CN104893472A - Waterproof elastic latex paint for building external wall and preparation method of waterproof elastic latex paint - Google Patents

Waterproof elastic latex paint for building external wall and preparation method of waterproof elastic latex paint Download PDF

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Publication number
CN104893472A
CN104893472A CN201510327249.8A CN201510327249A CN104893472A CN 104893472 A CN104893472 A CN 104893472A CN 201510327249 A CN201510327249 A CN 201510327249A CN 104893472 A CN104893472 A CN 104893472A
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CN
China
Prior art keywords
parts
water
elastic latex
latex paint
minutes
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Pending
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CN201510327249.8A
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Chinese (zh)
Inventor
许涛
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Hefei Qi Hua Environmental Protection Technology Co Ltd
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Hefei Qi Hua Environmental Protection Technology Co Ltd
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Priority to CN201510327249.8A priority Critical patent/CN104893472A/en
Publication of CN104893472A publication Critical patent/CN104893472A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses waterproof elastic latex paint for a building external wall and a preparation method of the waterproof elastic latex paint. The waterproof elastic latex paint is prepared from the following raw materials in parts by weight: 35-40 parts of elastic acrylic emulsion, 3-5 parts of waste glass fiber, 18-22 parts of nano-silica, 6-8 parts of clay, 8-10 parts of rectorite, 7-9 parts of pearl wool leftover material, 103-107 parts of water, 2-3 parts of emulsified asphalt, 1-2 parts of lecithin, 2-3 parts of carboxymethyl cellulose, 2.5-3.5 parts of sodium bicarbonate, and 1-1.5 parts of diethylene glycol monobutyl ether. According to the invention, the elastic acrylic emulsion is used as a film formation base material, and is matched with added emulsified asphalt, so that the adhesiveness and waterproofness are improved; the processed waste glass fiber, clay and rectorite are added to change the surface tension, and can be better mixed with the emulsion, and the film of the prepared paint is excellent in elasticity and durability, good in waterproofness and stain resistance, and not easy to crack.

Description

A kind of water-proof elastic latex coating for external wall and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of water-proof elastic latex coating for external wall and preparation method thereof.
Background technology
When being used as exterior coating, the very short internal structure such as time inner concrete, fragment of brick can because climate change bring the phenomenon of expanding with heat and contract with cold to rigidity coating, and various body of wall is because of the degree difference of expanding with heat and contract with cold, and can produce internal stress.When internal stress is applied to the globality that namely surface of wall can affect exterior wall film, thus there is the phenomenon of cracking, foaming, even fall in flakes.There is elastic exterior coating to be out of shape along with expanding with heat and contract with cold of body of wall, and then keep the continuity of film, keep whole structure for a long time.But elastic exterior coating material has two larger shortcomings: one is that the bond effect of film and body of wall is poor, because the cohesive force only having the elasticity of film self to be greater than film and ground just can produce recoverable deformation, otherwise the effect of the coating that will follow the string; Two is that elasticity film coated surface specific rigidity film viscosity is large, when film is subject to exposing to the sun and rain outer, is easily bonded on film, and affects appearance of film when dust etc. fall.So when elastic exterior coating material carries out large-scale application, make great efforts the waterproof pollution resistance and the viscosity that solve elastic emulsion coating.
Summary of the invention
The object of this invention is to provide a kind of water-proof elastic latex coating for external wall and preparation method thereof.The present invention adopts elastomeric propylene yogurt liquid as film forming binder, coordinates the interpolation of emulsified bitumen, enhances binding property and water-repellancy; Add scrap glass fiber, clay, the rectorite leng after process, change surface tension, can better mix with emulsion, the coating made is coated with film elasticity, and good endurance, water-proof stain-resistant is good, not easy to crack.
In order to realize object of the present invention, the present invention is by following scheme implementation:
For a water-proof elastic latex coating for external wall, be made up of the raw material of following weight part: elastomeric propylene yogurt liquid 35-40, scrap glass fiber 3-5, nano silicon 18-22, clay 6-8, rectorite leng 8-10, PE Foam scrap stock 7-9, water 103-107, emulsified bitumen 2-3, Yelkin TTS 1-2, carboxymethyl cellulose 2-3, sodium bicarbonate 2.5-3.5, butyl carbitol 1-1.5;
A kind of water-proof elastic latex coating for external wall of the present invention, be made up of following concrete steps:
(1) scrap glass fiber, rectorite leng are ground into 200 order powder, then with clay mixing and ball milling 20 minutes, water and the Yelkin TTS of 3 times amount is added in the mixed powder after ball milling, dispersed paste is formed after stirring 40 minutes with the speed of 600 revs/min, again by dispersed paste spraying dry, control spray-dired inlet temperature 150-180 DEG C, temperature out 60-75 DEG C, obtain surface active filler;
(2) carboxymethyl cellulose is added in the water of 3 times amount, be stirred to formation clear solution, then granulation in tablets press is jointly joined with surface active filler, sodium bicarbonate in step (1), the particle obtained first is sintered 60 minutes at the temperature of 220-250 DEG C, then 500-550 DEG C of sintering 2-2.5 hour is warming up to, be ground into 250 orders after being cooled to room temperature, obtain mixed powder A;
(3) PE Foam scrap stock are ground into 200 orders for subsequent use, the water of residual content is joined in dispersion cylinder, elastomeric propylene yogurt liquid, emulsified bitumen is slowly added under the rotating speed of 450-500 rev/min, disperse after 30-40 minute, improve rotating speed to 800 rev/min, add the PE Foam scrap stock after the mixed powder A of step (2), pulverizing and all the other remaining components successively, disperse after 30 minutes, raise speed to 1500 revs/min again, continue dispersion until fineness is less than 60 μm and get final product.
The invention has the beneficial effects as follows: present component reasonable ratio, the manufacturing process of employing science, first the fillers such as scrap glass fiber, clay are carried out surface active, then add appropriate sodium bicarbonate and carry out granulation, pulverize after final high temperature sintering, the Activation filling made has loose porous feature, has certain sound-absorbing and the effect of insulation, there is good surface tension simultaneously, make to be uniformly dispersed in coating.
The present invention adopts elastomeric propylene yogurt liquid as film forming binder, coordinates the interpolation of emulsified bitumen, enhances binding property and water-repellancy; Add scrap glass fiber, clay, the rectorite leng after process, change surface tension, can better mix with emulsion, the coating made is coated with film elasticity, and good endurance, water-proof stain-resistant is good, not easy to crack.
Specific embodiments
Below by specific examples, the present invention is described in detail.
For a water-proof elastic latex coating for external wall, be made up of the raw material of following weight part (kilogram): elastomeric propylene yogurt liquid 35, scrap glass fiber 3, nano silicon 18, clay 6, rectorite leng 8, PE Foam scrap stock 7, water 103, emulsified bitumen 2, Yelkin TTS 1, carboxymethyl cellulose 2, sodium bicarbonate 2.5, butyl carbitol 1;
A kind of water-proof elastic latex coating for external wall of the present invention, be made up of following concrete steps:
(1) scrap glass fiber, rectorite leng are ground into 200 order powder, then with clay mixing and ball milling 20 minutes, water and the Yelkin TTS of 3 times amount is added in the mixed powder after ball milling, dispersed paste is formed after stirring 40 minutes with the speed of 600 revs/min, again by dispersed paste spraying dry, control spray-dired inlet temperature 150-180 DEG C, temperature out 60-75 DEG C, obtain surface active filler;
(2) carboxymethyl cellulose is added in the water of 3 times amount, be stirred to formation clear solution, then granulation in tablets press is jointly joined with surface active filler, sodium bicarbonate in step (1), the particle obtained first is sintered 60 minutes at the temperature of 220-250 DEG C, then 500-550 DEG C of sintering 2-2.5 hour is warming up to, be ground into 250 orders after being cooled to room temperature, obtain mixed powder A;
(3) PE Foam scrap stock are ground into 200 orders for subsequent use, the water of residual content is joined in dispersion cylinder, elastomeric propylene yogurt liquid, emulsified bitumen is slowly added under the rotating speed of 500 revs/min, disperse after 30 minutes, improve rotating speed to 800 rev/min, add the PE Foam scrap stock after the mixed powder A of step (2), pulverizing and all the other remaining components successively, disperse after 30 minutes, raise speed to 1500 revs/min again, continue dispersion until fineness is less than 60 μm and get final product.
Water-based exterior wall paint of the present invention adopts the form of construction work of roller coat, brushing, spraying, and coating appearance of film of the present invention is full, smooth, good without lump, glossiness; Water-fast 96 hours, alkaline-resisting 48 hours without exception; Abrasion resistance is tested 2000 times and is passed through, and film is without breakage; Artificial ageing resistance test 600 hours non-foaming, do not peel off, flawless.

Claims (2)

1. the water-proof elastic latex coating for external wall, it is characterized in that, be made up of the raw material of following weight part: elastomeric propylene yogurt liquid 35-40, scrap glass fiber 3-5, nano silicon 18-22, clay 6-8, rectorite leng 8-10, PE Foam scrap stock 7-9, water 103-107, emulsified bitumen 2-3, Yelkin TTS 1-2, carboxymethyl cellulose 2-3, sodium bicarbonate 2.5-3.5, butyl carbitol 1-1.5.
2. a kind of water-proof elastic latex coating for external wall according to claim 1, is characterized in that, be made up of following concrete steps:
(1) scrap glass fiber, rectorite leng are ground into 200 order powder, then with clay mixing and ball milling 20 minutes, water and the Yelkin TTS of 3 times amount is added in the mixed powder after ball milling, dispersed paste is formed after stirring 40 minutes with the speed of 600 revs/min, again by dispersed paste spraying dry, control spray-dired inlet temperature 150-180 DEG C, temperature out 60-75 DEG C, obtain surface active filler;
(2) carboxymethyl cellulose is added in the water of 3 times amount, be stirred to formation clear solution, then granulation in tablets press is jointly joined with surface active filler, sodium bicarbonate in step (1), the particle obtained first is sintered 60 minutes at the temperature of 220-250 DEG C, then 500-550 DEG C of sintering 2-2.5 hour is warming up to, be ground into 250 orders after being cooled to room temperature, obtain mixed powder A;
(3) PE Foam scrap stock are ground into 200 orders for subsequent use, the water of residual content is joined in dispersion cylinder, elastomeric propylene yogurt liquid, emulsified bitumen is slowly added under the rotating speed of 450-500 rev/min, disperse after 30-40 minute, improve rotating speed to 800 rev/min, add the PE Foam scrap stock after the mixed powder A of step (2), pulverizing and all the other remaining components successively, disperse after 30 minutes, raise speed to 1500 revs/min again, continue dispersion until fineness is less than 60 μm and get final product.
CN201510327249.8A 2015-06-15 2015-06-15 Waterproof elastic latex paint for building external wall and preparation method of waterproof elastic latex paint Pending CN104893472A (en)

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CN201510327249.8A CN104893472A (en) 2015-06-15 2015-06-15 Waterproof elastic latex paint for building external wall and preparation method of waterproof elastic latex paint

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CN201510327249.8A CN104893472A (en) 2015-06-15 2015-06-15 Waterproof elastic latex paint for building external wall and preparation method of waterproof elastic latex paint

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281029A (en) * 2016-08-08 2017-01-04 凡音环保科技(苏州)有限公司 A kind of macromolecule high resiliency environment-friendly materials
CN106380992A (en) * 2016-08-26 2017-02-08 枣阳市恒泰化工有限公司 Preparation of latex for building waterproofing and preparation method
CN111040551A (en) * 2019-12-30 2020-04-21 佛山科学技术学院 Wall coating

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101575472A (en) * 2009-06-04 2009-11-11 无锡市艺博涂料有限公司 Anti-cracking stain-resistant exterior wall latex paint and preparation method thereof
CN103666155A (en) * 2013-12-11 2014-03-26 青岛益群漆业集团有限公司 Nano modified high-stain-resistance elastic paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101575472A (en) * 2009-06-04 2009-11-11 无锡市艺博涂料有限公司 Anti-cracking stain-resistant exterior wall latex paint and preparation method thereof
CN103666155A (en) * 2013-12-11 2014-03-26 青岛益群漆业集团有限公司 Nano modified high-stain-resistance elastic paint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281029A (en) * 2016-08-08 2017-01-04 凡音环保科技(苏州)有限公司 A kind of macromolecule high resiliency environment-friendly materials
CN106380992A (en) * 2016-08-26 2017-02-08 枣阳市恒泰化工有限公司 Preparation of latex for building waterproofing and preparation method
CN111040551A (en) * 2019-12-30 2020-04-21 佛山科学技术学院 Wall coating

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Application publication date: 20150909

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