CN106189672A - A kind of anti-scratch type water paint and preparation method thereof - Google Patents
A kind of anti-scratch type water paint and preparation method thereof Download PDFInfo
- Publication number
- CN106189672A CN106189672A CN201610620120.0A CN201610620120A CN106189672A CN 106189672 A CN106189672 A CN 106189672A CN 201610620120 A CN201610620120 A CN 201610620120A CN 106189672 A CN106189672 A CN 106189672A
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- water paint
- type water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of anti-scratch type water paint, be made up of following raw materials according: phenol-formaldehyde resin modified, pure-acrylic emulsion, chlorinated rubber resin, Cu-Zn alloy powder, barium sulfate, normal propyl alcohol, butanone, synergist, defoamer, thickening agent, ferrophosphorus powder, bentonite, deionized water, PU glue；Its preparation method comprises the steps: that (1) prepares mixed liquor；(2) supending；(3) solution is prepared；(4) liquid mixing of These steps is uniform, filter to obtain finished product.The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves the anti-scratch performance of compositions；Preparation method of the present invention is simple, it is achieved that making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production, possesses preferable economic benefit and social benefit.
Description
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, particularly relate to a kind of anti-scratch type aqueous and be coated with
Material and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in the overall situation of green economy globalization
Under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green
Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green
The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection
Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil
Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 15,000,000
About Dun, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, crucial
It is to cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is big row in the common people consume
Its road, runs in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint will
Being widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint can
To apply the application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics.Water paint from raw material sources to produce and
The Life cycle used, the most beneficially sound development of environment.It is the most in process of production by volatile organic solvent
Substitute, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs to disappear
Consumption fossil feedstock, is a major challenge to resource in the present stage of resource scarcity, and the appearance of water paint solves this and asks
Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week
Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating of energy-conserving and environment-protective
Industry is just welcoming unprecedented opportunity to develop, and market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces
The difficulty of construction of water paint, improve serviceability, be water paint expansive approach field, extensive popularization and application when business
Anxious.Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public the prejudice of water paint and misgivings etc.
The attention of related work, also will play the effect of promotion to the application development of water paint.As Green Product, aqueous is coated with
Material necessarily obtains the accreditation of people and is widely used.Before the market demand huge in the face of water paint and ever-increasing application
Scape, strengthens research and development capabilities, and updates and promote the properties of product of water paint, accelerates product quality upgrading, develops in skill
The water paint more showing powerful competitive advantage in art, on cost, in performance has the meaning of reality and wide market
Space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of anti-scratch type water paint and
Preparation method, this coating products excellent performance, there are good anti-scratch performance, and energy-conserving and environment-protective, possess preferable economic benefit
And social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of anti-scratch type water paint, is prepared by the raw materials in: phenol-formaldehyde resin modified 15～35 parts, pure third breast
Liquid 5～20 parts, chlorinated rubber resin 5～20 parts, Cu-Zn alloy powder 3～15 parts, barium sulfate 3～15 parts, normal propyl alcohol 0.3～1.5 parts, first
Ethyl ketone 0.5～2 parts, synergist 0.3～1.5 parts, defoamer 0.3～1.2 parts, thickening agent 0.2～1 part, ferrophosphorus powder 1～5 parts, swollen
2～8 parts of profit soil, deionized water 20～45 parts, PU glue 3～15 parts；
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, chlorinated rubber resin, Cu-Zn alloy powder, barium sulfate and normal propyl alcohol are put into reaction
In container, it is slowly heated to 40～50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, bentonite, butanone are joined in blender with PU glue, be stirred continuously until mix homogeneously, obtain
Standby to suspension；
(3) synergist, defoamer, thickening agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100～200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described defoamer is polyester modification siloxanes.
Preferably, described thickening agent is carboxymethyl cellulose.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves compositions
Anti-scratch performance, use the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, hot strength and extension at break
Rate is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.；Preparation method of the present invention is simple, it is achieved
Making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, be suitable to industrial mass
Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of anti-scratch type water paint, is prepared by the raw materials in: phenol-formaldehyde resin modified 15 parts, pure-acrylic emulsion 5
Part, chlorinated rubber resin 5 parts, Cu-Zn alloy powder 3 parts, 3 parts of barium sulfate, normal propyl alcohol 0.3 part, butanone 0.5 part, synergist 0.3 part, disappear
Infusion 0.3 part, thickening agent 0.2 part, 1 part of ferrophosphorus powder, bentonite 2 parts, deionized water 20 parts, 3 parts of PU glue；
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, chlorinated rubber resin, Cu-Zn alloy powder, barium sulfate and normal propyl alcohol are put into reaction
In container, it is slowly heated to 40～50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, bentonite, butanone are joined in blender with PU glue, be stirred continuously until mix homogeneously, obtain
Standby to suspension；
(3) synergist, defoamer, thickening agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
A kind of anti-scratch type water paint, is prepared by the raw materials in: phenol-formaldehyde resin modified 35 parts, pure-acrylic emulsion 20
Part, chlorinated rubber resin 20 parts, Cu-Zn alloy powder 15 parts, 15 parts of barium sulfate, normal propyl alcohol 1.5 parts, butanone 2 parts, synergist 1.5 parts,
Defoamer 1.2 parts, thickening agent 1 part, 5 parts of ferrophosphorus powder, bentonite 8 parts, deionized water 45 parts, 15 parts of PU glue；
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, chlorinated rubber resin, Cu-Zn alloy powder, barium sulfate and normal propyl alcohol are put into reaction
In container, it is slowly heated to 40～50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, bentonite, butanone are joined in blender with PU glue, be stirred continuously until mix homogeneously, obtain
Standby to suspension；
(3) synergist, defoamer, thickening agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine；
Described defoamer is polyester modification siloxanes；
Described thickening agent is carboxymethyl cellulose.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The anti-scratch performance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength and
Elongation at break is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.；Preparation method of the present invention letter
Single, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (4)
1. an anti-scratch type water paint, it is characterised in that be prepared by the raw materials in: phenol-formaldehyde resin modified 15～35
Part, pure-acrylic emulsion 5～20 parts, chlorinated rubber resin 5～20 parts, Cu-Zn alloy powder 3～15 parts, barium sulfate 3～15 parts, normal propyl alcohol 0.3
～1.5 parts, butanone 0.5～2 parts, synergist 0.3～1.5 parts, defoamer 0.3～1.2 parts, thickening agent 0.2～1 part, ferrophosphorus
Powder 1～5 parts, bentonite 2～8 parts, deionized water 20～45 parts, PU glue 3～15 parts；
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, chlorinated rubber resin, Cu-Zn alloy powder, barium sulfate and normal propyl alcohol are put into reaction vessel
In, it is slowly heated to 40～50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby；
(2) ferrophosphorus powder, bentonite, butanone are joined in blender with PU glue, be stirred continuously until mix homogeneously, hanged
Supernatant liquid is standby；
(3) synergist, defoamer, thickening agent are dissolved in deionized water and obtain solution；
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step (3) is added
The solution prepared, continues to stir, and crosses 100～200 mesh sieves, gets product.
One the most according to claim 1 anti-scratch type water paint, it is characterised in that described synergist is butyl triphenyl
Fluorination phosphine.
One the most according to claim 1 anti-scratch type water paint, it is characterised in that described defoamer is polyester modification silicon
Oxygen alkane.
One the most according to claim 1 anti-scratch type water paint, it is characterised in that described thickening agent is carboxymethyl cellulose
Element.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620120.0A CN106189672A (en) | 2016-08-01 | 2016-08-01 | A kind of anti-scratch type water paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610620120.0A CN106189672A (en) | 2016-08-01 | 2016-08-01 | A kind of anti-scratch type water paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189672A true CN106189672A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610620120.0A Pending CN106189672A (en) | 2016-08-01 | 2016-08-01 | A kind of anti-scratch type water paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113681007A (en) * | 2021-09-14 | 2021-11-23 | 山东金钻石金属材料有限公司 | Copper-gold powder collecting and storing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059656A (en) * | 2012-12-28 | 2013-04-24 | 大连金洁建筑材料科技发展有限公司 | Heat insulation waterproof architectural coating |
| CN103756473A (en) * | 2013-12-23 | 2014-04-30 | 安徽省金盾涂料有限责任公司 | Waterproof acid and alkali resistant paint |
| CN104293083A (en) * | 2014-09-04 | 2015-01-21 | 青岛佳尚创意文化有限公司 | Anticorrosion wear-resistant paint |
| CN104592853A (en) * | 2014-12-10 | 2015-05-06 | 成都拜迪新材料有限公司 | Preparation method for water-based phenolic red lead rusted antirust primer |
-
2016
- 2016-08-01 CN CN201610620120.0A patent/CN106189672A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059656A (en) * | 2012-12-28 | 2013-04-24 | 大连金洁建筑材料科技发展有限公司 | Heat insulation waterproof architectural coating |
| CN103756473A (en) * | 2013-12-23 | 2014-04-30 | 安徽省金盾涂料有限责任公司 | Waterproof acid and alkali resistant paint |
| CN104293083A (en) * | 2014-09-04 | 2015-01-21 | 青岛佳尚创意文化有限公司 | Anticorrosion wear-resistant paint |
| CN104592853A (en) * | 2014-12-10 | 2015-05-06 | 成都拜迪新材料有限公司 | Preparation method for water-based phenolic red lead rusted antirust primer |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113681007A (en) * | 2021-09-14 | 2021-11-23 | 山东金钻石金属材料有限公司 | Copper-gold powder collecting and storing method |
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Application publication date: 20161207 |
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