CN102344739A - Epoxy glass flake heavy-duty coating and preparation method thereof - Google Patents
Epoxy glass flake heavy-duty coating and preparation method thereof Download PDFInfo
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Abstract
The invention relates to an anti-corrosion coating, in particular to an epoxy glass flake heavy-duty coating and a preparation method thereof. The epoxy glass flake heavy-duty coating is prepared by mixing and curing a component A and a component B. The epoxy glass flake heavy-duty coating can be coated on the surface of a steel structure, and can be taken as a primer together with an epoxy zinc-rich primer. When taken as a finish coat, the anti-corrosion coating has high antirust and anti-corrosion performance. As proved by detection, a paint film does not become foamed or rusty when the salt spray resistance reaches 5,000 hours and has high weather resistance, and the coating and maintaining costs of a steel structure can be lowered. The production method of the epoxy glass flake heavy-duty coating does not need post-treatment, so that the process method is simple, energy is saved, and the cost is low. The component A and the component B can be automatically dried into a film at normal temperature after being uniformly mixed, so that high film forming performance is realized, and the product has high storing stability.
Description
Technical field
The present invention is a kind of protective system, particularly GLASS FLAKE and preparation method thereof.
Background technology
Sustainable development along with national economy and fundamental construction; The etch-proof requirement of key state project and heavy construction is also increasingly high; Large-scale steel equipment, member, pipeline are had higher requirement to coating; Promptly require coating to have excellent rust resistance and corrosion resistance performance, again good application property, flexibility and weather resistance must be arranged.As everyone knows, epoxy anti-rust paint has good chemical-resistant and antiseptic property.
But; Traditional epoxy anti-rust paint to steelwork surface treatment have relatively high expectations, when the engineering project of having moved will be keeped in repair application, must carry out secondary high quality processing of rust removing; Coating of application is again reprocessed in every separated maintenance just in several years, to prevent the iron and steel corrosion.Again must clear up on a large scale and eliminate rust before the application more thus; Cause manpower and materials greatly to drop into; And can can't carry out factors such as treat mechanically because of the engineering structure of complicated moulding; These problems have been brought great difficulty to construction, have also limited the good utilization of epoxy resin-based paint type products on the large-scale steel structure maintenance items of antiseptic property, simultaneously except that the maintenance cost height and because of also bringing negative impact for again environment to the processing on steelwork surface.
Summary of the invention
The present invention solves the deficiency that exists in the prior art, provides a kind of in be prone to the to get rusty GLASS FLAKE and the preparation method of steelwork surface construction, to satisfy the long-effective corrosion needs of the parties concerned.
Above-mentioned technical problem of the present invention mainly is able to solve through following technical proposals:
A kind of GLASS FLAKE obtains after mixing slaking by first component and second component, specifically by following step preparation:
(1), the raw material weight per-cent of first component is following:
Epoxy resin 42～45%, glass flake 25～26%, pigment 15～20%, filler 5～8%, nano material 3～4%, auxiliary agent 1.5～2.5%, solvent 3～5%;
(2), the raw material weight per-cent of second component is following:
8235 cashew nut oil modified epoxy hardeners, 10～15%, 650 daiamid epoxy curing agents 40～45%, mixed solvent 40～55%;
First component and second component obtain GLASS FLAKE after mixing slaking.
As preferably, the weight proportion of described first component and second component is 10:1.2.
As preferably, described auxiliary agent is the mixture of 904S wetting dispersing agent, 606 skimmers and CIMA240 anti-settling agent; 904S wetting dispersing agent: 606 skimmers: the weight ratio=0.5:0.4:0.6 of CIMA240 anti-settling agent; Described mixed solvent is made up of YLENE and butanols, YLENE: the weight ratio=7:3 of butanols; Solvent in the described first component is an epoxy lacquer diluent, and epoxy lacquer diluent is made up of butanols and YLENE; Described nano material is a nanometer grade calcium carbonate; Described pigment is phosphorus zinc white, white titanium pigment and N330 carbon black.
As preferably, described epoxy resin is the dihydroxyphenyl propane solid epoxy; The granularity of described glass flake is 400～500 orders; Described filler is the mixture of 1250 order talcum powder and lime carbonate, 1250 order talcum powder: the weight ratio=8:6 of lime carbonate.
A kind of its preparation method of GLASS FLAKE, carry out according to the following steps:
(1), butanols 8～10 ㎏ in YLENE 28～30 ㎏ and the solubilizing agent in dihydroxyphenyl propane solid epoxy 60～62 ㎏, the solubilizing agent in the first component is added reaction kettle and heat fusion; Steam-heated cal(l)andria to 85 ℃ in the reaction kettle～87 ℃; Be incubated 6～7 hours again; Under fully stirring, make it to be homogeneous transparent liquid and refilter and become work in-process, solids content is controlled at 60 ± 2%, be cooled to again 60 degrees centigrade test qualified;
(2), after the step (1); In work in-process, add phosphorus zinc white 11～12 ㎏, white titanium pigment 19～20 ㎏, nano-calcium carbonate 5～6 ㎏, 1250 order talcum powder, 7～8 ㎏ and N330 carbon black 0.1～0.11 ㎏; Carried out high-speed stirring 15～20 minutes; Rotating speed is 800～850 rev/mins, passes through sand milling to fineness again below 50 microns, forms transparent liquid;
In transparent liquid, add glass flake 24～25 ㎏, 606 skimmers, 0.4～0.45 ㎏ and epoxy lacquer diluent 2～3 ㎏; Through high-speed stirring 25～30 minutes; Rotating speed is 80～120 rev/mins; Make it to be behind the uniform liquid and filter with 80 eye mesh screens, obtain the first component of this product, first component viscosity controller was in 6# cup 80～100 seconds;
(3), 8235 cashew nut oil modified epoxy hardeners are put in the stirred pot; Adding 650 daiamid epoxy curing agents, YLENE and butanols more fully stirs; The time of stirring is 25～30 minutes; Rotating speed is 80～120 rev/mins, makes it to be behind the uniform liquid to filter the second component of De Deben product with 80 eye mesh screens;
(4), when using,, stir the formation product, churning time is 10～15 minutes, and in 5 hours, uses with first component and second component 10:1.2 by weight ratio.
The staple of CIMA240 anti-settling agent is a polyamide wax pulp, belongs to one of paint auxiliary agent kind.
First component viscosity controller was meant an index of the denseness size of paint in 80～100 seconds at the 6# cup, if the excessive difficulty of construction of viscosity is big, viscosity is little also not all right, thus 80～100 seconds elution time scope in instrument (to calculate second) be span of control.
The preferred bisphenol A epoxide resin of epoxy resin, the trade mark of producing like resin processing plant of nation of Shanghai unit are the bisphenol A epoxide resin of manufacturer production such as YPE-011, SM-601 three wood gums, E-20 profit send out; Pigment is conventional mineral dye, like white titanium pigment, zinc oxide, iron oxide red powder, glass flake, phosphorus zinc white etc.; 8235 cashew nut oil modified epoxy hardeners are the buying of Shanghai Mei Dong chemical company; 650 daiamid epoxy curing agents are the buying of the Changjiang river, Jiangsu chemical company; 218 white titanium pigments are that Panzhihua City titanium sea Science and Technology Ltd. produces; Phosphorus zinc white is that Shanghai Chrome Yellow Plant produces; Carbon black is that Shanghai heavenly steed pigment factory produces; Nanometer grade calcium carbonate is that Hangzhou ten thousand scape novel material ltds produce; 1250 order talcum powder are that Haicheng talcum powder factory produces; The skies, Langfang, glass flake Hebei glass flake factory produces; YLENE is that the production of organic chemical industry ltd is thought to reach in Hangzhou; Butanols is imported and exported ltd's supply of material for the Ningbo petrochemical industry; The 904S dispersion agent is that favour (moral the is modest) company of just going in Shanghai supplies; The anti-heavy rheological agent of CIMA240 is the production Hangzhou fine jade source chemical industry commission merchant supply of Korea S CFC company; 606 skimmers are the supply of Jin Bo Shanghai Wei Ka trading company.
The present invention compared with prior art has following advantage: when using GLASS FLAKE application of the present invention; Can be at the steelwork external coating; Also can make priming paint by supporting epoxy zinc rich primer, product of the present invention is done finish paint and is carried out the supporting good rust resistance and corrosion resistance performance that has, and reaching 5000 hours paint films through the detection salt spray resistance does not bubble, do not get rusty; Paint film weatherability is good, can reduce steelwork application maintenance cost.The working method that GLASS FLAKE of the present invention is coated with must aftertreatment, so process method is simple, save energy, cost are lower.Can be at normal temperatures after first component and second component mix drying and forming-film voluntarily, have good film forming properties, the stability in storage of product is good.
Embodiment
Through embodiment, do further bright specifically below to technical scheme of the present invention.
Embodiment 1:
A kind of GLASS FLAKE obtains after mixing slaking by first component and second component, specifically by following step preparation:
1, get the raw materials ready:
The raw material weight per-cent of first component is following:
Epoxy resin 42%, glass flake 26%, pigment 18%, filler 6.5%, nano material 3%, auxiliary agent 1.5%, solvent 3%;
The raw material weight per-cent of second component is following:
8235 cashew nut oil modified epoxy hardeners 10%, 650 daiamid epoxy curing agents 40%, mixed solvent 50%.
The weight proportion of described first component and second component is 10:1.2.
Described auxiliary agent is the mixture of 904S wetting dispersing agent, 606 skimmers and CIMA240 anti-settling agent; 904S wetting dispersing agent: 606 skimmers: the weight ratio=0.5:0.4:0.6 of CIMA240 anti-settling agent; Described mixed solvent is made up of YLENE and butanols, YLENE: the weight ratio=7:3 of butanols; Solvent in the described first component is an epoxy lacquer diluent, and epoxy lacquer diluent is made up of butanols and YLENE; Described nano material is a nanometer grade calcium carbonate; Described pigment is phosphorus zinc white, white titanium pigment and N330 carbon black.
Described epoxy resin is the dihydroxyphenyl propane solid epoxy; The granularity of described glass flake is 400 orders; Described filler is the mixture of 1250 order talcum powder and lime carbonate, 1250 order talcum powder: the weight ratio=8:6 of lime carbonate.
2, the preparation method carries out according to the following steps:
(1), butanols 8 ㎏ in YLENE 28 ㎏ and the solubilizing agent in dihydroxyphenyl propane solid epoxy 60 ㎏, the solubilizing agent in the first component is added reaction kettle and heat fusion; Steam-heated cal(l)andria to 85 ℃ in the reaction kettle; Be incubated 6 hours again; Make it to be homogeneous transparent liquid down and refilter and become work in-process fully stirring, solids content is controlled at 60 ± 2%, be cooled to again 60 spend test qualified;
(2), after the step (1); In work in-process, add phosphorus zinc white 11 ㎏, white titanium pigment 19 ㎏, nano-calcium carbonate 5 ㎏, 1250 order talcum powder, 7 ㎏ and N330 carbon black 0.1 ㎏; Carried out high-speed stirring 15 minutes; Rotating speed is 800 rev/mins, passes through sand milling to fineness again below 50 microns, forms transparent liquid;
In transparent liquid, add glass flake 24 ㎏, 606 skimmers, 0.4 ㎏ and epoxy lacquer diluent 2 ㎏; Through high-speed stirring 25 minutes, rotating speed was 80 rev/mins, filtered with 80 eye mesh screens after making it to be uniform liquid; Obtain the first component of this product, first component viscosity controller was in 6# cup 80 seconds;
(3), 8235 cashew nut oil modified epoxy hardeners are put in the stirred pot; Adding 650 daiamid epoxy curing agents, YLENE and butanols more fully stirs; The time of stirring is 25 minutes; Rotating speed is 80 rev/mins, makes it to be behind the uniform liquid to filter the second component of De Deben product with 80 eye mesh screens;
(4), when using,, stir the formation product, churning time is 10 minutes, and in 5 hours, uses with first component and second component 10:1.2 by weight ratio.
Embodiment 2:
A kind of GLASS FLAKE obtains after mixing slaking by first component and second component, specifically by following step preparation:
1, get the raw materials ready:
The weight percent of first component is following:
Epoxy resin 44%, glass flake 25%, pigment 15%, filler 7%, nano material 3%, auxiliary agent 2%, solvent 4%;
The weight percent of second component is following:
8235 cashew nut oil modified epoxy hardeners 14%, 650 daiamid epoxy curing agents 42%, mixed solvent 44%.
The weight proportion of described first component and second component is 10:1.2.
Described auxiliary agent is the mixture of 904S wetting dispersing agent, 606 skimmers and CIMA240 anti-settling agent; 904S wetting dispersing agent: 606 skimmers: the weight ratio=0.5:0.4:0.6 of CIMA240 anti-settling agent; Described mixed solvent is made up of YLENE and butanols, YLENE: the weight ratio=7:3 of butanols; Solvent in the described first component is an epoxy lacquer diluent, and epoxy lacquer diluent is made up of butanols and YLENE; Described nano material is a nanometer grade calcium carbonate; Described pigment is phosphorus zinc white, white titanium pigment and N330 carbon black.
Described epoxy resin is the dihydroxyphenyl propane solid epoxy; The granularity of described glass flake is 450 orders; Described filler is the mixture of 1250 order talcum powder and lime carbonate, 1250 order talcum powder: the weight ratio=8:6 of lime carbonate.
2, the preparation method carries out according to the following steps:
(1), butanols 9 ㎏ in YLENE 29 ㎏ and the solubilizing agent in dihydroxyphenyl propane solid epoxy 61 ㎏, the solubilizing agent in the first component is added reaction kettle and heat fusion; Steam-heated cal(l)andria to 86 ℃ in the reaction kettle; Be incubated 6.5 hours again; Make it to be homogeneous transparent liquid down and refilter and become work in-process fully stirring, solids content is controlled at 60 ± 2%, be cooled to again 60 spend test qualified;
(2), after the step (1); In work in-process, add phosphorus zinc white 11.5 ㎏, white titanium pigment 19.5 ㎏, nano-calcium carbonate 5.5 ㎏, 1250 order talcum powder, 7.5 ㎏ and N330 carbon black 0.1 ㎏; Carried out high-speed stirring 18 minutes; Rotating speed is 830 rev/mins, passes through sand milling to fineness again below 50 microns, forms transparent liquid;
In transparent liquid, add glass flake 24.5 ㎏, 606 skimmers, 0.4 ㎏ and epoxy lacquer diluent 2.5 ㎏; Through high-speed stirring 28 minutes; Rotating speed is 100 rev/mins; Make it to be behind the uniform liquid and filter with 80 eye mesh screens, obtain the first component of this product, first component viscosity controller was in 6# cup 90 seconds;
(3), 8235 cashew nut oil modified epoxy hardeners are put in the stirred pot; Adding 650 daiamid epoxy curing agents, YLENE and butanols more fully stirs; The time of stirring is 28 minutes; Rotating speed is 100 rev/mins, makes it to be behind the uniform liquid to filter the second component of De Deben product with 80 eye mesh screens;
(4), when using,, stir the formation product, churning time is 13 minutes, and in 5 hours, uses with first component and second component 10:1.2 by weight ratio.
Embodiment 3:
A kind of GLASS FLAKE obtains after mixing slaking by first component and second component, specifically by following step preparation:
1, get the raw materials ready:
The weight percent of first component is following:
Epoxy resin 44%, glass flake 25.5%, pigment 15%, filler 8%, nano material 3%, auxiliary agent 1.5%, solvent 3%;
The weight percent of second component is following:
8235 cashew nut oil modified epoxy hardeners 15%, 650 daiamid epoxy curing agents 45%, mixed solvent 40%.
The weight proportion of described first component and second component is 10:1.2.
Described auxiliary agent is the mixture of 904S wetting dispersing agent, 606 skimmers and CIMA240 anti-settling agent; 904S wetting dispersing agent: 606 skimmers: the weight ratio=0.5:0.4:0.6 of CIMA240 anti-settling agent; Described mixed solvent is made up of YLENE and butanols, YLENE: the weight ratio=7:3 of butanols; Solvent in the described first component is an epoxy lacquer diluent, and epoxy lacquer diluent is made up of butanols and YLENE; Described nano material is a nanometer grade calcium carbonate; Described pigment is phosphorus zinc white, white titanium pigment and N330 carbon black.
Described epoxy resin is the dihydroxyphenyl propane solid epoxy; The granularity of described glass flake is 400～500 orders; Described filler is the mixture of 1250 order talcum powder and lime carbonate, 1250 order talcum powder: the weight ratio=8:6 of lime carbonate.
2, the preparation method carries out according to the following steps:
(1), butanols 10 ㎏ in YLENE 30 ㎏ and the solubilizing agent in dihydroxyphenyl propane solid epoxy 62 ㎏, the solubilizing agent in the first component is added reaction kettle and heat fusion; Steam-heated cal(l)andria to 87 ℃ in the reaction kettle; Be incubated 7 hours again; Make it to be homogeneous transparent liquid down and refilter and become work in-process fully stirring, solids content is controlled at 60 ± 2%, be cooled to again 60 spend test qualified;
(2), after the step (1); In work in-process, add phosphorus zinc white 12 ㎏, white titanium pigment 20 ㎏, nano-calcium carbonate 6 ㎏, 1250 order talcum powder, 8 ㎏ and N330 carbon black 0.11 ㎏; Carried out high-speed stirring 20 minutes; Rotating speed is 850 rev/mins, passes through sand milling to fineness again below 50 microns, forms transparent liquid;
In transparent liquid, add glass flake 25 ㎏, 606 skimmers, 0.45 ㎏ and epoxy lacquer diluent 3 ㎏; Through high-speed stirring 30 minutes, rotating speed was 120 rev/mins, filtered with 80 eye mesh screens after making it to be uniform liquid; Obtain the first component of this product, first component viscosity controller was in 6# cup 100 seconds;
(3), 8235 cashew nut oil modified epoxy hardeners are put in the stirred pot; Adding 650 daiamid epoxy curing agents, YLENE and butanols more fully stirs; The time of stirring is 30 minutes; Rotating speed is 120 rev/mins, makes it to be behind the uniform liquid to filter the second component of De Deben product with 80 eye mesh screens;
(4), when using,, stir the formation product, churning time is 15 minutes, and in 5 hours, uses with first component and second component 10:1.2 by weight ratio.
Claims (5)
1. GLASS FLAKE is characterized in that comprising following material:
(1), the raw material weight per-cent of first component is following:
Epoxy resin 42～45%, glass flake 25～26%, pigment 15～20%, filler 5～8%, nano material 3～4%, auxiliary agent 1.5～2.5%, solvent 3～5%;
(2), the raw material weight per-cent of second component is following:
8235 cashew nut oil modified epoxy hardeners, 10～15%, 650 daiamid epoxy curing agents 40～45%, mixed solvent 40～55%;
First component and second component obtain GLASS FLAKE after mixing slaking.
2. a kind of GLASS FLAKE according to claim 1 is characterized in that: the weight proportion of described first component and second component is 10:1.2.
3. a kind of GLASS FLAKE according to claim 1 and 2 is characterized in that: described auxiliary agent is the mixture of 904S wetting dispersing agent, 606 skimmers and CIMA240 anti-settling agent; 904S wetting dispersing agent: 606 skimmers: the weight ratio=0.5:0.4:0.6 of CIMA240 anti-settling agent; Described mixed solvent is made up of YLENE and butanols, YLENE: the weight ratio=7:3 of butanols; Solvent in the described first component is an epoxy lacquer diluent, and epoxy lacquer diluent is made up of butanols and YLENE; Described nano material is a nanometer grade calcium carbonate; Described pigment is phosphorus zinc white, white titanium pigment and N330 carbon black.
4.1, a kind of GLASS FLAKE according to claim 1 and 2, it is characterized in that: described epoxy resin is the dihydroxyphenyl propane solid epoxy; The granularity of described glass flake is 400～500 orders; Described filler is the mixture of 1250 order talcum powder and lime carbonate, 1250 order talcum powder: the weight ratio=8:6 of lime carbonate.
5. its preparation method of a GLASS FLAKE is characterized in that carrying out according to the following steps:
(1), butanols 8～10 ㎏ in YLENE 28～30 ㎏ and the solubilizing agent in dihydroxyphenyl propane solid epoxy 60～62 ㎏, the solubilizing agent in the first component is added reaction kettle and heat fusion; Steam-heated cal(l)andria to 85 ℃ in the reaction kettle～87 ℃; Be incubated 6～7 hours again; Under fully stirring, make it to be homogeneous transparent liquid and refilter and become work in-process, solids content is controlled at 60 ± 2%, be cooled to again 60 degrees centigrade test qualified;
(2), after the step (1); In work in-process, add phosphorus zinc white 11～12 ㎏, white titanium pigment 19～20 ㎏, nano-calcium carbonate 5～6 ㎏, 1250 order talcum powder, 7～8 ㎏ and N330 carbon black 0.1～0.11 ㎏; Carried out high-speed stirring 15～20 minutes; Rotating speed is 800～850 rev/mins, passes through sand milling to fineness again below 50 microns, forms transparent liquid;
In transparent liquid, add glass flake 24～25 ㎏, 606 skimmers, 0.4～0.45 ㎏ and epoxy lacquer diluent 2～3 ㎏; Through high-speed stirring 25～30 minutes; Rotating speed is 80～120 rev/mins; Make it to be behind the uniform liquid and filter with 80 eye mesh screens, obtain the first component of this product, first component viscosity controller was in 6# cup 80～100 seconds;
(3), 8235 cashew nut oil modified epoxy hardeners are put in the stirred pot; Adding 650 daiamid epoxy curing agents, YLENE and butanols more fully stirs; The time of stirring is 25～30 minutes; Rotating speed is 80～120 rev/mins, makes it to be behind the uniform liquid to filter the second component of De Deben product with 80 eye mesh screens;
(4), when using,, stir the formation product, churning time is 10～15 minutes, and in 5 hours, uses with first component and second component 10:1.2 by weight ratio.
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| CN102734297A (en) * | 2012-06-08 | 2012-10-17 | 广东明阳风电产业集团有限公司 | Anchoring bolt for offshore wind power foundation |
| CN102775880A (en) * | 2012-08-24 | 2012-11-14 | 西北永新化工股份有限公司 | Low-temperature quick-drying type epoxy paste paint and preparation method thereof |
| CN103194131A (en) * | 2013-04-12 | 2013-07-10 | 广西大学 | Composite flake heavy-duty coating for ocean storage and transportation facilities |
| CN104194560A (en) * | 2014-08-15 | 2014-12-10 | 广西梧州龙鱼漆业有限公司 | Epoxy glass-flake antiseptic paint and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59123573A (en) * | 1982-12-28 | 1984-07-17 | Dainippon Toryo Co Ltd | Corrosion preventive coating method |
| US20040143037A1 (en) * | 2003-01-17 | 2004-07-22 | 3L&T, Inc. | Epoxy ebonite compositions |
| CN101671515A (en) * | 2009-09-01 | 2010-03-17 | 中国人民解放军海军后勤技术装备研究所 | Anticorrosive coating for concrete structure reinforcing bars and preparation method thereof |
| CN102181218A (en) * | 2011-03-18 | 2011-09-14 | 西北矿冶研究院 | Novel polymer anticorrosive coating material |
-
2011
- 2011-09-22 CN CN 201110282378 patent/CN102344739B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59123573A (en) * | 1982-12-28 | 1984-07-17 | Dainippon Toryo Co Ltd | Corrosion preventive coating method |
| US20040143037A1 (en) * | 2003-01-17 | 2004-07-22 | 3L&T, Inc. | Epoxy ebonite compositions |
| CN101671515A (en) * | 2009-09-01 | 2010-03-17 | 中国人民解放军海军后勤技术装备研究所 | Anticorrosive coating for concrete structure reinforcing bars and preparation method thereof |
| CN102181218A (en) * | 2011-03-18 | 2011-09-14 | 西北矿冶研究院 | Novel polymer anticorrosive coating material |
Cited By (15)
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| CN102734297A (en) * | 2012-06-08 | 2012-10-17 | 广东明阳风电产业集团有限公司 | Anchoring bolt for offshore wind power foundation |
| CN102775880A (en) * | 2012-08-24 | 2012-11-14 | 西北永新化工股份有限公司 | Low-temperature quick-drying type epoxy paste paint and preparation method thereof |
| CN103194131A (en) * | 2013-04-12 | 2013-07-10 | 广西大学 | Composite flake heavy-duty coating for ocean storage and transportation facilities |
| CN103194131B (en) * | 2013-04-12 | 2015-07-22 | 广西大学 | Composite flake heavy-duty coating for ocean storage and transportation facilities |
| CN104194560A (en) * | 2014-08-15 | 2014-12-10 | 广西梧州龙鱼漆业有限公司 | Epoxy glass-flake antiseptic paint and preparation method thereof |
| CN104341811A (en) * | 2014-11-10 | 2015-02-11 | 珠海市澜诺新材料科技有限公司 | Bonding agent for water-based over-rust corrosion protective coating, preparation method of bonding agent, and coating composition formed by bonding agent |
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