JP5201401B2 - Infrared reflective black pigment, paint and resin composition using the infrared reflective black pigment - Google Patents
Infrared reflective black pigment, paint and resin composition using the infrared reflective black pigment Download PDFInfo
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- JP5201401B2 JP5201401B2 JP2008194299A JP2008194299A JP5201401B2 JP 5201401 B2 JP5201401 B2 JP 5201401B2 JP 2008194299 A JP2008194299 A JP 2008194299A JP 2008194299 A JP2008194299 A JP 2008194299A JP 5201401 B2 JP5201401 B2 JP 5201401B2
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Description
本発明は、有害な元素を含有せず、しかも、優れた赤外線反射性を有する熱遮蔽性塗料を得ることができる赤外線反射性黒色系顔料に関する。本発明で黒色系顔料とは、黒色顔料、灰色顔料及び黒色顔料と灰色顔料との中間色の顔料を言う。 The present invention relates to an infrared-reflective black pigment that does not contain harmful elements and that can provide a heat-shielding paint having excellent infrared reflectivity. In the present invention, the black pigment refers to a black pigment, a gray pigment, and an intermediate color pigment between a black pigment and a gray pigment.
屋外で用いられている道路、建築物、備蓄タンク、自動車、船舶等は、太陽の日射によって内部温度が上昇するため、建築物及び自動車等の外観塗装を白色から淡色にすることで太陽光を反射させ、ある程度熱遮蔽効果を高めることが行われている。 Roads, buildings, stockpile tanks, automobiles, ships, etc. used outdoors increase the internal temperature due to solar radiation, so sunlight is reduced by changing the exterior paint of buildings and automobiles from white to light. It is reflected to increase the heat shielding effect to some extent.
しかしながら、殊に、屋外建築物の屋根などは、汚れを目立たなくするために、濃彩色から黒色を呈している場合が多く、外観塗装が濃彩色から黒色を有する建築物及び自動車等の場合には、淡色から白色の外観塗装を有する建築物及び自動車等に比べて太陽光を吸収しやすく、屋内の温度が著しく上昇する傾向にある。物品の輸送、保存に当たって、内部が高温になることは好ましいものではない。 However, in particular, the roofs of outdoor buildings are often dark to black in order to make the dirt inconspicuous, and in the case of buildings and automobiles etc. whose exterior paint has a dark to black color. Compared to buildings and automobiles having a light-to-white appearance paint, it is easier to absorb sunlight, and the indoor temperature tends to rise remarkably. It is not preferable that the temperature of the interior becomes high during transportation and storage of the article.
そこで、地球温暖化防止のためのエネルギー節約という観点からも、濃彩色から黒色の外観を有する建築物及び自動車等の内部温度の上昇を抑制することが強く望まれている。 Therefore, from the viewpoint of energy saving for preventing global warming, it is strongly desired to suppress an increase in internal temperature of buildings and automobiles having a dark to black appearance.
従来より、濃彩色から黒色の外観塗装を有する建築物及び自動車等の内部温度の上昇を低減するために、熱遮蔽性黒色塗料が知られている(例えば特許文献1〜3参照)。また、黒色度に優れたストロンチウム鉄酸化物ペロブスカイトが知られている(例えば特許文献4参照)。また、黒色度に優れたマグネシウム、アルミニウム含有酸化鉄が知られている(例えば特許文献5参照)。しかしながら次のような課題を有している。 Conventionally, heat-shielding black paints are known in order to reduce an increase in internal temperature of buildings and automobiles having a dark-colored to black appearance coating (see, for example, Patent Documents 1 to 3). In addition, strontium iron oxide perovskite having excellent blackness is known (for example, see Patent Document 4). Further, magnesium and aluminum-containing iron oxides having excellent blackness are known (see, for example, Patent Document 5). However, it has the following problems.
特許文献1には、CoO、Cr2O3及びFe2O3からなるスピネル構造を有する黒色焼成顔料が記載されているが、Crを含有するものであり、また、赤外線領域波長780〜2500nmにおける平均反射率が30%未満であり、十分な遮熱効果を有するとは言い難いものであった。 Patent Document 1 describes a black calcined pigment having a spinel structure composed of CoO, Cr 2 O 3 and Fe 2 O 3 , which contains Cr and has an infrared region wavelength of 780 to 2500 nm. The average reflectance was less than 30%, and it was difficult to say that it had a sufficient heat shielding effect.
また、特許文献2には、Fe2O3を必須成分とし、Cr2O3、Mn2O3又はNiOを含む焼成顔料からなる黒色顔料が記載されているが、Crを含有するものであるので好ましくない。 Patent Document 2 describes a black pigment composed of a calcined pigment containing Fe 2 O 3 as an essential component and containing Cr 2 O 3 , Mn 2 O 3, or NiO, but contains Cr. Therefore, it is not preferable.
また、特許文献3には、希土類元素、アルカリ土類金属及び鉄からなる黒色複合酸化物が記載されているが、十分な遮熱効果を有するとは言い難いものであった。 Patent Document 3 describes a black complex oxide composed of rare earth elements, alkaline earth metals, and iron, but it is difficult to say that it has a sufficient heat shielding effect.
また、特許文献4には、黒色度に優れたストロンチウム鉄酸化物ペロブスカイトが記載されているが、可視光領域波長250〜780nmにおける平均反射率が10%以下であって、且つ、赤外線領域波長780〜2500nmにおける平均反射率が30%未満であるので、十分な遮熱効果は得られていない。 Patent Document 4 describes a strontium iron oxide perovskite having excellent blackness, but has an average reflectance of 10% or less at a visible light region wavelength of 250 to 780 nm and an infrared region wavelength of 780. Since the average reflectance at ˜2500 nm is less than 30%, a sufficient heat shielding effect is not obtained.
また、特許文献5には、黒色度に優れたマグネシウム、アルミニウム含有スピネルが記載されているが、可視光領域波長250〜780nmにおける平均反射率が10%以下であって、且つ、赤外線領域波長780〜2500nmにおける平均反射率が30%未満であるので、十分な遮熱効果は得られていない。 Patent Document 5 describes magnesium-aluminum-containing spinels with excellent blackness, but has an average reflectance of 10% or less at a visible light region wavelength of 250 to 780 nm and an infrared region wavelength of 780. Since the average reflectance at ˜2500 nm is less than 30%, a sufficient heat shielding effect is not obtained.
上記課題を解決するため、本出願人は、有害な元素を含有せず、しかも優れた赤外線反射性を有する赤外線反射性黒色顔料を開発し既に特許出願を行っている(特許文献6参照)。この黒色顔料は、FeとCoとAlを含有し、更に、Mg、Ca、Sr、Ba、Ti、Zn、Sn、Zr、Si及びCuから選ばれる一種以上の金属元素を含有する複合酸化物からなる黒色顔料であって、該黒色顔料の平均粒子径が0.02〜2.0μmである赤外線反射性黒色顔料であり、有害な元素を含有せず、しかも優れた赤外線反射性を有する。しかしながら、赤外線領域波長1500nmの反射率が不十分である。 In order to solve the above problems, the present applicant has developed an infrared reflective black pigment that does not contain harmful elements and has excellent infrared reflectivity, and has already filed a patent application (see Patent Document 6). This black pigment contains Fe, Co, and Al, and further includes a composite oxide containing one or more metal elements selected from Mg, Ca, Sr, Ba, Ti, Zn, Sn, Zr, Si, and Cu. The black pigment is an infrared reflective black pigment having an average particle diameter of 0.02 to 2.0 μm, does not contain harmful elements, and has excellent infrared reflectivity. However, the reflectance in the infrared region wavelength of 1500 nm is insufficient.
熱遮蔽性を有する塗料については、黒色塗料のほか黒灰色塗料、灰色塗料ついても需要が大きいものの、これらについても有害な元素を含有せず、しかも優れた赤外線反射性を有する塗料は得られていない。従来、黒灰色顔料又は灰色顔料は、カーボンブラック等の黒色顔料と酸化チタン等の白色顔料とを混合し製造されるのが一般的であった。従来の2種類以上の顔料を混合して、所定の色を有する顔料を調整する方法では、塗料中で混合した2種類以上の顔料が分離し、色別れを生じる問題が指摘されていた。さらに混合した顔料の劣化速度の違いにより、時間経過とともに色彩が大きく変化する懸念もある。 As for paints having heat shielding properties, black paint, black gray paint, and gray paint are in great demand, but these paints do not contain harmful elements and have excellent infrared reflectivity. Absent. Conventionally, black gray pigments or gray pigments are generally produced by mixing a black pigment such as carbon black and a white pigment such as titanium oxide. In the conventional method of preparing a pigment having a predetermined color by mixing two or more kinds of pigments, a problem has been pointed out that two or more kinds of pigments mixed in the paint are separated and color separation occurs. Furthermore, there is a concern that the color may change greatly over time due to the difference in the deterioration rate of the mixed pigment.
有害な元素を含有せず、しかも、優れた赤外線反射性を有する熱遮蔽性塗料を得ることができる黒色顔料、黒灰色顔料及び灰色顔料を含む黒色系顔料は、現在最も要求されているところである。また黒色顔料を含めこれら黒色系顔料が、塗料構成基材に対し優れた分散性を示せばより好ましい。 Black pigments including black pigments, black gray pigments, and gray pigments that do not contain harmful elements and that can provide a heat-shielding coating material that has excellent infrared reflectivity are currently most demanded. . Further, it is more preferable that these black pigments including black pigments exhibit excellent dispersibility with respect to the paint constituting base material.
本発明の目的は、有害な元素を含有せず、しかも優れた赤外線反射性を有する赤外線反射性黒色系顔料を提供することである。 An object of the present invention is to provide an infrared reflective black pigment which does not contain harmful elements and has excellent infrared reflectivity.
前記目的は、次の通りの本発明によって達成できる。 The object can be achieved by the present invention as follows.
即ち、本発明は、実質的にCrを含有せず、少なくともCo、Mg、Fe、Al及びSiを含有する複合酸化物からなる黒色系顔料であって、Si/(Co+Mg+Fe+Al+Si)がモル比で10〜90%であり、該黒色系顔料の平均粒子径が0.02〜2.0μmであることを特徴とする赤外線反射性黒色系顔料である(本発明1)。 That is, the present invention is a black pigment that is substantially free of Cr and is made of a complex oxide containing at least Co, Mg, Fe, Al, and Si, wherein Si / (Co + Mg + Fe + Al + Si) has a molar ratio of 10 Infrared reflective black pigment characterized in that the black pigment has an average particle size of 0.02 to 2.0 μm (Invention 1).
また本発明は、請求項1記載の赤外線反射性黒色系顔料の(Co+Mg+Fe+Al+Si)/(Si+全金属元素)がモル比で50〜100%であることを特徴とする赤外線反射性黒色系顔料である(本発明2)。 Further, the present invention is an infrared reflective black pigment characterized in that (Co + Mg + Fe + Al + Si) / (Si + all metal elements) of the infrared reflective black pigment according to claim 1 is in a molar ratio of 50 to 100%. (Invention 2).
また本発明は、請求項1又は2記載の赤外線反射性黒色系顔料の真比重が2.6〜4.7であることを特徴とする赤外線反射性黒色系顔料である(本発明3)。 In addition, the present invention is an infrared reflective black pigment characterized in that the true specific gravity of the infrared reflective black pigment according to claim 1 or 2 is 2.6 to 4.7 (Invention 3).
また本発明は、請求項1乃至3のいずれか1項に記載の赤外線反射性黒色系顔料の明度(L*)が25以上40以下であることを特徴とする赤外線反射性黒色系顔料である(本発明4)。 Further, the present invention is an infrared reflective black pigment characterized in that the lightness (L * ) of the infrared reflective black pigment according to any one of claims 1 to 3 is 25 or more and 40 or less. (Invention 4).
また本発明は、請求項1乃至4のいずれか1項に記載の赤外線反射性黒色系顔料の日射反射率が35〜50%であることを特徴とする赤外線反射性黒色系顔料である(本発明5)。 Moreover, this invention is an infrared reflective black pigment characterized by the solar reflectance of 35 to 50% of the infrared reflective black pigment of any one of Claims 1 thru | or 4 (this book Invention 5).
また本発明は、請求項1乃至5のいずれか1項に記載の赤外線反射性黒色系顔料の表面がSi、Al、Zr、Tiから選ばれる一種以上の化合物で被覆されていることを特徴とする赤外線反射性黒色系顔料である(本発明6)。 Further, the present invention is characterized in that the surface of the infrared reflective black pigment according to any one of claims 1 to 5 is coated with one or more compounds selected from Si, Al, Zr, and Ti. Infrared reflective black pigment (Invention 6).
また本発明は、請求項1乃至6のいずれか1項に記載の赤外線反射性黒色系顔料を塗料構成基材中に配合したことを特徴とする塗料である(本発明7)。 Moreover, this invention is a coating material which mix | blended the infrared reflective black pigment of any one of Claims 1 thru | or 6 in the coating-material base material (this invention 7).
また本発明は、請求項1乃至6のいずれか1項に記載の赤外線反射性黒色系顔料を用いて着色したことを特徴とする樹脂組成物である(本発明8)。 Moreover, this invention is the resin composition characterized by coloring using the infrared reflective black pigment of any one of Claims 1 thru | or 6. (Invention 8).
本発明に係る赤外線反射性黒色系顔料は、有害な元素を含有しない黒色系顔料であって、しかも、赤外線反射性に優れているので赤外線反射性黒色系顔料として好適である。 The infrared reflective black pigment according to the present invention is a black pigment that does not contain harmful elements and is excellent in infrared reflectivity, and is therefore suitable as an infrared reflective black pigment.
本発明の構成をより詳しく説明すれば次の通りである。 The configuration of the present invention will be described in more detail as follows.
先ず、本発明に係る赤外線反射性黒色系顔料について述べる。 First, the infrared reflective black pigment according to the present invention will be described.
本発明に係る赤外線反射性黒色系顔料は、実質的にCrを含有せず、少なくともCo、Mg、Fe、Al及びSiを含有する複合酸化物からなる黒色系顔料であって、Si/(Co+Mg+Fe+Al+Si)がモル比で10〜90%である。黒色系顔料中のSi/(Co+Mg+Fe+Al+Si)がモル比で10%未満となると日射反射性が十分に高いとは言えず、Si/(Co+Mg+Fe+Al+Si)がモル比で90%を超えると明度が大きくなり過ぎる。実質的にCrを含有しないとは、不可避的に各種原料由来の不純物が混入する場合もあるけれども、この場合であっても、Crの含有量は1wt%以下であり、殊に、Cr6+の含有量は10ppm以下である。 The infrared reflective black pigment according to the present invention is a black pigment that is substantially free of Cr and is composed of a complex oxide containing at least Co, Mg, Fe, Al, and Si, and is Si / (Co + Mg + Fe + Al + Si). ) In a molar ratio of 10 to 90%. When the molar ratio of Si / (Co + Mg + Fe + Al + Si) in the black pigment is less than 10%, it cannot be said that the solar reflectance is sufficiently high. When the molar ratio of Si / (Co + Mg + Fe + Al + Si) exceeds 90%, the lightness becomes too high. . The fact that it does not substantially contain Cr may inevitably contain impurities derived from various raw materials, but even in this case, the Cr content is 1 wt% or less, and in particular, Cr 6+ The content is 10 ppm or less.
また本発明に係る赤外線反射性黒色系顔料の平均粒子径は0.02〜2.0μmである。平均粒子径が2.0μmを超える場合には、粒子サイズが大きすぎるため、着色力が低下する。平均粒子径が0.02μm未満の場合には、ビヒクル中への分散が困難となる場合がある。好ましくは0.025〜1.5μm、より好ましくは0.04〜1.2μmである。 The average particle diameter of the infrared reflective black pigment according to the present invention is 0.02 to 2.0 μm. When the average particle diameter is more than 2.0 μm, the particle size is too large and the coloring power is lowered. When the average particle size is less than 0.02 μm, dispersion in the vehicle may be difficult. Preferably it is 0.025-1.5 micrometers, More preferably, it is 0.04-1.2 micrometers.
本発明に係る赤外線反射性黒色系顔料は、(Co+Mg+Fe+Al+Si)/(Si+全金属元素)がモル比で50〜100%が好ましい。これから分かるように、本発明に係る赤外線反射性黒色系顔料は、Co、Mg、Fe、Al及びSiを含有する複合酸化物からなる黒色系顔料であってよく、さらに所定の量の他の金属元素を含む複合酸化物からなる黒色系顔料であってよい。これらの場合、不可避的に各種原料由来の不純物が混入する場合もあるけれども、この場合であっても、Crの含有量は1wt%以下であり、殊に、Cr6+の含有量は10ppm以下である。 In the infrared reflective black pigment according to the present invention, (Co + Mg + Fe + Al + Si) / (Si + all metal elements) is preferably 50 to 100% in molar ratio. As can be seen, the infrared-reflective black pigment according to the present invention may be a black pigment composed of a complex oxide containing Co, Mg, Fe, Al and Si, and a predetermined amount of another metal. It may be a black pigment made of a complex oxide containing an element. In these cases, impurities derived from various raw materials may be inevitably mixed, but even in this case, the Cr content is 1 wt% or less, and in particular, the Cr 6+ content is 10 ppm or less. is there.
Coの含有量は、黒色系顔料中のSi+全金属元素に対して、1〜20モル%が好ましく、2〜16モル%がより好ましく、Mgの含有量は、黒色系顔料中のSi+全金属元素に対して、1〜50モル%が好ましく、2〜30モル%がより好ましい。Fe及びAlの含有量は、共に黒色系顔料中のSi+全金属元素に対して、1〜50モル%が好ましく、2〜40モル%がより好ましい。 The Co content is preferably from 1 to 20 mol%, more preferably from 2 to 16 mol%, based on Si + total metal elements in the black pigment, and the Mg content is from Si + total metal in the black pigment. 1-50 mol% is preferable with respect to an element, and 2-30 mol% is more preferable. The content of Fe and Al is preferably 1 to 50 mol% and more preferably 2 to 40 mol% with respect to Si + all metal elements in the black pigment.
また本発明に係る赤外線反射性黒色系顔料は、真比重(密度)が2.6〜4.7であることが好ましい。真比重が上記範囲内であれば、塗料構成基材に本発明に係る赤外線反射性黒色系顔料を分散させたとき、優れた分散性を示す。 In addition, the infrared reflective black pigment according to the present invention preferably has a true specific gravity (density) of 2.6 to 4.7. If the true specific gravity is within the above range, excellent dispersibility is exhibited when the infrared-reflective black pigment according to the present invention is dispersed in the paint-constituting substrate.
本発明に係る赤外線反射性黒色系顔料のBET比表面積は、1〜100m2/gが好ましい。BET比表面積が1m2/g未満の場合には、粒子が粗大であったり、粒子及び粒子相互間で焼結が生じた粒子となっており、着色力が低下する。より好ましくは1.5〜75m2/g、更により好ましくは1.8〜60m2/gである。 The BET specific surface area of the infrared reflective black pigment according to the present invention is preferably 1 to 100 m 2 / g. When the BET specific surface area is less than 1 m 2 / g, the particles are coarse or the particles are sintered between the particles and the coloring power is reduced. More preferably, it is 1.5-75 m < 2 > / g, More preferably, it is 1.8-60 m < 2 > / g.
本発明に係る赤外線反射性黒色系顔料の明度(L*)は、25以上40以下が好ましい。明度(L*)が前記範囲外の場合には、黒色系の顔料とは言い難い。 The lightness (L * ) of the infrared reflective black pigment according to the present invention is preferably 25 or more and 40 or less. When the lightness (L * ) is outside the above range, it is difficult to say that it is a black pigment.
本発明に係る赤外線反射性黒色系顔料のa*は、−5〜+10が好ましい。a*が前記範囲外の場合には、黒色系の顔料とは言い難い。より好ましくは−1〜+5である。 The a * of the infrared reflective black pigment according to the present invention is preferably -5 to +10. When a * is out of the above range, it is difficult to say that it is a black pigment. More preferably, it is -1 to +5.
本発明に係る赤外線反射性黒色系顔料のb*は、−5〜+10が好ましい。b*が前記範囲外の場合には、黒色系の顔料とは言い難い。より好ましくは−1〜+5である。 The b * of the infrared reflective black pigment according to the present invention is preferably -5 to +10. When b * is out of the above range, it is difficult to say a black pigment. More preferably, it is -1 to +5.
本発明に係る赤外線反射性黒色系顔料の赤外線反射性は、赤外線領域波長1000nmの反射率が55%を超えることが好ましい。また赤外線領域波長1500nmの反射率が21%を超えることが好ましい。波長300〜2100nmの平均反射率で示される日射反射率は、35〜50%であることが好ましい。35%未満の場合には、赤外線反射性が十分に高いとは言い難い。 The infrared reflectivity of the infrared reflective black pigment according to the present invention is preferably such that the reflectance in the infrared region wavelength of 1000 nm exceeds 55%. Moreover, it is preferable that the reflectance of infrared region wavelength 1500nm exceeds 21%. It is preferable that the solar reflectance shown by the average reflectance of wavelength 300-2100nm is 35-50%. If it is less than 35%, it is difficult to say that the infrared reflectivity is sufficiently high.
本発明においては、粒子表面をSi、Al、Zr、Tiから選ばれる1種又は2種以上の化合物によって被覆しておいてもよい。被覆量は赤外線反射性黒色系顔料に対して0.1〜10wt%が好ましい。 In the present invention, the particle surface may be coated with one or more compounds selected from Si, Al, Zr, and Ti. The coating amount is preferably 0.1 to 10 wt% with respect to the infrared reflective black pigment.
次に、本発明に係る赤外線反射性黒色系顔料の製造法について述べる。 Next, a method for producing an infrared reflective black pigment according to the present invention will be described.
本発明に係る赤外線反射性黒色系顔料は、各種原料を混合、焼成して得ることができる。 The infrared reflective black pigment according to the present invention can be obtained by mixing and firing various raw materials.
出発原料は、前記各金属元素の酸化物、炭酸塩、硝酸塩、硫酸塩などを用いることができ、Siは酸化珪素を用いることができる。 As the starting material, oxides, carbonates, nitrates, sulfates and the like of the respective metal elements can be used, and silicon oxide can be used as Si.
出発原料の混合は、均一に混合することができれば、特に限定されるものではなく、湿式混合でも乾式混合でもよい。また湿式合成であってもよい。 The mixing of the starting materials is not particularly limited as long as the starting materials can be uniformly mixed, and may be wet mixing or dry mixing. Also, wet synthesis may be used.
加熱焼成温度は800〜1200℃が好ましく、800〜1150℃がより好ましい。加熱雰囲気は大気中である。 800-1200 degreeC is preferable and the heat-firing temperature has more preferable 800-1150 degreeC. The heating atmosphere is air.
加熱後の粉末は、常法に従って、水洗、粉砕を行えばよい。 The heated powder may be washed and pulverized according to a conventional method.
本発明においては、赤外線反射性黒色系顔料の粒子表面をSi、Al、Zr、Tiから選ばれる1種又は2種以上の化合物によって被覆しておいてもよい。表面処理方法は、湿式あるいは乾式方法等の常法に従って行えばよい。例えば、湿式方法は湿式分散した赤外線反射性黒色系顔料のスラリーに、Si、Al、Zr、Tiから選ばれる1種又は2種以上の可溶性化合物を、酸又はアルカリでpH調整しながら添加・混合して被覆する方法、乾式方法はヘンシェルミキサーなどの装置中で赤外線反射性黒色系顔料にSi、Al、Zr、Tiから選ばれる1種又は2種以上のカップリング剤などにより被覆処理する方法である。 In the present invention, the particle surface of the infrared reflective black pigment may be coated with one or more compounds selected from Si, Al, Zr, and Ti. The surface treatment method may be performed according to a conventional method such as a wet method or a dry method. For example, in the wet method, one or two or more soluble compounds selected from Si, Al, Zr, and Ti are added to and mixed with a slurry of wet-dispersed infrared reflective black pigment while adjusting the pH with acid or alkali. In this method, the infrared reflective black pigment is coated with one or more coupling agents selected from Si, Al, Zr and Ti in an apparatus such as a Henschel mixer. is there.
次に、本発明に係る赤外線反射性黒色系顔料を配合した塗料について述べる。 Next, a paint containing the infrared reflective black pigment according to the present invention will be described.
本発明に係る塗料中における赤外線反射性黒色系顔料の配合割合は、塗料構成基材100重量部に対して0.5〜100重量部の範囲で使用することができ、塗料のハンドリング性を考慮すれば、好ましくは1.0〜100重量部である。 The blending ratio of the infrared-reflective black pigment in the paint according to the present invention can be used in the range of 0.5 to 100 parts by weight with respect to 100 parts by weight of the paint constituent base material, and the handleability of the paint is taken into consideration. In this case, the amount is preferably 1.0 to 100 parts by weight.
塗料構成基材としては、樹脂、溶剤、必要により油脂、消泡剤、体質顔料、乾燥促進剤、界面活性剤、硬化促進剤、助剤等が配合される。 As the paint constituent base material, a resin, a solvent, and if necessary, fats and oils, an antifoaming agent, an extender pigment, a drying accelerator, a surfactant, a curing accelerator, an auxiliary agent and the like are blended.
樹脂としては、溶剤系塗料用や油性印刷インクに通常使用されているアクリル樹脂、アルキッド樹脂、ポリエステル樹脂、ポリウレタン樹脂、エポキシ樹脂、フェノール樹脂、メラミン樹脂、アミノ樹脂、塩化ビニル樹脂、シリコーン樹脂、ガムロジン、ライムロジン等のロジン系樹脂、マレイン酸樹脂、ポリアミド樹脂、ニトロセルロース、エチレン−酢酸ビニル共重合樹脂、ロジン変性フェノール樹脂、ロジン変性マレイン酸樹脂等のロジン変性樹脂、石油樹脂等を用いることができる。水系塗料用としては、水系塗料用や水性インクに通常使用されている水溶性アクリル樹脂、水溶性スチレン−マレイン酸樹脂、水溶性アルキッド樹脂、水溶性メラミン樹脂、水溶性ウレタンエマルジョン樹脂、水溶性エポキシ樹脂、水溶性ポリエステル樹脂等を用いることができる。 Resins include acrylic resin, alkyd resin, polyester resin, polyurethane resin, epoxy resin, phenol resin, melamine resin, amino resin, vinyl chloride resin, silicone resin, gum rosin that are usually used for solvent-based paints and oil-based printing inks. Rosin resins such as lime rosin, maleic acid resin, polyamide resin, nitrocellulose, ethylene-vinyl acetate copolymer resin, rosin modified phenolic resin, rosin modified maleic resin and other rosin modified resins, petroleum resins and the like can be used. . For water-based paints, water-soluble acrylic resins, water-soluble styrene-maleic acid resins, water-soluble alkyd resins, water-soluble melamine resins, water-soluble urethane emulsion resins, water-soluble epoxies commonly used for water-based paints and water-based inks Resins, water-soluble polyester resins, and the like can be used.
溶剤としては、溶剤系塗料用に通常使用されている大豆油、トルエン、キシレン、シンナー、ブチルアセテート、メチルアセテート、メチルイソブチルケトン、メチルセロソルブ、エチルセロソルブ、プロピルセロソルブ、ブチルセロソルブ、プロピレングリコールモノメチルエーテル等のグリコールエーテル系溶剤、酢酸エチル、酢酸ブチル、酢酸アミル等のエステル系溶剤、ヘキサン、ヘプタン、オクタン等の脂肪族炭化水素系溶剤、シクロヘキサン等の脂環族炭化水素系溶剤、ミネラルスピリット等の石油系溶剤、アセトン、メチルエチルケトン等のケトン系溶剤、メチルアルコール、エチルアルコール、プロピルアルコール、ブチルアルコール等のアルコール系溶剤、脂肪族炭化水素等を用いることができる。 Solvents include soybean oil, toluene, xylene, thinner, butyl acetate, methyl acetate, methyl isobutyl ketone, methyl cellosolve, ethyl cellosolve, propyl cellosolve, butyl cellosolve, propylene glycol monomethyl ether, etc. Glycol ether solvents, ester solvents such as ethyl acetate, butyl acetate, and amyl acetate, aliphatic hydrocarbon solvents such as hexane, heptane, and octane, alicyclic hydrocarbon solvents such as cyclohexane, and petroleum-based solvents such as mineral spirits Solvents, ketone solvents such as acetone and methyl ethyl ketone, alcohol solvents such as methyl alcohol, ethyl alcohol, propyl alcohol, and butyl alcohol, aliphatic hydrocarbons, and the like can be used.
水系塗料用溶剤としては、水と水系塗料用に通常使用されているエチルアルコール、プロピルアルコール、ブチルアルコール等のアルコール系溶剤、メチルセロソルブ、エチルセロソルブ、プロピルセロソルブ、ブチルセロソルブ等のグリコールエーテル系溶剤、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、ジプロピレングリコール、トリプロピレングリコール、ポリプロピレングリコール等のオキシエチレン又はオキシプロピレン付加重合体、エチレングリコール、プロピレングリコール、1,2,6−ヘキサントリオール等のアルキレングリコール、グリセリン、2−ピロリドン等の水溶性有機溶剤とを混合して使用することができる。 Water-based paint solvents include water and alcohol-based solvents usually used for water-based paints, such as ethyl alcohol, propyl alcohol, and butyl alcohol, methyl ether solvents such as methyl cellosolve, ethyl cellosolve, propyl cellosolve, and butyl cellosolve, and diethylene glycol. , Oxyethylene or oxypropylene addition polymers such as triethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol, alkylene glycol such as ethylene glycol, propylene glycol, 1,2,6-hexanetriol, glycerin, It can be used by mixing with a water-soluble organic solvent such as 2-pyrrolidone.
油脂としては、あまに油、きり油、オイチシカ油、サフラワー油等の乾性油を加工したボイル油を用いることができる。 As oils and fats, boil oils obtained by processing dry oils such as linseed oil, persimmon oil, sea lion oil, safflower oil and the like can be used.
消泡剤としては、ノプコ8034(商品名)、SNデフォーマー477(商品名)、SNデフォーマー5013(商品名)、SNデフォーマー247(商品名)、SNデフォーマー382(商品名)(以上、いずれもサンノプコ株式会社製)、アンチホーム08(商品名)、エマルゲン903(商品名)(以上、いずれも花王株式会社製)等の市販品を使用することができる。 Antifoaming agents include Nopco 8034 (product name), SN deformer 477 (product name), SN deformer 5013 (product name), SN deformer 247 (product name), SN deformer 382 (product name) (all of these are San Nopco Commercially available products such as manufactured by Co., Ltd., Antihome 08 (trade name), Emulgen 903 (trade name) (all of which are manufactured by Kao Corporation) can be used.
次に、本発明に係る赤外線反射性黒色系顔料を含有する樹脂組成物について述べる。 Next, the resin composition containing the infrared reflective black pigment according to the present invention will be described.
本発明に係る樹脂組成物中における赤外線反射性黒色系顔料の配合割合は、樹脂100重量部に対して0.01〜200重量部の範囲で使用することができ、樹脂組成物のハンドリング性を考慮すれば、好ましくは0.05〜150重量部、更に好ましくは0.1〜100重量部である。 The blending ratio of the infrared reflective black pigment in the resin composition according to the present invention can be used in the range of 0.01 to 200 parts by weight with respect to 100 parts by weight of the resin. Considering it, it is preferably 0.05 to 150 parts by weight, more preferably 0.1 to 100 parts by weight.
本発明に係る樹脂組成物における構成基材としては、赤外線反射性黒色系顔料と周知の熱可塑性樹脂とともに、必要により、滑剤、可塑剤、酸化防止剤、紫外線吸収剤、各種安定剤等の添加剤が配合される。 As a constituent substrate in the resin composition according to the present invention, an infrared reflective black pigment and a well-known thermoplastic resin, if necessary, addition of a lubricant, a plasticizer, an antioxidant, an ultraviolet absorber, various stabilizers, etc. An agent is blended.
樹脂としては、ポリエチレン、ポリプロピレン、ポリブテン、ポリイソブチレン等のポリオレフィン、ポリ塩化ビニル、ポリメチルペンテン、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリスチレン、スチレン−アクリル酸エステル共重合体、スチレン−酢酸ビニル共重合体、アクリロニトリル−ブタジエン−スチレン共重合体、アクリロニトリル−EPDM−スチレン共重合体、アクリル系樹脂、ポリアミド、ポリカーボネート、ポリアセタール、ポリウレタン等の熱可塑性樹脂、ロジン変性マレイン酸樹脂、フェノール樹脂、エポキシ樹脂、ポリエステル樹脂、シリコーン樹脂、ロジン・エステル、ロジン、天然ゴム、合成ゴム等を用いることができる。 Examples of the resin include polyolefins such as polyethylene, polypropylene, polybutene, and polyisobutylene, polyvinyl chloride, polymethylpentene, polyethylene terephthalate, polybutylene terephthalate, polystyrene, styrene-acrylic acid ester copolymer, styrene-vinyl acetate copolymer, Acrylonitrile-butadiene-styrene copolymer, acrylonitrile-EPDM-styrene copolymer, acrylic resin, polyamide, polycarbonate, polyacetal, polyurethane and other thermoplastic resins, rosin-modified maleic acid resin, phenol resin, epoxy resin, polyester resin, Silicone resin, rosin ester, rosin, natural rubber, synthetic rubber and the like can be used.
添加剤の量は、赤外線反射性黒色系顔料と樹脂との総和に対して50重量%以下であればよい。添加剤の含有量が50重量%を超える場合には、成形性が低下する。 The amount of the additive may be 50% by weight or less based on the total of the infrared reflective black pigment and the resin. When the content of the additive exceeds 50% by weight, the moldability is lowered.
本発明に係る樹脂組成物は、樹脂原料と赤外線反射性黒色系顔料をあらかじめよく混合し、次に、混練機もしくは押出機を用いて加熱下で強いせん断作用を加えて、赤外線反射性黒色系顔料の凝集体を破壊し、樹脂組成物中に赤外線反射性黒色系顔料を均一に分散させた後、目的に応じた形状に成形加工して使用する。 The resin composition according to the present invention is prepared by thoroughly mixing a resin raw material and an infrared reflective black pigment in advance, and then applying a strong shearing action under heating using a kneader or an extruder to produce an infrared reflective black After destroying the pigment aggregate and uniformly dispersing the infrared-reflective black pigment in the resin composition, it is molded into a shape suitable for the purpose and used.
また本発明に係る樹脂組成物は、マスターバッチペレットを経由して得ることもできる。 The resin composition according to the present invention can also be obtained via a master batch pellet.
本発明におけるマスターバッチペレットは、塗料及び樹脂組成物の構成基材としての結合材樹脂と前記赤外線反射性黒色系顔料とを必要により、リボンブレンダー、ナウターミキサー、ヘンシェルミキサー、スーパーミキサー等の混合機で混合した後、周知の単軸混練押出機や二軸混練押出機等で混練、成形した後切断するか、又は、上記混合物をバンバリーミキサー、加圧ニーダー等で混練して得られた混練物を粉砕又は成形、切断することにより製造される。 The master batch pellet in the present invention requires a binder resin as a constituent substrate of the paint and the resin composition and the infrared reflective black pigment, and is mixed with a ribbon blender, a Nauter mixer, a Henschel mixer, a super mixer, etc. Kneaded by mixing with a machine, kneaded with a known single-screw kneading extruder or twin-screw kneading extruder, etc., then cut, or kneaded by kneading the mixture with a Banbury mixer, pressure kneader, etc. Manufactured by crushing, molding, or cutting an object.
結合材樹脂と赤外線反射性黒色系顔料の混練機への供給は、それぞれを所定比率で定量供給してもよいし、両者の混合物を供給してもよい。 As for the supply of the binder resin and the infrared reflective black pigment to the kneader, each may be supplied in a fixed ratio at a predetermined ratio, or a mixture of both may be supplied.
本発明におけるマスターバッチペレットは、平均長径1〜6mm、好ましくは2〜5mmの範囲である。平均短径は2〜5mm、好ましくは2.5〜4mmである。平均長径が1mm未満の場合には、ペレット製造時の作業性が悪く好ましくない。6mmを超える場合には、希釈用結合材樹脂の大きさとの違いが大きく、十分に分散させるのが困難となる。また、その形状は種々のものができ、不定形及び球形等の粒状、円柱形、フレーク状等にできる。 The master batch pellet in the present invention has an average major axis of 1 to 6 mm, preferably 2 to 5 mm. The average minor axis is 2 to 5 mm, preferably 2.5 to 4 mm. When the average major axis is less than 1 mm, the workability at the time of producing the pellet is poor, which is not preferable. When the thickness exceeds 6 mm, the difference from the size of the binder resin for dilution is large, and it becomes difficult to sufficiently disperse. Moreover, the shape can be various, and can be indefinite and spherical, cylindrical, flakes, and the like.
本発明におけるマスターバッチペレットに使用する結合材樹脂としては、前記樹脂組成物用樹脂と同一の樹脂が使用できる。 As the binder resin used for the master batch pellet in the present invention, the same resin as the resin for resin composition can be used.
なお、マスターバッチペレット中の結合材樹脂の組成は、希釈用結合材樹脂と同一の樹脂を用いても、また、異なる樹脂を用いてもよいが、異なる樹脂を使用する場合には、樹脂同士の相溶性により決まる諸特性を考慮して決めればよい。 The composition of the binder resin in the masterbatch pellet may be the same resin as the diluent binder resin or a different resin, but if different resins are used, What is necessary is just to determine in consideration of the various characteristics determined by the compatibility.
マスターバッチペレット中に配合される赤外線反射性黒色系顔料の量は、結合材樹脂100重量部に対して1〜200重量部、好ましくは1〜150重量部、より好ましくは1〜100重量部である。1重量部未満の場合には、混練時の溶融粘度が不足し、赤外線反射性黒色系顔料の良好な分散混合が困難である。200重量部を超える場合には、赤外線反射性黒色系顔料に対する結合材樹脂が少ないため、赤外線反射性黒色系顔料の良好な分散混合が難しく、また、マスターバッチペレットの添加量のわずかな変化によって樹脂組成物中に配合される赤外線反射性黒色系顔料の含有量が大きく変化するため所望の含有量に調製することが困難となり好ましくない。また、機械摩耗が激しく適当ではない。 The amount of the infrared reflective black pigment blended in the masterbatch pellet is 1 to 200 parts by weight, preferably 1 to 150 parts by weight, more preferably 1 to 100 parts by weight with respect to 100 parts by weight of the binder resin. is there. When the amount is less than 1 part by weight, the melt viscosity at the time of kneading is insufficient, and it is difficult to disperse and mix the infrared reflective black pigment. When the amount exceeds 200 parts by weight, since there is little binder resin for the infrared reflective black pigment, it is difficult to disperse and mix the infrared reflective black pigment, and a slight change in the addition amount of the master batch pellets Since the content of the infrared-reflective black pigment blended in the resin composition changes greatly, it is difficult to prepare the desired content, which is not preferable. Also, mechanical wear is severe and not suitable.
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本発明において最も重要な点は、本発明に係る赤外線反射性黒色系顔料は、有害元素を含有することなく、高い赤外線反射性を有するという事実である。
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The most important point in the present invention is the fact that the infrared-reflective black pigment according to the present invention has high infrared reflectivity without containing harmful elements.
本発明に係る赤外線反射性黒色系顔料が高い赤外線反射性を有する理由は、未だ明らかではないが、後出する実施例及び比較例から明らかなとおり、実質的にCrを含有せず、少なくともCo、Mg、Fe、Al及びSiを含有する複合酸化物からなり、Si/(Co+Mg+Fe+Al+Si)をモル比で10〜90%、平均粒子径を0.02〜2.0μmとすることで、日射反射率及び赤外線反射率を向上させることができたものである。 The reason why the infrared-reflective black pigment according to the present invention has high infrared reflectivity is not yet clear, but as is apparent from Examples and Comparative Examples described later, it does not substantially contain Cr, and at least Co. , Mg, Fe, Al and Si containing composite oxide, Si / (Co + Mg + Fe + Al + Si) is 10 to 90% in molar ratio and the average particle diameter is 0.02 to 2.0 μm, so that the solar reflectance In addition, the infrared reflectance can be improved.
また、本発明に係る赤外線反射性黒色系顔料は、Cr6+などの有害金属元素を含有しておらず、安全な顔料である。 The infrared reflective black pigment according to the present invention does not contain a harmful metal element such as Cr 6+ and is a safe pigment.
本発明の代表的な実施例は、次の通りである。 A typical embodiment of the present invention is as follows.
粒子の平均粒子径は電子顕微鏡写真に示される粒子350個の粒子径をそれぞれ測定し、その平均値で示した。 The average particle size of the particles was measured by measuring the particle size of 350 particles shown in the electron micrograph, and the average value was shown.
比表面積値は、BET法により測定した値で示した。 The specific surface area value was indicated by a value measured by the BET method.
赤外線反射性黒色系顔料の金属元素及びSiの含有量は、「蛍光X線分析装置3063M型」(理学電機工業株式会社製)を使用し、JIS K0119の「けい光X線分析通則」に従って測定した。 The content of metallic elements and Si in the infrared reflective black pigment is measured in accordance with “Fluorescence X-ray analysis general rules” of JIS K0119 using a “fluorescence X-ray analyzer 3063M type” (manufactured by Rigaku Corporation). did.
Cr6+の測定方法は、「ICP発光分光分析装置」(エスエスアイ・ナノテクノロジー(株)社製)を使用し、JIS K0102 65.2.4の「ICP 発光分光分析法」に従って測定した。 The measuring method of Cr6 + was measured according to “ICP emission spectroscopic method” of JIS K0102 652.4 using “ICP emission spectroscopic analyzer” (manufactured by SSI Nanotechnology Co., Ltd.).
真比重(密度)の測定方法は、JIS K5101の「顔料試験方法」に従って測定した。 The true specific gravity (density) was measured according to “pigment test method” of JIS K5101.
赤外線反射性黒色系顔料の色相(L*値、a*値、b*値)は、試料0.5gとヒマシ油0.5mlとをフーバー式マーラーで練ってペースト状とし、このペーストにクリアラッカー4.5gを加え、混練、塗料化してキャストコート紙上に150μm(6mil)のアプリケーターを用いて塗布した塗布片(塗膜厚み:約30μm)を作製した塗膜片について、「多光源分光測色計MSC−IS−2D」(スガ試験機株式会社製)を用いて測定を行い、JIS Z 8729に定めるところに従って表色指数(L*値、a*値、b*値)で示した。 The hue (L * value, a * value, b * value) of the infrared reflective black pigment was prepared by kneading 0.5 g of a sample and 0.5 ml of castor oil with a Hoover-type Mahler to form a paste. Add 4.5g, knead, paint, and apply the coated piece (coating thickness: about 30μm) coated on cast-coated paper using a 150μm (6mil) applicator. Measurement was performed using “total MSC-IS-2D” (manufactured by Suga Test Instruments Co., Ltd.), and the color index (L * value, a * value, b * value) was indicated according to JIS Z 8729.
赤外線反射性黒色系顔料の可視光領域及び赤外線領域での波長の反射性は、上記の色相を測定するために作製した塗膜片について、「分光光度計 UV−3100PC」(株式会社島津製作所)を用いて測定を行い、300〜2100nmの波長における平均反射率(%)及び1000nm、1500nmの波長における反射率(%)で示した。 The reflectance of the wavelength in the visible light region and the infrared region of the infrared-reflective black pigment is determined by “spectrophotometer UV-3100PC” (Shimadzu Corporation) for the coating piece prepared for measuring the above hue. The measurement was carried out using the average reflectance (%) at a wavelength of 300 to 2100 nm and the reflectance (%) at a wavelength of 1000 nm and 1500 nm.
赤外線反射性黒色系顔料を含有する塗料の評価は、次の要領で行なった。
塗料の評価方法は、マヨネーズビン(内容積140ml)中に、ガラスビーズ90g、黒色系顔料10g、アミノアルキッド樹脂(クリヤー)16.0g 溶剤6.0g配合し、ペイントコンデイショナーで40分間分散後、更にアルミアルキッド樹脂(クリヤー)50g追加後、ペイントコンデイショナーで5分分散し、ガラスビーズと分離した。静置5時間後の塗料について、粘度はスパチュラかき混ぜにより、安定性は目視で分離状態を判定した。
Evaluation of the paint containing an infrared reflective black pigment was performed as follows.
The paint was evaluated by mixing 90 g of glass beads, 10 g of black pigment, 16.0 g of amino alkyd resin (clear) and 6.0 g of solvent in mayonnaise bottle (internal volume 140 ml), and dispersing for 40 minutes with a paint conditioner. Further, after adding 50 g of aluminum alkyd resin (clear), it was dispersed with a paint conditioner for 5 minutes and separated from glass beads. Regarding the paint after 5 hours of standing, the viscosity was determined by stirring with a spatula, and the stability was visually determined as a separated state.
実施例1
CoO、Al2O3、MgO、Fe2O3及びSiO2を、組成式(CoO)x・(MgO)1−x・(Fe2O3)y・(Al2O3)1−y・(MO)z・(SiO2)nにおいて、x=0.5、y=0.5、z=0、n=0.35となるように計量、混合し電気炉で1050℃で2時間焼成した。組成式中Mは金属元素である。焼成品を粉砕し平均粒子径0.7μm、BET比表面積5.4m2/gの黒色系顔料を得た。
Example 1
CoO, Al 2 O 3 , MgO, Fe 2 O 3 and SiO 2 are expressed by the composition formula (CoO) x · (MgO) 1-x · (Fe 2 O 3 ) y · (Al 2 O 3 ) 1-y · (MO) z · (SiO 2 ) n is weighed and mixed so that x = 0.5, y = 0.5, z = 0, n = 0.35, and baked in an electric furnace at 1050 ° C. for 2 hours. did. In the composition formula, M is a metal element. The fired product was pulverized to obtain a black pigment having an average particle diameter of 0.7 μm and a BET specific surface area of 5.4 m 2 / g.
得られた黒色系顔料は、可視光領域から赤外線領域波長300〜2100nmにおける平均反射率(日射反射率)が35%、赤外線領域波長1000nmにおける反射率が57%、赤外線領域波長1500nmにおける反射率が23%であった。 The obtained black pigment has an average reflectance (solar reflectance) of 35% from the visible light region to the infrared region wavelength of 300 to 2100 nm, a reflectance of 57% at the infrared region wavelength of 1000 nm, and a reflectance at the infrared region wavelength of 1500 nm. It was 23%.
実施例2
湿式法で合成した後、850℃で2時間焼成した以外は前記実施例1と同様にして黒色系顔料を得た。
Example 2
After synthesizing by a wet method, a black pigment was obtained in the same manner as in Example 1 except that it was calcined at 850 ° C. for 2 hours.
実施例3
前記実施例1と同様にして黒色系顔料を得た。次いで、得られた黒色系顔料を水中に湿式分散させ、70℃に保温した黒色系顔料のスラリーに対し水ガラス0.5wt%を滴下しながら塩酸及び水酸化ナトリウムでpH7に調整し1時間維持した。その後、水洗・乾燥・粉砕処理した。
Example 3
A black pigment was obtained in the same manner as in Example 1. Subsequently, the obtained black pigment was wet-dispersed in water, adjusted to pH 7 with hydrochloric acid and sodium hydroxide and maintained for 1 hour while dripping 0.5 wt% of water glass into the slurry of black pigment kept at 70 ° C. did. Then, it washed with water, dried and pulverized.
実施例4
焼成温度及び表面処理を変化させた以外は実施例3と同様にして黒色系顔料を得た。
Example 4
A black pigment was obtained in the same manner as in Example 3 except that the firing temperature and the surface treatment were changed.
比較例1
原料組成を変化させた以外は、実施例1と同様にして黒色系顔料を得た。
Comparative Example 1
A black pigment was obtained in the same manner as in Example 1 except that the raw material composition was changed.
比較例2
比較例1で得られたSiを含有しない黒色系顔料1モルに対して3.1モルの粉末状の酸化珪素を添加、自動乳鉢で30分混合し、混合物からなる黒色系の顔料を得た。該黒色系の顔料を塗料構成基材に添加混合したところ、塗料の粘度が上昇し、ゲル化し、かつSiを含有しない黒色系顔料と酸化珪素とが分離した。
Comparative Example 2
3.1 mol of powdered silicon oxide was added to 1 mol of the black pigment not containing Si obtained in Comparative Example 1, and mixed in an automatic mortar for 30 minutes to obtain a black pigment composed of the mixture. . When the black pigment was added to and mixed with the paint base material, the viscosity of the paint increased, gelled, and the black pigment not containing Si and silicon oxide separated.
実施例1〜実施例4、比較例1〜2の製造条件を表1に、得られた赤外線反射性黒色系顔料の諸特性、塗膜の特性(反射率%)及び塗料の特性を表2及び表3に示した。またCr6+の含有量が「5ppm未満」とは、前記測定装置の検出限界以下であることを示す。 The production conditions of Examples 1 to 4 and Comparative Examples 1 and 2 are shown in Table 1, and the properties of the obtained infrared reflective black pigment, the properties of the coating (reflectance%), and the properties of the paint are shown in Table 2. And in Table 3. Further, the content of Cr 6+ being “less than 5 ppm” indicates that it is below the detection limit of the measuring device.
本発明に係る赤外線反射性黒色系顔料は、赤外線反射性に優れているので赤外線反射性黒色系顔料として好適である。 Since the infrared reflective black pigment according to the present invention is excellent in infrared reflectivity, it is suitable as an infrared reflective black pigment.
Claims (8)
Si/(Co+Mg+Fe+Al+Si)がモル比で10〜90%であり、該黒色系顔料の平均粒子径が0.02〜2.0μmであることを特徴とする赤外線反射性黒色系顔料。 A black pigment that is substantially free of Cr and is made of a complex oxide containing at least Co, Mg, Fe, Al, and Si,
An infrared reflective black pigment, wherein Si / (Co + Mg + Fe + Al + Si) has a molar ratio of 10 to 90%, and the average particle size of the black pigment is 0.02 to 2.0 μm.
A resin composition characterized by being colored using the infrared-reflective black pigment according to any one of claims 1 to 6.
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