CN104293091A - Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof - Google Patents
Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof Download PDFInfo
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- CN104293091A CN104293091A CN201410469131.4A CN201410469131A CN104293091A CN 104293091 A CN104293091 A CN 104293091A CN 201410469131 A CN201410469131 A CN 201410469131A CN 104293091 A CN104293091 A CN 104293091A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a flame-retardant insulating paint capable of increasing the hardness of a paint film. The flame-retardant insulating paint is characterized by being prepared from the following raw materials in parts by weight: 30-34 parts of epoxy resin, 8-11 parts of furfural acetone resin, 2-3 parts of itaconate, 2-3 parts of di(ethylene glycol) benzoate, 4-6 parts of (H2NCH2C6H4)2O, 1-2 parts of p-tert-butyl benzoic acid, 2-4 parts of magnesium hypophosphite, 1-3 parts of sodium silicate, 8-11 parts of ethyl acetate, 10-13 parts of ethylene glycol, 6-8 parts of dimethylbenzene, 1-2 parts of wood fiber, 2-3 parts of bamboo pulp fiber, 14-17 parts of modified asphalt, 1-2 parts of activated alumina micro powder, 2-3 parts of tungsten carbide, 0.5-1.0 part of flake graphite powder, 0.4-0.9 part of a titanate coupling agent and 4-7 parts of modified waste clay sand. The paint disclosed by the invention has a good film-forming property, and the paint film is flat and smooth and has good insulativity, flame retardancy, acid/alkali resistance, and the properties of most of organic solvents; the added modified waste clay sand enhances the corrosion resistance and heat resistance of the paint, and the secondary utilization of wastes is realized, thereby saving energy resources and protecting the environment; and the paint disclosed by the invention is simple in preparation process, and wide in application, and especially applicable to the severe anti-corrosion engineering of ships and the like.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of fire-retarding insulation lacquer improving hardness of paint film and preparation method thereof.
Background technology
The general composition of paint comprises filmogen, pigment, solvent, auxiliary agent.Paint is that one firmly can cover body surface, plays protection, decoration, mark and the chemical mixture coating of other special purposes.More authoritative coating process one book of China's coating circle is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating." belonging to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The classification of the Chemicals of passing through according to the modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.
Clay-bonded sand is the molding sand using clay as binding agent, clay-bonded sand is recycling the thermolysis due to each component in process, there occurs the change of physicals, surface also has the dead clay losing viscosifying power because of heat, the ash content that coal dust etc. are residual and iron content, the composition silicate of the compositions such as aluminium, the words of recycling reduce the quality of molding sand, having to be replaced becomes Discarding Type sand, bulk deposition can have a strong impact on the quality of environmental pollution and soil, serious words are due to rainwash, wherein injurious factor can be left to river along with rainwater, the places such as plantation, finally be gathered in people's body by food chain, very large harm is brought to health, the present invention is directed to this situation discarded clay-bonded sand is carried out modification to add in priming paint as filler, not only reduce environmental pollution, and enhance the weathering resistance of priming paint, thermotolerance, erosion resistance, reduce the effect of production cost etc.
Summary of the invention
The object of this invention is to provide a kind of fire-retarding insulation lacquer improving hardness of paint film and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of fire-retarding insulation lacquer improving hardness of paint film, be made up of the raw material of following weight part: epoxy resin 30-34, furfural acetone resin 8-11, itaconic ester 2-3, glycol ether benzoic ether 2-3, phenoxybenzamine base ether 4-6, p-tert-butyl benzoic acid 1-2, magnesium hypophosphite 2-4, water glass 1-3, vinyl acetic monomer 8-11, ethylene glycol 10-13, dimethylbenzene 6-8, wood fibre 1-2, bamboo pulp fiber 2-3, modifying asphalt 14-17, Reactive alumina 1-2, wolfram varbide 2-3, crystalline graphite powder 0.5-1.0, titanate coupling agent 0.4-0.9, modified abandoned clay-bonded sand 4-7,
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of fire-retarding insulation lacquer improving hardness of paint film of the present invention, be made up of following concrete steps:
(1) epoxy resin, furfural acetone resin, modifying asphalt, itaconic ester, phenoxybenzamine base ether, vinyl acetic monomer, ethylene glycol, dimethylbenzene mixing are added in reactor and are heated to 200-250 ° of C,, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, Reactive alumina, crystalline graphite powder, wolfram varbide, titanate coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Advantage of the present invention is: paint of the present invention has good film-forming properties, paint film flat smooth and there is the character of good insulativity, flame retardant resistance, acid and alkali-resistance and most of organic solvent, the discarded clay-bonded sand also adding modification strengthens erosion resistance and the resistance toheat of paint, second stage employ is carried out to refuse, saves; Energy resources protect environment, and preparation technology of the present invention is simple, of many uses, is particularly useful for the severe antiseptic projects such as boats and ships.
specific embodiments
Below by specific examples, the present invention is described in detail.
Improve a fire-retarding insulation lacquer for hardness of paint film, be made up of the raw material of following weight part (kilogram): epoxy resin 34, furfural acetone resin 8, itaconic ester 2, glycol ether benzoic ether 2, phenoxybenzamine base ether 4, p-tert-butyl benzoic acid 1, magnesium hypophosphite 2, water glass 1, vinyl acetic monomer 9, ethylene glycol 11, dimethylbenzene 7, wood fibre 2, bamboo pulp fiber 2, modifying asphalt 15, Reactive alumina 1, wolfram varbide 2, crystalline graphite powder 0.7, titanate coupling agent 0.7, modified abandoned clay-bonded sand 5;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): chlorinated rubber 13, pitch 93, stearylamide 0.3, Diisopropyl azodicarboxylate 0.2, octa-BDE 0.4, water 6, polyoxyethylenated castor oil 0.5, Magnesium Stearate 0.7, Nano carbon white 2, nano diatomite 0.6, turps 8, synourin oil 3, hexanediamine 1, rare earth nitrate 0.02, the atlapulgite 2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of fire-retarding insulation lacquer improving hardness of paint film of the present invention, be made up of following concrete steps:
(1) epoxy resin, furfural acetone resin, modifying asphalt, itaconic ester, phenoxybenzamine base ether, vinyl acetic monomer, ethylene glycol, dimethylbenzene mixing are added in reactor and are heated to 200-250 ° of C,, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, Reactive alumina, crystalline graphite powder, wolfram varbide, titanate coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
The each functional parameter of paint of the present invention is as follows: viscosity (S/25 DEG C) 80, and salt water resistance (30 days) paint film is unchanged, non-foaming, do not come off, non-corrosive, salt fog resistance (1000h) paint film is unchanged, non-foaming, do not come off, non-corrosive, resistance to distilled water (30 days) paint film is non-foaming, does not come off, sticking power (Mpa) 5.2, wear resistance (mg/500 turns) 5.3, shock-resistance (cm) 50, snappiness (mm) 1, artificial accelerated aging (1000h) paint film variable color≤2, without efflorescence flawless phenomenon.
Claims (3)
1. one kind is improved the fire-retarding insulation lacquer of hardness of paint film, it is characterized in that, be made up of the raw material of following weight part: epoxy resin 30-34, furfural acetone resin 8-11, itaconic ester 2-3, glycol ether benzoic ether 2-3, phenoxybenzamine base ether 4-6, p-tert-butyl benzoic acid 1-2, magnesium hypophosphite 2-4, water glass 1-3, vinyl acetic monomer 8-11, ethylene glycol 10-13, dimethylbenzene 6-8, wood fibre 1-2, bamboo pulp fiber 2-3, modifying asphalt 14-17, Reactive alumina 1-2, wolfram varbide 2-3, crystalline graphite powder 0.5-1.0, titanate coupling agent 0.4-0.9, modified abandoned clay-bonded sand 4-7,
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of fire-retarding insulation lacquer improving hardness of paint film according to claim 1, is characterized in that, be made up of following concrete steps:
(1) epoxy resin, furfural acetone resin, modifying asphalt, itaconic ester, phenoxybenzamine base ether, vinyl acetic monomer, ethylene glycol, dimethylbenzene mixing are added in reactor and are heated to 200-250 ° of C,, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, Reactive alumina, crystalline graphite powder, wolfram varbide, titanate coupling agent stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned clay-bonded sand according to claim 1, it is characterized in that, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
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CN201410469131.4A CN104293091A (en) | 2014-09-16 | 2014-09-16 | Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof |
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CN201410469131.4A CN104293091A (en) | 2014-09-16 | 2014-09-16 | Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106046956A (en) * | 2016-08-01 | 2016-10-26 | 安庆瑞泰化工有限公司 | Insulating water-based coating and preparation method for same |
CN107699019A (en) * | 2017-10-25 | 2018-02-16 | 成都纽兰晶茂商贸有限公司 | A kind of preparation method of anti-corrosion fire-retardant paint |
CN107987664A (en) * | 2017-11-27 | 2018-05-04 | 四川威亿塑胶制品有限公司 | High fire-retarding insulation lacquer of a kind of hardness of paint film and preparation method thereof |
EP3450509A1 (en) * | 2017-08-29 | 2019-03-06 | Kirchmayer, Johann | Composition intended to be applied to a surface for forming a salt and brine solid coating, method for producing such a composition, their use, method for coating an object and resinous coating |
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CN101153196A (en) * | 2006-09-27 | 2008-04-02 | 大日本油墨化学工业株式会社 | Aquosity composition for single rust-proof treatment of metal panel and single rust-proof treatment metal panel |
CN101386673A (en) * | 2008-09-25 | 2009-03-18 | 中国海洋石油总公司 | Oil modified epoxy resins and precoating coiled material coatings containing above resins |
JP2010018798A (en) * | 2008-06-13 | 2010-01-28 | Grow Chemical:Kk | Aqueous epoxy resin coating and foaming agent type flame retardant coating composition for indoor and outdoor use |
CN102533048A (en) * | 2011-12-21 | 2012-07-04 | 天津盛霖化工有限公司 | Archaistic floor paint and preparation method, application and using method thereof |
CN103289413A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Shock resistant and stretch proof plastic containing dimethyl silicone rubber |
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CN1760291A (en) * | 2005-11-18 | 2006-04-19 | 西北师范大学 | Anti-corrosive paint of epoxy resin based on aqueous bitumen, and preparation method |
CN1876740A (en) * | 2006-07-12 | 2006-12-13 | 海洋化工研究院 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
CN101153196A (en) * | 2006-09-27 | 2008-04-02 | 大日本油墨化学工业株式会社 | Aquosity composition for single rust-proof treatment of metal panel and single rust-proof treatment metal panel |
JP2010018798A (en) * | 2008-06-13 | 2010-01-28 | Grow Chemical:Kk | Aqueous epoxy resin coating and foaming agent type flame retardant coating composition for indoor and outdoor use |
CN101386673A (en) * | 2008-09-25 | 2009-03-18 | 中国海洋石油总公司 | Oil modified epoxy resins and precoating coiled material coatings containing above resins |
CN102533048A (en) * | 2011-12-21 | 2012-07-04 | 天津盛霖化工有限公司 | Archaistic floor paint and preparation method, application and using method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106046956A (en) * | 2016-08-01 | 2016-10-26 | 安庆瑞泰化工有限公司 | Insulating water-based coating and preparation method for same |
EP3450509A1 (en) * | 2017-08-29 | 2019-03-06 | Kirchmayer, Johann | Composition intended to be applied to a surface for forming a salt and brine solid coating, method for producing such a composition, their use, method for coating an object and resinous coating |
CN107699019A (en) * | 2017-10-25 | 2018-02-16 | 成都纽兰晶茂商贸有限公司 | A kind of preparation method of anti-corrosion fire-retardant paint |
CN107987664A (en) * | 2017-11-27 | 2018-05-04 | 四川威亿塑胶制品有限公司 | High fire-retarding insulation lacquer of a kind of hardness of paint film and preparation method thereof |
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