CN108707400A - A kind of fishing gear water paint and preparation method thereof - Google Patents
A kind of fishing gear water paint and preparation method thereof Download PDFInfo
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- CN108707400A CN108707400A CN201810291484.8A CN201810291484A CN108707400A CN 108707400 A CN108707400 A CN 108707400A CN 201810291484 A CN201810291484 A CN 201810291484A CN 108707400 A CN108707400 A CN 108707400A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/544—Polycondensates of aldehydes with nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Abstract
The invention discloses a kind of fishing gear water paints and preparation method thereof, are related to water paint field.It is prepared by the raw material of following parts by weight：35-50 parts of water-based hydroxyl acrylic emulsion, 5-8 parts of curing agent, 5-8 parts of amino resins, 2-5 parts of cosolvent, 1-5 parts of organic silicone powder, 1-5 parts of nano aluminium oxide, 0.5-2 parts of nano zircites, 0.05-0.5 parts of nano zine oxide, 0-10 parts of fluorescent powder, 0.1-0.2 parts of pH adjusting agent, 0.1-0.2 parts of antifoaming agent, 2-5 parts of coalescents, 0.3-0.5 parts of dispersant, 0.3-0.5 parts of substrate wetting agents, 5-10 parts of deionized water, 0.5-1.0 parts of thickener.The coating has good water resistance, is suitable for contact water for a long time；Coating surface energy is low, has the effect of persistently sterilizing；Also certain automatically cleaning effect, the markings such as anti-fingerprint, greasy dirt, holding surface are bright and clean；And there is smooth feel, gorgeous appearance.
Description
Technical field
The present invention relates to water paint fields, and in particular to bamboo and wood, high molecular material fishing gear coating.
Background technology
Currently, since long-time contacts water, fishing gear is mostly oil paint with coating, and VOC content is high, with environmental consciousness
Enhancing, the water paint of low VOC content are gradually received by people.The present invention provides a kind of fishing gear water paint, by reasonable
Collocation, enable coating be suitable for timber, plastics, glass fiber reinforced plastic surface, have preferable appearance, good water resistance and suppression
Bacterium effect (fungus-resistant).
VOC meanings：Volatile organic compounds (volatile organic compounds)；VOC is that volatility is organic
The English abbreviation of compound, harmful chemical substance (except heavy metal) refers to just VOC in usually said wall finiss.
These volatile organic compounds include the substances such as formaldehyde, ammonia, ethylene glycol, esters.When VOC reaches a certain concentration, can cause
The symptoms such as headache, Nausea and vomiting, weak even cause twitch, stupor, injury liver, kidney, brain and nerveous system when serious
System, causes the serious consequences such as failure of memory.And common coating is solvent reducible coatings, can be released under room temperature toluene, benzene,
A variety of volatile organic compounds such as dimethylbenzene.Environment is also polluted, photochemical pollution, region gray haze, acid rain etc. are aggravated
The compound dirt of air, and bring health hazard to people.In recent years, environment increasingly deteriorates, and haze is increasingly severe, and society is to environmental protection
Requirement it is higher and higher, the coating for developing environmental protection has become the common recognition of people.Wherein coating Water-borne modification is as a kind of effective
Approach, but even water paint still contain a certain amount of VOC, so it is ultralow to develop function admirable, VOC content
Coating becomes the developing direction of coating industry.
Invention content
The technical problem to be solved in the present invention is to provide a kind of fishing gear water paints and preparation method thereof, which has
Good water resistance is suitable for contact water for a long time；Coating surface energy is low, has the effect of persistently sterilizing；It is also certain from
Cleaning effect, the markings such as anti-fingerprint, greasy dirt, holding surface are bright and clean；And there is smooth feel, gorgeous appearance.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of fishing gear water paint, by as follows
The raw material of parts by weight is prepared：It is prepared by the raw material of following parts by weight：35-50 parts of water-based hydroxyl acrylic emulsion,
5-8 parts of curing agent, 5-8 parts of amino resins, 2-5 parts of cosolvent, 1-5 parts of organic silicone powder, 1-5 parts nano oxidized
Aluminium, 0.5-2 part nano zircite, 0.05-0.5 parts of nano zine oxide, 0-10 parts of fluorescent powder, 0.1-0.2 parts of pH are adjusted
Agent, 0.1-0.2 parts of antifoaming agent, 2-5 parts of coalescents, 0.3-0.5 parts of dispersant, 0.3-0.5 parts of substrate wetting agents,
5-10 parts of deionized water, 0.5-1.0 parts of thickener.
Preferably, water-based hydroxyl acrylic emulsion is the A2695 of Bayer, mainly for the preparation of certainly dry or force drying
Coating system, coating have very high chemical-resistant.Hardness of paint film after solidification is high, and flexibility is good, and gloss is high, richness
Height, and there is good weatherability, light resistance and excellent chemical-resistant.
Preferably, curing agent is the hydrophilic modifying aliphatic polymeric isocyanate of isophorone diisocyanate (IPDI)；Such as,
(Bayhydur) 401-70 of Bayer, Bayhydur 401-70 and A2695, which is added, to form a film, and can improve aqueous dual-component
The performance of polyurethane coating.
Preferably, amino resins is Chongqing Jian Feng Hao Kang Chemical Co., Ltd.s Haminol 303w amino resins, is improved
The flexibility that can have also been obtained while hardness.
Preferably, coalescents be Guangzhou Yu Tai Chemical Industry Science Co., Ltd propylene glycol phenyl ethers environmentally friendly ordor removing type at
The mixture of both alcohol ester-12 coalescents of film auxiliary agent A F and U.S. Yi Shiman, wherein coalescents AF and alcohol ester-12
Weight ratio is 1:1 to 1:2.
Preferably, cosolvent is propylene glycol methyl ether acetate；Such as, the propylene glycol methyl ether acetate of Dow chemical industry is
The less toxic advanced industrial solvent of function admirable is mainly used for dissolving cured dose in of the invention.
Preferably, organic silicone powder is polymethylsilsesquioxane；Such as, the BT-9273 of Guangzhou Ba Tai Chemical Co., Ltd.s
Silicone powder.Using the high-performance organic inorganic hybridization material of true spherical structure polysiloxane polymer class made of special process technology
The advantages of material has insoluble insoluble thermosetting property, integrates inorganic particle and organic powder has good lubricity, also
Pigment can be promoted to disperse, prevent pigment and particle agglomerate.Main performance is shown：(1) temperature in use of coating can be made to increase；
(2) mechanical property of coating can be improved；(3) can make to prevent the sedimentations such as metal powder from reuniting；(4) good water-fast, resistant effect
Fruit has automatically cleaning and scrub performance.Hydrophobic film, oleophobic stain, anti-slide mark, anti-fingerprint marking and other effects can be improved.
Preferably, nano aluminium oxide is the nano aluminium oxide that cut new material Co., Ltd is protected in Nanjing, with excellent
The performances such as wear-resisting, hardening, high temperature resistant and insulation are widely used in wear-resistant paint, modified resin, and price is relatively cheap.
Preferably, nano oxidized pick is the TGP-M100 nano zircite (nano oxygens of Nanjing Tian Hang new materials Co., Ltd
Change zirconium for grinding-material, coating, structural ceramics, plays the performances such as wear-resisting, anticorrosive, high temperature resistant.Performance is better than nano oxidized
Aluminium, effect is similar, raising coating hardness, fire resistant flame retardant performance, wear-resisting property, corrosion resistance etc., but price, so with
Amount is few).
Preferably, nano zine oxide is the nanometer Zinc oxide powder (nano oxygen of the dense nanosecond science and technology Co., Ltd of Nantong darcy
Change zinc volume is fluffy, grain size is small, large specific surface area, and dosage is few, and antibacterial sterilization ability is excellent, compared with bactericidal nano-silver：Nanometer
Silver-colored bactericidal effect is notable, but it also has damage for benign cell, and zinc is human essential elements, safe and healthy；Nano silver is easy
Discoloration, influences coloured light, nano zine oxide then avoids this disadvantage；Nano silver category contact sterilization, and nano zine oxide not only contacts
Formula is sterilized, and good antibacterial sterilization effect can be still played under conditions of Guang Heshui).
Preferably, dispersant is polyester modification polyphosphoric acid esters dispersant.Such as the AFCONA- of (angstrom husband's Kona) AFCONA
5010.AFCONA-5010 aims at inorganic particulate and the dispersant with high efficiency that designs, also has in hydroxy acrylic acid dual-component coating
It is catalyzed the effect of reaction.
Preferably, substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class.Such as Tego-100 of (enlightening is high) TEGO,
One or both of the BYK346 of (Bick) BYK.Two kinds of auxiliary agents can play the role of slip agent, levelling agent, make paint film
Up to seeming more plentiful.
Fluorescent powder is commercially available aqueous fluorescent powder, if the fluorescent powder of Langfang City Hang Fan trade Co., Ltds is (according to customer requirement
Color is adjusted).
Preferably, thickener is polyurethane-type thickener.Such as the polyurethane-type thickener PS202 of Ning Baidi.
Preferably, antifoaming agent is the mixture that phosphoric acid lipid hydrophobicity defoams both foam inhibitor and organic silicon antifoaming agent.
Phosphoric acid lipid hydrophobicity defoams foam inhibitor, as (in aqueous body coating system, a small amount of addition can't by the 941PL of MOUSSEX companies
Paint film appearance is influenced, and has good defoaming suds effect)；Organic silicon antifoaming agent, such as defoaming of (BIC Corp) BYK are made
Used additives BYK-028 or BYK024, two types antifoaming agent are used in mixed way, and phosphoric acid lipid hydrophobicity defoams foam inhibitor and organosilicon
Class antifoaming agent weight ratio is 1:1 or so.
The preparation method of above-mentioned fishing gear water paint, includes the following steps：
Step a, first by 1/2 deionized water, 1/2 pH adjusting agent, dispersant, 1/2 antifoaming agent, nano oxidized
Aluminium, nano zircite, nano zine oxide, organic silicone powder, fluorescent powder are mixed, and stirring obtains mixture；
Step b, add successively under stirring condition water-based hydroxyl acrylic emulsion, remaining 1/2 deionized water, amino resins,
Coalescents, 1/2 pH adjusting agent, 1/2 antifoaming agent, substrate wetting agents；Then mixture obtained by step a, stirring is added；
Thickener is added, -4 glasss of viscosity of painting of stirring, adjustment viscosity to 25 DEG C are 60-90s, as component A；
Curing agent is dissolved in cosolvent under drying condition, is sealed as B component by step c；
Step d, in use, component A, B component are used in mixed way, wherein the weight ratio of component A and B component is 5:1.
It is using advantageous effect caused by above-mentioned technical proposal：
(1) present invention selects the coalescents of water-based hydroxyl acrylic emulsion and higher boiling environmental protection, obtains high glaze, high dress
The aqueous lacquer coat of decorations property, high hydrophobicity, wherein the water paint VOC≤60g/L prepared, smell are very low, than existing coating
It is more environmentally-friendly, prevent pollution environment；
(2) present invention selects the coalescents AF (242.7 DEG C of boiling point DEG C) and alcohol ester-12 coalescents of higher boiling environmental protection
(247 DEG C of boiling point), two kinds of coalescents are environmentally friendly auxiliary agent, are the strong solvents of emulsion polymer.Emulsion paint can effectively be reduced
Minimum film formation temperature, improve the scrub resistance and film quality of emulsion paint.It can be obviously improved filming performance, improve the light of paint film
Damp degree, intensity and anti-grinded hardness index and enhancement levelability；Excellent wet film performance, raising weatherability and color developing；
(3) it is polymethylsilsesquioxane that the present invention, which selects organic silicone powder, in terms of filming performance：Reach good resistance to
Water, resistant effect have automatically cleaning and scrub performance, can easily wipe a variety of paintings such as dust-free chalk, dust and tea stain, greasy dirt
Crow substance or household stains, pollution wiping persistence is good (automatically cleaning characteristic, reach lotus leaf effect) repeatedly.In stability and use
Property aspect：With good lubricity, moreover it is possible to promote pigment to disperse, prevent pigment and particle agglomerate.Main performance is shown：1)
The temperature in use of coating can be made to increase；2) mechanical property of coating can be improved；3) can make to prevent the sedimentations such as powder from reuniting；
(4) the hydrophilic modifying aliphatic polymeric isocyanate conduct of isophorone diisocyanate (IPDI) is used in the present invention
Curing agent greatly improves the hardness and gloss of coating, is swift in response, fast at mould；
(5) present invention uses amino resins, is reacted with hydroxy acrylic acid under high temperature, forms fine and close coating；
(6) two kinds of present invention collocation isocyanates, amino resins curing agent, low temperature partial reaction and high-temperature part reaction,
Make coating that there is better film forming and compactness；
(7) paint coatings of the present invention have preferable wear-resisting, fungistatic effect；
(8) select nano zircite, nano aluminium oxide as filler in the present invention, compared with similar products, in hardness, attached
Put forth effort, have great raising in terms of pollution resistance and weatherability；The use of nano aluminium oxide and nano oxidized pick, both improves coating
Hardness, and the water resistance of coating can be improved；
(9) present invention by introduce nano zine oxide achieve the purpose that it is lasting, mildly sterilize, and to the skin of contact pierce
Swash small；
(10) by the present invention in that with fluorescent powder, make coating that there is gorgeous color and luminous effect；
(11) this coating has good water resistance, is suitable for contact water for a long time；Coating surface energy is low, has and persistently kills
The effect of bacterium；Also certain automatically cleaning effect, the markings such as anti-fingerprint, greasy dirt, holding surface are bright and clean；And there is smooth hand
Sense, gorgeous appearance.The present invention enables coating to be suitable for timber, plastics, glass fiber reinforced plastic surface, has by reasonably arranging in pairs or groups
Preferable appearance, good water resistance and fungistatic effect (fungus-resistant), and in particular to bamboo and wood, the fishing gear use of high molecular material
Coating extends fishing gear usage time.
Specific implementation mode
The present invention will be further described in detail with reference to the specific embodiments；
The type of part material used in the embodiment of the present invention, manufacturer are as follows：
Water-based hydroxyl acrylic emulsion is the A2695 of Bayer；
Curing agent is (Bayhydur) 401-70 of Bayer；
Amino resins is Chongqing Jian Feng Hao Kang Chemical Co., Ltd.s Haminol 303w amino resins；
Coalescents are the environmentally friendly ordor removing type coalescents of the propylene glycol phenyl ethers of Guangzhou Yu Tai Chemical Industry Science Co., Ltd
The mixture of both alcohol ester-12 coalescents of AF and U.S. Yi Shiman, wherein the weight ratio of coalescents AF and alcohol ester-12
It is 1:1 to 1:2；
Cosolvent is the propylene glycol methyl ether acetate of Dow chemical industry；
Organic silicone powder is the BT-9273 silicone powders of Guangzhou Ba Tai Chemical Co., Ltd.s；
Nano aluminium oxide is that cut new material Co., Ltd nano aluminium oxide is protected in Nanjing；
Nano oxidized pick is the TGP-M100 nano zircites of Nanjing Tian Hang new materials Co., Ltd；
Nano zine oxide is the nanometer Zinc oxide powder of the dense nanosecond science and technology Co., Ltd of Nantong darcy；
Dispersant is the AFCONA-5010 of the AFCONA of angstrom husband's Kona；
Substrate wetting agents are one or both of the BYK346 of the Tego-100 of (enlightening is high) TEGO, (Bick) BYK；
Fluorescent powder is commercially available aqueous fluorescent powder, if the fluorescent powder of Langfang City Hang Fan trade Co., Ltds is (according to customer requirement
Color is adjusted)；
Thickener is the polyurethane-type thickener PS202 of Ning Baidi；
Antifoaming agent is the mixture that phosphoric acid lipid hydrophobicity defoams both foam inhibitor and organic silicon antifoaming agent.Phosphoric acid lipid
Hydrophobicity defoams the 941PL that foam inhibitor is MOUSSEX companies；The defoaming effect that organic silicon antifoaming agent is BIC Corp BYK helps
Agent BYK-028 or BYK024, two types antifoaming agent are used in mixed way, and phosphoric acid lipid hydrophobicity defoaming foam inhibitor and organic silicon disappear
Infusion weight ratio is 1:1.
Table 1 is the raw material proportioning of the embodiment of the present invention 1-3：
Table 1
The preparation method of above-mentioned fishing gear water paint, includes the following steps：
Step a, according to the raw material proportioning, first by 1/2 deionized water, 1/2 pH adjusting agent, dispersant, 1/2
Antifoaming agent, nano aluminium oxide, nano zircite, nano zine oxide, organic silicone powder, fluorescent powder are mixed, with 1000r/min
Speed stir 15 minutes, obtain mixture；
Step b adds water-based hydroxyl acrylic acid successively according to the raw material proportioning under the speed stirring condition of 500r/min
Lotion, remaining 1/2 deionized water, amino resins, coalescents, 1/2 pH adjusting agent, 1/2 antifoaming agent, base material wetting
The speed of agent, 1000r/min stirs 10 minutes；Then mixture obtained by step a is added, the speed of 600r/min stirs 10 points
Clock；Thickener is added, the speed of 500r/min stirs 10 minutes, and -4 glasss of viscosity of painting of adjustment viscosity to 25 DEG C are 60-90s, are made
For component A；
Curing agent is dissolved in cosolvent under drying condition, is sealed as B component by step c；
Step d, in use, component A, B component are used in mixed way, wherein the weight ratio of component A and B component is 5:1.
The test result of fishing gear water paint made from above-described embodiment 1-3 is shown in Table 2：
Table 2
Fishing gear of the present invention has good water resistance with water paint, is suitable for contact water for a long time；Coating surface can it is low,
Have the effect of persistently sterilizing；Also certain automatically cleaning effect, the markings such as anti-fingerprint, greasy dirt, holding surface are bright and clean；And have
There are smooth feel, gorgeous appearance.
The present invention enables coating to be suitable for timber, plastics, glass fiber reinforced plastic surface, has preferable by reasonably arranging in pairs or groups
Appearance, good water resistance and fungistatic effect (fungus-resistant), and in particular to bamboo and wood, high molecular material fishing gear coating,
Extend fishing gear usage time.
Claims (10)
1. a kind of fishing gear water paint, which is characterized in that be prepared by the raw material of following parts by weight：35-50 parts aqueous
Hydroxyl acrylic emulsion, 5-8 parts of curing agent, 5-8 parts of amino resins, 2-5 parts of cosolvent, 1-5 parts of organic silicone powder,
1-5 parts of nano aluminium oxide, 0.5-2 parts of nano zircites, 0.05-0.5 parts of nano zine oxide, 0-10 parts of fluorescent powder,
0.1-0.2 parts of pH adjusting agent, 0.1-0.2 parts of antifoaming agent, 2-5 parts of coalescents, 0.3-0.5 parts of dispersant, 0.3-
0.5 part of substrate wetting agents, 5-10 parts of deionized water, 0.5-1.0 parts of thickener.
2. a kind of fishing gear water paint according to claim 1, it is characterised in that the water-based hydroxyl acrylic emulsion
For the A2695 of Bayer.
3. a kind of fishing gear water paint according to claim 1, it is characterised in that the curing agent is isophorone two
The hydrophilic modifying aliphatic polymeric isocyanate of isocyanates IPDI.
4. a kind of fishing gear water paint according to claim 1, it is characterised in that the amino resins is Chongqing Jian Feng
Hao Kang Chemical Co., Ltd.s Haminol 303w amino resins.
5. a kind of fishing gear water paint according to claim 1, it is characterised in that the coalescents are that Guangzhou space is safe
The alcohol ester-12 of the environmentally friendly ordor removing type coalescents AF and U.S. Yi Shiman of the propylene glycol phenyl ethers of Chemical Industry Science Co., Ltd form a film
The mixture of both auxiliary agents, wherein the weight ratio of coalescents AF and alcohol ester-12 is 1:1 to 1:2.
6. a kind of fishing gear water paint according to claim 1, it is characterised in that the cosolvent is propylene glycol monomethyl ether
Acetate.
7. a kind of fishing gear water paint according to claim 1, it is characterised in that the organic silicone powder is poly- methyl
Silsesquioxane.
8. a kind of fishing gear water paint according to claim 1, it is characterised in that the dispersant is poly- for polyester modification
Phosphoric acid ester dispersant.
9. a kind of fishing gear water paint according to claim 1, it is characterised in that the substrate wetting agents change for polyethers
The polysiloxane-based wetting agent of property；Thickener is polyurethane-type thickener；Antifoaming agent is that phosphoric acid lipid hydrophobicity defoams foam inhibitor
With the mixture of both organic silicon antifoaming agent.
10. according to a kind of preparation method of fishing gear water paint of claim 1-9 any one of them, which is characterized in that packet
Include following steps：
Step a, first by 1/2 deionized water, 1/2 pH adjusting agent, dispersant, 1/2 antifoaming agent, nano aluminium oxide, receive
Rice zirconium oxide, nano zine oxide, organic silicone powder, fluorescent powder are mixed, and are stirred, are obtained mixture；
Step b adds water-based hydroxyl acrylic emulsion, remaining 1/2 deionized water, amino resins, film forming under stirring condition successively
Auxiliary agent, 1/2 pH adjusting agent, 1/2 antifoaming agent, substrate wetting agents；Then mixture obtained by step a, stirring is added；It is added
- 4 glasss of viscosity of painting of thickener, stirring, adjustment viscosity to 25 DEG C are 60-90s, as component A；
Curing agent is dissolved in cosolvent under drying condition, is sealed as B component by step c；
Step d, in use, component A, B component are used in mixed way, wherein the weight ratio of component A and B component is 5:1.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810291484.8A CN108707400A (en) | 2018-04-03 | 2018-04-03 | A kind of fishing gear water paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810291484.8A CN108707400A (en) | 2018-04-03 | 2018-04-03 | A kind of fishing gear water paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108707400A true CN108707400A (en) | 2018-10-26 |
Family
ID=63867099
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810291484.8A Pending CN108707400A (en) | 2018-04-03 | 2018-04-03 | A kind of fishing gear water paint and preparation method thereof |
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| CN110761082A (en) * | 2019-11-08 | 2020-02-07 | 上海工程技术大学 | Polysulfonamide composite fabric and preparation method and application thereof |
| CN113956731A (en) * | 2021-11-22 | 2022-01-21 | 浙江优艺雅涂料有限公司 | Primer for aluminum plate curtain wall, preparation method of primer, composite paint for aluminum plate curtain wall and preparation method of aluminum plate curtain wall |
| CN115537108A (en) * | 2022-10-12 | 2022-12-30 | 安徽衡光新材料科技有限公司 | Water-based nanoscale anticorrosive paint for watch shells and preparation method thereof |
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