CN105908561A - Wear-resistant flame retardation wallpaper raw paper and making method thereof - Google Patents
Wear-resistant flame retardation wallpaper raw paper and making method thereof Download PDFInfo
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- CN105908561A CN105908561A CN201610253118.4A CN201610253118A CN105908561A CN 105908561 A CN105908561 A CN 105908561A CN 201610253118 A CN201610253118 A CN 201610253118A CN 105908561 A CN105908561 A CN 105908561A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
- D21H15/12—Composite fibres partly organic, partly inorganic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
- D21H13/46—Non-siliceous fibres, e.g. from metal oxides
- D21H13/50—Carbon fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a wear-resistant flame retardation wallpaper raw paper. Present technologies and present formulas are improved, meerschaum powder-antimony oxide-chlorinated paraffin is adopted as a flame retardant and is modified, H. and OH. free radicals in the chain reaction and for keeping combustion in a paper combustion reaction gas phase are captured to change the reaction mode in the gas phase, the heat release amount of the reaction is reduced to quench flame, and nanometer calcium carbonate is added to raw materials after being organically modified to improve the brush ability of raw paper and make the raw paper be closely combined with a decoration layer and not shed. The flame retardation property of the flame retardation wallpaper raw paper meets GB/T14656-93 requirements, the tearability, the folding strength, the ring crush strength and the tensile strength are improved, and wallpaper produced by using the raw paper has the advantages of environmental protection, no pollution, wear resistance, difficult shedding, full utilization of the moisture absorption, ventilation, bacteriostasis, anti-bacterium, warmness in winter, coolness in summer and humidity adjustment characteristics of bamboo charcoal fibers to purify and adjust air, and avoiding of damages of harmful materials to the health of human bodies.
Description
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of abrasion resistant fire blocking hanging raw stock and preparation method thereof.
Background technology
Wallpaper, also known as wallpaper, is with paper, non-weaving cloth or woven cloths as base material, adds decorative layer, be widely used in the decoration of some metopes or wall.Although wallpaper is not requisite to the decoration function of building, but it has been to build room style, atmosphere and the important means of color.No matter the especially wallpaper with paper as base material, enjoy the favor of people from properties of product or environmental requirement.
Paper is requisite article during people live.All many-sides such as packaging material, construction material, industrial or agricultural and daily living article it are widely used in along with socioeconomic development, paper and paper products.The burning-point of paper is at 130～230 DEG C, and oxygen index (OI), between 15%～20%, is the most incendive article.It is often rendered as the material or promote the medium that advances rapidly of the intensity of a fire of igniting of fire.And the wallpaper with paper as base material, once breaking out of fire, flame easily spreads along wallpaper, causes the intensity of a fire to expand rapidly, thus is the important means of the fire-retardant research of wallpaper to the fire-retardant research of paper.The fire-retardant way of tradition is mostly to decorative layer in addition flame treatment, but the decorative layer having used wallpaper surface of long duration and covering easily weares and teares to come off or affected by other external environments and causes the anti-flammability of wallpaper to reduce, it is clear that wallpaper base material body paper is carried out flame treatment particularly important.
" development of sepiolite powder fire retardant papers " literary composition describes the preparation method of fire retardant papers, is studied for the flame-retardant system of host inorganic additive with sepiolite powder.Result shows, time merely with sepiolite powder for additive, addition reaches more than 70% just preferable anti-flammability；Add a certain amount of chlorinated paraffin-antimony oxide and can be greatly improved the fire resistance of paper.The proportioning being obtained mixing fire retardant by screening is 7: 1: 2, and addition is 30%, and the fire resistance of paper reaches GB/T14656-93 requirement, and its tensile strength, tearability, folding strength, ring crush intensity have reached preferable level.
The anti-flammability of body paper is only analyzed by literary composition, but current wallpaper is usually present easy laying dust dirty, meets the problems such as water is the wettest, soundproof effect is poor, function singleness, it is coated with and functions only as decoration function on the wall, do not reach people's technical specification to indoor environment high request, and can be mouldy at sough or wet climates especially south plum rain season, it being difficult to preserve, service life is shorter, wallpaper often changed by so needs, relatively costly.Therefore, the present invention improves existing production technology and formula, prepares the wallpaper composite flame-proof body paper of diverse in function.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of abrasion resistant fire blocking hanging raw stock and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of abrasion resistant fire blocking hanging raw stock, is prepared by the raw materials in: birch pulp 62-64, bagasse 7-9, Folium Pini 6-8, bamboo carbon fiber 11-13, sepiolite powder 16.8-17.8, chlorinated paraffin 2.6-2.9, antimony oxide 4.4-4.7, calcium phosphate 0.2-0.4, high wear-resistant carbon black 1.2-1.4, litsea cubeba oil 2.3-2.5, nano-calcium carbonate 0.3-0.5.
The manufacture method of described a kind of abrasion resistant fire blocking hanging raw stock, comprises the following steps:
(1) under nitrogen protection by litsea cubeba oil heated and boiled, add nano-calcium carbonate and keep temperature magnetic agitation 1-2 hour, filter, wash after drying, freezing 3-5 hour at subzero 15-20 DEG C, prepare modified nano calcium carbonate；
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L and soak 8-9 hour, continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds high wear-resistant carbon black, antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutrality vacuum drying, and cooling adds chlorinated paraffin, step (1) material ultrasonic grinding obtains modified meerschaum powder in 30-40 minute；
(3) add water pulping by bagasse, Folium Pini, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, uses flowing water rinsed clean, add bamboo carbon fiber and grind to form mixed slurry；
(4) birch pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
The invention have the advantage that the present invention improves existing technique and formula with sepiolite powder-antimony oxide-chlorinated paraffin for fire retardant in addition modified, by catching H and the OH free radical of the chain reaction maintaining burning in burning paper reaction gas phase, and then the reaction pattern in change gas phase, reduce exothermic heat of reaction amount and make flame cancellation, the present invention also adds in raw material after organically-modified for nano-calcium carbonate simultaneously, improve the brushability of body paper, being tightly combined difficult drop-off with decorative layer, the flame wallpaper body paper firing resistance utilizing the present invention to prepare reaches
GB/T14656-93 requirement, its tearability, folding strength, ring crush intensity, tensile strength are improved, utilize its wallpaper produced environment friendly and pollution-free, wear-resisting difficult drop-off, the features such as bamboo carbon fiber moisture absorption ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, humidity regulation that make full use of purify regulation air, it is to avoid the deleterious material injury to health.
Detailed description of the invention
A kind of abrasion resistant fire blocking hanging raw stock, is prepared by the raw materials in: birch pulp 62, bagasse 7, Folium Pini 6, bamboo carbon fiber 11, sepiolite powder 16.8, chlorinated paraffin 2.6, antimony oxide 4.4, calcium phosphate 0.2, high wear-resistant carbon black 1.2, litsea cubeba oil 2.3, nano-calcium carbonate 0.3.
The manufacture method of described a kind of abrasion resistant fire blocking hanging raw stock, comprises the following steps:
(1) under nitrogen protection by litsea cubeba oil heated and boiled, add nano-calcium carbonate and keep temperature magnetic agitation 1-2 hour, filter, wash after drying, freezing 3-5 hour at subzero 15-20 DEG C, prepare modified nano calcium carbonate；
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L and soak 8-9 hour, continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds high wear-resistant carbon black, antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutrality vacuum drying, and cooling adds chlorinated paraffin, step (1) material ultrasonic grinding obtains modified meerschaum powder in 30-40 minute；
(3) add water pulping by bagasse, Folium Pini, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, uses flowing water rinsed clean, add bamboo carbon fiber and grind to form mixed slurry；
(4) birch pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
The flame wallpaper body paper utilizing the present invention to prepare has a following technical specification:
Tensile strength/kN m–1: 3.35；
Tearability/mN:425；
Folding strength/and time: 56；
Ring crush intensity/kN m–1: 2.65.
Claims (2)
1. an abrasion resistant fire blocking hanging raw stock, it is characterized in that, be prepared by the raw materials in: birch pulp 62-64, bagasse 7-9, Folium Pini 6-8, bamboo carbon fiber 11-13, sepiolite powder 16.8-17.8, chlorinated paraffin 2.6-2.9, antimony oxide 4.4-4.7, calcium phosphate 0.2-0.4, high wear-resistant carbon black 1.2-1.4, litsea cubeba oil 2.3-2.5, nano-calcium carbonate 0.3-0.5.
The manufacture method of a kind of abrasion resistant fire blocking hanging raw stock the most according to claim 1, it is characterised in that comprise the following steps:
(1) under nitrogen protection by litsea cubeba oil heated and boiled, add nano-calcium carbonate and keep temperature magnetic agitation 1-2 hour, filter, wash after drying, freezing 3-5 hour at subzero 15-20 DEG C, prepare modified nano calcium carbonate；
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L and soak 8-9 hour, continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds high wear-resistant carbon black, antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutrality vacuum drying, and cooling adds chlorinated paraffin, step (1) material ultrasonic grinding obtains modified meerschaum powder in 30-40 minute；
(3) add water pulping by bagasse, Folium Pini, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, uses flowing water rinsed clean, add bamboo carbon fiber and grind to form mixed slurry；
(4) birch pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610253118.4A CN105908561A (en) | 2016-04-22 | 2016-04-22 | Wear-resistant flame retardation wallpaper raw paper and making method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610253118.4A CN105908561A (en) | 2016-04-22 | 2016-04-22 | Wear-resistant flame retardation wallpaper raw paper and making method thereof |
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| CN105908561A true CN105908561A (en) | 2016-08-31 |
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| CN201610253118.4A Pending CN105908561A (en) | 2016-04-22 | 2016-04-22 | Wear-resistant flame retardation wallpaper raw paper and making method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108729297A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
| CN108729303A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Child room wallpaper and preparation method thereof |
| CN108729304A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Infant room wallpaper and preparation method thereof |
| CN108755273A (en) * | 2018-05-25 | 2018-11-06 | 安徽银兔装饰材料有限公司 | Wallpaper base material and preparation method thereof |
| CN108755272A (en) * | 2018-05-25 | 2018-11-06 | 安徽银兔装饰材料有限公司 | Flame wallpaper base material and preparation method thereof |
| CN108797217A (en) * | 2018-05-25 | 2018-11-13 | 安徽银兔装饰材料有限公司 | Child room wallpaper and preparation method thereof |
| CN108797218A (en) * | 2018-05-25 | 2018-11-13 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
| CN108842504A (en) * | 2018-05-25 | 2018-11-20 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08100389A (en) * | 1994-09-28 | 1996-04-16 | New Oji Paper Co Ltd | Flame retardant paper for backing vinyl wallpaper |
| CN103044756A (en) * | 2012-11-25 | 2013-04-17 | 安徽六方重联机械股份有限公司 | Preparation method of packaging plastic base material film containing modified calcined fluorite powder |
| CN103756094A (en) * | 2014-01-10 | 2014-04-30 | 安徽瑞升电气科技有限公司 | Halogen-free flame-retardant polyphenyl ether cable material |
| CN105220557A (en) * | 2015-09-11 | 2016-01-06 | 姚志宏 | Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof |
| CN105256643A (en) * | 2015-09-11 | 2016-01-20 | 姚志宏 | Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor |
-
2016
- 2016-04-22 CN CN201610253118.4A patent/CN105908561A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08100389A (en) * | 1994-09-28 | 1996-04-16 | New Oji Paper Co Ltd | Flame retardant paper for backing vinyl wallpaper |
| CN103044756A (en) * | 2012-11-25 | 2013-04-17 | 安徽六方重联机械股份有限公司 | Preparation method of packaging plastic base material film containing modified calcined fluorite powder |
| CN103756094A (en) * | 2014-01-10 | 2014-04-30 | 安徽瑞升电气科技有限公司 | Halogen-free flame-retardant polyphenyl ether cable material |
| CN105220557A (en) * | 2015-09-11 | 2016-01-06 | 姚志宏 | Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof |
| CN105256643A (en) * | 2015-09-11 | 2016-01-20 | 姚志宏 | Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor |
Non-Patent Citations (1)
| Title |
|---|
| 杨守生: "壁纸阻燃基纸的研制", 《新型建筑材料》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108729297A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
| CN108729303A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Child room wallpaper and preparation method thereof |
| CN108729304A (en) * | 2018-05-25 | 2018-11-02 | 安徽银兔装饰材料有限公司 | Infant room wallpaper and preparation method thereof |
| CN108755273A (en) * | 2018-05-25 | 2018-11-06 | 安徽银兔装饰材料有限公司 | Wallpaper base material and preparation method thereof |
| CN108755272A (en) * | 2018-05-25 | 2018-11-06 | 安徽银兔装饰材料有限公司 | Flame wallpaper base material and preparation method thereof |
| CN108797217A (en) * | 2018-05-25 | 2018-11-13 | 安徽银兔装饰材料有限公司 | Child room wallpaper and preparation method thereof |
| CN108797218A (en) * | 2018-05-25 | 2018-11-13 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
| CN108842504A (en) * | 2018-05-25 | 2018-11-20 | 安徽银兔装饰材料有限公司 | Environmental protection flame retardant wallpaper and preparation method thereof |
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Application publication date: 20160831 |