CN107033747A - A kind of automatically cleaning sealing wax - Google Patents
A kind of automatically cleaning sealing wax Download PDFInfo
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- CN107033747A CN107033747A CN201710139167.XA CN201710139167A CN107033747A CN 107033747 A CN107033747 A CN 107033747A CN 201710139167 A CN201710139167 A CN 201710139167A CN 107033747 A CN107033747 A CN 107033747A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of automatically cleaning sealing wax, include the component of following parts by weight：Water-base resin：35 50 parts of aqueous acrylic modified epoxy emulsions, 5 20 parts of amino resins；Pigment：3 20 parts of titanium dioxides, 19 parts of expansion light powder, 1 part of 10 parts of organic silicone powder；Auxiliary agent：0.1 0.2 parts of PH conditioning agents, 0.1 0.2 parts of defoamers, 25 parts of coalescents, 1 part 10 parts efficient lotus leaf water-repelling agents, 0.3 0.5 parts of wetting dispersing agents, 0.3 0.5 parts of substrate wetting agents, 5 10 parts of deionized waters, 0.5 1.0 parts of thickeners.The automatically cleaning sealing wax of the present invention is the aqueous light industry sealing wax of zero VOC, by improving the hydrophobicity of coating, to reduce area and the time that coating is contacted with water, is finally reached the purpose for improving water-resistant coating energy.Present invention also offers a kind of application by the automatically cleaning sealing wax stated in lampshade or metal and a kind of lampshade, the lampshade scribbles described automatically cleaning sealing wax.
Description
Technical field
The present invention, which is related to, belongs to technical field of coatings, more particularly, to a kind of automatically cleaning sealing wax, applied to lampshade or metal.
Background technology
Either in house life or working environment, light fixture is a kind of essential illumination and decorating apparatus.But
It is due to the influence for the carelessness and environment thought, without cleaning light fixture can be made to descend slowly and lightly one layer of dust using light fixture for a long time, both shadow
Sound is attractive in appearance, and illuminating effect is reduced again.Particularly pendant lamp, more add the difficulty of scouring.The present invention prepares a kind of self-cleaning
Lampshade coating, by reducing the surface tension of coating, reach reduction coating surface dust spot glues glutinous purpose, so as to subtract
The worry brought is cleaned less.
VOC implications：VOC (volatile organic compounds)；VOC is that volatility is organic
Harmful chemical substance (except heavy metal) just refers to VOC in the English abbreviation of compound, usually said wall finiss.
These VOCs include the materials such as formaldehyde, ammonia, ethylene glycol, esters.When VOC reaches finite concentration, it can cause
The symptom such as headache, Nausea and vomiting, weak, even triggers tic, stupor, injury liver, kidney, brain and nerveous system when serious
System, causes the serious consequences such as failure of memory.And conventional coating be can discharge under solvent reducible coatings, normal temperature toluene, benzene,
A variety of VOCs such as dimethylbenzene.Environment is also polluted, photochemical pollution, region gray haze, acid rain etc. is aggravated
The compound dirt of air, gives people to bring health hazard again.In recent years, environment increasingly deteriorates, and haze is increasingly severe, and society is to environmental protection
Requirement more and more higher, the coating of development environmental protection has become the common recognition of people.Wherein coating Water-borne modification is as a kind of effective
Approach, but even water paint, appoint and so contain a certain amount of VOC, so it is ultralow to develop function admirable, VOC content
Coating turns into the developing direction of coating industry.
The content of the invention
It is an object of the invention to provide a kind of automatically cleaning sealing wax, it is the aqueous light industry sealing wax of zero VOC, and by carrying
The hydrophobic performance of high coating, to reduce area and the time that coating is contacted with water, is finally reached the mesh for improving water-resistant coating energy
's.
In order to solve the above technical problems, the present invention is adopted the following technical scheme that：
A kind of automatically cleaning sealing wax, includes the component of following parts by weight：
Water-base resin：35-50 parts of aqueous acrylic modified epoxy emulsion, 5-20 parts of amino resins；
Pigment：3-20 parts of titanium dioxides, 1 part of -9 parts of expansion light powder, 1 part of -10 parts of organic silicone powder；
Auxiliary agent：It is 0.1-0.2 parts of PH conditioning agents, 0.1-0.2 parts of defoamer, 2-5 parts of coalescents, 1 part -10 parts high
Imitate lotus leaf water-repelling agent, 0.3-0.5 parts of wetting dispersing agent, 0.3-0.5 parts of substrate wetting agents, 5-10 parts of deionized water,
0.5-1.0 parts of thickener.
Further, the aqueous acrylic modified epoxy emulsion is the WPA5324 with moral.(compared with similar products, soon
Speed hardness increase, initial stage water-tolerant, excellent rustless property, certain weatherability, machinery and storage stability it is good, it is resistance to freeze
Melt).
Further, the amino resins is amino tree (the methyl-etherified amino containing high imino group of U.S.'s cyanogen spy Cymel 325
Resin, just can rapid curing without strong acid catalyst).
Further, described titanium dioxide is rutile class titanium dioxide, e.g., R706 the or TPIAQUE companies of E.I.Du Pont Company
R-980 in a kind or two kinds.
Further, it is that the U.S. steps figure expansion light powder TOSPEARL 105 to expand light powder, and it has excellent lubricity, produces soft
It is soft, smooth, soyeux to feel, it is added in ming tree fat, or surface, it can make, through light diverging, to be used as reduction reflected light
Photodiffusion material is used, and compared with serial titanium oxide barium sulfate of the inorganic matter usually used etc., is had high-penetration, is reduced light
The waste of penetrance, the effect for improving definition.
Further, the coalescents are net taste type coalescents AF (the Guangzhou space Thailandizations of environmental protection of propylene glycol phenyl ethers
Work Science and Technology Ltd.) and alcohol ester-12 coalescents (U.S. Yi Shiman).(the two ratio 1:1 to 1:2).
Further, described efficient lotus leaf water-repelling agent be organosilicon, acrylic polymer, inorganic raw material reaction and
Into microemulsion, the efficient lotus leaf water-repelling agents of HY-4021 of such as river Chemical Industry Science Co., Ltd of Chengdu million.
(agent is novel organosilicon, the efficient lotus leaf water-repelling agent of acrylic polymer, inorganic raw material reaction,
With dual hydrophobic mechanism, the macromolecule filming of organic matter had not only been breathed freely but also the guarantor of hydrophobic together with building the surface of basal plane and being formed
Cuticula, generates hydrophobic group, produces waterproofing function, falls rainwater and slid in surface of wall as falling on lotus leaf, no
Stay water mark.The permeability of inorganic matter crosslinks reaction with building internal layer alkaline matter, and its product is by capillary in building
Channel blockage, thus reach block water, not permeable purpose, the globule rolls landing still as on lotus leaf, and double protection can make to refuse
Water effect is taken stopgap measures and effected a permanent cure, and is reached long-term hydrophobic.)
Further, described organic silicone powder is polymethylsilsesquioxane, e.g., Guangzhou Ba Tai Chemical Co., Ltd.s
BT-9273 silicone powders.
(the high-performance organic inorganic hybridization for the true spherical structure polysiloxane polymer class being made of special process technology
Material, with insoluble insoluble thermosetting, integrates the advantage of inorganic particle and organic powder, with good lubricity,
Pigment can also be promoted to disperse, pigment and particle agglomerate is prevented.Main performance is shown：(1) can increase the temperature in use of coating
Plus；(2) mechanical property of coating can be improved；(3) it can make coating that there is significant delayed combustion characteristic)
Further, the pH value conditioning agent is one or both of dimethylethanolamine, multifunctional assistant AMP-95.
Further, the defoamer is the deaeration of polyether siloxane copolymer class defoamer, such as (Di Gao companies) TEGO
Make used additives Tego-902w, organic silicon defoamer, such as (BIC Corp) BYK froth breaking effect auxiliary agent B two kinds of mixing of YK-028
Thing, ratio is 1:1 or so.
Further, the wetting dispersing agent is polyester modification polyphosphoric acid esters dispersant, such as (angstrom husband's Kona) AFCONA
AFCONA-5010.The dispersant with high efficiency that AFCONA-5010 aims at titanium dioxide and designed, also has catalysis in amino-stoving varnish
The effect of reaction.
Further, described substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class, such as (enlightening is high) TEGO
One or both of Tego-245, (angstrom husband's Kona) AFCONA AFCONA-3031.Two kinds of auxiliary agents can play increasing and slide
Agent, the effect of levelling agent, reach paint film and seem that comparison is plentiful.
Further, the thickener be polyurethane-type thickener, such as Ning Baidi polyurethane-type thickener PS202, and
Alkali soluble rises type thickener, and such as Ning Baidi alkali soluble rises two kinds of mixtures of type thickener ASE60, and proportion is 1:1 to 2:1.
Present invention also offers a kind of preparation method of automatically cleaning sealing wax, comprise the following steps：
Step a, according to the raw material proportioning, first by pH value conditioning agent, the wetting and dispersing of the deionized water of half, half
Agent, the defoamer of half, titanium dioxide, expansion light powder and organic silicone powder etc. are mixed, and 15 points are stirred with 500r/min speed
Clock；
Step b, processing is ground by grinder, and fineness is qualified stand-by less than 25 microns；
Step c, according to the raw material proportioning, aqueous acrylic emulsion is added in pot of getting the raw materials ready, with 500r/min speed
Degree stirring 5 minutes；Then the remainder of part environmentally friendly solvent, the pH value conditioning agent of half, water is graded and is added in pot of getting the raw materials ready,
900r/min speed is stirred 10 minutes；Then add successively remaining defoamer, levelling agent, water-repelling agent, substrate wetting agents and
Amino resins, 1200r/min speed is stirred 10 minutes；Then step b mixture, 1200r/min speed stirring are added
10 minutes；Sequentially add thickener, 1000r/min speed is stirred 10 minutes, adjustment viscosity is to qualified.(the regulation viscosity
For 25 DEG C -4 glasss of viscosity of painting, described -4 glasss of viscosity of painting are 70-90s).
From the coalescents of water soluble acrylic acid dispersion, and higher boiling environmental protection, obtain high glaze, high-decoration, height and dredge
Aqueous aqueous lacquer coat, wherein the water paint VOC≤20g/L prepared, smell is very low, prevents from polluting environment.
It is novel organosilicon, acrylic polymer, the efficient lotus leaf water-repelling agent of inorganic raw material reaction, is had
Dual hydrophobic mechanism, the macromolecule filming of organic matter had not only been breathed freely but also the protection of hydrophobic together with building the surface of basal plane and being formed
Film, generates hydrophobic group, produces waterproofing function, falls rainwater and slid in surface of wall as falling on lotus leaf, do not stayed
Water mark.The permeability of inorganic matter crosslinks reaction with building internal layer alkaline matter, and its product leads to capillary in building
Road is blocked, thus reach block water, not permeable purpose, the globule rolls landing still as on lotus leaf, and double protection can make water repellent
Effect is taken stopgap measures and effected a permanent cure, and is reached long-term hydrophobic.Make coating that there are good lotus leaf double hydrophobicity, self-cleaning, hydrophobicity, waterproofs
The performance such as property, resistance to soiling, scrub resistance.
Coalescents AF (242.7 DEG C of boiling point DEG C) and alcohol ester-12 coalescents (her scholar of the U.S. from higher boiling environmental protection
It is graceful) agent (247 DEG C of boiling point), two kinds of coalescents are environmentally friendly auxiliary agent, are the strong solvents of emulsion polymer.Can effectively it reduce
The MFT of emulsion paint, improves the scrub resistance and film quality of emulsion paint.Filming performance can be obviously improved, paint is improved
Glossiness, intensity and the anti-grinded hardness index and enhancement levelability of film；Excellent wet film performance, raising weatherability and color developing.
The high-performance organic inorganic hybridization for the true spherical structure polysiloxane polymer class being made of special process technology
Material, with insoluble insoluble thermosetting, integrates the advantage of inorganic particle and organic powder, with good lubricity,
Pigment can also be promoted to disperse, pigment and particle agglomerate is prevented, strengthen the self-cleaning of coating, hydrophobicity, water proofing property, resistance to soiling, resistance to
The performances such as scrubbing character.Had further the advantage that additionally as hydridization filler:(1) can make the temperature in use of coating increases；(2) may be used
To improve the mechanical property of coating；(3) it can make coating that there is significant delayed combustion characteristic.
Using amino resins, the hardness of coating is greatly improved.
Present invention also offers it is a kind of by the automatically cleaning sealing wax stated in the application of lampshade or metal.
Present invention also offers a kind of lampshade, the lampshade scribbles above-mentioned automatically cleaning sealing wax.
Compared with prior art, advantageous effects of the invention：
From water-base resin system, VOC≤20g/L, smell is very low, more more environmentally-friendly than existing material；
From efficient water-repelling agent and organic silicone powder, good water-fast, resistant effect is reached, with automatically cleaning and scrubbing resistance
Performance, can easily wipe a variety of scribble materials such as dust-free chalk, dust, worm dung and tea stain or household stains, and pollution repeatedly is wiped
Persistence is good；
The coalescents of collocation environmental protection, reduce VOC content；
From acrylic modified epoxy ester emulsion as film forming matter, compared with similar products, with more excellent resistance to
Water, quick-drying performance, anti-yellowing property.
Embodiment
The raw material and weight distribution ratio of each embodiment are as follows：
Wherein：The aqueous acrylic modified epoxy emulsion is the WPA5324 with moral；The amino resins is that U.S.'s cyanogen is special
The amino trees of Cymel 325；Described titanium dioxide is rutile class titanium dioxide；Described organic silicone powder is poly- methyl silicon sesquialter oxygen
Alkane, the BT-9273 silicone powders of Guangzhou Ba Tai Chemical Co., Ltd.s；The coalescents are the net taste type of environmental protection of propylene glycol phenyl ethers
Coalescents AF (Guangzhou Yu Tai Chemical Industry Science Co., Ltd) and alcohol ester-12 coalescents (U.S. Yi Shiman), (the two ratio 1:
1 to 1:2)；Described efficient lotus leaf water-repelling agent is organosilicon, acrylic polymer, the micro emulsion of inorganic raw material reaction
The efficient lotus leaf water-repelling agents of HY-4021 of liquid, such as the river Chemical Industry Science Co., Ltd of Chengdu million；The pH value conditioning agent is dimethyl
One or both of monoethanolamine, multifunctional assistant AMP-95；The defoamer is polyether siloxane copolymer class defoamer, such as
Used additives Tego-902w, organic silicon defoamer are made in (Di Gao companies) TEGO deaeration, and such as (BIC Corp) BYK froth breaking is made
Two kinds of mixtures of used additives BYK-028, ratio is 1:1 or so；The wetting dispersing agent is scattered for polyester modification polyphosphoric acid esters
The AFCONA-5010 of agent, such as (angstrom husband's Kona) AFCONA；Described substrate wetting agents are the wetting of Siloxane-Oxyalkylene Copolymers class
Agent, such as one or both of (enlightening is high) TEGO Tego-245, (angstrom husband's Kona) AFCONA AFCONA-3031；It is described to increase
Thick dose is that polyurethane-type thickener, such as Ning Baidi polyurethane-type thickener PS202, and alkali soluble rise type thickener, such as Ning Baidi
Alkali soluble rise two kinds of mixtures of type thickener ASE60, proportion is 1:1 to 2:1.
Its preparation method is as follows：
Step a, according to the raw material proportioning, first by pH value conditioning agent, the wetting and dispersing of the deionized water of half, half
Agent, the defoamer of half, titanium dioxide, expansion light powder and organic silicone powder etc. are mixed, and 15 points are stirred with 500r/min speed
Clock；
Step b, processing is ground by grinder, and fineness is qualified stand-by less than 25 microns；
Step c, according to the raw material proportioning, aqueous acrylic emulsion is added in pot of getting the raw materials ready, with 500r/min speed
Degree stirring 5 minutes；Then the remainder of part environmentally friendly solvent, the pH value conditioning agent of half, water is graded and is added in pot of getting the raw materials ready,
900r/min speed is stirred 10 minutes；Then add successively remaining defoamer, levelling agent, water-repelling agent, substrate wetting agents and
Amino resins, 1200r/min speed is stirred 10 minutes；Then step b mixture, 1200r/min speed stirring are added
10 minutes；Sequentially add thickener, 1000r/min speed is stirred 10 minutes, adjustment viscosity is to qualified.(the regulation viscosity
For 25 DEG C -4 glasss of viscosity of painting, described -4 glasss of viscosity of painting are 70-90s.)
The effect of embodiment 1：Cost is minimum in four formulation examples, with certain self-cleaning performance, hardness highest, lead
Hardness is 2H, with certain barrier propterty.
The effect of embodiment 2：Cost is general in four formulation examples, and with good self-cleaning performance, pencil hardness is
H-2H.With certain barrier propterty.
The effect of embodiment 3：Cost is general in four formulation examples, and with best self-cleaning performance, pencil hardness is
H.There is best barrier propterty and higher gloss, cost performance highest in being formulated at four.
The effect of embodiment 4：The cost highest in four formulation examples, with preferable self-cleaning performance, pencil hardness is
H-2H.With certain barrier propterty and highest gloss.
Embodiment described above is only that the preferred embodiment of the present invention is described, and not the scope of the present invention is carried out
Limit, on the premise of design spirit of the present invention is not departed from, those of ordinary skill in the art make to technical scheme
Various modifications and improvement, all should fall into claims of the present invention determination protection domain in.
Claims (10)
1. a kind of automatically cleaning sealing wax, it is characterised in that include the component of following parts by weight：
Water-base resin：35-50 parts of aqueous acrylic modified epoxy emulsion, 5-20 parts of amino resins；
Pigment：3-20 parts of titanium dioxides, 1-9 parts of expansion light powder, 1 part of -10 parts of organic silicone powder；
Auxiliary agent：0.1-0.2 parts of PH conditioning agents, 0.1-0.2 parts of defoamer, 2-5 parts of coalescents, 1 part of -10 parts of high-performance charge
Leaf water-repelling agent, 0.3-0.5 parts of wetting dispersing agent, 0.3-0.5 parts of substrate wetting agents, 5-10 parts of deionized water, 0.5-1.0
The thickener of part.
2. automatically cleaning sealing wax according to claim 1, it is characterised in that the aqueous acrylic modified epoxy emulsion is same
The WPA5324 of moral；The amino resins is the amino trees of U.S.'s cyanogen spy Cymel 325；Described titanium dioxide is rutile class titanium white
Powder.
3. automatically cleaning sealing wax according to claim 1, it is characterised in that the coalescents are the ring of propylene glycol phenyl ethers
Net taste type coalescents AF and alcohol ester-12 coalescents are protected, described efficient lotus leaf water-repelling agent is organosilicon, acrylic ester polymers
Compound, the microemulsion of inorganic raw material reaction.
4. automatically cleaning sealing wax according to claim 1, it is characterised in that described organic silicone powder is poly- methyl silicon sesquialter
Oxygen alkane, the defoamer is polyether siloxane copolymer class defoamer.
5. automatically cleaning sealing wax according to claim 1, it is characterised in that the pH value conditioning agent be dimethylethanolamine,
One or both of multifunctional assistant AMP-95.
6. automatically cleaning sealing wax according to claim 1, it is characterised in that the wetting dispersing agent is polyester modification polyphosphoric acid
Esters dispersant, described substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class.
7. automatically cleaning sealing wax according to claim 1, it is characterised in that the thickener is polyurethane-type thickener.
8. a kind of preparation method of automatically cleaning sealing wax, it is characterised in that comprise the following steps：
Step a, according to the raw material proportioning, first by the deionized water of half, the pH value conditioning agent of half, wetting dispersing agent, one
Defoamer partly, titanium dioxide, expansion light powder and organic silicone powder etc. are mixed, and are stirred 15 minutes with 500r/min speed；
Step b, processing is ground by grinder, and fineness is qualified stand-by less than 25 microns；
Step c, according to the raw material proportioning, aqueous acrylic emulsion is added in pot of getting the raw materials ready, stirred with 500r/min speed
Mix 5 minutes；Then the remainder of environmentally friendly solvent, the pH value conditioning agent of half, water is graded and is added in pot of getting the raw materials ready, 900r/min
Speed stir 10 minutes；Then remaining defoamer, levelling agent, water-repelling agent, substrate wetting agents and amino resins are added successively,
1200r/min speed is stirred 10 minutes；Then step b mixture is added, 1200r/min speed is stirred 10 minutes；According to
Secondary addition thickener, 1000r/min speed is stirred 10 minutes, and adjustment viscosity is to qualified.
9. by the automatically cleaning sealing wax described in claim 1-17 any one in the application of lampshade or metal.
10. a kind of lampshade, it is characterised in that the lampshade scribbles the automatically cleaning sealing wax described in claim 1-7 any one.
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| CN201710139167.XA CN107033747A (en) | 2017-03-09 | 2017-03-09 | A kind of automatically cleaning sealing wax |
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| CN201710139167.XA CN107033747A (en) | 2017-03-09 | 2017-03-09 | A kind of automatically cleaning sealing wax |
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| CN107629593A (en) * | 2017-09-15 | 2018-01-26 | 河北晨阳工贸集团有限公司 | Electrical equipment water-soluble multifunctional coating and preparation method thereof |
| CN107868559A (en) * | 2017-11-28 | 2018-04-03 | 河北晨阳工贸集团有限公司 | Formula, preparation method and its application method of a kind of water-based antiultraviolet allochroic paint of fabric |
| CN107903773A (en) * | 2017-11-09 | 2018-04-13 | 河北晨阳工贸集团有限公司 | A kind of water-fast, antibacterial, automatically cleaning sealing wax and preparation method thereof |
| CN108610888A (en) * | 2018-03-14 | 2018-10-02 | 河北晨阳工贸集团有限公司 | A kind of metal surface sealing wax and preparation method thereof |
| CN108690393A (en) * | 2018-04-03 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of water-based decorative paint and preparation method thereof |
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| CN107629593B (en) * | 2017-09-15 | 2020-07-28 | 河北晨阳工贸集团有限公司 | Water-based multifunctional coating for electric appliance and preparation method thereof |
| CN107903773A (en) * | 2017-11-09 | 2018-04-13 | 河北晨阳工贸集团有限公司 | A kind of water-fast, antibacterial, automatically cleaning sealing wax and preparation method thereof |
| CN107868559A (en) * | 2017-11-28 | 2018-04-03 | 河北晨阳工贸集团有限公司 | Formula, preparation method and its application method of a kind of water-based antiultraviolet allochroic paint of fabric |
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| CN108690393A (en) * | 2018-04-03 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of water-based decorative paint and preparation method thereof |
| CN108707400A (en) * | 2018-04-03 | 2018-10-26 | 河北晨阳工贸集团有限公司 | A kind of fishing gear water paint and preparation method thereof |
| CN111410877A (en) * | 2019-01-08 | 2020-07-14 | 疏科纳米疏水科技(嘉兴)有限公司 | Method for preparing super-hydrophobic coating |
| CN109777256A (en) * | 2019-01-15 | 2019-05-21 | 海安南京大学高新技术研究院 | A kind of preparation method of aqueous high rigidity anti-fingerprint coating |
| CN111908829A (en) * | 2020-08-11 | 2020-11-10 | 龚俊琼 | Water repellent agent and pervious concrete for building |
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