CN106957571A - Low multi-functional sealing waxes of VOC and preparation method thereof - Google Patents
Low multi-functional sealing waxes of VOC and preparation method thereof Download PDFInfo
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- CN106957571A CN106957571A CN201710084506.9A CN201710084506A CN106957571A CN 106957571 A CN106957571 A CN 106957571A CN 201710084506 A CN201710084506 A CN 201710084506A CN 106957571 A CN106957571 A CN 106957571A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of low multi-functional sealing waxes of VOC and preparation method thereof, belong to paint field, be formulated as follows count by weight percentage：Water-base resin：60 70 parts of aqueous acrylic emulsion；Pigment：5 20 parts of titanium dioxide；Auxiliary agent：Environmentally friendly 25 parts of the coalescents of 0.1 0.2 parts of nertralizer, 0.1 0.2 parts of defoamer, higher boiling, 1 10 parts of efficient water-repelling agent, 0.3 0.5 parts of wetting dispersing agent, 0.3 0.5 parts of substrate wetting agents, 5 10 parts of deionized water, 0.5 1.0 parts of thickener.The present invention selects water-base resin system, and smell is very low, more more environmentally-friendly than existing material；From efficient water-repelling agent, reach good water-fast, resistant effect, with automatically cleaning and scrub performance, a variety of scribble materials such as aqueous white board marker, watercolor pencil, dust-free chalk, shoe polish, ink, catsup, coffee ＆ tea stain or household stains can be easily wiped, pollution wiping persistence is good repeatedly；The environmentally friendly coalescents of higher boiling of arranging in pairs or groups, reduce VOC content.
Description
Technical field
The invention belongs to paint field, more particularly to a kind of multi-functional sealing waxes of low VOC and preparation method thereof.
Background technology
VOC is VOC（volatile organic compounds）English abbreviation, it is usually said
Wall finiss in harmful chemical substance（Except heavy metal）Just refer to VOC.These VOCs include
The materials such as formaldehyde, ammonia, ethylene glycol, esters.When VOC reaches finite concentration, the disease such as headache, Nausea and vomiting, weak can be caused
Shape, even triggers tic, stupor, injury liver, kidney, brain and nervous system cause failure of memory etc. serious when serious
Consequence.
Among our daily lifes, the process tail gas of industrial discharge such as chemical plant discharge, in the flue gas of castoff burning
Just contain a variety of VOC；Contain imperfect combustion hydrocarbons in the tail gas of vehicular emission；Interior decoration, finishing material are such as
Paint and its solvent, timber preservative, coating, glued board etc., can discharge that toluene, benzene, dimethylbenzene etc. are a variety of to be waved under normal temperature
Hair property organic compound；Cosmetics used in everyday, insecticide, various detergent can also discharge VOC into air.It can be seen that, VOC
Source it is quite varied, and it also pollutes environment, aggravates the compound dirt of the air such as photochemical pollution, region gray haze, acid rain.
In recent years, environment increasingly deteriorates, and haze is increasingly severe, and society develops the coating of environmental protection to the requirement more and more higher of environmental protection
Have become the common recognition of people.Wherein coating Water-borne modification is as a kind of effective approach, but even water paint, still contains
There is a certain amount of VOC, so developing the ultralow coating of function admirable, VOC content turns into the developing direction of coating industry.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of multi-functional sealing waxes of low VOC, by improving the hydrophobic of coating
Performance, area and time that reduction coating is contacted with water, is finally reached the purpose for improving water-resistant coating energy.
In order to solve the above technical problems, the multi-functional sealing waxes of low VOC that the present invention is provided are adopted the technical scheme that：Formula
It is as follows count by weight percentage：Water-base resin：60-70 parts of aqueous acrylic emulsion；Pigment：5-20 parts of titanium dioxide；Auxiliary agent：In
With 0.1-0.2 parts of agent, 0.1-0.2 parts of defoamer, environmentally friendly 2-5 parts of the coalescents of higher boiling, efficient water-repelling agent 1-10 parts, wetting point
0.3-0.5 parts of powder, 0.3-0.5 parts of substrate wetting agents, 5-10 parts of deionized water, 0.5-1.0 parts of thickener.
Further, described titanium dioxide is rutile class titanium dioxide.
Further, the environmentally friendly coalescents of the higher boiling for propylene glycol phenyl ethers the net taste type coalescents AF of environmental protection and
The net taste coalescents of esters higher boiling organic compound GVE, the two ratio 1:1 to 1:2.
Further, described efficient water-repelling agent is the microemulsion that a variety of waxes and emulsifying agent are compounded.
Further, the nertralizer is the one or two in dimethylethanolamine, multifunctional assistant AMP-95.
Further, the defoamer is polyether siloxane copolymer class defoamer and organic silicon defoamer, and both compare
Example is 1:1.
Further, the wetting dispersing agent is the defoamer of poly-hydroxy acid salt class dispersant and nonionic, the two ratio
For 1:1.
Further, described substrate wetting agents are the wetting agent of Siloxane-Oxyalkylene Copolymers class, described polyether-modified poly-
The wetting agent of type siloxane is the one or two in Tego-245 and Tego-270.
Further, the thickener is that polyurethane-type thickener and alkali soluble rise type thickener, and ratio is 1:1 to 2:1.
Yet another object of the present invention is to provide a kind of preparation method of the low multi-functional sealing waxes of VOC, including：
According to raw material proportioning, first portions of de-ionized water, part nertralizer, part defoamer, wetting dispersing agent and pigment are carried out
Mixing, is stirred 15 ± 5 minutes with 500 ± 50 r/min speed；
Processing is ground by grinder, fineness is qualified stand-by less than 25 microns；
According to raw material proportioning, aqueous acrylic emulsion is added in pot of getting the raw materials ready, 5 ± 1 are stirred with 500 ± 50r/min speed
Minute；Then the remainder of the environmentally friendly coalescents of part higher boiling, part nertralizer, deionized water is added to pot of getting the raw materials ready
In, stirred 10 ± 2 minutes with 900 ± 50r/min speed；Then remaining defoamer, efficient water-repelling agent, base material are added successively
Wetting agent, is stirred 10 ± 2 minutes with 1200 ± 100r/min speed；Then add and be ground rear qualified stand-by mixing
Thing, is stirred 10 ± 2 minutes with 1200 ± 100r/min speed；Thickener is added, 10 are stirred with 1000 ± 50r/min speed
± 2 minutes, adjustment viscosity was to qualified.
Beneficial effect produced by the multi-functional sealing waxes of low VOC that the present invention is provided is：
（1）From water-base resin system, smell is very low, more more environmentally-friendly than existing material；
（2）From efficient water-repelling agent, good water-fast, resistant effect is reached, with automatically cleaning and scrub performance, can easily be wiped
Fall a variety of scribble materials such as aqueous white board marker, watercolor pencil, dust-free chalk, shoe polish, ink, catsup, coffee ＆ tea stain or life
Spot, pollution wiping persistence is good repeatedly；
（3）The environmentally friendly coalescents of higher boiling of arranging in pairs or groups, reduce VOC content；
The preparation method provided using the present invention, you can prepare the sealing wax mentioned by the present invention.
Embodiment
With reference to embodiment, the present invention is further detailed explanation.
The specific embodiment for the multi-functional sealing waxes of low VOC that the present invention is provided is as follows.
Embodiment 1
Formula is as follows count by weight percentage：Water-base resin：60-70 parts of aqueous acrylic emulsion；Pigment：Titanium dioxide 5-20
Part；Auxiliary agent：Environmentally friendly 2-5 parts of the coalescents of 0.1-0.2 parts of nertralizer, 0.1-0.2 parts of defoamer, higher boiling, efficient water-repelling agent 1-
10 parts, 0.3-0.5 parts of wetting dispersing agent, 0.3-0.5 parts of substrate wetting agents, 5-10 parts of deionized water, 0.5-1.0 parts of thickener.
Sealing wax dispensing of the present invention selects water-base resin system, and smell is very low, more more environmentally-friendly than existing material；From efficiently thin
Aqua, reaches good water-fast, resistant effect, with automatically cleaning and scrub performance, can easily wipe aqueous white board marker, watercolor
A variety of scribble materials such as pen, dust-free chalk, shoe polish, ink, catsup, coffee ＆ tea stain or household stains, repeatedly pollution are wiped
Persistence is good；The environmentally friendly coalescents of higher boiling of arranging in pairs or groups, reduce VOC content.The present invention is improved and applied by above-mentioned dispensing and proportioning
The hydrophobic performance of layer, area and time that reduction coating is contacted with water, is finally reached the purpose for improving water-resistant coating energy.
The dispensing of the present invention, from aqueous acrylic emulsion and the environmentally friendly coalescents of higher boiling, obtains high glaze, high decoration
Property, the aqueous lacquer coat of high hydrophobicity, wherein the water paint VOC≤7g/L prepared, smell is very low, prevent from polluting environment.
The present invention is used not only for light industry, is additionally operable to the indoor and outdoors such as building decoration and fitment due to ultralow volatilization.
Embodiment 2
On the basis of embodiment 1, concrete model and the producer of each dispensing are given, it is as follows：
Wherein, aqueous acrylic emulsion is the aqueous acrylic emulsion 0612 of ten thousand China's chemistry, VOC≤7g/L, with like product phase
Than with more excellent water resistance.
Wherein, titanium dioxide is rutile class titanium dioxide, e.g., the R706 of E.I.Du Pont Company.
Wherein, the environmentally friendly cosolvent of higher boiling is the net taste type coalescents AF of environmental protection of propylene glycol phenyl ethers（As Guangzhou space is safe
Chemical Industry Science Co., Ltd）With the net taste coalescents of esters higher boiling organic compound GVE（As micro- limited public affairs of industry are accumulated in Shanghai
Department）, the two ratio 1:1 to 1:2.
Wherein, efficient water-repelling agent is the microemulsion that a variety of waxes and emulsifying agent are compounded, and the safe Jilin Chemical chemical product in such as Henan has
The efficient water-repelling agent of limit company or Dongguan City Australia reach the lotus leaf water-repelling agent of Chemical Co., Ltd..Add coating in can coating into
Film surface modification contact angle forms a kind of special water-resistant structure, surface had extremely strong hydrophobic, hydrophobic, waterproof, improved taste masking
Effect；The gas permeability of film is not influenceed simultaneously.Both the recoatability of organic silicon hydrophobic material difference had been avoided, it also avoid other hydrophobic
The situation of agent poor air permeability.Make coating that there are the double hydrophobicitys of good lotus leaf, it is self-cleaning, hydrophobicity, water proofing property, resistance to soiling, resistance to
The performances such as scrubbing character.
Wherein, nertralizer is the one or two in dimethylethanolamine, multifunctional assistant AMP-95.
Wherein, defoamer is polyether siloxane copolymer class defoamer, and used additives are made in the high company's T EGO of such as enlightening deaeration
The froth breaking effect auxiliary agent B YK-028 of Tego-902w, organic silicon defoamer, such as BIC Corp BYK, two kinds of froth breaking agent compositions,
Ratio is typically maintained in 1:1, it can be adjusted according to Ju Ti Pei Fang and different geographical, temperature.
Wherein, wetting dispersing agent be poly-hydroxy acid salt class dispersant, such as hamming this FX600 and nonionic defoamer,
Such as this FX365 of hamming, the two ratio is 1:1.
Wherein, substrate wetting agents be Siloxane-Oxyalkylene Copolymers class wetting agent, the high TEGO of such as enlightening Tego-245,
One or two in Tego-270.
Wherein, thickener is that polyurethane-type thickener, such as Ning Baidi polyurethane-type thickener PS202, and alkali soluble rise type
The alkali soluble of thickener, such as Ning Baidi rises type thickener ASE60, two kinds of mixtures, and proportion is 1:1 to 2:1.
The dispensing of the present invention, from aqueous acrylic emulsion and the environmentally friendly coalescents of higher boiling, obtains high glaze, high decoration
Property, the aqueous lacquer coat of high hydrophobicity, wherein the water paint VOC≤7g/L prepared, smell is very low, prevent from polluting environment.
The dispensing of the present invention, the efficient water-repelling agent of selection is a variety of waxes and the microemulsion of emulsifying agent compounding, adds and applies
Can change contact angle in coating film formation surface in material and form a kind of special water-resistant structure, make surface have extremely strong hydrophobic, hydrophobic,
Waterproof, raising taste masking effect, while not influenceing the gas permeability of film；Both the recoatability of organic silicon hydrophobic material difference had been avoided,
Avoid the situation of other water-repelling agent poor air permeabilities.Make coating that there are the double hydrophobicitys of good lotus leaf, it is self-cleaning, hydrophobicity, anti-
The performances such as aqueous, resistance to soiling, scrub resistance.
The dispensing of the present invention, from the environmentally friendly coalescents AF of higher boiling（242.7 DEG C of boiling point）With the net taste coalescents of GVE
（275 DEG C of boiling point, higher than 250 DEG C of EU criteria）, two kinds of coalescents are environmentally friendly auxiliary agent, applied to aqueous high molecular
Emulsion paint, is the strong solvent of emulsion polymer.The MFT of emulsion paint can be effectively reduced, the anti-scratch of emulsion paint is improved
Washing property and film quality.Filming performance can be obviously improved, glossiness, intensity and the anti-grinded hardness index of paint film is improved and promotes stream
Levelling；Excellent wet film performance, raising weatherability and color developing.
The dispensing of the present invention, is compounded from different types of defoamer, solves the air bubble problem in sealing wax；From not
The thickener compounding of same type, solves the thixotropic property of sealing wax.
It should be pointed out that the title and the model of component of company cited in the present invention, merely to illustrating this hair
The bright and specific embodiment enumerated, is the preferred plan that can be selected through overtesting, but be not construed as limiting the invention.
It should also be noted that, the present invention is used not only for light industry, is additionally operable to building decoration and fitment due to ultralow volatilization
Etc. indoor and outdoor.
The Ju Ti Pei Fang of the multi-functional sealing waxes of low VOC provided in an embodiment of the present invention is given below, as shown in table 1：
Each embodiment in above-mentioned table is analyzed as follows：
The effect of embodiment 3：Cost is minimum in four embodiments in table, with certain hydrophobic performance, hardness highest, pencil
Hardness is H, with certain barrier propterty.
The effect of embodiment 4：Cost is general in four embodiments in table, with good hydrophobic performance, pencil hardness
For HB-H, with certain barrier propterty.
The effect of embodiment 5：Cost is general in four embodiments in table, with best hydrophobic performance, pencil hardness
For H, there is best barrier propterty and higher gloss, cost performance highest in being formulated at four.
The effect of embodiment 6：The cost highest in four embodiments in table, with preferable hydrophobic performance, pencil hardness
For HB-H, with certain barrier propterty and highest gloss.
In order to obtain the higher-quality multi-functional sealing waxes of low VOC, the embodiment of the present invention additionally provides a kind of preparation method, step
It is rapid as follows：
Step a, according to the raw material proportioning, first by part water, part nertralizer, wetting dispersing agent, part defoamer and pigment
Deng being mixed, stirred 15 minutes with 500r/min speed.
Step b, processing is ground by grinder, and fineness is qualified stand-by less than 25 microns.
Step c, according to the raw material proportioning, water-based acrylic resin is added in pot of getting the raw materials ready, with 500r/min speed
Degree stirring 5 minutes；Then the remainder of part environmentally friendly solvent, part nertralizer, water is graded and is added in pot of getting the raw materials ready, 900r/
Min speed is stirred 10 minutes；Then remaining defoamer, levelling agent, water-repelling agent, substrate wetting agents, 1200r/ are added successively
Min speed is stirred 10 minutes；Then step b mixture is added, 1200r/min speed is stirred 10 minutes；Sequentially add
Thickener, 1000r/min speed is stirred 10 minutes, and adjustment viscosity is to qualified.
It should be pointed out that the order of above method institute steps taken, is not construed as limiting the invention.
The technical scheme that the present invention is provided is described in detail above, using specific case to the present invention in the present invention
Embodiment be set forth, the explanation of above example is only intended to help and understands the present invention, it is noted that for this skill
For the technical staff in art field, under the premise without departing from the principles of the invention, some improvement can be also carried out to the present invention, these
Improvement is also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of multi-functional sealing waxes of low VOC, it is characterised in that formula is as follows count by weight percentage：Water-base resin：Aqueous third
60-70 parts of olefin(e) acid emulsion；Pigment：5-20 parts of titanium dioxide；Auxiliary agent：0.1-0.2 parts of nertralizer, 0.1-0.2 parts of defoamer, higher boiling
Environmentally friendly coalescents 2-5 parts, efficient water-repelling agent 1-10 parts, 0.3-0.5 parts of wetting dispersing agent, 0.3-0.5 parts of substrate wetting agents, go
5-10 parts of ionized water, 0.5-1.0 parts of thickener.
2. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that described titanium dioxide is rutile class titanium
White powder.
3. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that the environmentally friendly coalescents of the higher boiling are
The net taste type coalescents AF of environmental protection and the net taste coalescents of esters higher boiling organic compound GVE of propylene glycol phenyl ethers, the two
Ratio 1:1 to 1:2.
4. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that described efficient water-repelling agent is a variety of waxes
The microemulsion compounded with emulsifying agent.
5. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that the nertralizer be dimethylethanolamine,
One or two in multifunctional assistant AMP-95.
6. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that the defoamer is common for polyether silicone
Polymers class defoamer and organic silicon defoamer, both ratios are 1:1.
7. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that the wetting dispersing agent is poly-hydroxy acid salt
The defoamer of class dispersant and nonionic, the two ratio is 1:1.
8. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that described substrate wetting agents change for polyethers
Property polysiloxane-based wetting agent, during the wetting agent of the Siloxane-Oxyalkylene Copolymers class is Tego-245 and Tego-270
It is one or two kinds of.
9. the multi-functional sealing waxes of low VOC according to claim 1, it is characterised in that the thickener thickens for polyurethane-type
Agent and alkali soluble rise type thickener, and ratio is 1:1 to 2:1.
10. the preparation method of the low multi-functional sealing waxes of VOC as claimed in any one of claims 1-9 wherein, it is characterised in that including：
According to raw material proportioning, first portions of de-ionized water, part nertralizer, part defoamer, wetting dispersing agent and pigment are carried out
Mixing, is stirred 15 ± 5 minutes with 500 ± 50 r/min speed；
Processing is ground by grinder, fineness is qualified stand-by less than 25 microns；
According to raw material proportioning, aqueous acrylic emulsion is added in pot of getting the raw materials ready, 5 ± 1 are stirred with 500 ± 50r/min speed
Minute；Then the remainder of the environmentally friendly coalescents of part higher boiling, part nertralizer, deionized water is added to pot of getting the raw materials ready
In, stirred 10 ± 2 minutes with 900 ± 50r/min speed；Then remaining defoamer, efficient water-repelling agent, base material are added successively
Wetting agent, is stirred 10 ± 2 minutes with 1200 ± 100r/min speed；Then add and be ground rear qualified stand-by mixing
Thing, is stirred 10 ± 2 minutes with 1200 ± 100r/min speed；Thickener is added, 10 are stirred with 1000 ± 50r/min speed
± 2 minutes, adjustment viscosity was to qualified.
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| CN201710084506.9A CN106957571A (en) | 2017-02-16 | 2017-02-16 | Low multi-functional sealing waxes of VOC and preparation method thereof |
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| CN201710084506.9A CN106957571A (en) | 2017-02-16 | 2017-02-16 | Low multi-functional sealing waxes of VOC and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556855A (en) * | 2017-07-31 | 2018-01-09 | 河北晨阳工贸集团有限公司 | Sealing wax and preparation method thereof and radiator and preparation method thereof |
| CN107903773A (en) * | 2017-11-09 | 2018-04-13 | 河北晨阳工贸集团有限公司 | A kind of water-fast, antibacterial, automatically cleaning sealing wax and preparation method thereof |
| CN108395837A (en) * | 2018-02-01 | 2018-08-14 | 河北晨阳工贸集团有限公司 | A kind of aqueous anti-graffiti coating and preparation method thereof |
| CN108795189A (en) * | 2018-04-11 | 2018-11-13 | 河北晨阳工贸集团有限公司 | A kind of environment-friendly type aqueous motor case paint special and preparation method thereof |
| CN110003696A (en) * | 2019-04-03 | 2019-07-12 | 济南鸿泰华丰机械有限公司 | A kind of 5G communication base station |
| NL2031693A (en) * | 2021-04-26 | 2022-06-27 | Runtai New Mat Co Ltd | Coalescing agent for aqueous coating, coalescing agent composition and aqueous coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107556855A (en) * | 2017-07-31 | 2018-01-09 | 河北晨阳工贸集团有限公司 | Sealing wax and preparation method thereof and radiator and preparation method thereof |
| CN107903773A (en) * | 2017-11-09 | 2018-04-13 | 河北晨阳工贸集团有限公司 | A kind of water-fast, antibacterial, automatically cleaning sealing wax and preparation method thereof |
| CN108395837A (en) * | 2018-02-01 | 2018-08-14 | 河北晨阳工贸集团有限公司 | A kind of aqueous anti-graffiti coating and preparation method thereof |
| CN108795189A (en) * | 2018-04-11 | 2018-11-13 | 河北晨阳工贸集团有限公司 | A kind of environment-friendly type aqueous motor case paint special and preparation method thereof |
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| CN110003696B (en) * | 2019-04-03 | 2021-02-12 | 江西山水光电科技股份有限公司 | 5G communication base station |
| NL2031693A (en) * | 2021-04-26 | 2022-06-27 | Runtai New Mat Co Ltd | Coalescing agent for aqueous coating, coalescing agent composition and aqueous coating |
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Application publication date: 20170718 |