CN104293190A - Strong anti-corrosion paint for ship and preparation method thereof - Google Patents
Strong anti-corrosion paint for ship and preparation method thereof Download PDFInfo
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- CN104293190A CN104293190A CN201410469155.XA CN201410469155A CN104293190A CN 104293190 A CN104293190 A CN 104293190A CN 201410469155 A CN201410469155 A CN 201410469155A CN 104293190 A CN104293190 A CN 104293190A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a strong anti-corrosion paint for a ship. The strong anti-corrosion paint is characterized by being prepared from the following raw materials in parts by weight: 6-9 parts of organic silicon resin, 3-5 parts of polyvinyl butyral, 10-13 parts of unsaturated polyester resin, 4-6 parts of trimethyl hexamethylenediamine, 1-2 parts of sodium petroleum sulfonate, 0.3-0.8 part of phthalocyanine green, 2-3 parts of light-weight magnesium chloride, 2-3 parts of zwieselite, 3-5 parts of wood wax oil, 0.5-1.0 part of rare earth chloride, 0.5-1.0 part of N-methyl pyrrolidinone, 1-3 parts of magnesium stearate, 0.2-0.5 part of cobaltous chloride, 43-47 parts of modified asphalt, 5-8 parts of modified waste resin sand, 2-3 parts of ammonium zinc sulfate, 6-9 parts of dimethyl benzene, 10-12 parts of butyl acetate and 5-7 parts of trichloroacetic acid. The strong anti-corrosion paint disclosed by the invention has the advantages that added polyvinyl butyral has very high anti-corrosion capacity and anti-rust capacity, high adhesive power and good water resistance; added zwieselite and sodium petroleum sulfonate have anti-corrosion and anti-rust effects, so that the anti-corrosion capacity of the paint is further ensured; the added wood wax oil has the effects of paint film surface hardness enhancement, water prevention, pollution prevention, abrasion resistance and rub resistance.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of severe anti-corrosion paint for boats and ships and preparation method thereof.
Background technology
Paint, it is attractive and durable, has gloss, particularly marine paints, it has the multinomial premium propertiess such as sun-proof, antirust, grease proofing, corrosion protection, antifouling, wear-resisting, cold-resistant, high temperature resistance, and it is shipbuilding n., depressed place is repaiied and indispensable important production material in ordinary maintenance maintenance.Boats and ships in operation paint that to carry out maintaining be work-ing life in order to extend boats and ships inside, outside and various equipment to greatest extent, and agree to the greatest extent to reduce hull bottom marine life, to reduce ship resistance, so require that marine paint has good sticking power, preferably water tolerance, chemical-resistant and wear resistance.
Resin sand is formed by mixed preparing such as silica sand, resin and stiffening agents.The various organic resin contained inside the waste resin sand of bulk deposition or organic-inorganic compound, decomposition rate is slow, serious harm is brought to soil, and can acidified soil soil property, some compounds can along with the inflow rivers that drench with rain, polluted source, people, once drink, bring serious infringement can to the health of people.For this situation, waste resin sand is carried out modification by the present invention, not only solves environmental pollution, and adds in paint the effects such as the dirt-resisting dustproof that improve paint, ageing-resistant and fire prevention to.
Summary of the invention
The object of this invention is to provide a kind of severe anti-corrosion paint for boats and ships and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of severe anti-corrosion paint for boats and ships, be made up of the raw material of following weight part: silicone resin 6-9, polyvinyl butyral acetal 3-5, unsaturated polyester resin 10-13, trimethylammonium is diamines 4-6, petroleum sodium sulfonate 1-2, phthalocyanine green 0.3-0.8, lightweight magnesium chloride 2-3, fluorine ferrophosphorus 2-3, wood wax oil 3-5, rare earth chloride 0.5-1.0, N-Methyl pyrrolidone 0.5-1.0, Magnesium Stearate 1-3, cobalt chloride 0.2-0.5, modifying asphalt 43-47, modified abandoned resin sand 5-8, ammonium sulfate zinc 2-3, dimethylbenzene 6-9, N-BUTYL ACETATE 10-12, Tricholroacetic Acid 5-7,
Described modifying asphalt is made up of the raw material of following weight part: pitch 78-84, sulphur 0.4-1.0, Poly Propylene Wax 0.4-0.8, nano diatomite 0.5-1.0, diaminodiphenylmethane 0.3-0.7, gac 1-2, vinyl chloride-vinyl acetate resin 8-12, maleic anhydride 4-6, Potassium aluminum sulfate dodecahydrate 0.3-0.6, tetrahydrofuran (THF) 7-9, zirconium iso-octoate 0.2-0.4, dibenzoyl peroxide 0.05-0.12, sodium lignosulfonate 0.4-0.8, nano-glass scale 0.4-0.7; Preparation method is to melting by asphalt heating; maleic anhydride and dibenzoyl peroxide is slowly added under the protection of nitrogen; temperature is controlled at 170-180 ° of C; modifying asphalt is obtained stir 0.5-1 hour under 600-800 rev/min after; vinyl chloride-vinyl acetate resin, tetrahydrofuran (THF), zirconium iso-octoate, diaminodiphenylmethane, Poly Propylene Wax are mixed and heated to 130-150 ° of C; then will mix with modifying asphalt, then add all the other surplus materialss and with 800-1200 rev/min of lower agitation grinding 1-1.5 hour.
A kind of severe anti-corrosion paint for boats and ships of the present invention, be made up of following concrete steps:
(1) modifying asphalt, silicone resin, unsaturated polyester resin, trimethylammonium diamines, dimethylbenzene, N-BUTYL ACETATE, Tricholroacetic Acid, polyvinyl butyral acetal, cobalt chloride are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned resin sand, lightweight magnesium chloride, fluorine ferrophosphorus, rare earth chloride, N-Methyl pyrrolidone stirring 30-50 minute, reduce temperature and add all the other remaining compositions again to 50-80 ° of C, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned resin sand of the present invention, discarded resin sand is added in shakeout to carry out knockout by preparation method, the metal sundries on removing surface and dirt settling, again by the effect of waste resin sand by oscillator, whizzer, the binding agent on removing surface, again antiquated sand is worn into 400-600 order fine powder by ball mill, add the nano-attapulgite of antiquated sand weight 12%, 5% nano zine oxide, 0.4% Sodium hexametaphosphate 99, the alkylphenol polyoxyethylene of 0.2%, the silicon sol of 8% and 0.5-1% silane coupling agent KH560 mixed grinding evenly.
Advantage of the present invention is: the polyvinyl butyral acetal that anti-corrosion paint of the present invention adds has very strong protection against corrosion, antirust ability, sticking power is high, water-tolerant, the fluorine ferrophosphorus added and petroleum sodium sulfonate have protection against corrosion and antirust effect, further ensure the resistance to corrosion of paint, the wood wax oil of adding has enhancing coating surface hardness, the effect of water proof anti-soil and wear-resisting scuff.
specific embodiments
Below by specific examples, the present invention is described in detail.
For a severe anti-corrosion paint for boats and ships, be made up of the raw material of following weight part (kilogram): silicone resin 9, polyvinyl butyral acetal 3, unsaturated polyester resin 12, trimethylammonium be diamines 4, petroleum sodium sulfonate 1, phthalocyanine green 0.4, lightweight magnesium chloride 2, fluorine ferrophosphorus 2, wood wax oil 3, rare earth chloride 0.5, N-Methyl pyrrolidone 0.6, Magnesium Stearate 1, cobalt chloride 0.3, modifying asphalt 43, modified abandoned resin sand 5, ammonium sulfate zinc 2, dimethylbenzene 9, N-BUTYL ACETATE 11, Tricholroacetic Acid 6;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): pitch 82, sulphur 0.6, Poly Propylene Wax 0.5, nano diatomite 0.8, diaminodiphenylmethane 0.4, gac 1, vinyl chloride-vinyl acetate resin 9, maleic anhydride 4, Potassium aluminum sulfate dodecahydrate 0.4, tetrahydrofuran (THF) 8, zirconium iso-octoate 0.2, dibenzoyl peroxide 0.07, sodium lignosulfonate 0.5, nano-glass scale 0.5; Preparation method is to melting by asphalt heating; maleic anhydride and dibenzoyl peroxide is slowly added under the protection of nitrogen; temperature is controlled at 170-180 ° of C; modifying asphalt is obtained stir 0.5-1 hour under 600-800 rev/min after; vinyl chloride-vinyl acetate resin, tetrahydrofuran (THF), zirconium iso-octoate, diaminodiphenylmethane, Poly Propylene Wax are mixed and heated to 130-150 ° of C; then will mix with modifying asphalt, then add all the other surplus materialss and with 800-1200 rev/min of lower agitation grinding 1-1.5 hour.
A kind of severe anti-corrosion paint for boats and ships of the present invention, be made up of following concrete steps:
(1) modifying asphalt, silicone resin, unsaturated polyester resin, trimethylammonium diamines, dimethylbenzene, N-BUTYL ACETATE, Tricholroacetic Acid, polyvinyl butyral acetal, cobalt chloride are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned resin sand, lightweight magnesium chloride, fluorine ferrophosphorus, rare earth chloride, N-Methyl pyrrolidone stirring 30-50 minute, reduce temperature and add all the other remaining compositions again to 50-80 ° of C, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned resin sand of the present invention, discarded resin sand is added in shakeout to carry out knockout by preparation method, the metal sundries on removing surface and dirt settling, again by the effect of waste resin sand by oscillator, whizzer, the binding agent on removing surface, again antiquated sand is worn into 400-600 order fine powder by ball mill, add the nano-attapulgite of antiquated sand weight 12%, 5% nano zine oxide, 0.4% Sodium hexametaphosphate 99, the alkylphenol polyoxyethylene of 0.2%, the silicon sol of 8% and 0.5-1% silane coupling agent KH560 mixed grinding evenly.
Paint paint film appearance flat smooth of the present invention, sticking power tests 5 grades, and salt water resistance (27 ° of C ± 6 ° C, 120h) paint film is non-foaming, do not come off, non-corrosive, water tolerance (27 ° of C ± 6 ° C, 58h) is non-foaming, does not come off, salt spray resistance (1000h) paint film is non-foaming, do not come off, non-corrosive, artificial accelerated aging performance (1200h) paint film is without efflorescence, without variable color, flawless, oil-proofness (96# gasoline, 72h) is non-foaming, do not soften, do not come off, acid resistance (72h) is non-foaming, does not come off, alkali resistance (72h) is non-foaming, does not come off.
Claims (3)
1. the severe anti-corrosion paint for boats and ships, it is characterized in that, be made up of the raw material of following weight part: silicone resin 6-9, polyvinyl butyral acetal 3-5, unsaturated polyester resin 10-13, trimethylammonium is diamines 4-6, petroleum sodium sulfonate 1-2, phthalocyanine green 0.3-0.8, lightweight magnesium chloride 2-3, fluorine ferrophosphorus 2-3, wood wax oil 3-5, rare earth chloride 0.5-1.0, N-Methyl pyrrolidone 0.5-1.0, Magnesium Stearate 1-3, cobalt chloride 0.2-0.5, modifying asphalt 43-47, modified abandoned resin sand 5-8, ammonium sulfate zinc 2-3, dimethylbenzene 6-9, N-BUTYL ACETATE 10-12, Tricholroacetic Acid 5-7,
Described modifying asphalt is made up of the raw material of following weight part: pitch 78-84, sulphur 0.4-1.0, Poly Propylene Wax 0.4-0.8, nano diatomite 0.5-1.0, diaminodiphenylmethane 0.3-0.7, gac 1-2, vinyl chloride-vinyl acetate resin 8-12, maleic anhydride 4-6, Potassium aluminum sulfate dodecahydrate 0.3-0.6, tetrahydrofuran (THF) 7-9, zirconium iso-octoate 0.2-0.4, dibenzoyl peroxide 0.05-0.12, sodium lignosulfonate 0.4-0.8, nano-glass scale 0.4-0.7; Preparation method is to melting by asphalt heating; maleic anhydride and dibenzoyl peroxide is slowly added under the protection of nitrogen; temperature is controlled at 170-180 ° of C; modifying asphalt is obtained stir 0.5-1 hour under 600-800 rev/min after; vinyl chloride-vinyl acetate resin, tetrahydrofuran (THF), zirconium iso-octoate, diaminodiphenylmethane, Poly Propylene Wax are mixed and heated to 130-150 ° of C; then will mix with modifying asphalt, then add all the other surplus materialss and with 800-1200 rev/min of lower agitation grinding 1-1.5 hour.
2. a kind of severe anti-corrosion paint for boats and ships according to claim 1, is characterized in that, be made up of following concrete steps:
(1) modifying asphalt, silicone resin, unsaturated polyester resin, trimethylammonium diamines, dimethylbenzene, N-BUTYL ACETATE, Tricholroacetic Acid, polyvinyl butyral acetal, cobalt chloride are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add modified abandoned resin sand, lightweight magnesium chloride, fluorine ferrophosphorus, rare earth chloride, N-Methyl pyrrolidone stirring 30-50 minute, reduce temperature and add all the other remaining compositions again to 50-80 ° of C, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned resin sand according to claim 1, it is characterized in that, discarded resin sand is added in shakeout to carry out knockout by preparation method, the metal sundries on removing surface and dirt settling, again waste resin sand is passed through oscillator, the effect of whizzer, the binding agent on removing surface, again antiquated sand is worn into 400-600 order fine powder by ball mill, add the nano-attapulgite of antiquated sand weight 12%, the nano zine oxide of 5%, the Sodium hexametaphosphate 99 of 0.4%, the alkylphenol polyoxyethylene of 0.2%, the silicon sol of 8% and the silane coupling agent KH560 mixed grinding of 0.5-1% are evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410469155.XA CN104293190A (en) | 2014-09-16 | 2014-09-16 | Strong anti-corrosion paint for ship and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410469155.XA CN104293190A (en) | 2014-09-16 | 2014-09-16 | Strong anti-corrosion paint for ship and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104293190A true CN104293190A (en) | 2015-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410469155.XA Pending CN104293190A (en) | 2014-09-16 | 2014-09-16 | Strong anti-corrosion paint for ship and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634395A (en) * | 2016-12-13 | 2017-05-10 | 天长市巨龙车船涂料有限公司 | Chemical-corrosion-resistant insecticidal antibacterial paint and preparation method thereof |
| CN107059106A (en) * | 2017-04-18 | 2017-08-18 | 安徽华辉塑业科技股份有限公司 | A kind of liquid pump blade derusting method |
| CN109401467A (en) * | 2018-10-26 | 2019-03-01 | 王宇硕 | A kind of energy saving signal tower of anticorrosive paint and preparation method and utilization anticorrosive paint |
Citations (4)
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| WO2003076533A1 (en) * | 2002-03-08 | 2003-09-18 | Binney & Smith, Inc. | Erasable inks |
| CN100434488C (en) * | 2003-05-08 | 2008-11-19 | 同济大学 | Steel-structure anti-corrosion coating and preparing mehtod thereof |
| CN103360948A (en) * | 2013-07-22 | 2013-10-23 | 天长市银狐漆业有限公司 | Low temperature resistant winter epoxy coal tar pitch coating |
| CN103497647A (en) * | 2013-09-03 | 2014-01-08 | 蚌埠德美过滤技术有限公司 | High-degassing-performance powdery paint |
-
2014
- 2014-09-16 CN CN201410469155.XA patent/CN104293190A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003076533A1 (en) * | 2002-03-08 | 2003-09-18 | Binney & Smith, Inc. | Erasable inks |
| CN100434488C (en) * | 2003-05-08 | 2008-11-19 | 同济大学 | Steel-structure anti-corrosion coating and preparing mehtod thereof |
| CN103360948A (en) * | 2013-07-22 | 2013-10-23 | 天长市银狐漆业有限公司 | Low temperature resistant winter epoxy coal tar pitch coating |
| CN103497647A (en) * | 2013-09-03 | 2014-01-08 | 蚌埠德美过滤技术有限公司 | High-degassing-performance powdery paint |
Non-Patent Citations (1)
| Title |
|---|
| 化学工业部: "《合成树脂及塑料手册 化工产品品种基础资料》", 31 December 1979 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634395A (en) * | 2016-12-13 | 2017-05-10 | 天长市巨龙车船涂料有限公司 | Chemical-corrosion-resistant insecticidal antibacterial paint and preparation method thereof |
| CN107059106A (en) * | 2017-04-18 | 2017-08-18 | 安徽华辉塑业科技股份有限公司 | A kind of liquid pump blade derusting method |
| CN109401467A (en) * | 2018-10-26 | 2019-03-01 | 王宇硕 | A kind of energy saving signal tower of anticorrosive paint and preparation method and utilization anticorrosive paint |
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Application publication date: 20150121 |
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