CN103540258A - Polyurethane modified epoxy resin wear resistant paint - Google Patents
Polyurethane modified epoxy resin wear resistant paint Download PDFInfo
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- CN103540258A CN103540258A CN201310482924.5A CN201310482924A CN103540258A CN 103540258 A CN103540258 A CN 103540258A CN 201310482924 A CN201310482924 A CN 201310482924A CN 103540258 A CN103540258 A CN 103540258A
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- epoxy resin
- modified epoxy
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- wearresistant
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Abstract
The invention discloses a polyurethane modified epoxy resin wear resistant paint. The polyurethane modified epoxy resin wear resistant paint comprises following raw materials, by weight, 10 to 20 parts of graphite, 5 to 15 parts of molybdenum disulfide, 5 to 10 parts of aluminium oxide, 2 to 6 parts of xylene, 2 to 6 parts of polyurethane modified epoxy resin, 2 to 6 parts of a curing agent, 12 to 15 parts of a bonding agent, 1 to 4 parts of an auxiliary agent and 15 to 20 parts of purified water.
Description
Technical field
The present invention relates to a kind of new coating and preparation method thereof, more particularly, relate to a kind of polyurethane modified epoxy resin wearresistant coatings.
Background technology
The result that inshore fishery mechanical erosion situation is investigated shows, due to fishing machine work under bad environment, and seriously corroded, the corrosion of wherein hanging oar is particularly outstanding.Extension oar is small Fishing Boat, diesel engine or other power-actuated small propeller for yacht afterbody, the wearing and tearing that the particles such as the hydraulicefficiency machinery that caused while rotating by sea-water corrosion, blade washes away, sand grains cause, require research to have the coating of excellent wear and corrosion behavior.
State's hanging outdoor unit paddle size is less, and rotating speed is up to 550 r/m in, and blade adopts aluminium alloy or stainless steel, and surface is comprised of prime coat, anti-zinc enamel paint layer and wear-resistant coating, and blade matrix is shielded.Domestic extension oar adopts cast iron cast aluminium material more, with red iron oxide alkyd primer and lacquer finish, makes surface decoration, and wear and corrosion behavior is poor, limited to the provide protection of blade.
Raw lacquer You Cheng state paint, has the performances such as excellent corrosion-resistant, insulation, oil resistant, wear-resisting, durable and high gloss, and we adopt modified raw lacquer is that base-material carries out the research of wear-and corrosion-resistant coating.There are 17 kinds of modified raw lacquer standardized products in China at present, and in order to improve the wear resistance of modified raw lacquer, first the urushiol-furfural resin of synthesizing epoxy modification is as resin binder.Development wear-and corrosion-resistant coating also needs to select suitable color stuffing, document announcement, curing key is tired, silica powder can be used as wear resistant filler, and mica powder, iron mica and medium chrome yellow medium yellow can be used as corrosion-resistant color stuffing, in epoxy resin, also with curing key, improve wear resistance.Therefore, in synthetic SUMMARIES EPOXY MODIFIED URUSHIOL-FURFURAL RESIN, add the color stuffings such as curing aluminium, make wear-and corrosion-resistant coating.
Summary of the invention
Deficiency for existing in prior art, the invention provides polyurethane modified epoxy resin wearresistant coatings.
To achieve these goals, technical scheme of the present invention is as follows:
, the parts by weight of each raw material are:
10～20 parts, graphite
5～15 parts of molybdenumdisulphide
5～10 parts of aluminium sesquioxides
Dimethylbenzene 2-6 part
Polyurethane modified epoxy resin 2-6 part
Solidifying agent 2-6 part
12～15 parts of caking agents
Auxiliary agent 1-4 part
15～20 parts of pure water.
Preferably, solidifying agent is epoxy curing agent.
Preferably, the preparation of polyurethane modified epoxy resin: first take a certain amount of epoxy resin E-44, add again the base polyurethane prepolymer for use as preparing in right amount, then the acetone that adds people and two kinds of resin quality sum equivalent is made solvent, with electric mixer, fully stir, two kinds of resins are dissolved in solvent completely, then in 80 ℃ of thermostat water baths, react 3 h.
The preparation process of described base polyurethane prepolymer for use as is: by Toluene-2,4-diisocyanate, 4-bis-isocyanates (TD I) are added in Viscotrol C by determined initial value, then add people's acetone, the amount of acetone is the total amount of TD I and Viscotrol C, solution is mixed, with electric mixer, stir, in the water-bath of 40,45 ℃, heat 3 h.
Described auxiliary agent comprises: dispersion agent, mould inhibitor, defoamer, initiator, flow agent, film coalescence aid.
Described dispersion agent is that EFKA-5065 dispersion agent and EFKA-4050 dispersion agent are according to the mixture of 2:1; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 1:2.
Described defoamer and select respectively EFKA-2722 and EFKA-3239.
Described mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
A method for described polyurethane modified epoxy resin wearresistant coatings, it prepares by the following method:
The first step: each raw material of weighing: 10～20 parts, graphite, 5～15 parts of molybdenumdisulphide, 5～10 parts of aluminium sesquioxides, dimethylbenzene 2-6 part;
Second step: dissolve: the fine particle of the mixing that second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, stir while being heated to 50～60 ℃, and churning time is 45～60 minutes, obtains mixed emulsion;
The 3rd step: add polyurethane modified epoxy resin, solidifying agent to stir, the 3rd step gained mixed emulsion is obtained to exterior coating by 80～100 mesh sieve inherent filtrations.
The method of described polyurethane modified epoxy resin wearresistant coatings, its using method is brushing, wherein coating thickness 0. 18mm is best coating thickness.
Embodiment
For more detailed elaboration the present invention, this one embodiment of the invention is as follows:
Embodiment 1
, the parts by weight of each raw material are:
10～20 parts, graphite
5～15 parts of molybdenumdisulphide
5～10 parts of aluminium sesquioxides
Dimethylbenzene 2-6 part
Polyurethane modified epoxy resin 2-6 part
Solidifying agent 2-6 part
12～15 parts of caking agents
Auxiliary agent 1-4 part
15～20 parts of pure water.
Preferably, solidifying agent is epoxy curing agent.
Preferably, the preparation of polyurethane modified epoxy resin: first take a certain amount of epoxy resin E-44, add again the base polyurethane prepolymer for use as preparing in right amount, then the acetone that adds people and two kinds of resin quality sum equivalent is made solvent, with electric mixer, fully stir, two kinds of resins are dissolved in solvent completely, then in 80 ℃ of thermostat water baths, react 3 h.
The preparation process of described base polyurethane prepolymer for use as is: by Toluene-2,4-diisocyanate, 4-bis-isocyanates (TD I) are added in Viscotrol C by determined initial value, then add people's acetone, the amount of acetone is the total amount of TD I and Viscotrol C, solution is mixed, with electric mixer, stir, in the water-bath of 40,45 ℃, heat 3 h.
Described auxiliary agent comprises: dispersion agent, mould inhibitor, defoamer, initiator, flow agent, film coalescence aid.
Described dispersion agent is that EFKA-5065 dispersion agent and EFKA-4050 dispersion agent are according to the mixture of 2:1; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 1:2.
Described defoamer and select respectively EFKA-2722 and EFKA-3239.
Described mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
A method for described polyurethane modified epoxy resin wearresistant coatings, it prepares by the following method:
The first step: each raw material of weighing: 10～20 parts, graphite, 5～15 parts of molybdenumdisulphide, 5～10 parts of aluminium sesquioxides, dimethylbenzene 2-6 part;
Second step: dissolve: the fine particle of the mixing that second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, stir while being heated to 50～60 ℃, and churning time is 45～60 minutes, obtains mixed emulsion;
The 3rd step: add polyurethane modified epoxy resin, solidifying agent to stir, the 3rd step gained mixed emulsion is obtained to exterior coating by 80～100 mesh sieve inherent filtrations.
The method of described polyurethane modified epoxy resin wearresistant coatings, its using method is brushing, wherein coating thickness 0. 18mm is best coating thickness.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (10)
1. a polyurethane modified epoxy resin wearresistant coatings, the parts by weight of each raw material are:
10～20 parts, graphite
5～15 parts of molybdenumdisulphide
5～10 parts of aluminium sesquioxides
Dimethylbenzene 2-6 part
Polyurethane modified epoxy resin 2-6 part
Solidifying agent 2-6 part
12～15 parts of caking agents
Auxiliary agent 1-4 part
15～20 parts of pure water.
2. polyurethane modified epoxy resin wearresistant coatings according to claim 1, is characterized in that: solidifying agent is epoxy curing agent.
3. polyurethane modified epoxy resin wearresistant coatings according to claim 1, it is characterized in that: the preparation of polyurethane modified epoxy resin: first take a certain amount of epoxy resin E-44, add again the base polyurethane prepolymer for use as preparing in right amount, then the acetone that adds people and two kinds of resin quality sum equivalent is made solvent, with electric mixer, fully stir, two kinds of resins are dissolved in solvent completely, then in 80 ℃ of thermostat water baths, react 3 h.
4. polyurethane modified epoxy resin wearresistant coatings according to claim 3, it is characterized in that: the preparation process of described base polyurethane prepolymer for use as is: by Toluene-2,4-diisocyanate, 4-bis-isocyanates (TD I) are added in Viscotrol C by determined initial value, then add people's acetone, the amount of acetone is the total amount of TD I and Viscotrol C, solution is mixed, with electric mixer, stir, in the water-bath of 40,45 ℃, heat 3 h.
5. polyurethane modified epoxy resin wearresistant coatings according to claim 1, is characterized in that: described auxiliary agent comprises: dispersion agent, mould inhibitor, defoamer, initiator, flow agent, film coalescence aid.
6. polyurethane modified epoxy resin wearresistant coatings according to claim 5, is characterized in that: described dispersion agent is that EFKA-5065 dispersion agent and EFKA-4050 dispersion agent are according to the mixture of 2:1; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 1:2.
7. polyurethane modified epoxy resin wearresistant coatings according to claim 5, is characterized in that: described defoamer and select respectively EFKA-2722 and EFKA-3239.
8. polyurethane modified epoxy resin wearresistant coatings according to claim 5, is characterized in that: mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
9. a method of preparing polyurethane modified epoxy resin wearresistant coatings claimed in claim 1, it prepares by the following method:
The first step: each raw material of weighing: 10～20 parts, graphite, 5～15 parts of molybdenumdisulphide, 5～10 parts of aluminium sesquioxides, dimethylbenzene 2-6 part;
Second step: dissolve: the fine particle of the mixing that second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, stir while being heated to 50～60 ℃, and churning time is 45～60 minutes, obtains mixed emulsion;
The 3rd step: add polyurethane modified epoxy resin, solidifying agent to stir, the 3rd step gained mixed emulsion is obtained to exterior coating by 80～100 mesh sieve inherent filtrations.
10. the method for polyurethane modified epoxy resin wearresistant coatings according to claim 1, its using method is brushing, wherein coating thickness 0. 18mm is best coating thickness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310482924.5A CN103540258A (en) | 2013-10-16 | 2013-10-16 | Polyurethane modified epoxy resin wear resistant paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310482924.5A CN103540258A (en) | 2013-10-16 | 2013-10-16 | Polyurethane modified epoxy resin wear resistant paint |
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| CN103540258A true CN103540258A (en) | 2014-01-29 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295662A (en) * | 2015-12-04 | 2016-02-03 | 常熟市福达金属制件有限公司 | Iron hoop |
| CN107384117A (en) * | 2017-06-07 | 2017-11-24 | 常州聚盛节能工程有限公司 | A kind of epoxy resin-matrix composite wear-resistant coating material and preparation method thereof |
| CN107641414A (en) * | 2017-10-24 | 2018-01-30 | 赵圣恺 | Polyurethane modified epoxy resin composite coating |
| CN107868600A (en) * | 2017-11-29 | 2018-04-03 | 镇江兴润土石方工程有限公司 | A kind of preparation method of anticorrosion paint of excavator |
| CN107880757A (en) * | 2017-11-29 | 2018-04-06 | 镇江兴润土石方工程有限公司 | A kind of anticorrosive paint of excavator |
| CN113522697A (en) * | 2021-07-28 | 2021-10-22 | 西安热工研究院有限公司 | Wear-resistant and corrosion-resistant coating for front edge of wind power blade and preparation method thereof |
| CN115216959A (en) * | 2021-04-16 | 2022-10-21 | 江苏舒越手套有限公司 | Production process of graphite anti-static knitted gloves |
| CN115739573A (en) * | 2022-11-28 | 2023-03-07 | 成都彩星化工有限公司 | Polyurethane finish processing method for chemical raw material storage |
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| CN1232849A (en) * | 1998-04-22 | 1999-10-27 | 奥依列斯工业株式会社 | Lubricating coating, sliding structure and sliding bearing device using the same structure |
| US20080311369A1 (en) * | 2007-06-13 | 2008-12-18 | Nitto Denko Corporation | Pressure-sensitive adhesive sheet |
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| CN1232849A (en) * | 1998-04-22 | 1999-10-27 | 奥依列斯工业株式会社 | Lubricating coating, sliding structure and sliding bearing device using the same structure |
| US20080311369A1 (en) * | 2007-06-13 | 2008-12-18 | Nitto Denko Corporation | Pressure-sensitive adhesive sheet |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295662A (en) * | 2015-12-04 | 2016-02-03 | 常熟市福达金属制件有限公司 | Iron hoop |
| CN107384117A (en) * | 2017-06-07 | 2017-11-24 | 常州聚盛节能工程有限公司 | A kind of epoxy resin-matrix composite wear-resistant coating material and preparation method thereof |
| CN107641414A (en) * | 2017-10-24 | 2018-01-30 | 赵圣恺 | Polyurethane modified epoxy resin composite coating |
| CN107868600A (en) * | 2017-11-29 | 2018-04-03 | 镇江兴润土石方工程有限公司 | A kind of preparation method of anticorrosion paint of excavator |
| CN107880757A (en) * | 2017-11-29 | 2018-04-06 | 镇江兴润土石方工程有限公司 | A kind of anticorrosive paint of excavator |
| CN115216959A (en) * | 2021-04-16 | 2022-10-21 | 江苏舒越手套有限公司 | Production process of graphite anti-static knitted gloves |
| CN113522697A (en) * | 2021-07-28 | 2021-10-22 | 西安热工研究院有限公司 | Wear-resistant and corrosion-resistant coating for front edge of wind power blade and preparation method thereof |
| CN113522697B (en) * | 2021-07-28 | 2022-07-08 | 西安热工研究院有限公司 | Abrasion-resistant coating for wind power blade leading edge and preparation method thereof |
| CN115739573A (en) * | 2022-11-28 | 2023-03-07 | 成都彩星化工有限公司 | Polyurethane finish processing method for chemical raw material storage |
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Application publication date: 20140129 |