CN103756094A - Halogen-free flame-retardant polyphenyl ether cable material - Google Patents

Halogen-free flame-retardant polyphenyl ether cable material Download PDF

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Publication number
CN103756094A
CN103756094A CN201410012216.XA CN201410012216A CN103756094A CN 103756094 A CN103756094 A CN 103756094A CN 201410012216 A CN201410012216 A CN 201410012216A CN 103756094 A CN103756094 A CN 103756094A
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China
Prior art keywords
parts
minute
density polyethylene
halogen
polyphenyl ether
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Pending
Application number
CN201410012216.XA
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Chinese (zh)
Inventor
杨德华
周万华
徐善清
朱汝其
于振明
董学春
朱道德
张俊
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ANHUI RUISHENG ELECTRONIC SCIENCE & TECHNOLOGY Co Ltd
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ANHUI RUISHENG ELECTRONIC SCIENCE & TECHNOLOGY Co Ltd
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Priority to CN201410012216.XA priority Critical patent/CN103756094A/en
Publication of CN103756094A publication Critical patent/CN103756094A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
    • H01B3/427—Polyethers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a halogen-free flame-retardant polyphenyl ether cable material, which is prepared from the following raw materials in parts by weight: 30-40 parts of polyphenyl ether, 40-50 parts of medium density polyethylene, 20-30 parts of linear low density polyethylene, 1-2 parts of ammonium molybdate, 7-9 parts of precipitated white carbon black, 55-65 parts of modified sepiolite powder, 3-5 parts of MBS (Methacrylate Butadiene Styrene), 0.8-1.5 parts of vegetable oleic acid, 1.2-2.4 parts of ferrocene, 1-2 parts of vinyl tris-(2-methoxyethoxy)silane and 1.5-3 parts of glycerol triacetate.

Description

A kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS
Technical field
The present invention relates to CABLE MATERIALS field, is exactly a kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS.
Background technology
Resin dedicated cable insulating material and the cable jacket material of comprising of electric wire, raw materials used polyethylene and the polyvinyl chloride of mainly containing.Now, the above power cable of domestic 6 kV level all adopts polyethylene crosslinking Insulation Material; Low-voltage cable below 1 kV be take polyvinyl chloride insulation and pvc sheath as main, but due to polyvinyl chloride stability and electrical insulating property poor, therefore, more and more manyly by polyethylene, replaced; Communication cable is generally done insulation layer with high density polyethylene(HDPE), with linear low density polyethylene, does restrictive coating; Optical cable is mainly to use high density polyethylene(HDPE) and medium-density polyethylene as sheath material.
Summary of the invention
The object of the present invention is to provide a kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS.
Above-mentioned purpose realizes by following scheme:
A halogen-free fire-retardant polyphenyl ether CABLE MATERIALS, is characterized in that: it is that raw material by following weight parts makes:
Polyphenylene oxide 30-40, medium-density polyethylene 40-50, linear low density polyethylene 20-30, ammonium molybdate 1-2, precipitated silica 7-9, modified meerschaum powder 55-65, MBS 3-5, vegetable oil acid 0.8-1.5, ferrocene 1.2-2.4, vinyl three ('beta '-methoxy oxyethyl group) silane 1-2, Vanay 1.5-3;
The preparation method of modified meerschaum powder is:
(1) first, get sepiolite, pulverize, at 800-900 ℃, calcine after 2-4 hour, take out, pulverize, then add in deionized water, soak after 8-12 hour, dry;
(2) the dried sepiolite of step (1) is put into the hydrochloric acid soln that concentration is 4-6%, at 45-48 ℃, stir 30-50 minute, deionized water wash, oven dry;
(3) in the sepiolite after step (2) is processed, add and be equivalent to the Vanay of its weight 1-2%, after the silane coupling agent KH570 of 1-2% and suitable quantity of water stir, pack reactor into, while being then warming up to 50-55 ℃, insulation 10-18 minute, be warming up to 70-80 ℃, insulation 5-8 minute, is cooled to 33-35 ℃, insulation 6-8 minute, take out, dry, grind, cross 100-200 mesh sieve, obtain.
Described a kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS, is characterized in that:
Preparation method is:
(1) get polyphenylene oxide, linear low density polyethylene, vegetable oil acid, sodium bicarbonate, Vanay and mix by weight, in kneader, at 180-200 ℃, mediate after 8-10 minute, take out cooling;
(2), by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 180-210 ℃, obtains finished product.
Beneficial effect of the present invention is: the premium propertiess such as the present invention has good processability, halogen-free flameproof, density is low, tensile strength is high, can be widely used in cable insulating material.
Embodiment
A halogen-free fire-retardant polyphenyl ether CABLE MATERIALS, it is that raw material by following weight parts (kg) makes:
Polyphenylene oxide 40, medium-density polyethylene 40, linear low density polyethylene 30, ammonium molybdate 2, precipitated silica 9, modified meerschaum powder 65, MBS 5, vegetable oil acid 1.5, ferrocene 1.8, vinyl three ('beta '-methoxy oxyethyl group) silane 2, Vanay 1.8;
The preparation method of modified meerschaum powder is:
(1) first, get sepiolite, pulverize, at 900 ℃, calcine after 4 hours, take out, pulverize, then add in deionized water, soak after 12 hours, dry;
(2) the dried sepiolite of step (1) being put into concentration is 4% hydrochloric acid soln, at 48 ℃, stirs deionized water wash, oven dry 50 minutes;
(3) after adding the Vanay, 1.2% silane coupling agent KH570 and the suitable quantity of water that are equivalent to its weight 2% to stir in the sepiolite after step (2) is processed, pack reactor into, while being then warming up to 55 ℃, be incubated 18 minutes, be warming up to 80 ℃, be incubated 8 minutes, be cooled to 35 ℃, be incubated 8 minutes, take out, dry, grind, cross 200 mesh sieves, obtain.
Described a kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS, preparation method is:
(1) get polyphenylene oxide, linear low density polyethylene, vegetable oil acid, sodium bicarbonate, Vanay and mix by weight, in kneader, at 190 ℃, mediate after 10 minutes, take out cooling;
(2), by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 195 ℃, obtains finished product.
The present embodiment is carried out to performance test, tensile strength 16.5MPa, elongation at break 387%, fire-retardant rank V0.

Claims (2)

1. a halogen-free fire-retardant polyphenyl ether CABLE MATERIALS, is characterized in that: it is that raw material by following weight parts makes:
Polyphenylene oxide 30-40, medium-density polyethylene 40-50, linear low density polyethylene 20-30, ammonium molybdate 1-2, precipitated silica 7-9, modified meerschaum powder 55-65, MBS 3-5, vegetable oil acid 0.8-1.5, ferrocene 1.2-2.4, vinyl three ('beta '-methoxy oxyethyl group) silane 1-2, Vanay 1.5-3;
The preparation method of modified meerschaum powder is:
(1) first, get sepiolite, pulverize, at 800-900 ℃, calcine after 2-4 hour, take out, pulverize, then add in deionized water, soak after 8-12 hour, dry;
(2) the dried sepiolite of step (1) is put into the hydrochloric acid soln that concentration is 4-6%, at 45-48 ℃, stir 30-50 minute, deionized water wash, oven dry;
(3) in the sepiolite after step (2) is processed, add and be equivalent to the Vanay of its weight 1-2%, after the silane coupling agent KH570 of 1-2% and suitable quantity of water stir, pack reactor into, while being then warming up to 50-55 ℃, insulation 10-18 minute, be warming up to 70-80 ℃, insulation 5-8 minute, is cooled to 33-35 ℃, insulation 6-8 minute, take out, dry, grind, cross 100-200 mesh sieve, obtain.
2. a kind of halogen-free fire-retardant polyphenyl ether CABLE MATERIALS according to claim 1, is characterized in that:
Preparation method is:
(1) get polyphenylene oxide, linear low density polyethylene, vegetable oil acid, sodium bicarbonate, Vanay and mix by weight, in kneader, at 180-200 ℃, mediate after 8-10 minute, take out cooling;
(2), by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 180-210 ℃, obtains finished product.
CN201410012216.XA 2014-01-10 2014-01-10 Halogen-free flame-retardant polyphenyl ether cable material Pending CN103756094A (en)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104051056A (en) * 2014-05-30 2014-09-17 安徽三和电力技术有限公司 Insulating material for power grid device
CN105780602A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 High strength flame retardant base wallpaper and manufacture method thereof
CN105780603A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 Flame retardant base wallpaper added with nanometer carbon crystal powder and producing method thereof
CN105780600A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 Flame-retardant base wallpaper capable of removing formaldehyde and odor and making method for flame-retardant base wallpaper
CN105803860A (en) * 2016-04-22 2016-07-27 安徽索亚装饰材料有限公司 Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof
CN105803859A (en) * 2016-04-22 2016-07-27 安徽索亚装饰材料有限公司 High-toughness warm-keeping type flame-retardant wallpaper raw paper and manufacturing method of high-toughness warm-keeping type flame-retardant base wallpaper
CN105821714A (en) * 2016-04-22 2016-08-03 安徽索亚装饰材料有限公司 Flame-retardant wallpaper body paper with effect of releasing negative ions and manufacture method thereof
CN105862499A (en) * 2016-04-22 2016-08-17 安徽索亚装饰材料有限公司 Anti-flaming raw wall paper with function of purifying indoor air and manufacturing method thereof
CN105862500A (en) * 2016-04-22 2016-08-17 安徽索亚装饰材料有限公司 Breathable and mildew-proof type flame-retardant wall raw paper and preparation method thereof
CN105908575A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Germanium fiber-containing heat insulation and flame retardation wallpaper raw paper and making method thereof
CN105908573A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Water resisting flame retardation wallpaper raw paper and making method thereof
CN105908561A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Wear-resistant flame retardation wallpaper raw paper and making method thereof
CN105908559A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Environmentally-friendly high-printability flame retardation wallpaper raw paper and making method thereof
CN105908574A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Flame retardation wallpaper raw paper releasing clean air, and making method thereof
CN105908571A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Moisture and contamination resisting flame retardation wallpaper raw paper and making method thereof
CN105908572A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof
CN105926370A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Lasting antibacterial flame-retardant wallpaper base paper and preparation method thereof
CN105926346A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Flame-retardant wallpaper base paper with functions of sound insulation and noise reduction and preparation method thereof
CN105926349A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Antistatic flame-retardant wallpaper base paper and preparation method thereof
CN105926342A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Bio-based scratch-resistant type flame-retardant wallpaper base paper and preparation method thereof
CN110885489A (en) * 2019-12-16 2020-03-17 良和包装(浙江)有限公司 Low-temperature-resistant polyethylene plastic barrel and preparation process thereof

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104051056A (en) * 2014-05-30 2014-09-17 安徽三和电力技术有限公司 Insulating material for power grid device
CN105780602A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 High strength flame retardant base wallpaper and manufacture method thereof
CN105780603A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 Flame retardant base wallpaper added with nanometer carbon crystal powder and producing method thereof
CN105780600A (en) * 2016-04-22 2016-07-20 安徽索亚装饰材料有限公司 Flame-retardant base wallpaper capable of removing formaldehyde and odor and making method for flame-retardant base wallpaper
CN105803860A (en) * 2016-04-22 2016-07-27 安徽索亚装饰材料有限公司 Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof
CN105803859A (en) * 2016-04-22 2016-07-27 安徽索亚装饰材料有限公司 High-toughness warm-keeping type flame-retardant wallpaper raw paper and manufacturing method of high-toughness warm-keeping type flame-retardant base wallpaper
CN105821714A (en) * 2016-04-22 2016-08-03 安徽索亚装饰材料有限公司 Flame-retardant wallpaper body paper with effect of releasing negative ions and manufacture method thereof
CN105862499A (en) * 2016-04-22 2016-08-17 安徽索亚装饰材料有限公司 Anti-flaming raw wall paper with function of purifying indoor air and manufacturing method thereof
CN105862500A (en) * 2016-04-22 2016-08-17 安徽索亚装饰材料有限公司 Breathable and mildew-proof type flame-retardant wall raw paper and preparation method thereof
CN105908575A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Germanium fiber-containing heat insulation and flame retardation wallpaper raw paper and making method thereof
CN105908573A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Water resisting flame retardation wallpaper raw paper and making method thereof
CN105908561A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Wear-resistant flame retardation wallpaper raw paper and making method thereof
CN105908559A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Environmentally-friendly high-printability flame retardation wallpaper raw paper and making method thereof
CN105908574A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Flame retardation wallpaper raw paper releasing clean air, and making method thereof
CN105908571A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Moisture and contamination resisting flame retardation wallpaper raw paper and making method thereof
CN105908572A (en) * 2016-04-22 2016-08-31 安徽索亚装饰材料有限公司 Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof
CN105926370A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Lasting antibacterial flame-retardant wallpaper base paper and preparation method thereof
CN105926346A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Flame-retardant wallpaper base paper with functions of sound insulation and noise reduction and preparation method thereof
CN105926349A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Antistatic flame-retardant wallpaper base paper and preparation method thereof
CN105926342A (en) * 2016-04-22 2016-09-07 安徽索亚装饰材料有限公司 Bio-based scratch-resistant type flame-retardant wallpaper base paper and preparation method thereof
CN110885489A (en) * 2019-12-16 2020-03-17 良和包装(浙江)有限公司 Low-temperature-resistant polyethylene plastic barrel and preparation process thereof

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