CN104293184A - Heat-resistant and sun-proof fiber asphalt paint and preparation method thereof - Google Patents
Heat-resistant and sun-proof fiber asphalt paint and preparation method thereof Download PDFInfo
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- CN104293184A CN104293184A CN201410469120.6A CN201410469120A CN104293184A CN 104293184 A CN104293184 A CN 104293184A CN 201410469120 A CN201410469120 A CN 201410469120A CN 104293184 A CN104293184 A CN 104293184A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses heat-resistant and sun-proof fiber asphalt paint. The heat-resistant and sun-proof fiber asphalt paint is characterized by being prepared from the following raw materials in parts by weight: 12-17 parts of methyl silicone resin, 3-5 parts of liquid polysulfide rubber, 4-7 parts of methylene biscyclohexane amine, 0.1-0.4 part of o-hydroxybenzophenone, 2-4 parts of carbon black, 3-4 parts of nano aluminum nitride, 2-4 parts of mica powder, 2-3 parts of vermiculite powder, 2-3 parts of a polyethylene terephthalate fiber, 1-2 parts of a bamboo fiber, 2-3 parts of a polyvinyl alcohol fiber, 0.6-1.0 part of cuprous thiocyanate, 35-43 parts of modified asphalt, 6-10 parts of modified waste sodium silicate sand, 1-2 parts of a silane coupling agent KH560, 0.3-0.8 part of fluorescent powder, 6-9 parts of dimethylbenzene, 6-8 parts of sodium lignosulphonate, 5-7 parts of n-butyl acetate and 4-6 parts of trichloroacetic acid. According to the paint disclosed by the invention, the added mica powder is good in abrasion resistance and wear resistance, is heat-resistant and insulating, is hard to dissolve in acidic and alkaline solutions, and is stable in chemical performance; the added vermiculite powder can be used for increasing the viscosity of the paint, and has a flame-retardant effect; added o-hydroxybenzophenone and carbon black can be used for increasing the photo-stability of the paint, and are hard to age; and added nano aluminum nitride has good heat conduction and insulation properties. The heat-resistant and sun-proof fiber asphalt paint also can be used for modifying the waste sodium silicate sand, can be used for increasing the water resistance, fire resistance and dispersion performance of the paint, solves the problem of soil pollution, and also can be used for protecting the environment.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of heat-resisting sun-proof fiber asphalt paint and preparation method thereof.
Background technology
Bamboo fibers utilizes natural bamboo for raw material, and the regenerated cellulose fibre produced through special high-tech art breading is the fifth-largest natural fiber after cotton, fiber crops, hair, silk.Bamboo fibers have good ventilation property, moment the characteristic such as water-absorbent, stronger wear resistance and good dyeability, have again simultaneously natural antibacterial, antibacterial, except mite, deodorization and anti-ultraviolet function.Bamboo fibers is wide material sources on starting material, and usability is strong, is mainly manifested in the bamboo grows phase short, can becomes a useful person and once plant long-range business in 2-3, are a kind of raw materials that is natural, green, environment-friendly type.
Sodium silicate sand is formed by silica sand, water glass and additional thing mixed preparing.Water glass is colourless, odorless, nontoxic, in casting cycle, all do not have the spilling of pungency or toxic gas, but the add-on of water past glass is large, collapsibility is poor, on-the-spot in sand removal, silica dust flies upward, and causes silica dust to pollute, regenerating used difficulty, goes out of use in a large number, causes the alkaline pollution of environment.Widely, be used to manufacture the various silicates products such as silica gel, metasilicate pentahydrate sodium, silicon sol, sodium-potassium silicate at chemical system, be the basic raw material of silicon compound to the purposes of water glass; Being indispensable raw material in the washing composition such as washing powder, soap in light industry, is also water softener, settling agent; For helping dye, bleaching and sizing in textile industry; Casting, emery wheel manufacture and anticolodal etc. are widely used in machinery industry; For the manufacture of rapid hardening cement, soil-solidified-agent, refractory materials etc. in building trade; Agriculturally can manufacture silicon element fertilizer material; Be used as the high temperature material such as filler, laboratory crucibles of soap, anticolodal, water-softening agent, detergent builder, refractory materials and ceramic raw material, waterproof, leak stopping, fire retarding wood protection, food antiseptic and preparing adhesive etc. in addition.
Bituminous varnish has excellent erosion resistance, have excellent weather resistance, but poor heat resistance, the present invention is directed to this situation waste water glass sand is carried out modification to add in paint, not only reduce environmental pollution, and enhance the effects such as the acid resistance of paint, thermotolerance, dispersiveness and fire line, and add bamboo fibers can increase paint sterilization, antibacterial, except mite and anti-ultraviolet effect.
Summary of the invention
The object of this invention is to provide a kind of heat-resisting sun-proof fiber asphalt paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of heat-resisting sun-proof fiber asphalt paint, be made up of the raw material of following weight part: methyl silicon resin 12-17, liquid polysulphide rubber 3-5, methylene-bis hexamethylene alkanamine 4-7, O-hydroxyl-diphenyl ketone 0.1-0.4, carbon black 2-4, nano aluminum nitride 3-4, mica powder 2-4, vermiculite power 2-3, pet fiber 2-3, bamboo fibers 1-2, polyvinyl alcohol fiber 2-3, the cuprous 0.6-1.0 of sulfocyanic acid, modifying asphalt 35-43, modified abandoned sodium silicate sand 6-10, silane coupling agent KH5601-2, fluorescent material 0.3-0.8, dimethylbenzene 6-9, sodium lignosulfonate 6-8, n-butyl acetate 5-7, Tricholroacetic Acid 4-6,
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resisting sun-proof fiber asphalt paint of the present invention, be made up of following concrete steps:
(1) pet fiber, bamboo fibers, polyvinyl alcohol fiber, Tricholroacetic Acid are dropped in reactor and are heated to 200-250 ° of C, then add methyl silicon resin, liquid polysulphide rubber, methylene-bis hexamethylene alkanamine, modifying asphalt, dimethylbenzene, n-butyl acetate stir 2-3 hour under 600-800 rev/min;
(2) under identical rotating speed, add modified abandoned sodium silicate sand, carbon black, nano aluminum nitride, vermiculite power, silane coupling agent KH560 stir 30-50 minute, reduce temperature to 50-70 ° of C, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
The invention has the advantages that: mica powder resistance to abrasion and the wear resistance of paint interpolation of the present invention are good, high temperature insulation, be insoluble in acid-base solution, stable chemical nature, the vermiculite power added adds the viscosity of paint, and there is fire-retardant effect, the O-hydroxyl-diphenyl ketone added and carbon black can both strengthen the light stability of paint, not easily aging, the nano aluminum nitride added has good heat conduction, insulating property, discarded sodium silicate sand is also carried out modification by the present invention, enhance the water tolerance of paint, fire line and dispersiveness, solve the problem of soil pollution, protect environment.
specific embodiments
Below by specific examples, the present invention is described in detail.
A heat-resisting sun-proof fiber asphalt paint, is made up of the raw material of following weight part (kilogram): methyl silicon resin 14, liquid polysulphide rubber 4, methylene-bis hexamethylene alkanamine 4, O-hydroxyl-diphenyl ketone 0.4, carbon black 2, nano aluminum nitride 3, mica powder 2, vermiculite power 2, pet fiber 2, bamboo fibers 1, polyvinyl alcohol fiber 2, sulfocyanic acid are cuprous 0.6, modifying asphalt 35, modified abandoned sodium silicate sand 6, silane coupling agent KH5601, fluorescent material 0.5, dimethylbenzene 9, sodium lignosulfonate 7, n-butyl acetate 7, Tricholroacetic Acid 4;
Described modifying asphalt is made up of the raw material of following weight part (kilogram): pitch 82, aluminum stearate 0.5, C9 petroleum resin 5, carboxymethyl cellulose 1, thermoplastic elastomer 0.6, nano montmorillonite powder 2, polyethylene wax 0.4, dioctyl phthalate (DOP) 0.4, ester gum 0.7, isocaprylic acid zinc 0.3, fibrous magnesium silicate 1, polyoxyethylene gather fatty alcohol-ether 0.6, linseed oil 7, maleic acid 0.7, water 12, acetic acid butanols 2; Maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely; By asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
A kind of heat-resisting sun-proof fiber asphalt paint of the present invention, be made up of following concrete steps:
(1) pet fiber, bamboo fibers, polyvinyl alcohol fiber, Tricholroacetic Acid are dropped in reactor and are heated to 200-250 ° of C, then add methyl silicon resin, liquid polysulphide rubber, methylene-bis hexamethylene alkanamine, modifying asphalt, dimethylbenzene, n-butyl acetate stir 2-3 hour under 600-800 rev/min;
(2) under identical rotating speed, add modified abandoned sodium silicate sand, carbon black, nano aluminum nitride, vermiculite power, silane coupling agent KH560 stir 30-50 minute, reduce temperature to 50-70 ° of C, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
Modified abandoned sodium silicate sand of the present invention, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
Paint paint film flat smooth of the present invention, shock-resistance (/cm) 50, snappiness (mm) 2, sticking power (Mpa) 5, artificial accelerated aging (1200h) paint film without efflorescence, without variable color, flawless, salt spray resistance (1000h) paint film is non-foaming, does not come off, non-corrosive, water tolerance (27 ° of C ± 6 ° C, 500h) paint film is non-foaming, does not come off, non-corrosive, alkali resistance (GB/T9755-2001) 72h, high temperature resistant (130 ° of C) is greater than 600h.
Claims (3)
1. a heat-resisting sun-proof fiber asphalt paint, it is characterized in that, be made up of the raw material of following weight part: methyl silicon resin 12-17, liquid polysulphide rubber 3-5, methylene-bis hexamethylene alkanamine 4-7, O-hydroxyl-diphenyl ketone 0.1-0.4, carbon black 2-4, nano aluminum nitride 3-4, mica powder 2-4, vermiculite power 2-3, pet fiber 2-3, bamboo fibers 1-2, polyvinyl alcohol fiber 2-3, the cuprous 0.6-1.0 of sulfocyanic acid, modifying asphalt 35-43, modified abandoned sodium silicate sand 6-10, silane coupling agent KH5601-2, fluorescent material 0.3-0.8, dimethylbenzene 6-9, sodium lignosulfonate 6-8, n-butyl acetate 5-7, Tricholroacetic Acid 4-6,
Described modifying asphalt is made up of the raw material of following weight part: pitch 80-84, aluminum stearate 0.3-0.6, C9 petroleum resin 4-6, carboxymethyl cellulose 1-2, thermoplastic elastomer 0.4-0.8, nano montmorillonite powder 1-2, polyethylene wax 0.3-0.6, dioctyl phthalate (DOP) 0.3-0.6, ester gum 0.5-1.0, isocaprylic acid zinc 0.3-0.7, fibrous magnesium silicate 1-2, polyoxyethylene gathers fatty alcohol-ether 0.5-1.0, linseed oil 7-9, maleic acid 0.5-1.0, water 12-15, acetic acid butanols 2-3, maleic acid and linseed oil are mixed and heated to 160-190 ° of C by preparation method, obtain modipied natural apatite for subsequent use after reacting completely, by asphalt heating to 150-190 ° of C, through high speed centrifugation, shear the particulate grinding to form 10-30 μm, then polyoxyethylene is gathered the mixing of fatty alcohol-ether, aluminum stearate, thermoplastic elastomer, nano montmorillonite powder, C9 petroleum resin and water and be heated to 60-90 ° of C formation mixing solutions, again by the mixing of modipied natural apatite, pitch and mixing solutions with 600-800 rev/min of lower grinding distribution 20 minutes, add all the other surplus materialss again, and with 800-1200 rev/min of lower grinding distribution 20-30 minute.
2. a kind of heat-resisting sun-proof fiber asphalt paint according to claim 1, is characterized in that, be made up of following concrete steps:
(1) pet fiber, bamboo fibers, polyvinyl alcohol fiber, Tricholroacetic Acid are dropped in reactor and are heated to 200-250 ° of C, then add methyl silicon resin, liquid polysulphide rubber, methylene-bis hexamethylene alkanamine, modifying asphalt, dimethylbenzene, n-butyl acetate stir 2-3 hour under 600-800 rev/min;
(2) under identical rotating speed, add modified abandoned sodium silicate sand, carbon black, nano aluminum nitride, vermiculite power, silane coupling agent KH560 stir 30-50 minute, reduce temperature to 50-70 ° of C, finally add all the other remaining compositions, stir in reactor, disperse, material after dispersion is added to grinding distribution in sand mill even, and stirs 20-30 minute under 1200-1400 rev/min;
(3) finely dispersed material is added in filter filters, after filtration, obtain the material that fineness is 20-40 μm, by the material package after filtering.
3. modified abandoned sodium silicate sand according to claim 1, it is characterized in that, discarded sodium silicate sand is added in stoving oven by preparation method, high-temperature roasting 1-2 hour under 150-200 ° of C, waste water glass sand after heating is added in rotary grinding device while hot, surface treating adhesive is sloughed by high-speed stirring grinding, again this waste water glass sand is added to purified water sonic oscillation 2-3 hour, wash with water again to neutrality and dry, add the sepiolite of waste water glass sand weight 17% again, the carbon black of 4% and alumina lap to 400 order-600 order fine powder of 7%, add the tetrabutyl titanate mixed grinding of waste water glass sand weight 0.5-1% more evenly.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410469120.6A CN104293184A (en) | 2014-09-16 | 2014-09-16 | Heat-resistant and sun-proof fiber asphalt paint and preparation method thereof |
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| CN201410469120.6A CN104293184A (en) | 2014-09-16 | 2014-09-16 | Heat-resistant and sun-proof fiber asphalt paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832327A (en) * | 2015-12-07 | 2017-06-13 | 中国林业科学研究院木材工业研究所 | A kind of fluorescent base nano lignin and preparation method thereof |
| CN107384048A (en) * | 2017-08-29 | 2017-11-24 | 王迅 | A kind of preparation method of oceanographic equipment nano-antirust coating |
| CN110093057A (en) * | 2018-01-28 | 2019-08-06 | 姚建珍 | A kind of erosion-resisting Teflon environmental protection paint formula and its preparation process |
| CN117801678A (en) * | 2023-12-27 | 2024-04-02 | 浙江荣平建材科技有限公司 | Asphalt for glass fiber tile surface coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832327A (en) * | 2015-12-07 | 2017-06-13 | 中国林业科学研究院木材工业研究所 | A kind of fluorescent base nano lignin and preparation method thereof |
| CN107384048A (en) * | 2017-08-29 | 2017-11-24 | 王迅 | A kind of preparation method of oceanographic equipment nano-antirust coating |
| CN110093057A (en) * | 2018-01-28 | 2019-08-06 | 姚建珍 | A kind of erosion-resisting Teflon environmental protection paint formula and its preparation process |
| CN117801678A (en) * | 2023-12-27 | 2024-04-02 | 浙江荣平建材科技有限公司 | Asphalt for glass fiber tile surface coating and preparation method thereof |
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Application publication date: 20150121 |