CN106189750A - A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating - Google Patents

A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating Download PDF

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Publication number
CN106189750A
CN106189750A CN201610559808.2A CN201610559808A CN106189750A CN 106189750 A CN106189750 A CN 106189750A CN 201610559808 A CN201610559808 A CN 201610559808A CN 106189750 A CN106189750 A CN 106189750A
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unmanned plane
parts
alkyd resin
eyelid covering
modified alkyd
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CN201610559808.2A
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任新年
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Wenzhou Chuying Technology Co Ltd
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Wenzhou Chuying Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The present invention relates to unmanned plane field of material technology, be specifically related to the preparation method of a kind of unmanned plane eyelid covering modified alkyd resin coating.It is made up of the raw material of following weight portion: silicone alkyd 50 parts, acrylic resin 5 10 parts, nano silicon 25 parts, silane coupler 24 parts, plasticizer 13 parts, drier 13 parts, levelling agent 12 parts, pigment 46 parts, filler 25 parts, solvent 15 30 parts.The unmanned plane eyelid covering modified alkyd resin coating that the present invention provides has good ageing-resistant, weather-proof and crocking resistance.

Description

A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating
Technical field
The present invention relates to unmanned plane field of material technology, be specifically related to a kind of unmanned plane eyelid covering modified alkyd resin coating Preparation method.
Background technology
Coating and the coat system being made up of coating are important functional of a class that on unmanned plane eyelid covering, usage amount is bigger Material.In view of complexity and the multiformity of unmanned plane during flying environment, except requiring that the unmanned plane skin-surface coating used is resistant to purple Outside line, resistance to weathering, ageing-resistant, outside the performance such as high-low temperature resistant alternation, it is also desirable to have antifog, heat-resisting, oil resistant, to some electromagnetic wave The function absorbing, radiating.The erosion of the various liquid that the coating unmanned plane to be resistant to itself that unmanned plane uses uses, example Etch such as anti-lubricating oil, hydraulic oil etc..It can be seen that the protective coating that unmanned plane skin-surface is arranged, mainly to unmanned plane Structural material provides protection, extends the service life of unmanned plane.On the other hand, protective coating, also as ornament materials, beautifies nothing Man-machine outward appearance.
Domestic unmanned plane skining paint type currently mainly has: bi-component acrylic polyurethane unmanned plane skining paint, Bi-component polyester type polyurethane coating, fluorine carbon type unmanned plane skining paint and organosilicon modified polyester type unmanned plane eyelid covering are coated with Material.It is pointed out that existing conventional coating is difficult to meet current day by day harsh requirement.
Summary of the invention
For the deficiencies in the prior art, the invention provides and a kind of be difficult to unmanned plane aging, weather-proof, that crocking resistance is good Eyelid covering modified alkyd resin coating, and it preparation method.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of unmanned plane eyelid covering modified alkyd resin coating, is made up of the raw material of following weight portion: organic-silicon-modified alcohol Acid resin 50 parts, acrylic resin 5-10 part, nano silicon 2-5 part, silane coupler 2-4 part, plasticizer 1-3 part, urge Dry agent 1-3 part, levelling agent 1-2 part, pigment 4-6 part, filler 2-5 part, solvent 15-30 part.
Further, wherein during described plasticizer is dibutyl phthalate, dioctyl ester and blown castor oil Kind, levelling agent is silicone oil, and solvent is dimethylbenzene.
Further, described pigment is at least one in white lead, basic lead sulphate and zinc oxide, filler be Pulvis Talci, One or more compositionss in calcium carbonate, mica powder and kieselguhr, the fineness of pigment and filler is 2000-3000 mesh.
Further, described drier is weight ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: lead naphthenate: zinc naphthenate=1:1: The mixture of 8-10:6-7.
A kind of method preparing unmanned plane eyelid covering modified alkyd resin coating, comprises the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, The acrylic resin that must melt, is added thereto to nano silicon, carries out with the rotating speed of 1000-1500r/min in a reservoir Stirring, adds silane coupler, continues stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtains mixture A;
S2, the solvent of 50%, pigment and filler in the silicone alkyd of 40%, formula ratio in formula ratio are added Adding in mixture A, stir 30-45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, then by its turn To stirring container, being kept stirring for rotating speed is 500-600r/min, pours remaining organic-silicon-modified alkyd in stirring container Resin, stirs 5-10min, adds the plasticizer of formula ratio, levelling agent, and speed of agitator carries to 1200-1500r/min, stirring 15-20min, adds the drier of formula ratio, adjusts the viscosity of coating with remaining solution, continues stirring 10-15min, with 200 Mesh tiffany filters, and obtains unmanned plane eyelid covering modified alkyd resin coating.
Beneficial effects of the present invention:
Unmanned plane eyelid covering modified alkyd resin coating of the present invention has good wear-resisting, heat resistance;Received by interpolation Rice silicon dioxide, makes the anti-wear performance of coating improve 1 times, uses organosilicon modified to alkyd resin, further increases The thermostability of resin, pigment by reacting with the sour composition in film forming matter alkyd resin, forms the dense film that permeability is little, also The special role that modified alkyd resin coating is antirust can be given.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the enforcement of the present invention Example, is clearly and completely described the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection Scope.
Embodiment 1:
A kind of unmanned plane eyelid covering modified alkyd resin coating, is made up of the raw material of following weight portion: organic-silicon-modified alcohol Acid resin 50 parts, acrylic resin 5-10 part, nano silicon 2-5 part, silane coupler 2-4 part, plasticizer 1-3 part, urge Dry agent 1-3 part, levelling agent 1-2 part, pigment 4-6 part, filler 2-5 part, solvent 15-30 part.
Its preparation method, comprises the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, The acrylic resin that must melt, is added thereto to nano silicon, carries out with the rotating speed of 1000-1500r/min in a reservoir Stirring, adds silane coupler, continues stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtains mixture A;
S2, by the solvent xylene of 50%, fineness in the silicone alkyd of 40%, formula ratio in formula ratio it is The pigment white lead of 2000-3000 mesh and the filler Pulvis Talci that fineness is 2000-3000 mesh add to mixture A, stir 30- 45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, then by its turn To stirring container, being kept stirring for rotating speed is 500-600r/min, pours remaining organic-silicon-modified alkyd in stirring container Resin, stir 5-10min, add the plasticizer phthalic acid dibutyl ester of formula ratio, levelling agent silicone oil, speed of agitator carry to 1200-1500r/min, stirs 15-20min, the drier of addition formula ratio: weight ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: aphthenic acids Lead: the mixture of zinc naphthenate=1:1:8:6, adjusts the viscosity of coating with remaining dimethylbenzene, continues stirring 10-15min, uses 200 mesh tiffanys filter, and obtain unmanned plane eyelid covering modified alkyd resin coating.
Embodiment 2:
A kind of unmanned plane eyelid covering modified alkyd resin coating, is made up of the raw material of following weight portion: organic-silicon-modified alcohol Acid resin 50 parts, acrylic resin 8 parts, nano silicon 3 parts, silane coupler 3 parts, plasticizer 2 parts, drier 2 parts, stream Flat agent 1 part, pigment 5 parts, filler 4 parts, solvent 20 parts.
Its preparation method, comprises the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, The acrylic resin that must melt, is added thereto to nano silicon, carries out with the rotating speed of 1000-1500r/min in a reservoir Stirring, adds silane coupler, continues stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtains mixture A;
S2, by the solvent xylene of 50%, fineness in the silicone alkyd of 40%, formula ratio in formula ratio it is The pigment basic lead sulphate of 2000-3000 mesh and the filler-calcium carbonate that fineness is 2000-3000 mesh add to mixture A, stir Mixing 30-45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, then by its turn To stirring container, being kept stirring for rotating speed is 500-600r/min, pours remaining organic-silicon-modified alkyd in stirring container Resin, stirs 5-10min, adds the plasticizer dioctyl ester of formula ratio, levelling agent silicone oil, and speed of agitator carries to 1200- 1500r/min, stirs 15-20min, the drier of addition formula ratio: weight ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: lead naphthenate: ring The mixture of alkanoic acid zinc=1:1:9:6, adjusts the viscosity of coating with remaining solution dimethylbenzene, continues stirring 10-15min, uses 200 mesh tiffanys filter, and obtain unmanned plane eyelid covering modified alkyd resin coating.
Embodiment 3:
A kind of unmanned plane eyelid covering modified alkyd resin coating, is made up of the raw material of following weight portion: organic-silicon-modified alcohol Acid resin 50 parts, acrylic resin 6 parts, nano silicon 4 parts, silane coupler 3 parts, plasticizer 1 part, drier 3 parts, stream Flat agent 1 part, pigment 4 parts, filler 3 parts, solvent 25 parts.
Its preparation method, comprises the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, The acrylic resin that must melt, is added thereto to nano silicon, carries out with the rotating speed of 1000-1500r/min in a reservoir Stirring, adds silane coupler, continues stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtains mixture A;
S2, by the solvent xylene of 50%, fineness in the silicone alkyd of 40%, formula ratio in formula ratio it is The pigment white lead of 2000-3000 mesh and zinc oxide composition and the filler mica powder that fineness is 2000-3000 mesh are added to mixing In thing A, stirring 30-45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, then by its turn To stirring container, being kept stirring for rotating speed is 500-600r/min, pours remaining organic-silicon-modified alkyd in stirring container Resin, stirs 5-10min, adds the plasticizer blown castor oil of formula ratio, levelling agent silicone oil, and speed of agitator carries to 1200- 1500r/min, stirs 15-20min, the drier of addition formula ratio: weight ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: lead naphthenate: ring The mixture of alkanoic acid zinc=1:1:9:7, adjusts the viscosity of coating with remaining solution, continues stirring 10-15min, with 200 mesh silks Thin,tough silk filters, and obtains unmanned plane eyelid covering modified alkyd resin coating.
Embodiment 4:
A kind of unmanned plane eyelid covering modified alkyd resin coating, is made up of the raw material of following weight portion: organic-silicon-modified alcohol Acid resin 50 parts, acrylic resin 10 parts, nano silicon 5 parts, silane coupler 4 parts, plasticizer 3 parts, drier 3 parts, Levelling agent 2 parts, pigment 6 parts, filler 5 parts, solvent 30 parts.
Its preparation method, comprises the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, The acrylic resin that must melt, is added thereto to nano silicon, carries out with the rotating speed of 1000-1500r/min in a reservoir Stirring, adds silane coupler, continues stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtains mixture A;
S2, by the solvent xylene of 50%, fineness in the silicone alkyd of 40%, formula ratio in formula ratio it is Pigment zinc oxide kind and the filler kieselguhr that fineness is 2000-3000 mesh of 2000-3000 mesh add to mixture A, stirring 30-45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, then by its turn To stirring container, being kept stirring for rotating speed is 500-600r/min, pours remaining organic-silicon-modified alkyd in stirring container Resin, stirs 5-10min, adds the plasticizer blown castor oil of formula ratio, levelling agent silicone oil, and speed of agitator carries to 1200- 1500r/min, stirs 15-20min, the drier of addition formula ratio: weight ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: lead naphthenate: ring The mixture of alkanoic acid zinc=1:1:10:7, adjusts the viscosity of coating with remaining solution, continues stirring 10-15min, uses 200 mesh Tiffany filters, and obtains unmanned plane eyelid covering modified alkyd resin coating.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (5)

1. a unmanned plane eyelid covering modified alkyd resin coating, it is characterised in that be made up of the raw material of following weight portion: organic Si modification alkyd resin 50 parts, acrylic resin 5-10 part, nano silicon 2-5 part, silane coupler 2-4 part, plasticizer 1-3 part, drier 1-3 part, levelling agent 1-2 part, pigment 4-6 part, filler 2-5 part, solvent 15-30 part.
2. unmanned plane eyelid covering modified alkyd resin coating as claimed in claim 1, it is characterised in that described plasticizer is adjacent One of which in phthalic acid dibutyl ester, dioctyl ester and blown castor oil, levelling agent is silicone oil, and solvent is dimethylbenzene.
3. unmanned plane eyelid covering modified alkyd resin coating as claimed in claim 1, it is characterised in that described pigment is lead At least one in vain, in basic lead sulphate and zinc oxide, filler is the one in Pulvis Talci, calcium carbonate, mica powder and kieselguhr Or the fineness of numerous compositions, pigment and filler is 2000-3000 mesh.
4. unmanned plane eyelid covering modified alkyd resin coating as claimed in claim 1, it is characterised in that described drier is attached most importance to Amount ratio epoxyeicosatrienoic acid manganese: cobalt naphthenate: lead naphthenate: the mixture of zinc naphthenate=1:1:8-10:6-7.
5. the method preparing unmanned plane eyelid covering modified alkyd resin coating, it is characterised in that comprise the steps:
S1, the acrylic resin of formula ratio is placed on dry vessel in heating to 80-100 DEG C, constant temperature 60-120min, obtain molten The acrylic resin melted, is added thereto to nano silicon, is stirred with the rotating speed of 1000-1500r/min in a reservoir, Add silane coupler, continue stirring 10-20min, and constant temperature 1-1.5h at 80-100 DEG C, obtain mixture A;
S2, the solvent of 50% in the silicone alkyd of 40%, formula ratio in formula ratio, pigment and filler are added extremely In mixture A, stirring 30-45min, speed of agitator is 500-600r/min, obtains mixture B;
S3, pouring in sand mill by mixture B, the fineness of the particles to mixture B reaches below 100nm, is then gone to stir Mixing in container, being kept stirring for rotating speed is 500-600r/min, pours remaining silicone alkyd in stirring container, Stirring 5-10min, adds the plasticizer of formula ratio, levelling agent, and speed of agitator carries to 1200-1500r/min, stirs 15- 20min, adds the drier of formula ratio, adjusts the viscosity of coating with remaining solution, continues stirring 10-15min, uses 200 mesh Tiffany filters, and obtains unmanned plane eyelid covering modified alkyd resin coating.
CN201610559808.2A 2016-07-13 2016-07-13 A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating Pending CN106189750A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN107512060A (en) * 2017-09-08 2017-12-26 中国乐凯集团有限公司 A kind of solar energy unmanned plane wing cover material and preparation method thereof
CN108641431A (en) * 2018-05-23 2018-10-12 吕军 A kind of unmanned plane coating of use under complex environment
CN108795261A (en) * 2018-05-23 2018-11-13 吕军 A kind of unmanned plane coating process of strong adhesive force
CN108864861A (en) * 2018-05-23 2018-11-23 吕军 A kind of water paint for unmanned aerial vehicle body spraying

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107512060A (en) * 2017-09-08 2017-12-26 中国乐凯集团有限公司 A kind of solar energy unmanned plane wing cover material and preparation method thereof
CN108641431A (en) * 2018-05-23 2018-10-12 吕军 A kind of unmanned plane coating of use under complex environment
CN108795261A (en) * 2018-05-23 2018-11-13 吕军 A kind of unmanned plane coating process of strong adhesive force
CN108864861A (en) * 2018-05-23 2018-11-23 吕军 A kind of water paint for unmanned aerial vehicle body spraying

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Application publication date: 20161207