CN104312322A - Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof - Google Patents
Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof Download PDFInfo
- Publication number
- CN104312322A CN104312322A CN201410467536.4A CN201410467536A CN104312322A CN 104312322 A CN104312322 A CN 104312322A CN 201410467536 A CN201410467536 A CN 201410467536A CN 104312322 A CN104312322 A CN 104312322A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- add
- added
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses mildew-resistant bacteriostatic environmentally-friendly finish for ships. The mildew-resistant bacteriostatic environmentally-friendly finish for ships is prepared from 8-13 parts by weight of polyvinyl chloride resin, 35-38 parts by weight of epoxy acrylate resin, 9-14 parts by weight of medium-oil castor oil alkyd resin, 1-3 parts by weight of aryl thiourea derivative, 1-2 parts by weight of polyacrylamide, 4-6 parts by weight of m-amino-methylamine, 0.6-1.2 parts by weight of N,N-ethylene bis-stearamide, 0.4-1.0 part by weight of triethanolamine oleate, 4-6 parts by weight of diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide, 7-8 parts by weight of modified waste clay-bonded sand, 0.1-0.3 parts by weight of N, N-dimethylbenzylamine, 2-4 parts by weight of butyl glycidyl ether, 10-13 parts by weight of modified asphalt, 10-12 parts by weight of C12 alcohol ester, 6-8 parts by weight of xylene, 0.5-1.0 part by weight of nanometer boron nitride and 2-4 parts by weight of chitosan fibers. The epoxy acrylate resin as a main raw material has excellent water resistance, caking property, toughness and corrosion resistance. The used aryl thiourea derivative has good dry film corrosion resistance. The used chitosan fibers have effects of mildew prevention, bacterium inhibition, adsorption and biodegradation, do not damage the human body, can adsorb harmful particles in air and create a green and comfortable breathing environment. The used modified waste clay-bonded sand can realize change of waste into valuables and has effects of improving paint wear resistance and reducing a cost.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of fungus-resistant type ship environment-friendly type finish paint and preparation method thereof.
Background technology
Paint, it is attractive and durable, has gloss, particularly marine paints, it has the multinomial premium propertiess such as sun-proof, antirust, grease proofing, corrosion protection, antifouling, wear-resisting, cold-resistant, high temperature resistance, and it is shipbuilding n., depressed place is repaiied and indispensable important production material in ordinary maintenance maintenance.Boats and ships in operation paint that to carry out maintaining be work-ing life in order to extend boats and ships inside, outside and various equipment to greatest extent, and agree to the greatest extent to reduce hull bottom marine life, to reduce ship resistance, so require that marine paint has good sticking power, preferably water tolerance, chemical-resistant and wear resistance.
Clay-bonded sand is the molding sand using clay as binding agent, clay-bonded sand is recycling the thermolysis due to each component in process, there occurs the change of physicals, surface also has the dead clay losing viscosifying power because of heat, the ash content that coal dust etc. are residual and iron content, the composition silicate of the compositions such as aluminium, the words of recycling reduce the quality of molding sand, having to be replaced becomes Discarding Type sand, bulk deposition can have a strong impact on the quality of environmental pollution and soil, serious words are due to rainwash, wherein injurious factor can be left to river along with rainwater, the places such as plantation, finally be gathered in people's body by food chain, very large harm is brought to health, the present invention is directed to this situation discarded clay-bonded sand is carried out modification to add in paint as filler, not only reduce environmental pollution, and enhance the wear resistance of paint, thermotolerance, dispersed, strengthen the effects such as intensity.
Summary of the invention
The object of this invention is to provide a kind of fungus-resistant type ship environment-friendly type finish paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of fungus-resistant type ship environment-friendly type finish paint, be made up of the raw material of following weight part: polyvinyl chloride (PVC) RESINS 8-13, epoxy acrylic resin 35-38, medium-oil-length ricinoleyl alcohol acid resin 9-14, Arylurea derivatives 1-3, polyacrylamide 1-2, between aminomethylamine 4-6, vinyl bis-stearamides 0.6-1.2, triethanolamine oleate 0.4-1.0, 2, 4, 6 trimethyl benzoyl diphenyl base phosphine oxide 4-6, modified abandoned clay-bonded sand 7-8, N, N-dimethyl benzylamine 0.1-0.3, epoxy propane butyl ether 2-4, modifying asphalt 10-13, alcohol ester 12 10-12, dimethylbenzene 6-8, nm-class boron nitride 0.5-1.0, chitin fiber 2-4,
Described modifying asphalt is made up of the raw material of following weight part: magnesium hydroxide 0.3-0.6, AH-30 pitch 55-58, AH-70 pitch 30-34, apple anhydride dehydration resin 6-8, polyethylene terephthalate 3-5, rosin 1-2, calcium ferrite 0.4-1.0, basic lead chromate silicate 0.2-0.5, cobalt naphthenate 0.5-1.0, atlapulgite 0.3-0.7, tung oil 5-8, methyl acrylate 1-3, cyclohexanone peroxide 0.05-0.15, low molecular weight polyacrylamide viscosity-depression agent 0.4-0.9, ethanol 1-2, Tricholroacetic Acid 3-5, kerosene 2-3, cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use, polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
A kind of fungus-resistant type ship environment-friendly type finish paint of the present invention, be made up of following concrete steps:
(1) will be added in reactor after polyvinyl chloride (PVC) RESINS, epoxy acrylic resin, medium-oil-length ricinoleyl alcohol acid resin, modifying asphalt mixing, add alcohol ester 12, an aminomethylamine, polyacrylamide, N again, N-dimethyl benzylamine, dimethylbenzene, epoxy propane butyl ether are heated to 200-250 ° of C, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add vinyl bis-stearamides, modified abandoned clay-bonded sand, nm-class boron nitride, chitin fiber stirring 30-50 minute, cool to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Advantage of the present invention is: paint of the present invention take epoxy acrylic resin as major ingredient, there is excellent water tolerance, cohesiveness, toughness and erosion resistance, the Arylurea derivatives added has good dry film non-corrosibility, add chitin fiber also have good mildew-resistant, antibacterial, absorption and biodegradable performance, can not work the mischief to human body, and can unwanted particles in absorbed air, build green comfortable breathing environment, and the modified abandoned clay-bonded sand added can be turned waste into wealth, there is the effect increasing paint wearability and can reduce costs.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of fungus-resistant type ship environment-friendly type finish paint, be made up of the raw material of following weight part (kilogram): polyvinyl chloride (PVC) RESINS 13, epoxy acrylic resin 36, medium-oil-length ricinoleyl alcohol acid resin 9, Arylurea derivatives 2, polyacrylamide 1, between aminomethylamine 4, vinyl bis-stearamides 0.7, triethanolamine oleate 0.6, 2, 4, 6 trimethyl benzoyl diphenyl base phosphine oxides 4, modified abandoned clay-bonded sand 7, N, N-dimethyl benzylamine 0.3, epoxy propane butyl ether 2, modifying asphalt 10, alcohol ester 12, dimethylbenzene 5, nm-class boron nitride 0.7, chitin fiber 2,
Described modifying asphalt is made up of the raw material of following weight part (kilogram): magnesium hydroxide 0.3, AH-30 pitch 56, AH-70 pitch 30, apple anhydride dehydration resin 6, polyethylene terephthalate 4, rosin 2, calcium ferrite 0.4, basic lead chromate silicate 0.2, cobalt naphthenate 0.5, atlapulgite 0.5, tung oil 6, methyl acrylate 1, cyclohexanone peroxide 0.05, low molecular weight polyacrylamide viscosity-depression agent 0.5, ethanol 2, Tricholroacetic Acid 4, kerosene 3; Cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use; Polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
A kind of fungus-resistant type ship environment-friendly type finish paint of the present invention, be made up of following concrete steps:
(1) will be added in reactor after polyvinyl chloride (PVC) RESINS, epoxy acrylic resin, medium-oil-length ricinoleyl alcohol acid resin, modifying asphalt mixing, add alcohol ester 12, an aminomethylamine, polyacrylamide, N again, N-dimethyl benzylamine, dimethylbenzene, epoxy propane butyl ether are heated to 200-250 ° of C, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add vinyl bis-stearamides, modified abandoned clay-bonded sand, nm-class boron nitride, chitin fiber stirring 30-50 minute, cool to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Paint paint film of the present invention is smooth, bright, sticking power is good, without peeling phenomenon, snappiness is less than 2(mm), hardness is more than or equal to 2H, and shock-resistance is 50, and salt spray resistance (120h) is more than or equal to 2 grades, alkali resistance (48h) experiment show wrinkle resistant, do not come off, water-fast (4h) experiment show wrinkle resistant, do not come off, artificial weathering ageing resistance shows by 1200 hours, PASS experiment show that grade is 5.
Claims (3)
1. a fungus-resistant type ship environment-friendly type finish paint, it is characterized in that, be made up of the raw material of following weight part: polyvinyl chloride (PVC) RESINS 8-13, epoxy acrylic resin 35-38, medium-oil-length ricinoleyl alcohol acid resin 9-14, Arylurea derivatives 1-3, polyacrylamide 1-2, between aminomethylamine 4-6, vinyl bis-stearamides 0.6-1.2, triethanolamine oleate 0.4-1.0, 2, 4, 6 trimethyl benzoyl diphenyl base phosphine oxide 4-6, modified abandoned clay-bonded sand 7-8, N, N-dimethyl benzylamine 0.1-0.3, epoxy propane butyl ether 2-4, modifying asphalt 10-13, alcohol ester 12 10-12, dimethylbenzene 6-8, nm-class boron nitride 0.5-1.0, chitin fiber 2-4,
Described modifying asphalt is made up of the raw material of following weight part: magnesium hydroxide 0.3-0.6, AH-30 pitch 55-58, AH-70 pitch 30-34, apple anhydride dehydration resin 6-8, polyethylene terephthalate 3-5, rosin 1-2, calcium ferrite 0.4-1.0, basic lead chromate silicate 0.2-0.5, cobalt naphthenate 0.5-1.0, atlapulgite 0.3-0.7, tung oil 5-8, methyl acrylate 1-3, cyclohexanone peroxide 0.05-0.15, low molecular weight polyacrylamide viscosity-depression agent 0.4-0.9, ethanol 1-2, Tricholroacetic Acid 3-5, kerosene 2-3, cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use, polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
2. a kind of fungus-resistant type ship environment-friendly type finish paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) will be added in reactor after polyvinyl chloride (PVC) RESINS, epoxy acrylic resin, medium-oil-length ricinoleyl alcohol acid resin, modifying asphalt mixing, add alcohol ester 12, an aminomethylamine, polyacrylamide, N again, N-dimethyl benzylamine, dimethylbenzene, epoxy propane butyl ether are heated to 200-250 ° of C, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add vinyl bis-stearamides, modified abandoned clay-bonded sand, nm-class boron nitride, chitin fiber stirring 30-50 minute, cool to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned clay-bonded sand according to claim 1, it is characterized in that, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410467536.4A CN104312322A (en) | 2014-09-15 | 2014-09-15 | Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410467536.4A CN104312322A (en) | 2014-09-15 | 2014-09-15 | Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104312322A true CN104312322A (en) | 2015-01-28 |
Family
ID=52367647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410467536.4A Pending CN104312322A (en) | 2014-09-15 | 2014-09-15 | Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104312322A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038465A (en) * | 2015-09-09 | 2015-11-11 | 南阳理工学院 | Self-healing building inner wall electric-heating coating |
| CN106318158A (en) * | 2015-06-15 | 2017-01-11 | 天长市开林化工有限公司 | High performance alkyd resin paint special for ships |
| CN108264707A (en) * | 2018-03-02 | 2018-07-10 | 广西超盛网络科技有限责任公司 | A kind of antibiotic plastic formula |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103805030A (en) * | 2014-02-24 | 2014-05-21 | 深圳市宝骏环保涂料有限公司 | High-hardness waterborne environmental-friendly anticorrosive paint and production method thereof |
| CN103966897A (en) * | 2014-05-09 | 2014-08-06 | 吉翔宝（太仓）离型材料科技发展有限公司 | Uvioresistant antibacterial release paper and preparation method thereof |
-
2014
- 2014-09-15 CN CN201410467536.4A patent/CN104312322A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103805030A (en) * | 2014-02-24 | 2014-05-21 | 深圳市宝骏环保涂料有限公司 | High-hardness waterborne environmental-friendly anticorrosive paint and production method thereof |
| CN103966897A (en) * | 2014-05-09 | 2014-08-06 | 吉翔宝（太仓）离型材料科技发展有限公司 | Uvioresistant antibacterial release paper and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 施亦东: "《生态纺织品与环保染化助剂》", 28 February 2014 * |
| 林宣益: "《乳胶漆》", 31 July 2004 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106318158A (en) * | 2015-06-15 | 2017-01-11 | 天长市开林化工有限公司 | High performance alkyd resin paint special for ships |
| CN105038465A (en) * | 2015-09-09 | 2015-11-11 | 南阳理工学院 | Self-healing building inner wall electric-heating coating |
| CN105038465B (en) * | 2015-09-09 | 2017-03-08 | 南阳理工学院 | A kind of self-healing inner wall of building electrical heating coating |
| CN108264707A (en) * | 2018-03-02 | 2018-07-10 | 广西超盛网络科技有限责任公司 | A kind of antibiotic plastic formula |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104356884B (en) | A kind of for the low-temperature quick-drying type aqueous bottom surface of elevator rail unification protective paint and preparation method thereof | |
| CN102690589B (en) | Aqueous dispersed alkyd blend colored paint and preparation method thereof | |
| CN103992720B (en) | A kind of acrylic acid top-coat special-purpose coat and its preparation method | |
| CN101104770A (en) | Water-based epoxy intermediate paint | |
| CN102516863A (en) | Water dispersible environmentally-friendly nanometer structure automotive finish paint and preparation method thereof | |
| CN104312322A (en) | Mildew-resistant bacteriostatic environmentally-friendly finish for ships and preparation method thereof | |
| CN104293069A (en) | Mildew-proof wear-resistant asphalt paint and preparation method thereof | |
| CN104312412A (en) | Corrosion-resistant, moisture-resistant and wear-resistant paint for ships and preparation method thereof | |
| CN104530858A (en) | Water-based anticorrosive coating added with nanometer TiO2 | |
| CN106854406A (en) | A kind of aqueous antirust paint and its preparation technology for being exclusively used in submerged-arc welding | |
| CN104610840A (en) | Brightness improving and sterilizing epoxy paint and preparation method thereof | |
| CN104861751A (en) | Ship cabin sterilizing anti-corrosion anti-wear paint and preparation method thereof | |
| CN106519860A (en) | Environment-friendly industrial paint | |
| CN103360925A (en) | Modified alkyd resin paint | |
| CN104312375A (en) | Wear-resistant scratch-resistant anti-ultraviolet paint for ships and preparation method thereof | |
| CN104293091A (en) | Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof | |
| CN104293090A (en) | Flame-retardant and anti-rusting anti-adhesion epoxy paint and preparation method thereof | |
| CN104263042A (en) | Antiseptic antioxidant deodorizing green paint and preparation method thereof | |
| CN101280157A (en) | Preparation of rubber asphalt waterproof coating | |
| CN104293173A (en) | Not-easy-to-peel impact-resistant hull paint and preparation method thereof | |
| CN104449393A (en) | Super temperature-difference resistant and salt-mist corrosion resistant asphalt varnish and preparation method thereof | |
| CN104861815A (en) | Antirust anticorrosion rosin phenolic resin paint and preparation method thereof | |
| CN104312373A (en) | Epoxy paint for bacterium resistance, bacteriostasis and purification of air and preparation method thereof | |
| CN104293092A (en) | Epoxy sealing primer with enhanced property and reduced cost and preparation method thereof | |
| CN104231869A (en) | Natural corrosion-resistant oxidization-resistant epoxy insulating paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |