CN104312375A - Wear-resistant scratch-resistant anti-ultraviolet paint for ships and preparation method thereof - Google Patents
Wear-resistant scratch-resistant anti-ultraviolet paint for ships and preparation method thereof Download PDFInfo
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- CN104312375A CN104312375A CN201410467567.XA CN201410467567A CN104312375A CN 104312375 A CN104312375 A CN 104312375A CN 201410467567 A CN201410467567 A CN 201410467567A CN 104312375 A CN104312375 A CN 104312375A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses wear-resistant scratch-resistant anti-ultraviolet paint for ships and a preparation method thereof. The wear-resistant scratch-resistant anti-ultraviolet paint for ships is prepared from 30-36 parts by weight of E-44 epoxy resin, 15-17 parts by weight of rosin-modified phenolic resin, 5-7 parts by weight of polycarbonate, 2-3 parts by weight of white spirit, 6-8 parts by weight of butyl acetate, 10-15 parts by weight of dimethyl acetamide, 0.5-0.7 parts by weight of an antirust agent, 1-2 parts by weight of a silane coupling agent KH-550, 6-8 parts by weight of nanometer white clay, 4-6 parts by weight of methylene bis(cyclohexylammonium), 3-5 parts by weight of carborundum, 1-2 parts by weight of zinc powder, 2-3 parts by weight of butyltin tris(2-ethylhexanoate), 1-2 parts by weight of wood oil, 8-12 parts by weight of modified asphalt, 8-11 parts by weight of xylene and 6-9 parts by weight of modified waste sodium silicate sand. The used polycarbonate has good resistance to impact and thermal distortion and has good weatherability and high hardness. The used wood oil has wear resistance, scratch resistance, improved surface hardness and strength, good water resistance, ultraviolet resistance and weatherability. The used carborundum has effects of improving paint film wear resistance. The used modified waste sodium silicate sand protects the environment, realizes recycle of wastes, saves resources, improves paint heat resistance and flame resistance and improves paint quality.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of boats and ships of antiultraviolet of antifriction scuff are painted and preparation method thereof.
Background technology
Boats and ships are among ocean environment for a long time; ocean and land natural condition difference very large; there is salt fog ocean and band slight alkalinity, wherein seawater is more much harder than land to corrosion of metal, in ocean, also have diversified marine attaching organism; they can above alow adhere to; affect the ship speed of a ship or plane, increase fuel consumption, also have strong ultraviolet etc. simultaneously; if do not take sfgd., the work-ing life of boats and ships is very short.Marine paint is the tailor-(made) coating on ships; be used for protecting ship, naval vessels, offshore oil to adopt platform, harbour piling bar and offshore steel iron construction not by sea-water corrosion; marine paint must have excellent water tolerance, rust-preventing characteristic, erosion resistance etc., little to human toxicity during construction.
Sodium silicate sand is formed by silica sand, water glass and additional thing mixed preparing.Water glass is colourless, odorless, nontoxic, be stained with to rinse with water after skin and clothes and namely have not big harm, but avoid being splashed in eye.Water glass does not all have the spilling of pungency or toxic gas in casting cycle, but the add-on of water past glass is large, and collapsibility is poor, and on-the-spot in sand removal, silica dust flies upward, and causes silica dust to pollute, and regenerating used difficulty, goes out of use in a large number, cause the alkaline pollution of environment.Widely, be used to manufacture the various silicates products such as silica gel, metasilicate pentahydrate sodium, silicon sol, sodium-potassium silicate at chemical system, be the basic raw material of silicon compound to the purposes of water glass; Being indispensable raw material in the washing composition such as washing powder, soap in light industry, is also water softener, settling agent; For helping dye, bleaching and sizing in textile industry; Casting, emery wheel manufacture and anticolodal etc. are widely used in machinery industry; For the manufacture of rapid hardening cement, acid-proof cement dubbin, soil-solidified-agent, refractory materials etc. in building trade; Agriculturally can manufacture silicon element fertilizer material; Be used as the high temperature material such as filler, laboratory crucibles of soap, anticolodal, water-softening agent, detergent builder, refractory materials and ceramic raw material, waterproof, leak stopping, fire retarding wood protection, food antiseptic and preparing adhesive etc. in addition.The present invention is directed to this situation waste water glass sand is carried out modification to add in paint as filler, not only reduce environmental pollution, and enhance the effect such as acid resistance, thermotolerance, dispersiveness, fire line of paint.
Summary of the invention
The boats and ships that the object of this invention is to provide a kind of antiultraviolet of antifriction scuff are painted and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of boats and ships of antiultraviolet of antifriction scuff are painted, and are made up of the raw material of following weight part: E-44 epoxy resin 30-36, rosin phenolic resin 15-17, polycarbonate 5-7, painter's naphtha 2-3, butylacetate 6-8, N,N-DIMETHYLACETAMIDE 10-15, rust-preventive agent 0.5-0.7, silane resin acceptor kh-550 1-2, nanometer carclazyte 6-8, methylene-bis hexamethylene alkanamine 4-6, silicon carbide 3-5, zinc powder 1-2, three sad butyl tin 2-3, wood oil 1-2, modifying asphalt 8-12, dimethylbenzene 8-11, modified abandoned sodium silicate sand 6-9;
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
The boats and ships of the antiultraviolet of a kind of wear-resisting scuff of the present invention are painted, and are made up of following concrete steps:
(1) E-44 epoxy resin, rosin phenolic resin, polycarbonate, modifying asphalt, dimethylbenzene, butylacetate, N,N-DIMETHYLACETAMIDE, methylene-bis hexamethylene alkanamine, painter's naphtha, wood oil mixing are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add nanometer carclazyte, silicon carbide, zinc powder, silane resin acceptor kh-550 stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
The invention has the advantages that: the polycarbonate that paint of the present invention adds has good shock resistance, resisting heat distortion performance; and good weatherability, hardness are high; the wood oil added has wear-resisting scuff, strengthens surface hardness and intensity, good waterproof performance, anti-ultraviolet and weather-resistance are good; the silicon carbide added also has the effect improving paint film wear resisting property; the present invention also adds modified abandoned sodium silicate sand; not only protect environment to carry out refuse second stage employ and economize on resources; but also improve the thermotolerance of paint and the effect of fire line, improve the quality of paint.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of boats and ships of antiultraviolet of wear-resisting scuff are painted, and are made up of the raw material of following weight part (kilogram): E-44 epoxy resin 33, rosin phenolic resin 16, polycarbonate 6, painter's naphtha 2, butylacetate 6, N,N-DIMETHYLACETAMIDE 13, rust-preventive agent 0.5, silane resin acceptor kh-550 1, nanometer carclazyte 6, methylene-bis hexamethylene alkanamine 5, silicon carbide 3, the sad butyl tin 2 of zinc powder 1, three, wood oil 2, modifying asphalt 9, dimethylbenzene 8, modified abandoned sodium silicate sand 7;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): pitch 82, aluminum stearate 0.5, C9 petroleum resin 5, carboxymethyl cellulose 1, thermoplastic elastomer 0.6, nano montmorillonite powder 2, polyethylene wax 0.4, dioctyl phthalate (DOP) 0.4, ester gum 0.7, isocaprylic acid zinc 0.3, fibrous magnesium silicate 1, polyoxyethylene gather fatty alcohol-ether 0.6, linseed oil 7, maleic acid 0.7, water 12, acetic acid butanols 2; Maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely; By asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
The boats and ships of the antiultraviolet of a kind of wear-resisting scuff of the present invention are painted, and are made up of following concrete steps:
(4) E-44 epoxy resin, rosin phenolic resin, polycarbonate, modifying asphalt, dimethylbenzene, butylacetate, N,N-DIMETHYLACETAMIDE, methylene-bis hexamethylene alkanamine, painter's naphtha, wood oil mixing are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(5) under identical rotating speed, add nanometer carclazyte, silicon carbide, zinc powder, silane resin acceptor kh-550 stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(6) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Paint paint film flat smooth of the present invention, shock-resistance (/cm) 50, snappiness (mm) 1, sticking power (Mpa) 6, artificial accelerated aging (1000h) paint film without efflorescence, without variable color, flawless, salt spray resistance (1000h) paint film is non-foaming, does not come off, non-corrosive, water tolerance (27 ° of C ± 6 ° C, 500h) paint film is non-foaming, does not come off, non-corrosive, oil-proofness (96# gasoline, 120h) is non-foaming, does not soften, do not come off, abrasion-resistant (500g, 500 turns)/mg 6.3.
Claims (3)
1. the boats and ships of the antiultraviolet of an antifriction scuff are painted, it is characterized in that, be made up of the raw material of following weight part: E-44 epoxy resin 30-36, rosin phenolic resin 15-17, polycarbonate 5-7, painter's naphtha 2-3, butylacetate 6-8, N,N-DIMETHYLACETAMIDE 10-15, rust-preventive agent 0.5-0.7, silane resin acceptor kh-550 1-2, nanometer carclazyte 6-8, methylene-bis hexamethylene alkanamine 4-6, silicon carbide 3-5, zinc powder 1-2, three sad butyl tin 2-3, wood oil 1-2, modifying asphalt 8-12, dimethylbenzene 8-11, modified abandoned sodium silicate sand 6-9;
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of boats and ships of antiultraviolet of wear-resisting scuff are painted according to claim 1, it is characterized in that, are made up of following concrete steps:
E-44 epoxy resin, rosin phenolic resin, polycarbonate, modifying asphalt, dimethylbenzene, butylacetate, N,N-DIMETHYLACETAMIDE, methylene-bis hexamethylene alkanamine, painter's naphtha, wood oil mixing are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stirs 2-3 hour;
Nanometer carclazyte, silicon carbide, zinc powder, silane resin acceptor kh-550 stirring 30-50 minute is added under identical rotating speed, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
Finely dispersed material is added in filter and filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtration.
3. modified abandoned sodium silicate sand according to claim 1, it is characterized in that, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
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| CN201410467567.XA CN104312375A (en) | 2014-09-15 | 2014-09-15 | Wear-resistant scratch-resistant anti-ultraviolet paint for ships and preparation method thereof |
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| CN201410467567.XA CN104312375A (en) | 2014-09-15 | 2014-09-15 | Wear-resistant scratch-resistant anti-ultraviolet paint for ships and preparation method thereof |
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Cited By (5)
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| CN104861815A (en) * | 2015-04-08 | 2015-08-26 | 天长市巨龙车船涂料有限公司 | Antirust anticorrosion rosin phenolic resin paint and preparation method thereof |
| CN107952487A (en) * | 2017-12-10 | 2018-04-24 | 江苏师范大学 | A kind of preparation method of metaformaldehyde acetalation nano-porous catalyst |
| CN111286240A (en) * | 2020-03-19 | 2020-06-16 | 电子科技大学 | Ultraviolet radiation prevention film material and ultraviolet radiation prevention film for photoelectronic device and preparation method thereof |
| CN111662583A (en) * | 2019-03-08 | 2020-09-15 | 武汉叁木汽车部件有限公司 | Aluminum foil with corrosion resistance function and manufacturing process thereof |
| CN111978813A (en) * | 2020-08-07 | 2020-11-24 | 红旗集团电力金具有限公司 | High-strength strain clamp and processing technology thereof |
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| CN103788833A (en) * | 2014-02-11 | 2014-05-14 | 青岛海洋先进材料工程技术中心有限公司 | Organosilicon antiskid anticorrosion deck coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104861815A (en) * | 2015-04-08 | 2015-08-26 | 天长市巨龙车船涂料有限公司 | Antirust anticorrosion rosin phenolic resin paint and preparation method thereof |
| CN107952487A (en) * | 2017-12-10 | 2018-04-24 | 江苏师范大学 | A kind of preparation method of metaformaldehyde acetalation nano-porous catalyst |
| CN111662583A (en) * | 2019-03-08 | 2020-09-15 | 武汉叁木汽车部件有限公司 | Aluminum foil with corrosion resistance function and manufacturing process thereof |
| CN111662583B (en) * | 2019-03-08 | 2021-09-03 | 武汉叁木汽车部件有限公司 | Aluminum foil with corrosion resistance function and manufacturing process thereof |
| CN111286240A (en) * | 2020-03-19 | 2020-06-16 | 电子科技大学 | Ultraviolet radiation prevention film material and ultraviolet radiation prevention film for photoelectronic device and preparation method thereof |
| CN111978813A (en) * | 2020-08-07 | 2020-11-24 | 红旗集团电力金具有限公司 | High-strength strain clamp and processing technology thereof |
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Application publication date: 20150128 |
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