CN104312376A - High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof - Google Patents
High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof Download PDFInfo
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- CN104312376A CN104312376A CN201410467568.4A CN201410467568A CN104312376A CN 104312376 A CN104312376 A CN 104312376A CN 201410467568 A CN201410467568 A CN 201410467568A CN 104312376 A CN104312376 A CN 104312376A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses high temperature-resistant flame-retardant modified bituminous paint for ships. The high temperature-resistant flame-retardant modified bituminous paint is prepared from 32-35 parts by weight of E12 epoxy resin, 1-2 parts by weight of polycarbodiimide, 1-2 parts by weight of poly(ether ester), 3-4 parts by weight of graphene, 1-2 parts by weight of nickel-doped nanometer titanium dioxide, 0.3-0.7 parts by weight of cobaltous naphthenate, 1-2 parts by weight of dimer acid, 2-4 parts by weight of alicyclic amine, 2-3 parts by weight of cardanol, 2-4 parts by weight of cresyl glycidyl ether, 8-13 parts by weight of modified waste sodium silicate sand, 9-14 parts by weight of modified asphalt, 3-5 parts by weight of wood wax oil, 1-2 parts by weight of hexabromo-benzene, 2-3 parts by weight of polyvinyl ether, 8-11 parts by weight of xylene, 6-9 parts by weight of glycol, 0.5-1.0 part by weight of aluminum methylbutylphosphinate and 1-2 parts by weight of talcum powder. The used modified asphalt in the paint solves the problem that epoxy resin paint is pulverized easily at a high temperature and improves paint weatherability, corrosion resistance, moisture resistance and water resistance. The used aluminum methylbutylphosphinate has strong flame retardation. The used modified waste sodium silicate sand realizes environmental protection and improves paint heat resistance and flame resistance. The high temperature-resistant flame-retardant modified bituminous paint has a low production cost, a wide application range and excellent performances and is worthy of popularization use.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of heat-resistant fireproof type ship modifying asphalt paint and preparation method thereof.
Background technology
Boats and ships are among ocean environment for a long time; ocean and land natural condition difference very large; there is salt fog ocean and band slight alkalinity, wherein seawater is more much harder than land to corrosion of metal, in ocean, also have diversified marine attaching organism; they can above alow adhere to; affect the ship speed of a ship or plane, increase fuel consumption, also have strong ultraviolet etc. simultaneously; if do not take sfgd., the work-ing life of boats and ships is very short.Marine paint is the tailor-(made) coating on ships; be used for protecting ship, naval vessels, offshore oil to adopt platform, harbour piling bar and offshore steel iron construction not by sea-water corrosion; marine paint must have excellent water tolerance, rust-preventing characteristic, erosion resistance etc., little to human toxicity during construction.
Sodium silicate sand is formed by silica sand, water glass and additional thing mixed preparing.Water glass is colourless, odorless, nontoxic, in casting cycle, all do not have the spilling of pungency or toxic gas, but the add-on of water past glass is large, collapsibility is poor, on-the-spot in sand removal, silica dust flies upward, and causes silica dust to pollute, regenerating used difficulty, goes out of use in a large number, causes the alkaline pollution of environment.Widely, be used to manufacture the various silicates products such as silica gel, metasilicate pentahydrate sodium, silicon sol, sodium-potassium silicate at chemical system, be the basic raw material of silicon compound to the purposes of water glass; Being indispensable raw material in the washing composition such as washing powder, soap in light industry, is also water softener, settling agent; For helping dye, bleaching and sizing in textile industry; Casting, emery wheel manufacture and anticolodal etc. are widely used in machinery industry; For the manufacture of rapid hardening cement, soil-solidified-agent, refractory materials etc. in building trade; Agriculturally can manufacture silicon element fertilizer material; Be used as the high temperature material such as filler, laboratory crucibles of soap, anticolodal, water-softening agent, detergent builder, refractory materials and ceramic raw material, waterproof, leak stopping, fire retarding wood protection, food antiseptic and preparing adhesive etc. in addition.
Bituminous varnish has excellent erosion resistance, to have excellent weather resistance, but poor heat resistance, the present invention is directed to this situation and waste water glass sand and pitch are all carried out modification be prepared into paint, not only reduce environmental pollution, and enhance acid resistance, thermotolerance, the advantage such as dispersiveness and fire line of paint.
Summary of the invention
The object of this invention is to provide a kind of heat-resistant fireproof type ship modifying asphalt paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of heat-resistant fireproof type ship modifying asphalt paint, is made up of the raw material of following weight part: E12 epoxy resin 32-35, polycarbodiimide 1-2, polyether ester 1-2, Graphene 3-4, nickel doped nano titanium dioxide 1-2, cobalt naphthenate 0.3-0.7, dimeracid 1-2, aliphatic cyclic amine 2-4, cardanol 2-3, toluene glycidyl ether 2-4, modified abandoned sodium silicate sand 8-13, modifying asphalt 9-14, wood wax oil 3-5, hexabromobenzene 1-2, polyvinyl ether 2-3, dimethylbenzene 8-11, ethylene glycol 6-9, methyl butyl phospho acid aluminium 0.5-1.0, talcum powder 1-2;
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resistant fireproof type ship modifying asphalt paint of the present invention, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Advantage of the present invention is: the modifying asphalt that paint of the present invention adds overcomes the shortcoming of the easy efflorescence of epoxy resin-based paint high temperature; and improve the functions such as the weathering resistance of paint, erosion resistance, moisture resistivity and water tolerance; the methyl butyl phospho acid aluminium added has very strong flame retardant properties; and the modified abandoned sodium silicate sand utilization of waste material added; protect environment; add thermotolerance and the flame retardant resistance of paint; paint of the present invention has low production cost; of many uses; excellent performance, is worth of widely use.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of heat-resistant fireproof type ship modifying asphalt paint, is made up of the raw material of following weight part (kilogram): E12 epoxy resin 35, polycarbodiimide 1, polyether ester 1, Graphene 3, nickel doped nano titanium dioxide 1, cobalt naphthenate 0.4, dimeracid 1, aliphatic cyclic amine 3, cardanol 2, toluene glycidyl ether 2, modified abandoned sodium silicate sand 8, modifying asphalt 9, wood wax oil 3, hexabromobenzene 1, polyvinyl ether 2, dimethylbenzene 8, ethylene glycol 9, methyl butyl phospho acid aluminium 0.6, talcum powder 1;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): pitch 82, aluminum stearate 0.5, C9 petroleum resin 5, carboxymethyl cellulose 1, thermoplastic elastomer 0.6, nano montmorillonite powder 2, polyethylene wax 0.4, dioctyl phthalate (DOP) 0.4, ester gum 0.7, isocaprylic acid zinc 0.3, fibrous magnesium silicate 1, polyoxyethylene gather fatty alcohol-ether 0.6, linseed oil 7, maleic acid 0.7, water 12, acetic acid butanols 2; Maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely; By asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resistant fireproof type ship modifying asphalt paint of the present invention, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Paint paint film flat smooth of the present invention, shock-resistance (/cm) 50, snappiness (mm) 2, sticking power (Mpa) 5, artificial accelerated aging (1000h) paint film without efflorescence, without variable color, flawless, salt spray resistance (1000h) paint film is non-foaming, does not come off, non-corrosive, water tolerance (27 ° of C ± 6 ° C, 500h) paint film is non-foaming, does not come off, non-corrosive, time of drying (25 ° of C) surface drying 2h, does solid work 24h, and high temperature resistant (130 ° of C) is greater than 600h.
Claims (3)
1. a heat-resistant fireproof type ship modifying asphalt paint, it is characterized in that, be made up of the raw material of following weight part: E12 epoxy resin 32-35, polycarbodiimide 1-2, polyether ester 1-2, Graphene 3-4, nickel doped nano titanium dioxide 1-2, cobalt naphthenate 0.3-0.7, dimeracid 1-2, aliphatic cyclic amine 2-4, cardanol 2-3, toluene glycidyl ether 2-4, modified abandoned sodium silicate sand 8-13, modifying asphalt 9-14, wood wax oil 3-5, hexabromobenzene 1-2, polyvinyl ether 2-3, dimethylbenzene 8-11, ethylene glycol 6-9, methyl butyl phospho acid aluminium 0.5-1.0, talcum powder 1-2,
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of heat-resistant fireproof type ship modifying asphalt paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) E12 epoxy resin, modifying asphalt, aliphatic cyclic amine, cardanol, dimethylbenzene, ethylene glycol, toluene glycidyl ether are added in reactor and are heated to 200-250 ° of C, after being uniformly mixed by mixture, under 600-800 rev/min, stir 2-3 hour;
(2) under identical rotating speed, add polycarbodiimide, Graphene, nickel doped nano titanium dioxide, modified abandoned sodium silicate sand stirring 30-50 minute, be cooled to 50-80 ° of C and add all the other remaining compositions again, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned sodium silicate sand according to claim 1, it is characterized in that, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410467568.4A CN104312376A (en) | 2014-09-15 | 2014-09-15 | High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410467568.4A CN104312376A (en) | 2014-09-15 | 2014-09-15 | High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof |
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| CN104312376A true CN104312376A (en) | 2015-01-28 |
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| CN201410467568.4A Pending CN104312376A (en) | 2014-09-15 | 2014-09-15 | High temperature-resistant flame-retardant modified bituminous paint for ships and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107134297A (en) * | 2017-04-25 | 2017-09-05 | 扬中市众成管路配件有限公司 | A kind of insulation box for instrument of high antiseptic property |
| CN108699382A (en) * | 2016-02-25 | 2018-10-23 | 中国涂料株式会社 | Anticorrosive coating composition, anticorrosion film, the base material with anticorrosion film and its manufacturing method |
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| CN103113649A (en) * | 2013-02-02 | 2013-05-22 | 金发科技股份有限公司 | Flame retardant polyolefin and preparation method and product thereof |
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103567355A (en) * | 2013-10-11 | 2014-02-12 | 铜陵市经纬流体科技有限公司 | Organic ester sodium silicate self-hardening sand and preparation method thereof |
| CN103788833A (en) * | 2014-02-11 | 2014-05-14 | 青岛海洋先进材料工程技术中心有限公司 | Organosilicon antiskid anticorrosion deck coating and preparation method thereof |
| CN103897215A (en) * | 2012-12-26 | 2014-07-02 | 金发科技股份有限公司 | Composite fire retardant and use thereof |
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2014
- 2014-09-15 CN CN201410467568.4A patent/CN104312376A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103897215A (en) * | 2012-12-26 | 2014-07-02 | 金发科技股份有限公司 | Composite fire retardant and use thereof |
| CN103113649A (en) * | 2013-02-02 | 2013-05-22 | 金发科技股份有限公司 | Flame retardant polyolefin and preparation method and product thereof |
| CN103555204A (en) * | 2013-09-12 | 2014-02-05 | 宁波镭纳涂层技术有限公司 | High-polymer modified water-emulsion asphalt-based thick waterproof paint and preparation method thereof |
| CN103567355A (en) * | 2013-10-11 | 2014-02-12 | 铜陵市经纬流体科技有限公司 | Organic ester sodium silicate self-hardening sand and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108699382A (en) * | 2016-02-25 | 2018-10-23 | 中国涂料株式会社 | Anticorrosive coating composition, anticorrosion film, the base material with anticorrosion film and its manufacturing method |
| CN107134297A (en) * | 2017-04-25 | 2017-09-05 | 扬中市众成管路配件有限公司 | A kind of insulation box for instrument of high antiseptic property |
| CN107134297B (en) * | 2017-04-25 | 2019-10-22 | 扬中市众成管路配件有限公司 | A kind of insulation box for instrument of high antiseptic property |
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Application publication date: 20150128 |
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