CN104263042A - Antiseptic antioxidant deodorizing green paint and preparation method thereof - Google Patents
Antiseptic antioxidant deodorizing green paint and preparation method thereof Download PDFInfo
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- CN104263042A CN104263042A CN201410470151.3A CN201410470151A CN104263042A CN 104263042 A CN104263042 A CN 104263042A CN 201410470151 A CN201410470151 A CN 201410470151A CN 104263042 A CN104263042 A CN 104263042A
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Abstract
The invention discloses antiseptic antioxidant deodorizing green paint. The antiseptic antioxidant deodorizing green paint is characterized by being prepared from the following raw materials in parts by weight: 34-38 parts of EP-16 epoxy resin, 7-9 parts of polyurethane adhesive, 0.5-1.0 part of potassium phosphate, 0.5-1.0 part of bismuth dilaurate, 7-9 parts of silicone acrylic emulsion, 0.5-1.0 part of oleic acid polyoxyethylene ester, 4-6 parts of mica powder, 5-7 parts of activated carbon, 0.4-1.0 part of hydroxyethyl cellulose, 0.6-1.0 part of tolyfluanid, 2-3 parts of hydrophobic silica, 8-11 parts of n-butyl acetate, 4-7 parts of trichloro ethylene, 1-2 parts of a silane coupling agent KH550, 0.4-1.0 part of N-phenyl-N'-cyclohexyl benzene diamine, 1-2 parts of 1,2-benzisothiazolin-3-ketone, 7-9 parts of modified waste clay sand and 14-16 parts of modified asphalt. The paint disclosed by the invention can reduce dangerous factors, and can slow down the corrosion and oxidation rate of a switch cabinet when being applied to a high-tension switch cabinet; the service life of the safety cabinet is greatly prolonged; the safety coefficient of the safety cabinet is greatly improved; the paint disclosed by the invention has the effects of removing the peculiar smell, and improving the weather fastness, the water resistance, the toughness and the strength; and the added modified waste clay sand has the effects of protecting the environment, reducing land pollution, enhancing the abrasive resistance of the paint, and improving the strength.
Description
Technical field
The present invention relates to clean taste environmental protection paint of a kind of paint and preparation method thereof, particularly a kind of preservation antioxidation and preparation method thereof.
Background technology
High-tension switch cabinet refers to for power system generating, transmission of electricity, distribution, electric energy conversion and plays the effects such as break-make, control or protection in consuming, and has the five anti-effects preventing on-load from closing a floodgate, prevent line with ground from closing a floodgate, preventing mistakenly entering charged chamber, prevent charged splice grafting ground wire, prevent on-load broaching tool lock.High-tension switch cabinet is generally utilize cold-rolled steel to shape through numerical control metal plate, and in order to prevent the problems such as the burn into of material gets rusty, the paint for switching cabinet must have the performance of the aspects such as anticorrosive, antirust, insulation.
Epoxy resin-based paint take epoxy resin-based paint as the coating of main film forming substance.Strong adhesion, chemical-resistant, preservative property, water tolerance, thermostability and electrical insulating property are excellent, are widely used in the aspects such as building, chemical industry, automobile, naval vessel, electric insulation.
Clay-bonded sand is the molding sand using clay as binding agent, clay-bonded sand is recycling the thermolysis due to each component in process, there occurs the change of physicals, surface also has the dead clay losing viscosifying power because of heat, the ash content that coal dust etc. are residual and iron content, the composition silicate of the compositions such as aluminium, the words of recycling reduce the quality of molding sand, having to be replaced becomes Discarding Type sand, bulk deposition can have a strong impact on the quality of environmental pollution and soil, serious words are due to rainwash, wherein injurious factor can be left to river along with rainwater, the places such as plantation, finally be gathered in people's body by food chain, very large harm is brought to health, the present invention is directed to this situation discarded clay-bonded sand is carried out modification to add in paint as filler, not only reduce environmental pollution, and enhance the wear resistance of paint, thermotolerance, dispersed, strengthen the effects such as intensity.
Summary of the invention
Clean taste environmental protection paint that the object of this invention is to provide a kind of preservation antioxidation and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of clean taste environmental protection paint of preservation antioxidation, be made up of the raw material of following weight part: EP-16 epoxy resin 34-38, adhesive for polyurethane 7-9, potassium pyrophosphate 0.5-1.0, tin dilaurate bismuth 0.5-1.0, organosilicon crylic acid latex 7-9, polyoxyethylene oleic acid ester 0.5-1.0, mica powder 4-6, gac 5-7, Natvosol 0.4-1.0, Tolylfluanid 0.6-1.0, water drain silica 2-3, N-BUTYL ACETATE 8-11, trieline 4-7, Silane coupling agent KH550 1-2, N-phenyl-N '-cyclohexyl Ursol D 0.4-1.0, 1, 2-benzisothiazole-3-ketone 1-2, modified abandoned clay-bonded sand 7-9, modifying asphalt 14-16,
Described modifying asphalt is made up of the raw material of following weight part: magnesium hydroxide 0.3-0.6, AH-30 pitch 55-58, AH-70 pitch 30-34, apple anhydride dehydration resin 6-8, polyethylene terephthalate 3-5, rosin 1-2, calcium ferrite 0.4-1.0, basic lead chromate silicate 0.2-0.5, cobalt naphthenate 0.5-1.0, atlapulgite 0.3-0.7, tung oil 5-8, methyl acrylate 1-3, cyclohexanone peroxide 0.05-0.15, low molecular weight polyacrylamide viscosity-depression agent 0.4-0.9, ethanol 1-2, Tricholroacetic Acid 3-5, kerosene 2-3, cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use, polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
The clean taste environmental protection paint of a kind of preservation antioxidation of the present invention, be made up of following concrete steps:
(1) EP-16 epoxy resin, modifying asphalt mixing are added in reactor and are heated to 50-70 ° of C, after stirring, add polyoxyethylene oleic acid ester again, potassium pyrophosphate, adhesive for polyurethane, N-BUTYL ACETATE, trieline stir 1-1.5 hour under 600-800 rev/min;
(2) under identical rotating speed, add mica powder, gac, water drain silica, modification molding sand, organosilicon crylic acid latex, Silane coupling agent KH550 stirring 30-50 minute, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Advantage of the present invention is: paint of the present invention is used for the speed that high-tension switch cabinet can reduce Hazard Factor, slow down the oxidation of switching cabinet burn into, greatly improves work-ing life and the safety coefficient of safety cabinet; The organosilicon crylic acid latex that the present invention adds has the effect only eliminating the unusual smell, improve weathering resistance, water tolerance; the modifying asphalt added can improve the deficiency of epoxy resin-based paint; improve the effect of the weathering resistance of paint, toughness, intensity greatly; the modified abandoned clay-bonded sand added has protection of the environment, reduces Land pollution and strengthens the wear resistance of paint and improve the effect of intensity.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of clean taste environmental protection paint of preservation antioxidation, be made up of the raw material of following weight part (kilogram): EP-16 epoxy resin 35, adhesive for polyurethane 7, potassium pyrophosphate 0.6, tin dilaurate bismuth 0.5, organosilicon crylic acid latex 7, polyoxyethylene oleic acid ester 0.5, mica powder 4, gac 5, Natvosol 0.4, Tolylfluanid 0.6 water drain silica 2, N-BUTYL ACETATE 10, trieline 6, Silane coupling agent KH550 1, N-phenyl-N '-cyclohexyl Ursol D 0.4, BIT 1, modified abandoned clay-bonded sand 8, modifying asphalt 14;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): magnesium hydroxide 0.3, AH-30 pitch 56, AH-70 pitch 30, apple anhydride dehydration resin 6, polyethylene terephthalate 4, rosin 2, calcium ferrite 0.4, basic lead chromate silicate 0.2, cobalt naphthenate 0.5, atlapulgite 0.5, tung oil 6, methyl acrylate 1, cyclohexanone peroxide 0.05, low molecular weight polyacrylamide viscosity-depression agent 0.5, ethanol 2, Tricholroacetic Acid 4, kerosene 3; Cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use; Polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
The clean taste environmental protection paint of a kind of preservation antioxidation of the present invention, be made up of following concrete steps:
(1) EP-16 epoxy resin, modifying asphalt mixing are added in reactor and are heated to 50-70 ° of C, after stirring, add polyoxyethylene oleic acid ester again, potassium pyrophosphate, adhesive for polyurethane, N-BUTYL ACETATE, trieline stir 1-1.5 hour under 600-800 rev/min;
(2) under identical rotating speed, add mica powder, gac, water drain silica, modification molding sand, organosilicon crylic acid latex, Silane coupling agent KH550 stirring 30-50 minute, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Paint paint film of the present invention is smooth, bright, and density is 1.26 g/cm
3alkali resistance (48h) experiment show wrinkle resistant, do not come off, acid resistance (48h) experiment show wrinkle resistant, do not fade, water-fast (4h) experiment shows without obscission, wear test shows that wear resistance is good, PASS experiment shows that grade is less than or equal to 1, and snappiness is less than 1mm, and shock strength is for being greater than 50kg/cm.
Claims (3)
1. the clean taste environmental protection paint of a preservation antioxidation, it is characterized in that, be made up of the raw material of following weight part: EP-16 epoxy resin 34-38, adhesive for polyurethane 7-9, potassium pyrophosphate 0.5-1.0, tin dilaurate bismuth 0.5-1.0, organosilicon crylic acid latex 7-9, polyoxyethylene oleic acid ester 0.5-1.0, mica powder 4-6, gac 5-7, Natvosol 0.4-1.0, Tolylfluanid 0.6-1.0, water drain silica 2-3, N-BUTYL ACETATE 8-11, trieline 4-7, Silane coupling agent KH550 1-2, N-phenyl-N '-cyclohexyl Ursol D 0.4-1.0, 1, 2-benzisothiazole-3-ketone 1-2, modified abandoned clay-bonded sand 7-9, modifying asphalt 14-16,
Described modifying asphalt is made up of the raw material of following weight part: magnesium hydroxide 0.3-0.6, AH-30 pitch 55-58, AH-70 pitch 30-34, apple anhydride dehydration resin 6-8, polyethylene terephthalate 3-5, rosin 1-2, calcium ferrite 0.4-1.0, basic lead chromate silicate 0.2-0.5, cobalt naphthenate 0.5-1.0, atlapulgite 0.3-0.7, tung oil 5-8, methyl acrylate 1-3, cyclohexanone peroxide 0.05-0.15, low molecular weight polyacrylamide viscosity-depression agent 0.4-0.9, ethanol 1-2, Tricholroacetic Acid 3-5, kerosene 2-3, cyclohexanone peroxide is dissolved in ethanol by preparation method, is added in tung oil by solution and methyl acrylate, and mix and blend is heated to mixture and occurs wire drawing phenomenon, stops heating, and being cooled to room temperature, to obtain modified tung oil for subsequent use, polyethylene terephthalate is heated to molten state, add apple anhydride dehydration resin, rosin and Tricholroacetic Acid to be again uniformly mixed, temperature is controlled at 120-130 ° of C, add AH-70 pitch, AH-30 pitch and modified tung oil again and stir 1-1.5 hour at 1200-1400 rev/min of down cut, add all the other surplus materialss again, and within 20-40 minute, filter with identical rotating speed grinding distribution.
2. the clean taste environmental protection paint of a kind of preservation antioxidation according to claim 1, is characterized in that, be made up of following concrete steps:
(1) EP-16 epoxy resin, modifying asphalt mixing are added in reactor and are heated to 50-70 ° of C, after stirring, add polyoxyethylene oleic acid ester again, potassium pyrophosphate, adhesive for polyurethane, N-BUTYL ACETATE, trieline stir 1-1.5 hour under 600-800 rev/min;
(2) under identical rotating speed, add mica powder, gac, water drain silica, modification molding sand, organosilicon crylic acid latex, Silane coupling agent KH550 stirring 30-50 minute, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned clay-bonded sand according to claim 1, it is characterized in that, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the sulphuric acid soln of 30% and soak 30-50 minute, wash with water again to neutrality and dry, add the discarded wilkinite of clay-bonded sand weight 15% again and the titanium dioxide of 10% is ground to 400 order-600 order fine powders, add the distearyl acyl-oxygen aluminum isopropoxide acid esters mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410470151.3A CN104263042A (en) | 2014-09-16 | 2014-09-16 | Antiseptic antioxidant deodorizing green paint and preparation method thereof |
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| CN201410470151.3A CN104263042A (en) | 2014-09-16 | 2014-09-16 | Antiseptic antioxidant deodorizing green paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047082A (en) * | 2016-08-12 | 2016-10-26 | 安庆市七仙女电器制造有限公司 | Scratch-resistant coating for hair dryer and preparation method thereof |
| CN115449272A (en) * | 2022-10-21 | 2022-12-09 | 南通千诚电子科技有限公司 | Formula and production process of anti-cracking environment-friendly paint for plate surface treatment |
| CN115746662A (en) * | 2022-11-21 | 2023-03-07 | 南通千诚电子科技有限公司 | Efficient manufacturing process of intelligent display cabinet |
| CN116515333A (en) * | 2023-02-09 | 2023-08-01 | 山西新虹涂材料有限公司 | Production method of environment-friendly waste material recycling paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62285962A (en) * | 1986-06-03 | 1987-12-11 | Kubota Ltd | Emulsion paint |
| CN102898912A (en) * | 2012-09-07 | 2013-01-30 | 南通博宇机电有限公司 | Electromechanical corrosion resistance coating material |
| CN103540225A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Electrical cabinet anti-corrosive base coat and preparation method thereof |
| CN103773151A (en) * | 2014-02-10 | 2014-05-07 | 南通新昱化工有限公司 | High temperature resistance acid-proof alkali-proof coating |
-
2014
- 2014-09-16 CN CN201410470151.3A patent/CN104263042A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62285962A (en) * | 1986-06-03 | 1987-12-11 | Kubota Ltd | Emulsion paint |
| CN102898912A (en) * | 2012-09-07 | 2013-01-30 | 南通博宇机电有限公司 | Electromechanical corrosion resistance coating material |
| CN103540225A (en) * | 2013-10-28 | 2014-01-29 | 安徽明都电气有限公司 | Electrical cabinet anti-corrosive base coat and preparation method thereof |
| CN103773151A (en) * | 2014-02-10 | 2014-05-07 | 南通新昱化工有限公司 | High temperature resistance acid-proof alkali-proof coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047082A (en) * | 2016-08-12 | 2016-10-26 | 安庆市七仙女电器制造有限公司 | Scratch-resistant coating for hair dryer and preparation method thereof |
| CN115449272A (en) * | 2022-10-21 | 2022-12-09 | 南通千诚电子科技有限公司 | Formula and production process of anti-cracking environment-friendly paint for plate surface treatment |
| CN115746662A (en) * | 2022-11-21 | 2023-03-07 | 南通千诚电子科技有限公司 | Efficient manufacturing process of intelligent display cabinet |
| CN116515333A (en) * | 2023-02-09 | 2023-08-01 | 山西新虹涂材料有限公司 | Production method of environment-friendly waste material recycling paint |
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Application publication date: 20150107 |