CN103937362A - Thermal insulation sealing paint, preparation method and applications thereof - Google Patents
Thermal insulation sealing paint, preparation method and applications thereof Download PDFInfo
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- CN103937362A CN103937362A CN201310017748.8A CN201310017748A CN103937362A CN 103937362 A CN103937362 A CN 103937362A CN 201310017748 A CN201310017748 A CN 201310017748A CN 103937362 A CN103937362 A CN 103937362A
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Abstract
The invention relates to the field of thermal insulation construction, and specifically relates to a thermal insulation sealing paint and applications thereof. The thermal insulation sealing paint is composed of the following components in parts by weight: 20 to 40 parts of tert-acetic styrene acrylic emulsion, 20 to 30 parts of thermal insulation powder, 25 to 30 parts of pigments and fillers, 1 to 10 parts of auxiliary agent, and 30 to 40 parts of water. The thermal insulation sealing paint has a strong far infrared emission property, good sealing property, high adhering strength, and advantages of low cost, good thermal insulation property, green, and environment-friendliness.
Description
Technical field
The present invention relates to heat preservation construction material field, be specifically related to a kind of insulation back cover coating and preparation and application.
Background technology
Based on the national conditions of resource anxiety, environmental carrying capacity weakness.Along with socioeconomic fast development, heat preservation energy-saving has become the focus of whole society's growing interest.In recent years since, the environmental problem that Global warming causes is very outstanding, the each state in the whole world all recognizes if do not strengthen the control to energy consumption, since growing this, going from bad to worse of environment for human survival will be caused, finally bring extinction to human society, building energy consumption accounts for 30% of the whole society of China total energy consumption, and country has gone out a series of policies for building thermal-insulation energy-saving.
Heat insulation coating is in the time that sunlight is strong, and coating can reduce body surface temperature more than 5 DEG C, cloudy day with can lower the temperature night more than 3 DEG C or be reduced to consistent with free air temperature.
Priming paint is the first layer of paint system, for improve finish paint sticking power, increase finish paint fullness ratio, alkali-resistivity is provided, anti-corrosion function etc. is provided, can ensure the even absorption of finish paint simultaneously, make paint system performance best effect.Surface paint quality well just can be without priming paint, and this saying is not right, because finish paint is different from the function of priming paint, finish paint lays particular emphasis on final decoration and apparent effect more, and priming paint lays particular emphasis on and improves sticking power, anti-corrosion function, alkali-resistivity etc.
How priming paint function singleness of the prior art, provide a kind of basic function both with priming paint, has marketable value again with stronger far-infrared transmitting function, stronger closure and the priming paint of cohesive strength.
Summary of the invention
The object of the invention is to overcome the defect of prior art, provide one both to there is common priming paint function, there is again the insulation back cover coating of stronger far-infrared transmitting function, stronger closure and cohesive strength.
First the present invention discloses a kind of insulation back cover coating, and its composition comprises each component of following weight part:
Tertiary acrylic emulsion:
Preferably, the raw material composition of described tertiary acrylic emulsion comprises core portion raw material and shell portion raw material, and the weight ratio of described core portion's raw material and shell portion raw material is 1:0.2~0.4;
The composition of described core portion raw material comprises each component of following weight part: tensio-active agent 1-3 part, initiator 0.2-0.3 part, the soft monomer 10-20 of core portion part, the hard monomer 5-15 of core portion part, organo-siloxane monomer 3-5 part, the function monomer 0.5-1.5 of core portion part, water 40-45 part;
The composition of described shell portion raw material comprises each component of following weight part: tensio-active agent 0.2-0.5 part; Initiator 0.1-0.3 part; The soft monomer 3-8 of shell portion part; The hard monomer 5-10 of shell portion part; Organo-siloxane monomer 1-2 part; The function monomer 0.2-1.0 of shell portion part; Water 5-10 part.
More excellent, described core portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, tertiary monocarboxylic acid ethyl ester, ethyl acrylate;
Described core portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid;
Described core portion function monomer is selected from one or more the combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, diacetone-acryloamide(DAA);
Described shell portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate;
Described shell portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid;
Described shell portion function monomer is selected from one or more the combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, diacetone-acryloamide(DAA);
Described organo-siloxane monomer is selected from one or more the combination in vinyl silane triisopropoxide, r-methyl-prop acyloxy propyl group three isopropoxy silane, eight vinyl cyclotetrasiloxanes, octamethylcyclotetrasiloxane.
Tensio-active agent used in the present invention is the tensio-active agent of this area routine.More excellent, described tensio-active agent is selected from sulfo-succinic acid alkyl ethoxylated ester sodium salt, side chain alcohol ether and containing one or more the mixing in the polyether thiourea hydrochlorate of allyl group alkoxyl group.
More excellent, described initiator is selected from any in ammonium persulphate, Potassium Persulphate or Sodium Persulfate.
Priming paint heat-insulating powder:
Preferably, described priming paint heat-insulating powder is selected from one or more the mixing in 4A molecular sieve, 3A molecular sieve, mica powder and zinc oxide.
Color stuffing:
Preferably, described color stuffing is selected from one or more the combination in titanium dioxide, calcium carbonate, kaolin powder, Sai Boya nanometer rubber powder.
Auxiliary agent:
Preferably, described auxiliary agent comprises one or more the combination in dispersion agent, wetting agent, wetting ability defoamer, hydrophobicity defoamer, sterilant, mould inhibitor, flow agent, compound film former.
More excellent, described auxiliary agent comprises each component of following weight part: dispersion agent 0.2-0.5 part, wetting agent 0.1-0.4 part, wetting ability defoamer 0.1-0.25 part, hydrophobicity defoamer 0.1-0.25 part, sterilant 0.1-0.2 part, mould inhibitor 0.2-0.4 part, flow agent 0.5-1.0 part, compound film former 0.5-1 part.
More excellent, described core portion raw material comprises the following component in weight part: tensio-active agent 1.5-2.5 part, initiator 0.2-0.3 part, the soft monomer 13-17 of core portion part, the hard monomer 10-14 of core portion part, organo-siloxane monomer 3.5-4.5 part, the function monomer 0.8-1.2 of core portion part, water 40-45 part.Described shell portion raw material comprises the following component in weight part: tensio-active agent 0.3-0.4 part, initiator 0.1-0.2 part; The soft monomer 3.5-6 of shell portion part; The hard monomer 8-10 of shell portion part; Organo-siloxane monomer 1-2 part; The function monomer 0.2-1.0 of shell portion part; Deionized water 5.5-8.4 part.
Preferably, institute of the present invention water is deionized water.
Preferably, the raw material of described tertiary acrylic emulsion also comprises sterilant, and the weight ratio of the consumption of described sterilant and core portion raw material and shell portion raw material total mass is 0.5~2:100.
More excellent, the raw material of described tertiary acrylic emulsion also comprises sterilant, the weight ratio of the consumption of described sterilant and core portion raw material and shell portion raw material total mass is 1:100.
The effect of sterilant is rotten in order to prevent the long-term tertiary acrylic emulsion of placing.
Second aspect present invention discloses the preparation method of aforementioned insulation back cover coating, and step is as follows:
1) by the water of 1/2~3/4 quality in core portion raw material, the tensio-active agent of 1/10~1/2 quality, the initiator of 1/5~1/2 quality, the core portion soft monomer of 1/5~1/2 quality, the core portion hard monomer of 1/15~2/5 quality, the core portion function monomer of 1/4~2/3 quality and the organo-siloxane monomer of 1/10~1/3 quality add in reactor, under agitation condition, be warming up to 80~87 DEG C, reaction 10min~15min obtains seed crystal; Remaining core portion raw material is mixed and obtains core portion pre-emulsion; Core portion pre-emulsion is added drop-wise in the seed crystal of reactor, after dropping finishes, the reactant in reactor is warming up to 83~90 DEG C, insulation reaction 2~3h, obtains stratum nucleare emulsion particle;
2) whole shell portion raw material is mixed, obtain shell portion pre-emulsion; Shell portion pre-emulsion is dropped in step 1) gained stratum nucleare emulsion particle, after dropping finishes, the reactant in reactor is warming up to 83~90 DEG C, insulation reaction 2~3h, after finishing, reaction is cooled to below 40 DEG C, regulator solution pH is 7~8, filters, and obtains tertiary acrylic emulsion;
3) after water, the dispersion agent in auxiliary agent, wetting agent, wetting ability defoamer in insulation back cover coating composition are stirred, under agitation condition, add wherein the heat-insulating powder of whole color stuffings and 1/2~2/3 total mass, disperse, grind, obtain raw material powder slurry;
4) in the raw material powder slurry of step 3), add remaining heat-insulating powder, remaining auxiliary agent and step 2) the tertiary acrylic emulsion that makes, stir, regulator solution pH is 8.0~8.5, filters, and obtains insulation back cover coating.
Preferably, step 1) is: by the water of 2/3 quality in core portion raw material, tensio-active agent 1/3, initiator 1/3, core portion soft monomer 1/4, core portion hard monomer 1/6, core portion function monomer 1/4, organo-siloxane monomer 1/6 add reactor, be warming up to 80~87 DEG C of reaction 10min~15min and obtain seed crystal under agitation condition.
Preferably, in the time that the raw material of described tertiary acrylic emulsion also comprises sterilant, step 2) be: whole shell portion raw material is mixed, obtain shell portion pre-emulsion; Shell portion pre-emulsion is dropped in step 1) gained stratum nucleare emulsion particle, after dropping finishes, the reactant in reactor is warming up to 83~90 DEG C, insulation reaction 2~3h, be cooled to 20~40 DEG C, regulator solution pH is 7~8, adds sterilant, filter, obtain tertiary acrylic emulsion.
Preferably, step 2) insulation reaction 2~3h, after finishing, reaction is cooled to 20~40 DEG C.
Preferably, the particle fineness of the slurry of raw material powder described in step 3) is 18~22 μ m.
Preferably, while dripping core portion pre-emulsion in described step 1), the temperature of seed crystal is 80~87 DEG C.Drop rate is 1~2ml/min; Be preferably 1.1~1.3ml/min.
Preferably, described step 2) in while dripping shell portion pre-emulsion, the temperature of stratum nucleare emulsion particle is 80~87 DEG C.Drop rate is 1.1~1.3ml/min; Be preferably 1.1~1.3ml/min.
Preferably, the solution that regulates pH value to use is NaOH solution.Preferably, NaOH concentration is 15~20%.
Third aspect present invention discloses the application of aforementioned insulation back cover coating as green heat preservation construction material.
Insulation back cover coating of the present invention both can be for external wall body (exterior wall), also can be for inside wall body (interior wall).
The beneficial effect that the present invention is incubated back cover coating is: insulation back cover coating of the present invention has stronger far-infrared transmitting function, stronger closure and cohesive strength, and with low cost, good heat insulating, environmental protection, the advantages such as strong water-repellancy.
Embodiment
Before further describing the specific embodiment of the invention, should be understood that protection scope of the present invention is not limited to following specific specific embodiments; It is also understood that the term using in the embodiment of the present invention is in order to describe specific specific embodiments, instead of in order to limit the scope of the invention.
The preparation of embodiment 1 tertiary acrylic emulsion
Method one
1) core portion raw material composition
2) shell portion raw material composition
The deionized water 3/4 that above-mentioned reactant is filled a prescription in core portion feed composition, tensio-active agent 2/5, initiator 1/3, core portion soft monomer 1/4, core portion hard monomer 1/6, core portion function monomer 1/4, organo-siloxane monomer 1/6 add in reactor, under agitation condition, be warming up to 87 DEG C of reactions, after stable reaction 10-15min, form seed nanocrystal emulsion, then drip the core portion pre-emulsion that in core portion raw material, remainder forms, the weight ratio of core portion raw material and shell portion raw material is 1:0.2; 90 DEG C are reacted 3 hours, form stratum nucleare emulsion particle.Then continue to drip shell portion raw material and mix rear prepared shell portion pre-emulsion, 90 DEG C are reacted 2 hours, and initiation grafting copolymerization, is cooled to 20 DEG C, and regulating pH value is 8, obtains tertiary acrylic emulsion.
Method two
1) raw material of core portion raw material composition
2) raw material of shell portion raw material composition
By in above-mentioned core portion feed composition, the deionized water of 1/2 quality, the tensio-active agent of 1/2 quality, the initiator of 1/5 quality, the core portion soft monomer of 1/5 quality, the core portion hard monomer of 2/5 quality, the core portion function monomer of 1/4 quality, the organo-siloxane monomer of 1/10 quality add in reactor, under agitation condition, be warming up to 80 DEG C of reactions, after stable reaction 10-15min, form seed nanocrystal emulsion and then the raw material of remainder in core portion raw material composition is mixed, obtain stratum nucleare pre-emulsion; 83 DEG C are reacted 2 hours, form stratum nucleare emulsion particle.Then continue to drip shell portion raw material and mix rear prepared shell portion pre-emulsion, the weight ratio of core portion raw material and shell portion raw material is 1:0.4, and 83 DEG C are reacted 2 hours, and initiation grafting copolymerization, is cooled to 40 DEG C, and regulating pH value is 7, obtains tertiary acrylic emulsion.
Method three
1) raw material of core portion raw material composition
2) raw material of shell portion raw material composition
By in above-mentioned core portion feed composition, the deionized water of 3/4 quality, the tensio-active agent of 1/10 quality, the initiator of 1/2 quality, the core portion soft monomer of 1/2 quality, the core portion hard monomer of 1/15 quality, the core portion function monomer of 2/3 quality, the organo-siloxane monomer of 1/3 quality add in reactor, are warming up to 87 DEG C of reactions under agitation condition, after stable reaction 10-15min, form seed nanocrystal emulsion, then drip the core portion pre-emulsion that in core portion raw material, remainder forms; 90 DEG C are reacted 2 hours, form stratum nucleare emulsion particle.Then continue to drip shell portion raw material and mix rear prepared shell portion pre-emulsion, the weight ratio of core portion raw material and shell portion raw material is 1:0.3,90 DEG C are reacted 3 hours, initiation grafting copolymerization, be cooled to 20 DEG C, regulating pH value is 8, adds sterilant, the weight ratio of the consumption of sterilant and core portion raw material and shell portion raw material total mass is 2:100, obtains tertiary acrylic emulsion.
Embodiment 2 is incubated the preparation of back cover coating
1. reagent
Dispersion agent S-70S is provided by the loyal Chemical Co., Ltd. in Shanghai, and dispersion agent 2320 is provided by Shenzhen Hai Chuan company limited.Wetting agent LB407, wetting agent EFS4070, by Shanghai, loyal Chemical Co., Ltd. provides.Wetting ability defoamer 315 is provided by Shenzhen Hai Chuan company limited, and hydrophobicity defoamer DF538 is provided by the loyal Chemical Co., Ltd. in Shanghai.Titanium dioxide 996, by Shanghai, Yan Tai company limited provides.4A molecular sieve, by Luoyang, Jian Long company limited provides.Sai Boya nanometer rubber powder adds sincere nonmetal mining industry company limited by Yuhang to be provided.Flow agent LEV-202, by Shanghai, loyal Chemical Co., Ltd. provides.Sterilant 515, by Shanghai, Chao Ling company limited provides.Mould inhibitor A2W, by Shanghai, Chao Ling company limited provides.Wetting agent EFS-407 is provided by the loyal Chemical Co., Ltd. in Shanghai.Surfactant A 6820 (sulfo-succinic acid alkyl ethoxylated ester sodium salt), tensio-active agent V20S (containing the polyether thiourea hydrochlorate of allyl group alkoxyl group), surfactant PS 925 (side chain alcohol ether) are provided by the loyal Fine Chemical Co., Ltd in Shanghai.
2. formula
Method one: (unit: g)
Remove ionized water and add dispersion agent, wetting agent, wetting ability defoamer 315 to stir, add the heat-insulating powder of whole color stuffings and 1/2 quality under agitation condition, high speed dispersion 30min-45min, enters on shredder and grinds, and sampling detects.In the time that product particle fineness reaches 20 μ m left and right, stop grinding.Add remaining heat-insulating powder, tertiary acrylic emulsion (embodiment 1 method 1), mould inhibitor, sterilant, film coalescence aid, hydrophobicity defoamer 538, flow agent stir, and regulating ph is 8.0, filter, and packaging, must be incubated back cover coating, and Performance Detection is as shown in table 1.
Method two: formula: (unit: g)
Technological process:
Remove ionized water and add dispersion agent, wetting agent, defoamer 315 to stir, add the heat-insulating powder of whole color stuffings and 2/3 quality under agitation condition, high speed dispersion 30min-45min, enters on shredder and grinds, and sampling detects.In the time that product particle fineness reaches 18 μ m left and right, stop grinding.Add remaining heat-insulating powder, tertiary acrylic emulsion (prepared by embodiment 1), mould inhibitor, sterilant,, film coalescence aid, defoamer 538, thickening leveling agent stir, and filter, and regulating ph is 8.5, and packaging, must be incubated back cover coating, and Performance Detection is as shown in table 1.
Method three: formula: (unit: g)
Technological process:
Remove ionized water and add dispersion agent, wetting agent, defoamer 315 to stir, add the heat-insulating powder of whole color stuffings and 1/2 quality under agitation condition, high speed dispersion 30min-45min, enters on shredder and grinds, and sampling detects.In the time that product particle fineness reaches 22 μ m left and right, stop grinding.Add remaining heat-insulating powder, add tertiary acrylic emulsion (prepared by embodiment 1), mould inhibitor, sterilant, film coalescence aid, defoamer 538, thickening leveling agent to stir, filter, regulating ph is 8.0, packaging, must be incubated back cover coating, and Performance Detection is as shown in table 1.
Method four: formula: (unit: g)
Technological process:
Remove ionized water and add dispersion agent, wetting agent, defoamer 315 to stir, add the heat-insulating powder of whole color stuffings and 1/2 quality under agitation condition, high speed dispersion 30min-45min, enters on shredder and grinds, and sampling detects.In the time that product particle fineness reaches 20 μ m left and right, stop grinding.Add remaining heat-insulating powder, add tertiary acrylic emulsion (prepared by embodiment 1), mould inhibitor, sterilant, film coalescence aid, defoamer 538, thickening leveling agent to stir, regulating ph is 8.5, filter, packaging, must be incubated back cover coating, and Performance Detection is as shown in table 1.
3. insulation back cover coating property test
The insulation back cover coating of preparing taking the present embodiment method 1~4 is as detected object, method for testing performance is with reference to standard GB/T/T9756-2009 " resin latex dope ", and GB18582-2008 " limits of harmful substances in indoor decorating and refurnishing materials interior wall coating " JG/T210-2007 " building inside and outside wall priming paint ", detected result is in table 1.
Table 1 is incubated back cover coating property and detects
As shown in Table 1, insulation back cover coating of the present invention has preferably abrasion resistance, and volatile organic matter content is low, and harmful volatile matter such as benzene, toluene, ethylbenzene, dimethylbenzene do not detect, and soluble heavy metal does not detect; Purifying formaldehyde ability is strong and lasting, can be used as green non-pollution building materials and is applied to finishing field, less to human injury; Effective heat insulation temperature reaches more than 4 DEG C.
In sum, the present invention has effectively overcome various shortcoming of the prior art and tool high industrial utilization both can play heat-blocking action in the time that external temperature is higher, also can in the time that external temperature is lower, play thermal effect.
Claims (10)
1. an insulation back cover coating, its composition comprises each component of following weight part:
2. insulation back cover coating as claimed in claim 1, is characterized in that, the raw material composition of described tertiary acrylic emulsion comprises core portion raw material and shell portion raw material, and the weight ratio of described core portion's raw material and shell portion raw material is 1:0.2~0.4; The composition of described core portion raw material comprises each component of following weight part: tensio-active agent 1-3 part, initiator 0.2-0.3 part, the soft monomer 10-20 of core portion part, the hard monomer 5-15 of core portion part, organo-siloxane monomer 3-5 part, the function monomer 0.5-1.5 of core portion part, water 40-45 part; The composition of described shell portion raw material comprises each component of following weight part: tensio-active agent 0.2-0.5 part; Initiator 0.1-0.3 part; The soft monomer 3-8 of shell portion part; The hard monomer 5-10 of shell portion part; Organo-siloxane monomer 1-2 part; The function monomer 0.2-1.0 of shell portion part; Water 5-10 part.
3. insulation back cover coating as claimed in claim 2, is characterized in that, described core portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, tertiary monocarboxylic acid ethyl ester, ethyl acrylate; Described core portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid; Described core portion function monomer is selected from one or more the combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, diacetone-acryloamide(DAA); Described shell portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate; Described shell portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid; Described shell portion function monomer is selected from one or more the combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, diacetone-acryloamide(DAA); Described organo-siloxane monomer is selected from one or more the combination in vinyl silane triisopropoxide, r-methyl-prop acyloxy propyl group three isopropoxy silane, eight vinyl cyclotetrasiloxanes, octamethylcyclotetrasiloxane.
4. insulation back cover coating as claimed in claim 2, is characterized in that, described initiator is selected from any in ammonium persulphate, Potassium Persulphate or Sodium Persulfate.
5. insulation back cover coating as claimed in claim 1, is characterized in that, described priming paint heat-insulating powder is selected from one or more the mixing in 4A molecular sieve, 3A molecular sieve, mica powder and zinc oxide.
6. insulation back cover coating as claimed in claim 1, is characterized in that, described color stuffing is selected from one or more the combination in titanium dioxide, calcium carbonate, kaolin powder, Sai Boya nanometer rubber powder.
7. insulation back cover coating as claimed in claim 1, is characterized in that, described auxiliary agent comprises one or more the combination in dispersion agent, wetting agent, wetting ability defoamer, hydrophobicity defoamer, sterilant, mould inhibitor, flow agent, compound film former.
8. insulation back cover coating as claimed in claim 2, is characterized in that, the raw material of described tertiary acrylic emulsion also comprises sterilant.
9. the preparation method who is incubated back cover coating described in the arbitrary claim of claim 1-8, step is as follows:
1) by the water of 1/2~3/4 quality in core portion raw material, the tensio-active agent of 1/10~1/2 quality, the initiator of 1/5~1/2 quality, the core portion soft monomer of 1/5~1/2 quality, the core portion hard monomer of 1/15~2/5 quality, the core portion function monomer of 1/4~2/3 quality and the organo-siloxane monomer of 1/10~1/3 quality add reactor, under agitation condition, be warming up to 80~87 DEG C, reaction 10min~15min obtains seed crystal; Remaining core portion raw material is mixed and obtains core portion pre-emulsion; Core portion pre-emulsion is added drop-wise in the seed crystal of reactor, after dropping finishes, the reactant in reactor is warming up to 83~90 DEG C, insulation reaction 2~3h, obtains stratum nucleare emulsion particle;
2) whole shell portion raw material is mixed, obtain shell portion pre-emulsion; Shell portion pre-emulsion is dropped in step 1) gained stratum nucleare emulsion particle, after dropping finishes, the reactant in reactor is warming up to 83~90 DEG C, insulation reaction 2~3h, after finishing, reaction is cooled to below 40 DEG C, regulator solution pH is 7~8, filters, and obtains tertiary acrylic emulsion;
3) after water, the dispersion agent in auxiliary agent, wetting agent, wetting ability defoamer in insulation back cover coating composition are stirred, under agitation condition, add wherein the heat-insulating powder of whole color stuffings and 1/2~2/3 total mass, disperse, grind, obtain raw material powder slurry;
4) in the raw material powder slurry of step 3), add remaining heat-insulating powder, remaining auxiliary agent and step 2) the tertiary acrylic emulsion that makes, stir, regulator solution pH is 8.0~8.5, filters, and obtains insulation back cover coating.
10. described in the arbitrary claim of claim 1-8, be incubated the application of back cover coating as green heat preservation construction material.
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Cited By (1)
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CN109650838A (en) * | 2019-01-24 | 2019-04-19 | 南京富源资源利用有限公司 | Stalk thermal insulation coatings and preparation method thereof |
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CN1613882A (en) * | 2004-09-14 | 2005-05-11 | 上海市建筑科学研究院有限公司 | High performance silicon emulsion and its preparation |
JP2009102627A (en) * | 2007-09-28 | 2009-05-14 | Eternal Chemical Co Ltd | Modified acrylic oligomer, and antifouling coating containing the oligomer |
CN101210128A (en) * | 2007-12-25 | 2008-07-02 | 资阳赛特化工有限公司 | Thin type reflective insulation exterior wall paint |
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