CN101210128A - Thin type reflective insulation exterior wall paint - Google Patents

Thin type reflective insulation exterior wall paint Download PDF

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Publication number
CN101210128A
CN101210128A CNA2007100509628A CN200710050962A CN101210128A CN 101210128 A CN101210128 A CN 101210128A CN A2007100509628 A CNA2007100509628 A CN A2007100509628A CN 200710050962 A CN200710050962 A CN 200710050962A CN 101210128 A CN101210128 A CN 101210128A
Authority
CN
China
Prior art keywords
exterior wall
resin
wall paint
reflective insulation
thin type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2007100509628A
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Chinese (zh)
Inventor
刘恩林
李慢珠
余航
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZIYANG SAITE CHEMICAL CO Ltd
Original Assignee
ZIYANG SAITE CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZIYANG SAITE CHEMICAL CO Ltd filed Critical ZIYANG SAITE CHEMICAL CO Ltd
Priority to CNA2007100509628A priority Critical patent/CN101210128A/en
Publication of CN101210128A publication Critical patent/CN101210128A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a thin reflective insulation exterior wall paint which is characterized in that the paint is prepared by mixing pigments and fillers as well as multiple synthetic resin solution or emulsion, the pigment ratio 0.9 to 1.3 of the pigment ratio, and the remaining is addition agent and solvent. The invention has good thermal insulation effect, thus reducing the energy consumption of a building. The paint has thin coating and smooth surface, and the contamination is not easy; the painting engineering cost is obviously lowered and the maintenance fee is obviously reduced.

Description

Thin type reflective insulation exterior wall paint
Technical field
The present invention relates to a kind of book type sun reflective heat-insulation paint, particularly relate to thin type reflective insulation exterior wall paint.
Background technology
China is the country of a rich coal, oil-poor, weak breath, and energy workable reserve is lower than world average level per capita.At present, China's energy production occupies the third place in the world, and energy consumption but leaps to the second place of the world, in addition, because China's energy use efficiency that causes backward in technique is low, wastes surprising.According to statistics in 2000,12.74 tons of standard coals of the average per ten thousand dollars of GDP power consumption of China are higher 2.4 times than world average level.
At present, the annual town and country of China newly constructed house area 2,000,000,000 m nearly 2, wherein 95% is the highly energy-consuming building, original 42,000,000,000 m 2In the building, all the highly energy-consuming building more than 98%.The building energy consumption of China has accounted for 30% of social terminal energy consumption, and China's residential housing energy consumption is 3 times of developed country under the homoclime condition.The Chinese government has proposed to set up the call of conservation-minded society, has formulated various energy-saving and emission-reduction policies and rules in succession; Aspect building energy conservation, require on the energy consumption benchmark of the building eighties in 20th century, to reduce more than 50%, and begin to execute on January 1st, 2006.Major portion in the building energy consumption is heating and refrigerating energy consumption, account for 50~60%, this partly energy consumption mainly be by the thermal property decision of architectural exterior-protecting construction (roofing, exterior wall, external door, exterior window and transparent curtain wall), therefore, the thermal property of raising architectural exterior-protecting construction is the major measure of building energy conservation.
In present architectural design and building, mainly be that the method that promptly reduces heat transfer coefficient (K) reduces the heat that imports into or spread out of via body of wall by raising wall heat resistance (R), thereby reach the purpose that reduces building energy consumption.But, proof after deliberation, when K value drops to below the certain level, it is not obvious to the effect of reduction building energy consumption.From the heat transfer equation formula as can be known, the transmission of heat is directly proportional with the temperature difference of the surfaces externally and internally of body of wall.When using air conditioner refrigerating summer, indoor temperature generally all maintains 25~27 ℃, is constant basically, if can reduce the temperature of exterior surface of wall, can reduce importing into of heat, reduces the energy consumption of building.
In the nineties in 20th century, the reflection-type outer wall thermal insulation coating that successively begins one's study has both at home and abroad also been delivered some research reports and patent application.Take a broad view of these reported in literature, it is main pigment that majority all adopts Rutile type Titanium Dioxide, is stopping composition with the boracic hollow glass micropearl, and the reflectivity of its solar radiation (0.2~3.0 μ m) can reach 80~87%; Domestic also relevant for the report of dosing the infrared external reflection powder, these powders are made with the agglomerating method mostly.The main drawback of above-mentioned reflection-type outer wall thermal insulation coating is: (1) coatingsurface is coarse, easily stain, and (2) thick coating (200~300 μ m), (3) cost is higher, and this makes it in popularization, is difficult to be built the developer and accepts.
Summary of the invention
The object of the present invention is to provide the thin type reflective insulation exterior wall paint of a kind of surface smoothing, difficult contamination, good heat-insulation effect; It can replace pasting the external wall heat insulation system (JGT144-2004) of polystyrene foam plate or blade coating granules of polystyrene mortar, is used for the warm summer in cold in winter and hot in summer and winter thermally to distinguish.
In order to achieve the above object, the present invention adopts following technical scheme: a kind of thin type reflective insulation exterior wall paint, use the preparation of color stuffing and multiple synthetic resin solution or emulsion, and resin-pigment ratio is 0.9~1.3, surplus is auxiliary agent and solvent; Described synthetic resin solution is a kind of in hydroxyl fluorocarbon resin, Hydroxylated acrylic resin, acrylic acid modified alkyd resin, thermoplastic acrylic resin, alicyclic isocyanate modified alkyd resin, the silicone alkyd.Described synthetic resin emulsion is a kind of in pure acrylic resin emulsion, organosilicon modified crylic acid resin emulsion, phenylethene modified Emulsion acrylic resin and the tertiary ethylene carbonate modified Emulsion acrylic resin.Described color stuffing is Rutile type Titanium Dioxide and other pigment and stopping composition; The shared weight percent of Rutile type Titanium Dioxide is 80~90%, and the shared weight percent of other color stuffing is 5~10%, and the shared weight percent of stopping composition is 5~10%; Other pigment in the described color stuffing is tindioxide, zinc sulphide, zinc oxide, barium metaborate, mica titanium perlatolic powder and various toning with a certain or several mixtures in pigment dyestuff, the mill base (be that these pigment can add separately, also can compositely use); Stopping composition in the described color stuffing is a certain or several mixtures (be that these stopping composition can add separately, also can compositely use) in kaolin, calcined kaolin, calcined diatomite, boron-containing glass powder, mica powder, wollastonite powder, the talcum powder.
The present invention is because not adopt traditional hollow glass bead be stopping composition, and is to use general pigment and stopping composition, thereby the build that the present invention's coating forms is 150~200 μ m, surface smoothing, is difficult for staiing; The reflectivity of solar radiation reaches 83~86%, and infrared normal emittance can reach 93~95%.The present invention also provides the optimum pigment-vehicle ratio scope of book type reflective heat-insulation paint prescription, also available PVC value representation.Find through test of many times, during the color stuffing system that in using the present invention, proposes, resin-pigment ratio is controlled between 0.9~1.3, can make the reflectivity of solar radiation be controlled at 80~86%, infrared normal emittance can be controlled between 0.9~0.95%, and the kind of they and used synthetic resin solution or emulsion is irrelevant.
Embodiment
By following examples the present invention is described in detail
Embodiment 1: light vinylformic acid reflective insulation exterior wall paint
1, prescription % (by weight percentage)
Titanium dioxide (R-962) 30.0
Zinc oxide (technical grade) 2.0
Calcined diatomite (800 order) 2.5
Flatting silica (SD530) 3.0
Acrylic acid modified alkyd resin (PJ17-60A) 56.5
Dispersion agent (904S) 0.3
Flow agent (466) 0.2
Cobalt liquid (3%) 0.1
Manganese liquid (3%) 0.4
Plumbous liquid (10%) 1.2
Anti-skinning agent (98%) 0.2
Heavy aromatics (100#) 2.0
Dimethylbenzene 1.6
Add up to 100.0
In the above-mentioned composition: flatting silica (SD530), dispersion agent (904S), flow agent (466), cobalt liquid (8%), manganese liquid (3%), plumbous liquid (10%), anti-skinning agent (98%) are auxiliary agent, and heavy aromatics (100#), dimethylbenzene are solvent.
2, formulation parameter
(1) solid part: 71.4%
(2) resin-pigment ratio: 1.11
3, preparation technology
Coating preparation technology of the present invention is identical with the production technique of general coating, and equipment used is also just the same.Normally make the master grind of white earlier, add rest part then, mix.At last, with a little pigment dyestuff color paste toning.Through filtering, can pack.
Embodiment 2: light acroleic acid polyurethane reflective insulation exterior wall paint (2K)
1, first component % (by weight)
Titanium dioxide (R-906) 39.0
Mica titanium perlatolic powder (800 order) 3.0
Wollastonite powder (800 order) 3.0
Flatting silica (SD530) 3.3
Hydroxylated acrylic resin (FS-3270) 41.5
Dispersion agent (904S) 0.3
Isocaprylic acid zinc (2%) 0.2
Gas-phase silica (HL-300) 0.3
Defoamer (5400) 0.2
Flow agent (466) 0.2
Heavy aromatics (100#) 3.0
Butyl ester 3.0
CAC 3.0
Add up to 100.0
2, component B: solidifying agent (TPA-90) 12.0
In the above-mentioned composition: flatting silica (SD530), dispersion agent (904S), isocaprylic acid zinc (2%), gas-phase silica (HL-300), defoamer (5400), flow agent (466) are that auxiliary agent, heavy aromatics (100#), butyl ester, CAC are solvent.
3, formulation parameter
(1) solid part: 78.7%
(2) resin-pigment ratio: 1.21
(3)NCO/OH:1.1
4, preparation technology
Identical with embodiment 1.
Embodiment 3: light fluorine carbon reflective insulation exterior wall paint (2K)
1, first component % (by weight)
Titanium dioxide (R-244) 35.5
Zinc sulphide 2.1
Calcined kaolin (800 order) 3.0
Hydroxyl fluorocarbon resin (F100) 52.0
Dispersion agent (904S) 0.3
Isocaprylic acid zinc (2%) 0.2
Gas-phase silica (HL-300) 0.3
Flatting silica (SD530) 3.3
Flow agent (466) 0.2
Defoamer (5400) 0.2
Mixed solvent * 2.9
Add up to 100.0
2, component B: solidifying agent (TPA-90) 10.0
In the above-mentioned composition: (5400 is auxiliary agent, and mixed solvent is a solvent for dispersion agent (904S), isocaprylic acid zinc (2%), gas-phase silica (HL-300), flatting silica (SD530), flow agent (466), defoamer.
* mixed solvent: dimethylbenzene: butyl ester: methyl iso-butyl ketone (MIBK) (MIBK)=40: 40: 20
3, formulation parameter
(1) solid part: 73.1%
(2) resin-pigment ratio: 1.2
(3)NCO/OH:1.1
4, preparation technology
Identical with embodiment 1.
Embodiment 4: light water-based reflective insulation exterior wall paint
1, prescription % (by weight)
Titanium dioxide (R-706) 23.6
Tindioxide (800 order) 1.5
Mica powder (800 order) 1.5
Flatting silica (W-300) 0.4
Dispersion agent (SN-5027) 1.0
Wetting agent (PE100) 0.1
Sanitas (LXE) 0.2
Frostproofer (propylene glycol) 3.0
PH conditioning agent (AMP-95) 0.1
(organosilicon modified crylic acid resin emulsion) 51.0
Organosilicon crylic acid latex (KB-26)
Thickening material (mixing) * 0.6
Mould inhibitor (N-253) 0.4
Film coalescence aid (Texanol) 2.5
Defoamer (NXZ) 0.3
Deionized water 13.8
Add up to 100.0
* mix thickening material (TT-925+ASE-60)
In the above-mentioned composition: flatting silica (SD530), dispersion agent (SN-5027), wetting agent (PE100), sanitas (LXE), frostproofer (propylene glycol), PH conditioning agent (AMP-95), thickening material (mixing), mould inhibitor (N-253), film coalescence aid (Texanol), defoamer (NXZ) are that auxiliary agent, deionized water are thinner.
2, formulation parameter
(1) solid part: 51.5%
(2) resin-pigment ratio: 1.1
3, preparation technology
Identical with embodiment 1.
Embodiment 5: light water-based reflective insulation exterior wall paint
1, prescription % (by weight)
Titanium dioxide (R-996) 23.0
Zinc sulphide 2.0
Boron-containing glass powder (800 order) 2.6
Flatting silica (W-300) 0.4
Dispersion agent (SN-5027) 1.2
Wetting agent (PE100) 0.1
Sanitas (LXE) 0.3
Frostproofer (propylene glycol) 3.5
PH conditioning agent (AMP-95) 0.1
(pure acrylic resin emulsion) pure-acrylic emulsion 52.0
(AC261)
Thickening material (mixing) * 0.5
Mould inhibitor (N-253) 0.4
Film coalescence aid (Texanol) 2.6
Defoamer (NXZ) 0.3
Deionized water 11.0
Add up to 100.0
* mix thickening material (TT-925+ASE-60)
In the above-mentioned composition: flatting silica (W-300), dispersion agent (SN-5027), wetting agent (PE100), sanitas (LXE), frostproofer (propylene glycol), PH conditioning agent (AMP-95), thickening material (mixing), mould inhibitor (N-253), film coalescence aid (Texanol), defoamer (NXZ) are auxiliary agent.Deionized water is a thinner.
2, formulation parameter
(1) solid part: 53%
(2) resin-pigment ratio: 1.12
3, preparation technology
Identical with embodiment 1.
Embodiment 6: light water-based reflective insulation exterior wall paint
1, prescription % (by weight)
Titanium dioxide (R-996) 21.8
Barium metaborate 2.0
Talcum powder (800 order) 2.1
Flatting silica (W-300) 0.4
Dispersion agent (SN-5027) 1.0
Wetting agent (PE100) 0.1
Sanitas (LXE) 0.4
Frostproofer (propylene glycol) 3.5
PH conditioning agent (AMP-95) 0.1
(tertiary ethylene carbonate modified acrylic resin 53.0
Emulsion) uncle's acrylic emulsion (PD-9B)
Thickening material (mixing) * 0.4
Mould inhibitor (N-253) 0.4
Film coalescence aid (Texanol) 2.5
Defoamer (NXZ) 0.2
Deionized water 12.1
Add up to 100.0
* mix thickening material (TT-925+ASE-60)
In the above-mentioned composition: flatting silica (W-300), dispersion agent (SN-5027), wetting agent (PE100), sanitas (LXE), frostproofer (propylene glycol), PH conditioning agent (AMP-95), thickening material (mixing), mould inhibitor (N-253), film coalescence aid (Texanol), defoamer (NXZ) are auxiliary agent.Deionized water is a thinner.
2, formulation parameter
(1) solid part: 51.7%
(2) resin-pigment ratio: 1.03
3, preparation technology
Identical with embodiment 1.

Claims (6)

1. thin type reflective insulation exterior wall paint is characterized in that: coating is color stuffing and multiple synthetic resin solution or emulsion preparation, and resin-pigment ratio is 0.9~1.3, and surplus is auxiliary agent and solvent.
2. thin type reflective insulation exterior wall paint according to claim 1 is characterized in that: described synthetic resin solution is a kind of in hydroxyl fluorocarbon resin, Hydroxylated acrylic resin, acrylic acid modified alkyd resin, thermoplastic acrylic resin, alicyclic isocyanate modified alkyd resin, the silicone alkyd.
3. thin type reflective insulation exterior wall paint according to claim 1 is characterized in that: described synthetic resin emulsion is a kind of in pure acrylic resin emulsion, organosilicon modified crylic acid resin emulsion, phenylethene modified Emulsion acrylic resin and the tertiary ethylene carbonate modified Emulsion acrylic resin.
4. thin type reflective insulation exterior wall paint according to claim 1, it is characterized in that: described color stuffing is Rutile type Titanium Dioxide and other pigment and stopping composition, wherein the shared weight percent of Rutile type Titanium Dioxide is 80%~90%, the shared weight percent of other pigment is 5~10%, and the shared weight percent of stopping composition is 5~10%.
5. thin type reflective insulation exterior wall paint according to claim 4 is characterized in that: other pigment in the described color stuffing is tindioxide, zinc sulphide, zinc oxide, barium metaborate, mica titanium perlatolic powder and various toning one or more mixtures with pigment dyestuff, mill base.
6. thin type reflective insulation exterior wall paint according to claim 4 is characterized in that: the stopping composition in the described color stuffing is a certain or several mixtures in kaolin, calcined kaolin, calcined diatomite, boron-containing glass powder, mica powder, wollastonite powder, the talcum powder.
CNA2007100509628A 2007-12-25 2007-12-25 Thin type reflective insulation exterior wall paint Pending CN101210128A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002293A (en) * 2010-11-12 2011-04-06 航天材料及工艺研究所 Thin multifunctional solar reflecting coating and preparation method thereof
CN102518227A (en) * 2011-11-24 2012-06-27 朱勤辉 Fireproof heat preservation sound insulation board and preparation method thereof
CN102676014A (en) * 2012-05-30 2012-09-19 浙江好途程新型建材有限公司 Staining-resistant heat-insulationcoating and preparation method thereof
CN102850871A (en) * 2011-06-29 2013-01-02 比亚迪股份有限公司 Coating material and preparation method thereof
CN102933669A (en) * 2010-06-09 2013-02-13 昭和电工株式会社 Aqueous resin composition for forming a thick film, and surface treatment method using said composition
CN102977698A (en) * 2012-11-30 2013-03-20 无锡市虎皇漆业有限公司 Normal-temperature fluorocarbon paint and preparation method thereof
CN103173076A (en) * 2013-02-26 2013-06-26 安徽真信涂料有限公司 Exterior wall coating and preparation method thereof
CN103937356A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Thermal insulation finish paint, preparation and applications thereof
CN103937362A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Thermal insulation sealing paint, preparation method and applications thereof
CN103937363A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Reflective thermal insulation paint, preparation and applications thereof
CN104292796A (en) * 2014-09-30 2015-01-21 山东阳谷华泰化工股份有限公司 Application of zinc isoocatanoate in reduction on agglomeration of white carbon black, white carbon black dispersing agent containing zinc isoocatanoate and preparation method thereof
CN105131776A (en) * 2015-09-14 2015-12-09 安徽华润涂料有限公司 Adhesive for domestic anti-theft window prime paint and preparation method of adhesive
CN105368180A (en) * 2015-11-23 2016-03-02 安徽酉阳防水科技有限公司 Building insulation exterior wall heat-insulation paint having strong crack-resistance performance
CN105419540A (en) * 2015-12-25 2016-03-23 广州市福田化学工业涂料有限公司 Reflection and heat-insulation coating and preparation method therof
CN106189750A (en) * 2016-07-13 2016-12-07 温州雏鹰科技有限公司 A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating
CN106554687A (en) * 2016-11-22 2017-04-05 上海保立佳新材料有限公司 A kind of external wall water-and acrylate emulsion
CN109423189A (en) * 2017-07-04 2019-03-05 天津市新丽华色材有限责任公司 A kind of polyurethane lacquer of anti-flaming thermal-insulation
CN109503138A (en) * 2018-12-14 2019-03-22 广东金意陶陶瓷集团有限公司 Fire resisting foamed ceramic and preparation method thereof
CN110564220A (en) * 2019-07-25 2019-12-13 安徽沃尔德新材料有限公司 Preparation method of novel glass heat-insulating coating material capable of improving elongation
CN111574161A (en) * 2020-06-01 2020-08-25 铁正检测科技有限公司 Fluorescent multicolor permeable concrete pavement brick and preparation method thereof

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102933669A (en) * 2010-06-09 2013-02-13 昭和电工株式会社 Aqueous resin composition for forming a thick film, and surface treatment method using said composition
CN102002293A (en) * 2010-11-12 2011-04-06 航天材料及工艺研究所 Thin multifunctional solar reflecting coating and preparation method thereof
CN102002293B (en) * 2010-11-12 2012-11-21 航天材料及工艺研究所 Thin multifunctional solar reflecting coating and preparation method thereof
CN102850871B (en) * 2011-06-29 2015-08-26 比亚迪股份有限公司 A kind of coating and preparation method thereof
CN102850871A (en) * 2011-06-29 2013-01-02 比亚迪股份有限公司 Coating material and preparation method thereof
CN102518227B (en) * 2011-11-24 2014-06-25 赵成颐 Fireproof heat preservation sound insulation board and preparation method thereof
CN102518227A (en) * 2011-11-24 2012-06-27 朱勤辉 Fireproof heat preservation sound insulation board and preparation method thereof
CN102676014A (en) * 2012-05-30 2012-09-19 浙江好途程新型建材有限公司 Staining-resistant heat-insulationcoating and preparation method thereof
CN102977698A (en) * 2012-11-30 2013-03-20 无锡市虎皇漆业有限公司 Normal-temperature fluorocarbon paint and preparation method thereof
CN102977698B (en) * 2012-11-30 2016-08-10 无锡市虎皇漆业有限公司 A kind of Normal-temperature fluorocarbon paint and preparation method thereof
CN103937356B (en) * 2013-01-17 2016-03-30 上海绿色建材研究中心有限公司 A kind of insulation finish paint and Synthesis and applications thereof
CN103937356A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Thermal insulation finish paint, preparation and applications thereof
CN103937362A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Thermal insulation sealing paint, preparation method and applications thereof
CN103937363A (en) * 2013-01-17 2014-07-23 上海绿色建材研究中心有限公司 Reflective thermal insulation paint, preparation and applications thereof
CN103937362B (en) * 2013-01-17 2016-03-09 上海绿色建材研究中心有限公司 A kind of insulation back cover coating and Synthesis and applications thereof
CN103173076A (en) * 2013-02-26 2013-06-26 安徽真信涂料有限公司 Exterior wall coating and preparation method thereof
CN103173076B (en) * 2013-02-26 2016-04-27 安徽真信涂料有限公司 A kind of exterior coating and preparation method thereof
CN104292796A (en) * 2014-09-30 2015-01-21 山东阳谷华泰化工股份有限公司 Application of zinc isoocatanoate in reduction on agglomeration of white carbon black, white carbon black dispersing agent containing zinc isoocatanoate and preparation method thereof
CN105131776A (en) * 2015-09-14 2015-12-09 安徽华润涂料有限公司 Adhesive for domestic anti-theft window prime paint and preparation method of adhesive
CN105131776B (en) * 2015-09-14 2017-11-24 安徽华润涂料有限公司 A kind of adhesive of home security window subbing and preparation method thereof
CN105368180A (en) * 2015-11-23 2016-03-02 安徽酉阳防水科技有限公司 Building insulation exterior wall heat-insulation paint having strong crack-resistance performance
CN105419540A (en) * 2015-12-25 2016-03-23 广州市福田化学工业涂料有限公司 Reflection and heat-insulation coating and preparation method therof
CN106189750A (en) * 2016-07-13 2016-12-07 温州雏鹰科技有限公司 A kind of preparation method of unmanned plane eyelid covering modified alkyd resin coating
CN106554687A (en) * 2016-11-22 2017-04-05 上海保立佳新材料有限公司 A kind of external wall water-and acrylate emulsion
CN106554687B (en) * 2016-11-22 2018-12-18 上海保立佳新材料有限公司 A kind of external wall water-and acrylate lotion
CN109423189A (en) * 2017-07-04 2019-03-05 天津市新丽华色材有限责任公司 A kind of polyurethane lacquer of anti-flaming thermal-insulation
CN109503138A (en) * 2018-12-14 2019-03-22 广东金意陶陶瓷集团有限公司 Fire resisting foamed ceramic and preparation method thereof
CN110564220A (en) * 2019-07-25 2019-12-13 安徽沃尔德新材料有限公司 Preparation method of novel glass heat-insulating coating material capable of improving elongation
CN111574161A (en) * 2020-06-01 2020-08-25 铁正检测科技有限公司 Fluorescent multicolor permeable concrete pavement brick and preparation method thereof

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