CN105803860A - Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof - Google Patents
Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof Download PDFInfo
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- CN105803860A CN105803860A CN201610253105.7A CN201610253105A CN105803860A CN 105803860 A CN105803860 A CN 105803860A CN 201610253105 A CN201610253105 A CN 201610253105A CN 105803860 A CN105803860 A CN 105803860A
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- Prior art keywords
- flaming
- body stock
- wallpaper body
- wallpaper
- hour
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses anti-flaming wallpaper body stock with a mosquito repelling effect. According to the anti-flaming wallpaper body stock disclosed by the invention, an existing technology and an existing formula are improved, sea-foam stone powder, antimonous oxide and chlorinated paraffin are adopted as flame retardants and are modified, a reaction mode in a gas phase is changed through capturing H. and OH. radicals maintaining a combustion chain type reaction in a paper combustion reaction gas phase, and the heat release of the reaction is reduced so as to quench flame; meanwhile, nano antimony tin oxide is added into the raw materials after being organically modified, so that the brushing property of the anti-flaming wallpaper body stock is increased, and the anti-flaming wallpaper body stock is tightly combined with a decoration layer and is unlikely to fall off; by utilizing the anti-flaming wallpaper body stock disclosed by the invention, the flame resistance can meet the requirement of GB/T14656-93, the tearing strength, the folding strength, the ring crush compression resistance and the tensile strength of the anti-flaming wallpaper body stock are all increased; in wallpaper prepared by the anti-flaming wallpaper body stock, not only are excellent properties of bacterial resistance, acarid prevention, moisture adsorption, ventilation and peculiar smell adsorption of hemp maintained, but also the mosquito repelling effect is obtained, and the application range is wide.
Description
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of flame wallpaper body paper with mosquito repellent function and preparation method thereof.
Background technology
Wallpaper, also known as wallpaper, is with paper, non-weaving cloth or woven cloths as base material, adds decorative layer, be widely used in the decoration of some metopes or wall.Although wallpaper is not requisite to the decoration function of building, but it has been to build room style, atmosphere and the important means of color.No matter the especially wallpaper with paper as base material, enjoy the favor of people from properties of product or environmental requirement.
Paper is requisite article during people live.All many-sides such as packaging material, construction material, industrial or agricultural and daily living article it are widely used in along with socioeconomic development, paper and paper products.The burning-point of paper is at 130~230 DEG C, and oxygen index (OI), between 15%~20%, is the most incendive article.It is often rendered as the material or promote the medium that advances rapidly of the intensity of a fire of igniting of fire.And the wallpaper with paper as base material, once breaking out of fire, flame easily spreads along wallpaper, causes the intensity of a fire to expand rapidly, thus is the important means of the fire-retardant research of wallpaper to the fire-retardant research of paper.The fire-retardant way of tradition is mostly to decorative layer in addition flame treatment, but the decorative layer having used wallpaper surface of long duration and covering easily weares and teares to come off or affected by other external environments and causes the anti-flammability of wallpaper to reduce, it is clear that wallpaper base material body paper is carried out flame treatment particularly important.
" development of sepiolite powder fire retardant papers " literary composition describes the preparation method of fire retardant papers, is studied for the flame-retardant system of host inorganic additive with sepiolite powder.Result shows, time merely with sepiolite powder for additive, addition reaches more than 70% just preferable anti-flammability;Add a certain amount of chlorinated paraffin-antimony oxide and can be greatly improved the fire resistance of paper.The proportioning being obtained mixing fire retardant by screening is 7: 1: 2, and addition is 30%, and the fire resistance of paper reaches GB/T14656-93 requirement, and its tensile strength, tearability, folding strength, ring crush intensity have reached preferable level.
The anti-flammability of body paper is only analyzed by literary composition, but current wallpaper is usually present easy laying dust dirty, meets the problems such as water is the wettest, soundproof effect is poor, function singleness, it is coated with and functions only as decoration function on the wall, do not reach people's technical specification to indoor environment high request, and can be mouldy at sough or wet climates especially south plum rain season, it being difficult to preserve, service life is shorter, wallpaper often changed by so needs, relatively costly.Therefore, the present invention improves existing production technology and formula, prepares the wallpaper composite flame-proof body paper of diverse in function.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of flame wallpaper body paper with mosquito repellent function and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of flame wallpaper body paper with mosquito repellent function, is prepared by the raw materials in: softwood pulp 63-65, sepiolite powder 18.2-18.5, chlorinated paraffin 2.2-2.8, antimony oxide 5.1-5.3, tourmaline powder 3-4, china-hemp fibers 2-4, aethiops vegetabilis fiber 4-5, polybutylene terephthalate 5-7, Folium Artemisiae Argyi 6-7, Fericarpium Citri Limoniae 7-8, carbamide 0.2-0.4, nano antimony tin oxide 0.1-0.3.
The manufacture method of described a kind of flame wallpaper body paper with mosquito repellent function, comprises the following steps:
(1) under nitrogen protection polybutylene terephthalate is heated to molten condition; add nano antimony tin oxide, aethiops vegetabilis fiber keeps temperature magnetic agitation 1-2 hour; grind 30-40 minute after condensation, freezing 3-5 hour at subzero 15-20 DEG C, prepare organic modified nano tin-antiomony oxide;
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutral vacuum drying, condensation adds carbamide and pulverizes, and addition chlorinated paraffin, step (1) material ultrasonic grinding obtain organically-modified sepiolite powder in 30-40 minute;
(3) add water pulping by Folium Artemisiae Argyi, Fericarpium Citri Limoniae, adds china-hemp fibers and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry;
(4) softwood pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
nullThe invention have the advantage that the present invention improves existing technique and formula with sepiolite powder-antimony oxide-chlorinated paraffin for fire retardant in addition modified,By catching H and the OH free radical of the chain reaction maintaining burning in burning paper reaction gas phase,And then the reaction pattern in change gas phase,Reduce exothermic heat of reaction amount and make flame cancellation,The most also add in raw material after organically-modified for nano antimony tin oxide,Improve the brushability of body paper,It is tightly combined difficult drop-off with decorative layer,The flame wallpaper body paper firing resistance utilizing the present invention to prepare reaches GB/T14656-93 requirement,Its tearability、Folding strength、Ring crush intensity、Tensile strength is improved,And wallpaper prepared by this body paper,Not only keep the antibacterial anti-demodicid mite of Fructus Cannabis、Moisture absorption is breathed freely、The excellent in performance of absorption abnormal flavour,Also there is mosquito repellent function,Applied widely.
Detailed description of the invention
A kind of flame wallpaper body paper with mosquito repellent function, is prepared by the raw materials in: softwood pulp 63, sepiolite powder 18.2, chlorinated paraffin 2.2, antimony oxide 5.1, tourmaline powder 3, china-hemp fibers 2, aethiops vegetabilis fiber 4, polybutylene terephthalate 5, Folium Artemisiae Argyi 6, Fericarpium Citri Limoniae 7, carbamide 0.2, nano antimony tin oxide 0.1.
The manufacture method of described a kind of flame wallpaper body paper with mosquito repellent function, comprises the following steps:
(1) under nitrogen protection polybutylene terephthalate is heated to molten condition; add nano antimony tin oxide, aethiops vegetabilis fiber keeps temperature magnetic agitation 1-2 hour; grind 30-40 minute after condensation, freezing 3-5 hour at subzero 15-20 DEG C, prepare organic modified nano tin-antiomony oxide;
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutral vacuum drying, condensation adds carbamide and pulverizes, and addition chlorinated paraffin, step (1) material ultrasonic grinding obtain organically-modified sepiolite powder in 30-40 minute;
(3) add water pulping by Folium Artemisiae Argyi, Fericarpium Citri Limoniae, adds china-hemp fibers and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry;
(4) softwood pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
The flame wallpaper body paper utilizing the present invention to prepare has a following technical specification:
Tensile strength/kN m–1: 3.42;
Tearability/mN:432;
Folding strength/and time: 55;
Ring crush intensity/kN m–1: 2.72.
Claims (2)
1. a flame wallpaper body paper with mosquito repellent function, it is characterized in that, be prepared by the raw materials in: softwood pulp 63-65, sepiolite powder 18.2-18.5, chlorinated paraffin 2.2-2.8, antimony oxide 5.1-5.3, tourmaline powder 3-4, china-hemp fibers 2-4, aethiops vegetabilis fiber 4-5, polybutylene terephthalate 5-7, Folium Artemisiae Argyi 6-7, Fericarpium Citri Limoniae 7-8, carbamide 0.2-0.4, nano antimony tin oxide 0.1-0.3.
The manufacture method of a kind of flame wallpaper body paper with mosquito repellent function the most according to claim 1, it is characterised in that comprise the following steps:
(1) under nitrogen protection polybutylene terephthalate is heated to molten condition; add nano antimony tin oxide, aethiops vegetabilis fiber keeps temperature magnetic agitation 1-2 hour; grind 30-40 minute after condensation, freezing 3-5 hour at subzero 15-20 DEG C, prepare organic modified nano tin-antiomony oxide;
(2) sepiolite powder is put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour under 730-740 DEG C of temperature conditions to neutral vacuum drying, condensation adds carbamide and pulverizes, and addition chlorinated paraffin, step (1) material ultrasonic grinding obtain organically-modified sepiolite powder in 30-40 minute;
(3) add water pulping by Folium Artemisiae Argyi, Fericarpium Citri Limoniae, adds china-hemp fibers and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry;
(4) softwood pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
Priority Applications (1)
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CN201610253105.7A CN105803860A (en) | 2016-04-22 | 2016-04-22 | Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof |
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CN201610253105.7A CN105803860A (en) | 2016-04-22 | 2016-04-22 | Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof |
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CN201610253105.7A Pending CN105803860A (en) | 2016-04-22 | 2016-04-22 | Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106283792A (en) * | 2016-08-30 | 2017-01-04 | 南宁东印时代广告有限公司 | The mosquito-proof environment protection type wallpaper of noctilucence |
CN106283789A (en) * | 2016-08-30 | 2017-01-04 | 南宁东印时代广告有限公司 | Mosquito-proof environment protection type wallpaper |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08100389A (en) * | 1994-09-28 | 1996-04-16 | New Oji Paper Co Ltd | Flame retardant paper for backing vinyl wallpaper |
CN103044756A (en) * | 2012-11-25 | 2013-04-17 | 安徽六方重联机械股份有限公司 | Preparation method of packaging plastic base material film containing modified calcined fluorite powder |
CN103059696A (en) * | 2012-12-12 | 2013-04-24 | 滁州市宏源喷涂有限公司 | Powder coating containing modified sepiolite powder and preparing method thereof |
CN103756094A (en) * | 2014-01-10 | 2014-04-30 | 安徽瑞升电气科技有限公司 | Halogen-free flame-retardant polyphenyl ether cable material |
CN105220557A (en) * | 2015-09-11 | 2016-01-06 | 姚志宏 | Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof |
CN105256643A (en) * | 2015-09-11 | 2016-01-20 | 姚志宏 | Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor |
-
2016
- 2016-04-22 CN CN201610253105.7A patent/CN105803860A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08100389A (en) * | 1994-09-28 | 1996-04-16 | New Oji Paper Co Ltd | Flame retardant paper for backing vinyl wallpaper |
CN103044756A (en) * | 2012-11-25 | 2013-04-17 | 安徽六方重联机械股份有限公司 | Preparation method of packaging plastic base material film containing modified calcined fluorite powder |
CN103059696A (en) * | 2012-12-12 | 2013-04-24 | 滁州市宏源喷涂有限公司 | Powder coating containing modified sepiolite powder and preparing method thereof |
CN103756094A (en) * | 2014-01-10 | 2014-04-30 | 安徽瑞升电气科技有限公司 | Halogen-free flame-retardant polyphenyl ether cable material |
CN105220557A (en) * | 2015-09-11 | 2016-01-06 | 姚志宏 | Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof |
CN105256643A (en) * | 2015-09-11 | 2016-01-20 | 姚志宏 | Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor |
Non-Patent Citations (1)
Title |
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杨守生: ""壁纸阻燃基纸的研制"", 《新型建筑材料》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106283792A (en) * | 2016-08-30 | 2017-01-04 | 南宁东印时代广告有限公司 | The mosquito-proof environment protection type wallpaper of noctilucence |
CN106283789A (en) * | 2016-08-30 | 2017-01-04 | 南宁东印时代广告有限公司 | Mosquito-proof environment protection type wallpaper |
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Application publication date: 20160727 |