CN103992558A - Cable material containing mica powder - Google Patents
Cable material containing mica powder Download PDFInfo
- Publication number
- CN103992558A CN103992558A CN201410172306.5A CN201410172306A CN103992558A CN 103992558 A CN103992558 A CN 103992558A CN 201410172306 A CN201410172306 A CN 201410172306A CN 103992558 A CN103992558 A CN 103992558A
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- CN
- China
- Prior art keywords
- parts
- powder
- mica powder
- cable material
- dicyclopentadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a cable material containing mica powder. The cable material is prepared from the following raw materials by weight: 30 to 40 parts of isotactic polypropylene, 0.1 to 0.2 part of urotropine, 1 to 2 parts of molybdenum oxide, 0.4 to 0.6 part of dibutyltin dilaurate, 10 to 20 parts of powdered nitrile rubber, 20 to 40 parts of shell powder, 0.1 to 0.4 part of beta-dione, 10 to 25 parts of attapulgite, 13 to 15 parts of tricapryl trimellitate, 50 to 70 parts of aluminum hydroxide, 4 to 6 parts of magnesium hydroxide, 1 to 2 parts of ammonium polyphosphate, 1 to 2 parts of dioctyl phthalate, 1 to 3 parts of a bamboo shoot shell fiber, 0.1 to 0.2 part of epoxidized soybean oil, 1 to 2 parts of polyacrylonitrile, 1 to 2 parts of dicyclopentadiene, 0.2 to 0.4 part of polyisobutylene, 0.1 to 0.2 part of an antioxidant 1010, 1 to 2 parts of calcium stearate, 13 to 36 parts of an ABS resin, 80 to 85 parts of SG-3 PVC resin powder and 3 to 5 parts of modified mica powder. The cable material produced in the invention has good physical and mechanical properties; and through addition of modified mica powder particles during preparation, compatibility of the raw materials is enhanced.
Description
Technical field
The present invention relates to CABLE MATERIALS field, is exactly a kind of CABLE MATERIALS that contains mica powder.
Background technology
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, comprising multiple kinds such as rubber, plastics, nylon.CABLE MATERIALS manufacturing enterprise is taking cable manufacturing enterprise as user, as long as live wire cable demand just has the market of CABLE MATERIALS.In electric wire product, except the bare wire such as Aluminium Cable Steel Reinforced, insulated wire product, nearly all need insulation layer mouth.Nearly 5000 of live wire cable manufacturing enterprise of China at present, there are again upgrading urban and rural power grids, development of the West Regions and the great demand of communications facility big area upgrading to electric wire product, thereby from for some time, CABLE MATERIALS has future develop widely in China.
Summary of the invention
The object of the present invention is to provide a kind of CABLE MATERIALS that contains mica powder.
Above-mentioned purpose realizes by following scheme:
A kind of CABLE MATERIALS that contains mica powder, it is characterized in that: it is to be made by the raw material of following weight parts: isotatic polypropylene 30-40, urotropine 0.1-0.2, molybdenum oxide 1-2, dibutyl tin laurate 0.4-0.6, Powdered acrylonitrile-butadiene rubber 10-20, oyster shell whiting 20-40, beta-diketon 0.1-0.4, attapulgite 10-25, trioctyl trimellitate 13-15, aluminium hydroxide 50-70, magnesium hydroxide 4-6, ammonium polyphosphate 1-2, dioctyl ester 1-2, bamboo shoot case fibre 1-3, epoxy soybean oil 0.1-0.2, polyacrylonitrile 1-2, dicyclopentadiene 1-2, polyisobutene 0.2-0.4, antioxidant 1010 0.1-0.2, calcium stearate 1-2, ABS resin 13-36, SG-3PVC resin-oatmeal 80-85, modified micaceous powder 3-5,
In the hydrochloric acid that the preparation method of modified micaceous powder is is 12-18% by mica powder concentration, steep while stirring after 2-3 hour, refilter, clean with deionized water, dry, after the silane coupling agent DL171 that is equivalent to 2-nonyl-phthalate ester, the 2-4% of celestite powder, the 1-2% of ground barium sulfate, the 8-12% of mica powder weight 2-4% mixes, ovendry power is broken into powder and get final product.
Described a kind of CABLE MATERIALS that contains mica powder, is characterized in that:
Preparation method is:
(1) get ABS resin, dibutyl tin laurate, dicyclopentadiene, oyster shell whiting and mix by weight, in kneader, at 150-160 DEG C, mediate after 7-9 minute, take out cooling;
(2), by the cooled material of step (1) gained and the each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 168-180 DEG C, obtains finished product.
Beneficial effect of the present invention is: the CABLE MATERIALS that the present invention produces has good physical and mechanical properties,, by add the particle of modified micaceous powder in preparation, strengthen the consistency of each stock yard.
Embodiment
A kind of CABLE MATERIALS that contains mica powder, it is to be made by the raw material of following weight KG: isotatic polypropylene 40, urotropine 0.2, molybdenum oxide 2, dibutyl tin laurate 0.6, Powdered acrylonitrile-butadiene rubber 20, oyster shell whiting 20, beta-diketon 0.4, attapulgite 25, trioctyl trimellitate 15, aluminium hydroxide 70, magnesium hydroxide 6, ammonium polyphosphate 2, dioctyl ester 2, bamboo shoot case fibre 1, epoxy soybean oil 0.2, polyacrylonitrile 2, dicyclopentadiene 1, polyisobutene 0.4, antioxidant 1010 0.2, calcium stearate 2, ABS resin 36, SG-3PVC resin-oatmeal 85, modified micaceous powder 5,
In the hydrochloric acid that the preparation method of modified micaceous powder is is 18% by mica powder concentration, steep while stirring after 3 hours, refilter, clean with deionized water, dry, after ground barium sulfate, 12% celestite powder, 2% 2-nonyl-phthalate ester, 4% the silane coupling agent DL171 that is equivalent to mica powder weight 4% mixes, ovendry power is broken into powder and get final product.
Described a kind of CABLE MATERIALS that contains mica powder,
Preparation method is:
(1) get ABS resin, dibutyl tin laurate, dicyclopentadiene, oyster shell whiting and mix by weight, in kneader, at 150 DEG C, mediate after 7 minutes, take out cooling;
(2), by the cooled material of step (1) gained and the each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 168-180 DEG C, obtains finished product.
The present embodiment is carried out to performance test, tensile strength 19.2MPa, elongation at break 480%, fire-retardant rank V2.
Claims (2)
1. a CABLE MATERIALS that contains mica powder, it is characterized in that: it is to be made by the raw material of following weight parts: isotatic polypropylene 30-40, urotropine 0.1-0.2, molybdenum oxide 1-2, dibutyl tin laurate 0.4-0.6, Powdered acrylonitrile-butadiene rubber 10-20, oyster shell whiting 20-40, beta-diketon 0.1-0.4, attapulgite 10-25, trioctyl trimellitate 13-15, aluminium hydroxide 50-70, magnesium hydroxide 4-6, ammonium polyphosphate 1-2, dioctyl ester 1-2, bamboo shoot case fibre 1-3, epoxy soybean oil 0.1-0.2, polyacrylonitrile 1-2, dicyclopentadiene 1-2, polyisobutene 0.2-0.4, antioxidant 1010 0.1-0.2, calcium stearate 1-2, ABS resin 13-36, SG-3PVC resin-oatmeal 80-85, modified micaceous powder 3-5,
In the hydrochloric acid that the preparation method of modified micaceous powder is is 12-18% by mica powder concentration, steep while stirring after 2-3 hour, refilter, clean with deionized water, dry, after the silane coupling agent DL171 that is equivalent to 2-nonyl-phthalate ester, the 2-4% of celestite powder, the 1-2% of ground barium sulfate, the 8-12% of mica powder weight 2-4% mixes, ovendry power is broken into powder and get final product.
2. a kind of CABLE MATERIALS that contains mica powder according to claim 1, is characterized in that:
Preparation method is:
(1) get ABS resin, dibutyl tin laurate, dicyclopentadiene, oyster shell whiting and mix by weight, in kneader, at 150-160 DEG C, mediate after 7-9 minute, take out cooling;
(2), by the cooled material of step (1) gained and the each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature at 168-180 DEG C, obtains finished product.
Priority Applications (1)
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CN201410172306.5A CN103992558A (en) | 2014-04-25 | 2014-04-25 | Cable material containing mica powder |
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CN201410172306.5A CN103992558A (en) | 2014-04-25 | 2014-04-25 | Cable material containing mica powder |
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CN201410172306.5A Pending CN103992558A (en) | 2014-04-25 | 2014-04-25 | Cable material containing mica powder |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104212064A (en) * | 2014-09-22 | 2014-12-17 | 无为县华祥电缆材料有限公司 | High-strength high-toughness cable sheath material |
CN104212175A (en) * | 2014-08-21 | 2014-12-17 | 安徽吉安特种线缆制造有限公司 | Modified mica for fire-resistant silicon rubber power cable material and preparation method of modified mica |
CN104900333A (en) * | 2015-04-29 | 2015-09-09 | 安徽五洲特种电缆集团有限公司 | Cable for automobiles |
CN104974425A (en) * | 2015-07-19 | 2015-10-14 | 李孟平 | Preparation method of weather-resistant cable sheath material |
CN105199295A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | High-thermostability flame-retardant mine rubber jacketed cable sheathing compound |
CN106046419A (en) * | 2016-08-05 | 2016-10-26 | 雷春生 | Preparation method of high pressure resistant insulating material |
CN107987429A (en) * | 2017-12-27 | 2018-05-04 | 成都新柯力化工科技有限公司 | A kind of high voltage direct current cable material and preparation method for suppressing space charge accumulation |
CN108034115A (en) * | 2017-12-19 | 2018-05-15 | 上海至正道化高分子材料股份有限公司 | A kind of used in nuclear power station cross-linking radiation insulating material for communication cables and preparation method thereof |
CN108250763A (en) * | 2017-11-28 | 2018-07-06 | 安徽华源电缆集团有限公司 | A kind of high intensity braiding layer cable material |
CN109135047A (en) * | 2018-06-20 | 2019-01-04 | 安徽瑞鑫自动化仪表有限公司 | A kind of field high compressive strength detection cable insulation preparation method for material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103540064A (en) * | 2013-10-29 | 2014-01-29 | 绿宝电缆(集团)有限公司 | Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material |
CN103554823A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Heat-resistant and corrosion-resistant insulating material for wire harnesses of refrigerator |
CN103554570A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | High-strength wear-resisting nitrile butadiene rubber cable material |
-
2014
- 2014-04-25 CN CN201410172306.5A patent/CN103992558A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103554570A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | High-strength wear-resisting nitrile butadiene rubber cable material |
CN103540064A (en) * | 2013-10-29 | 2014-01-29 | 绿宝电缆(集团)有限公司 | Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material |
CN103554823A (en) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | Heat-resistant and corrosion-resistant insulating material for wire harnesses of refrigerator |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104212175A (en) * | 2014-08-21 | 2014-12-17 | 安徽吉安特种线缆制造有限公司 | Modified mica for fire-resistant silicon rubber power cable material and preparation method of modified mica |
CN104212064A (en) * | 2014-09-22 | 2014-12-17 | 无为县华祥电缆材料有限公司 | High-strength high-toughness cable sheath material |
CN104900333A (en) * | 2015-04-29 | 2015-09-09 | 安徽五洲特种电缆集团有限公司 | Cable for automobiles |
CN104974425A (en) * | 2015-07-19 | 2015-10-14 | 李孟平 | Preparation method of weather-resistant cable sheath material |
CN105199295A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | High-thermostability flame-retardant mine rubber jacketed cable sheathing compound |
CN106046419A (en) * | 2016-08-05 | 2016-10-26 | 雷春生 | Preparation method of high pressure resistant insulating material |
CN108250763A (en) * | 2017-11-28 | 2018-07-06 | 安徽华源电缆集团有限公司 | A kind of high intensity braiding layer cable material |
CN108034115A (en) * | 2017-12-19 | 2018-05-15 | 上海至正道化高分子材料股份有限公司 | A kind of used in nuclear power station cross-linking radiation insulating material for communication cables and preparation method thereof |
CN107987429A (en) * | 2017-12-27 | 2018-05-04 | 成都新柯力化工科技有限公司 | A kind of high voltage direct current cable material and preparation method for suppressing space charge accumulation |
CN109135047A (en) * | 2018-06-20 | 2019-01-04 | 安徽瑞鑫自动化仪表有限公司 | A kind of field high compressive strength detection cable insulation preparation method for material |
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Application publication date: 20140820 |
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