CN104293090A - Flame-retardant and anti-rusting anti-adhesion epoxy paint and preparation method thereof - Google Patents
Flame-retardant and anti-rusting anti-adhesion epoxy paint and preparation method thereof Download PDFInfo
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- CN104293090A CN104293090A CN201410469116.XA CN201410469116A CN104293090A CN 104293090 A CN104293090 A CN 104293090A CN 201410469116 A CN201410469116 A CN 201410469116A CN 104293090 A CN104293090 A CN 104293090A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses flame-retardant and anti-rusting anti-adhesion epoxy paint which is characterized by being prepared from the following raw materials in parts by weight: 30-40 parts of E-51 epoxy resin, 12-17 parts of fluorosilicone resin, 8-12 parts of polybutadiene epoxy resin, 3-5 parts of vinyl triamine, 2-3 parts of urotropine, 0.4-0.8 part of bis(P,P-bis-ethylhexyl diphosphato)ethanediolato titanate, 12-15 parts of modified asphalt, 2-4 parts of asbestos, 1-2 parts of sodium silicate, 3-6 parts of modified waste clay sand, 3-4 parts of hexachlorocyclopentadiene, 1-3 parts of p-nitrobenzoic acid, 3-4 parts of single methyl phosphinic acid calcium, 0.5-1.0 part of phenethyl naphthol polyoxyethylene ether, 2-4 parts of nano calcium carbonate, 5-7 parts of diethylene glycol, 7-9 parts of xylene and 9-13 parts of acetic ether. The fluorosilicone resin added into the paint disclosed by the invention is excellent in temperature resistance, adhesion prevention, chemical resistance, antifouling property and rain corrosion resistance; the mutual synergistic effects of pentaerythritol phosphate, single methyl phosphinic acid calcium and hexachlorocyclopentadiene added into the paint are brought into play, so that the flame retardancy of the paint is improved; as the waste clay sand is modified and added into the paint, both the cost of the paint is lowered, the weather resistance and corrosion resistance of the paint are improved, and the environment pollution is also alleviated.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of fire-retardant antirust antiseized resistant epoxy paint and preparation method thereof.
Background technology
According to statistics, the direct economic loss that China causes due to metallic corrosion every year accounts for 4% of gross national product.Corrosion of metal not only causes huge waste of material, and also result in huge financial loss.Therefore the Anticorrosion Problems of metal more and more causes the concern of people.Paint and be widely used in all kinds of construction work and family, public place decoration, along with the raising of people's living standard, the use of various electrical equipment etc., adds the potential safety hazard of fire, so the paint with Fireproof fire retardation type arises at the historic moment.
Clay-bonded sand is the molding sand using clay as binding agent, clay-bonded sand is recycling the thermolysis due to each component in process, there occurs the change of physicals, surface also has the dead clay losing viscosifying power because of heat, the ash content that coal dust etc. are residual and iron content, the composition silicate of the compositions such as aluminium, the words of recycling reduce the quality of molding sand, having to be replaced becomes Discarding Type sand, bulk deposition can have a strong impact on the quality of environmental pollution and soil, serious words are due to rainwash, wherein injurious factor can be left to river along with rainwater, the places such as plantation, finally be gathered in people's body by food chain, very large harm is brought to health, the present invention is directed to this situation discarded clay-bonded sand is carried out modification to add in paint as filler, not only reduce environmental pollution, and enhance the weathering resistance of paint, thermotolerance, erosion resistance, reduce the effect of production cost etc.
Summary of the invention
The object of this invention is to provide a kind of fire-retardant antirust antiseized resistant epoxy paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of fire-retardant antirust antiseized resistant epoxy paint, be made up of the raw material of following weight part: E-51 epoxy resin 30-40, fluorine silicon resin 12-17, polybutadiene epoxy resin 8-12, vinyl triamine 3-5, Wu Tuoluo product 2-3, Di(dioctylpyrophosphato) ethylene titanate 0.4-0.8, modifying asphalt 12-15, asbestos 2-4, water glass 1-2, modified abandoned clay-bonded sand 3-6, hexachlorocyclopentadiene 3-4, p-nitrobenzoic acid 1-3, monomethyl phospho acid calcium 3-4, styroyl naphthols Soxylat A 25-7 0.5-1.0, nano-calcium carbonate 2-4, glycol ether 5-7, dimethylbenzene 7-9, vinyl acetic monomer 9-13,
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of fire-retardant antirust antiseized resistant epoxy paint of the present invention, be made up of following concrete steps:
(1) E-51 epoxy resin, fluorine silicon resin, polybutadiene epoxy resin, modifying asphalt, vinyl triamine, vinyl acetic monomer, glycol ether, dimethylbenzene are added in reactor, be heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, asbestos, water glass, nano-calcium carbonate, Di(dioctylpyrophosphato) ethylene titanate stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
Advantage of the present invention is: the fluorine silicon resin that paint of the present invention adds has the effect of excellent temperature tolerance, resistance to bond, chemical-resistant, didirtresistance, anti-weathering, the pentaerythritol phosphate added, monomethyl phospho acid calcium and hexachlorocyclopentadiene act synergistically mutually, improve the flame retardant properties of paint, discarded clay-bonded sand is also carried out modification and adds in paint by the present invention, both the cost of paint had been reduced, improve weathering resistance and the erosion resistance of paint, also reduce the pollution of environment.
specific embodiments
Below by specific examples, the present invention is described in detail.
A fire-retardant antirust antiseized resistant epoxy paint, is made up of the raw material of following weight part (kilogram): E-51 epoxy resin 35, fluorine silicon resin 14, polybutadiene epoxy resin 9, vinyl triamine 4, Wu Tuoluo product 2, Di(dioctylpyrophosphato) ethylene titanate 0.5, modifying asphalt 12, asbestos 3, water glass 1, modified abandoned clay-bonded sand 4, hexachlorocyclopentadiene 3, p-nitrobenzoic acid 1, monomethyl phospho acid calcium 3, styroyl naphthols Soxylat A 25-7 0.6, nano-calcium carbonate 2, glycol ether 6, dimethylbenzene 8, vinyl acetic monomer 11;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): chlorinated rubber 13, pitch 93, stearylamide 0.3, Diisopropyl azodicarboxylate 0.2, octa-BDE 0.4, water 6, polyoxyethylenated castor oil 0.5, Magnesium Stearate 0.7, Nano carbon white 2, nano diatomite 0.6, turps 8, synourin oil 3, hexanediamine 1, rare earth nitrate 0.02, the atlapulgite 2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of fire-retardant antirust antiseized resistant epoxy paint of the present invention, be made up of following concrete steps:
(1) E-51 epoxy resin, fluorine silicon resin, polybutadiene epoxy resin, modifying asphalt, vinyl triamine, vinyl acetic monomer, glycol ether, dimethylbenzene are added in reactor, be heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, asbestos, water glass, nano-calcium carbonate, Di(dioctylpyrophosphato) ethylene titanate stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned clay-bonded sand of the present invention, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
The each functional parameter of paint of the present invention is as follows: viscosity (S/25 DEG C) 77, and salt water resistance (30 days) paint film is unchanged, non-foaming, do not come off, non-corrosive, salt fog resistance (1000h) paint film is unchanged, non-foaming, do not come off, non-corrosive, resistance to distilled water (30 days) paint film is non-foaming, does not come off, sticking power (Mpa) 5.5, wear resistance (mg/500 turns) 5.7, shock-resistance (cm) 50, snappiness (mm) 1, artificial accelerated aging (1000h) paint film variable color≤2, without efflorescence flawless phenomenon.
Claims (3)
1. a fire-retardant antirust antiseized resistant epoxy paint, it is characterized in that, be made up of the raw material of following weight part: E-51 epoxy resin 30-40, fluorine silicon resin 12-17, polybutadiene epoxy resin 8-12, vinyl triamine 3-5, Wu Tuoluo product 2-3, Di(dioctylpyrophosphato) ethylene titanate 0.4-0.8, modifying asphalt 12-15, asbestos 2-4, water glass 1-2, modified abandoned clay-bonded sand 3-6, hexachlorocyclopentadiene 3-4, p-nitrobenzoic acid 1-3, monomethyl phospho acid calcium 3-4, styroyl naphthols Soxylat A 25-7 0.5-1.0, nano-calcium carbonate 2-4, glycol ether 5-7, dimethylbenzene 7-9, vinyl acetic monomer 9-13,
Described modifying asphalt is made up of the raw material of following weight part: chlorinated rubber 11-14, pitch 92-94, stearylamide 0.2-0.4, Diisopropyl azodicarboxylate 0.2-0.4, octa-BDE 0.3-0.7, water 5-8, polyoxyethylenated castor oil 0.3-0.6, Magnesium Stearate 0.6-1.2, Nano carbon white 1-2, nano diatomite 0.4-0.8, turps 6-9, synourin oil 2-3, hexanediamine 1-2, rare earth nitrate 0.02-0.07, the atlapulgite 1-2 of 40%; Preparation method is to 150-190 ° of C by asphalt heating, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then the mixing of Magnesium Stearate, polyoxyethylenated castor oil, Nano carbon white, nano diatomite, synourin oil, Diisopropyl azodicarboxylate and water is heated to 60-90 ° of C and forms mixing solutions, again by the mixing of the chlorinated rubber of 40%, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of fire-retardant antirust antiseized resistant epoxy paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) E-51 epoxy resin, fluorine silicon resin, polybutadiene epoxy resin, modifying asphalt, vinyl triamine, vinyl acetic monomer, glycol ether, dimethylbenzene are added in reactor, be heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned clay-bonded sand, asbestos, water glass, nano-calcium carbonate, Di(dioctylpyrophosphato) ethylene titanate stirring 30-50 minute, temperature is reduced to 50-80 ° of C and adds all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned clay-bonded sand according to claim 1, it is characterized in that, discarded clay-bonded sand is added in rotary grinding device by preparation method, by clashing into, the dirt settling of sand grain surface is removed, again the material after grinding is added in Fluo-Solids roaster, high-temperature roasting 1-2 hour under 500-700 ° of C, be added to after cooling in the hydrochloric acid soln of 20% and soak 30-50 minute, wash with water again to neutrality and dry, add the halloysite of discarded clay-bonded sand weight 8% again, the wollastonite of 8% and the bentonite of 10% are ground to 400 order-600 order fine powders, add the isopropyl tri (dioctylphosphato)titanate mixed grinding of discarded clay-bonded sand weight 0.5-1% more evenly.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410469116.XA CN104293090A (en) | 2014-09-16 | 2014-09-16 | Flame-retardant and anti-rusting anti-adhesion epoxy paint and preparation method thereof |
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| CN201410469116.XA CN104293090A (en) | 2014-09-16 | 2014-09-16 | Flame-retardant and anti-rusting anti-adhesion epoxy paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802399A (en) * | 2016-03-25 | 2016-07-27 | 徐洁 | Method for preparing steel structure water-based fireproof paint |
| CN108129890A (en) * | 2017-12-25 | 2018-06-08 | 衢州南高峰化工股份有限公司 | A kind of organic fluorinated silicone modified corrosion-resistant epoxy paint and Organic fluoride modified epoxy corrosion-inhibiting coating |
| CN111019443A (en) * | 2019-12-24 | 2020-04-17 | 国网山东省电力公司临沂供电公司 | Anticorrosive paint for underground cable and preparation method thereof |
| CN111363421A (en) * | 2020-04-24 | 2020-07-03 | 衢州市闻天化工有限公司 | Fluorine-silicon nano waterproof heat-insulation composite material and preparation method thereof |
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| JPS58171456A (en) * | 1982-03-08 | 1983-10-08 | Dainichi Seika Kogyo Kk | Coating composition for road and floor |
| US20120104319A1 (en) * | 2009-04-01 | 2012-05-03 | David Postma | Luminescent paints and methods of making the same |
| CN103382332A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Antirust flame-retardant modified fluorine-silicon coating |
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103602114A (en) * | 2013-10-22 | 2014-02-26 | 芜湖市鸿坤汽车零部件有限公司 | Wear-resistant pressure-resistant epoxy paint and preparation method thereof |
-
2014
- 2014-09-16 CN CN201410469116.XA patent/CN104293090A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58171456A (en) * | 1982-03-08 | 1983-10-08 | Dainichi Seika Kogyo Kk | Coating composition for road and floor |
| US20120104319A1 (en) * | 2009-04-01 | 2012-05-03 | David Postma | Luminescent paints and methods of making the same |
| CN103382332A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Antirust flame-retardant modified fluorine-silicon coating |
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103602114A (en) * | 2013-10-22 | 2014-02-26 | 芜湖市鸿坤汽车零部件有限公司 | Wear-resistant pressure-resistant epoxy paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802399A (en) * | 2016-03-25 | 2016-07-27 | 徐洁 | Method for preparing steel structure water-based fireproof paint |
| CN108129890A (en) * | 2017-12-25 | 2018-06-08 | 衢州南高峰化工股份有限公司 | A kind of organic fluorinated silicone modified corrosion-resistant epoxy paint and Organic fluoride modified epoxy corrosion-inhibiting coating |
| CN108129890B (en) * | 2017-12-25 | 2020-01-21 | 衢州南高峰化工股份有限公司 | Organic fluorine-silicon modified epoxy anticorrosive paint and organic fluorine-modified epoxy anticorrosive coating |
| CN111019443A (en) * | 2019-12-24 | 2020-04-17 | 国网山东省电力公司临沂供电公司 | Anticorrosive paint for underground cable and preparation method thereof |
| CN111363421A (en) * | 2020-04-24 | 2020-07-03 | 衢州市闻天化工有限公司 | Fluorine-silicon nano waterproof heat-insulation composite material and preparation method thereof |
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Application publication date: 20150121 |