint according to claim 1, it is characterised in that:
The LED-UV woodenware is with the weight percent content of transparent repair priming paint each component:
Epocryl 25~29%;
Pure acrylate resin 5~6%;
Specific functionality acrylate 10~12%;
Monomer 26~30%;
Light trigger 8~10%;
Anti-settling agent 0.5%-0.7%;
Wetting dispersing agent 0.3-0.5%;
Filler 11~20%;
The filler is made up of the transparent powder of the talcum powder and 6-8% that account for coating gross weight 10-12%.
3. the preparation method of LED-UV woodenware transparent repair priming paint described in claim 1~2 any one, it is characterised in that bag
Include following steps:
Step one, it is slow by epoxy acrylate successively according to the proportioning under conditions of daylight or ultraviolet light is avoided
Resin, pure acrylate resin, the functional acrylic resin of low energy solidification, monomer, light trigger, anti-settling agent, wetting point
Powder is stirred to well mixed, keeps mixed material temperature to be less than 50 DEG C in whipping process, mixing speed be 500-8000 turn/
Point, continue 5 minutes;
Step 2, talcum powder and transparent powder are added according to the proportioning, scattered 10 minutes with 800-1000 revs/min of mixing speed
It is less than 60um to fineness, so as to obtain described LED-UV woodenware transparent repair priming paint.
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CN106349890A (en) * | 2016-08-30 | 2017-01-25 | 河北晨阳工贸集团有限公司 | Woodware primer applicable to solidification of handheld LED-UV light source and preparing method |
CN109401424A (en) * | 2018-09-20 | 2019-03-01 | 永修县利君科技有限公司 | A kind of cured high temperature sintering varnish of LED-UV cold light source and preparation method thereof |
CN109439130A (en) * | 2018-09-29 | 2019-03-08 | 成都展辰涂料有限公司 | A kind of LED-UV woodenware real color chipping primer and preparation method thereof |
CN111718643A (en) * | 2020-07-22 | 2020-09-29 | 成都巴德士涂料有限公司 | Spraying transparent primer for LED-UV woodware paster and preparation method thereof |
CN112812662A (en) * | 2021-02-24 | 2021-05-18 | 东莞大宝化工制品有限公司 | LED (light-emitting diode) curing high-filling vacuum spraying primer and preparation method thereof |
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CN102532967B (en) * | 2011-12-17 | 2014-08-06 | 东莞隽思印刷有限公司 | Rapid curing coating applicable to UV-LED (Ultraviolet-Light-Emitting Diode) light source and preparation method thereof |
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