CN103540064A - Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material - Google Patents

Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material Download PDF

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Publication number
CN103540064A
CN103540064A CN201310519225.3A CN201310519225A CN103540064A CN 103540064 A CN103540064 A CN 103540064A CN 201310519225 A CN201310519225 A CN 201310519225A CN 103540064 A CN103540064 A CN 103540064A
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parts
polyvinyl chloride
powder
oil
modified polyvinyl
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CN201310519225.3A
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CN103540064B (en
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谢华
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Jiangsu Xiangyun Plastic Technology Co ltd
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Lvbao Cable Group Co Ltd
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Abstract

The invention relates to a cable material, and particularly relates to an oil-proof flame-retardant modified polyvinyl chloride cable sheathing material. The material comprises the following raw materials in parts by weight: 35-38 parts of SG-2 polyvinyl chloride, 12-14 parts of light calcium carbonate, 2-3 parts of stearic acid, 7-9 parts of titanium dioxide, 23-26 parts of chlorinated polyethylene, 12-14 parts of isotactic polypropylene, 6-9 parts of acrylonitrile butadiene styrene (ABS) high-glue powder, 7-9 parts of ethylene vinyl acetate (EVA), 14-18 parts of nano celestite powder, 1-2 parts of triethanolamine, 23-24 parts of castor oil, 1-2 parts of bisphenol A, 12-13 parts of semi-refined paraffin wax, and 14-16 parts of assistant. By adopting the insulated material, the advantages of the raw materials such as the SG-2 polyvinyl chloride, the chlorinated polyethylene, the isotactic polypropylene and the like are combined; the prepared material is high in strength, good in weathering resistance, ozone resistance, oil-resistant flame retardancy and chemical stability, safe to use, and wide in market demand prospect, and can be widely applied to fabrication of kinds of cable sheath insulated materials.

Description

The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant
Technical field
The present invention relates to a kind of CABLE MATERIALS, be specifically related to flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant and preparation method thereof.
Background technology
Along with expanding economy, need to use the place of cable to become diversified, the performance index of cable jacket material have been had to stricter and various requirement, such as insulativity, tensile strength, use temperature, the indexs such as flame retardant properties all have strict requirement, constantly improve the performance of sheath material, it is the active demand of economy and social development, there is poor fire more in traditional sheath material, poor chemical stability, high temperature is yielding, poor mechanical property, the problems such as work-ing life is short, bring a lot of inconvenience to actual use, even threaten people's the security of the lives and property, therefore, be badly in need of changing original sheath material formula, improve material property, with the various demand in appropriate cable market.
Summary of the invention
The object of the invention is to, provide a kind of oil resistant flame-retardant modified polyvinyl chloride cable sheathing compound, promoted the performance of traditional polychloroethylene blended material, make it possess good mechanical property and processing characteristics, can adapt to specific environment for use condition, to achieve these goals, the technical solution used in the present invention is as follows:
A flame-retardant modified polyvinyl chloride cable sheathing compound, is characterized in that, the component that this invention material comprises following weight part: SG-2 polyvinyl chloride 35-38, light calcium carbonate 12-14, stearic acid 2-3, titanium dioxide 7-9, chlorinatedpolyethylene 23-26, isotatic polypropylene 12-14, ABS high glue powder 6-9, EVA 7-9, nanometer celestite powder 14-18, trolamine 1-2, Viscotrol C 23-24, dihydroxyphenyl propane 1-2, SEMI-REFINED PARAFFIN WAX 12-13, auxiliary agent 14-16.
The raw material that described auxiliary agent comprises following weight part: lazurite 20-25, linking agent TAC 4-5, Viscoat 295 2-3, Vulcanization accelerator TMTD 1-2, polyisobutene 2-3, aluminate coupling agent DL-411 1-2, ferrocene 2-3, dibasic lead phosphite 1-2, aluminum nitride powder 2-3, nanometer jade powder 2-3, methyl acrylate 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into calcining furnace by lazurite to calcine 3-4 hour at 550-570 ℃, cooling, be ground into and put into 12-15% hydrochloric acid soln after 50-100 order and soak 2-3 hour, filter out lazurite powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
The described flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant, its preparation method is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 110-170 ℃, mediate 6-15min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
The present invention combines the advantage of the raw materials such as SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA, promoted the performance of traditional polychloroethylene blended material, make it have good processing characteristics and mechanical property, the strength of materials of preparation is high, weather-proof aging, resistance to ozone, oil resistant is fire-retardant, and chemical stability is good, long service life, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Embodiment
The raw material that the present embodiment comprises following weight part: SG-2 polyvinyl chloride 38, light calcium carbonate 14, stearic acid 3, titanium dioxide 9, chlorinatedpolyethylene 26, isotatic polypropylene 14, ABS high glue powder 8, EVA 8, nanometer celestite powder 18, trolamine 2, Viscotrol C 24, dihydroxyphenyl propane 2, SEMI-REFINED PARAFFIN WAX 13, auxiliary agent 15.
The raw material that described auxiliary agent comprises following weight part: lazurite 25, linking agent TAC 5, Viscoat 295 3, Vulcanization accelerator TMTD 2, polyisobutene 3, aluminate coupling agent DL-411 2, ferrocene 3, dibasic lead phosphite 2, aluminum nitride powder 3, nanometer jade powder 3, methyl acrylate 3, Fructus Zanthoxyli oil 2; Preparation method puts into calcining furnace by lazurite at 570 ℃, to calcine 4 hours, cooling, is ground into put into 15% hydrochloric acid soln after 80 orders and soak 3 hours, filters out lazurite powder, clear water is cleaned, and dries, and is ground into 300 order powder, mix with other remaining component, grinding distribution 2 hours, obtains.
The described flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant, its preparation method is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 160 ℃, mediate 10min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
The performance test results of material of the present invention is: tensile strength is 18.8Mpa, elongation at break is 435%, after 90 ℃ * 70h of IRM902 oil processes, tensile strength and elongation at break are respectively 17.9Mpa, 402%, after 136 ℃ * 168h hot air aging, stretching strength retentivity 98.4%, elongation at break conservation rate is that 98.2%, 20 ℃ of volume specific resistance is 1.25 * 10 14Ω m, through 15% the NaCl solution soaking of 60 ℃, after 7 days, the pick up of material is 0.0026%, and after soaking, volume specific resistance velocity of variation is 0.003%, through 80 ℃ of toluene solvants, soak after 7 days, without obviously swelling and cracking phenomena, under the condition of ozone concn 0.025%, 26 ℃ * 20h, without cracking phenomena, after the artificial weathering test through 1000 hours, the slight velocity of variation that stretches is 28.4%, and elongation at break velocity of variation is 29.1%, and oxygen index is 41%.

Claims (2)

1. the flame-retardant modified polyvinyl chloride cable sheathing compound of oil resistant, is characterized in that, this Insulation Material is comprised of the raw material of following weight part: SG-2 polyvinyl chloride 35-38, light calcium carbonate 12-14, stearic acid 2-3, titanium dioxide 7-9, chlorinatedpolyethylene 23-26, isotatic polypropylene 12-14, ABS high glue powder 6-9, EVA 7-9, nanometer celestite powder 14-18, trolamine 1-2, Viscotrol C 23-24, dihydroxyphenyl propane 1-2, SEMI-REFINED PARAFFIN WAX 12-13, auxiliary agent 14-16;
The raw material that described auxiliary agent comprises following weight part: lazurite 20-25, linking agent TAC 4-5, Viscoat 295 2-3, Vulcanization accelerator TMTD 1-2, polyisobutene 2-3, aluminate coupling agent DL-411 1-2, ferrocene 2-3, dibasic lead phosphite 1-2, aluminum nitride powder 2-3, nanometer jade powder 2-3, methyl acrylate 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into calcining furnace by lazurite to calcine 3-4 hour at 550-570 ℃, cooling, be ground into and put into 12-15% hydrochloric acid soln after 50-100 order and soak 2-3 hour, filter out lazurite powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
2. the flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant as claimed in claim 1, its manufacture craft is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 110-170 ℃, mediate 6-15min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
CN201310519225.3A 2013-10-29 2013-10-29 The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant Expired - Fee Related CN103540064B (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881268A (en) * 2014-02-27 2014-06-25 安徽伊法拉电力科技有限公司 Antiflaming shock resistant modified PVC cable sheath material
CN103992558A (en) * 2014-04-25 2014-08-20 安徽华鸿电气股份有限公司 Cable material containing mica powder
CN104004290A (en) * 2014-04-22 2014-08-27 天长市富信电子有限公司 Power line sheath material for hot and humid areas and preparation method thereof
CN104130453A (en) * 2014-06-26 2014-11-05 合肥和安机械制造有限公司 Filler specialized for breakdown-resistant cable sheath material, and preparation method thereof
CN104559036A (en) * 2015-01-23 2015-04-29 淮南文峰航天电缆有限公司 Light-power high-light-stability cable material and preparation method thereof
CN105175935A (en) * 2015-08-28 2015-12-23 苏州莱特复合材料有限公司 PVC plastic alloy and preparation method therefor
CN105482295A (en) * 2015-12-15 2016-04-13 中冠电缆有限公司 High-hydrophobic and high-strength modified polyvinyl chloride (PVC) cable material and preparation method thereof
CN105860304A (en) * 2016-06-01 2016-08-17 许婷 Low-temperature-resistant cable material and preparation method thereof
CN106750937A (en) * 2016-12-20 2017-05-31 安徽华天电缆有限公司 One kind is unlikely to deform rigid polyvinyl chloride cable material
CN107090147A (en) * 2017-06-16 2017-08-25 安徽滁州德威新材料有限公司 A kind of low-temperature impact-resistant modified polyvinyl chloride CABLE MATERIALS
CN107163444A (en) * 2017-07-03 2017-09-15 安徽真劲智能科技有限公司 A kind of electronic tag PVC printing layer rapidoprints
CN114479434A (en) * 2021-12-28 2022-05-13 苏州爱得华塑化有限公司 Preparation process of flame-retardant material for cable protective sleeve of charging pile

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CN1235175A (en) * 1998-05-12 1999-11-17 广州金发科技发展有限公司 Halide-free smokeless flame-resistant thermoplatstic polyolefine composition and preparation thereof
CN102352057A (en) * 2011-09-08 2012-02-15 西北师范大学 Non-halogen composite flame retardant and application thereof in preparation of flame retardant thermoplastic elastomer composite
CN103122097A (en) * 2013-01-22 2013-05-29 安徽华津电缆集团有限公司 Thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and preparation method thereof
CN103232631A (en) * 2013-06-03 2013-08-07 北京理工大学 Halogen-free low-smoke flame-retardant cable sheath material and preparation method of same
CN103265740A (en) * 2013-04-27 2013-08-28 安徽省康利亚实业有限公司 Ozone-resistant cable sheath material

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Publication number Priority date Publication date Assignee Title
CN1235175A (en) * 1998-05-12 1999-11-17 广州金发科技发展有限公司 Halide-free smokeless flame-resistant thermoplatstic polyolefine composition and preparation thereof
CN102352057A (en) * 2011-09-08 2012-02-15 西北师范大学 Non-halogen composite flame retardant and application thereof in preparation of flame retardant thermoplastic elastomer composite
CN103122097A (en) * 2013-01-22 2013-05-29 安徽华津电缆集团有限公司 Thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and preparation method thereof
CN103265740A (en) * 2013-04-27 2013-08-28 安徽省康利亚实业有限公司 Ozone-resistant cable sheath material
CN103232631A (en) * 2013-06-03 2013-08-07 北京理工大学 Halogen-free low-smoke flame-retardant cable sheath material and preparation method of same

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881268B (en) * 2014-02-27 2016-03-09 安徽伊法拉电力科技有限公司 A kind of flame-proof impact resistant-modified PVC cable sheath material
CN103881268A (en) * 2014-02-27 2014-06-25 安徽伊法拉电力科技有限公司 Antiflaming shock resistant modified PVC cable sheath material
CN104004290A (en) * 2014-04-22 2014-08-27 天长市富信电子有限公司 Power line sheath material for hot and humid areas and preparation method thereof
CN103992558A (en) * 2014-04-25 2014-08-20 安徽华鸿电气股份有限公司 Cable material containing mica powder
CN104130453A (en) * 2014-06-26 2014-11-05 合肥和安机械制造有限公司 Filler specialized for breakdown-resistant cable sheath material, and preparation method thereof
CN104559036A (en) * 2015-01-23 2015-04-29 淮南文峰航天电缆有限公司 Light-power high-light-stability cable material and preparation method thereof
CN105175935A (en) * 2015-08-28 2015-12-23 苏州莱特复合材料有限公司 PVC plastic alloy and preparation method therefor
CN105482295A (en) * 2015-12-15 2016-04-13 中冠电缆有限公司 High-hydrophobic and high-strength modified polyvinyl chloride (PVC) cable material and preparation method thereof
CN105860304A (en) * 2016-06-01 2016-08-17 许婷 Low-temperature-resistant cable material and preparation method thereof
CN106750937A (en) * 2016-12-20 2017-05-31 安徽华天电缆有限公司 One kind is unlikely to deform rigid polyvinyl chloride cable material
CN107090147A (en) * 2017-06-16 2017-08-25 安徽滁州德威新材料有限公司 A kind of low-temperature impact-resistant modified polyvinyl chloride CABLE MATERIALS
CN107163444A (en) * 2017-07-03 2017-09-15 安徽真劲智能科技有限公司 A kind of electronic tag PVC printing layer rapidoprints
CN114479434A (en) * 2021-12-28 2022-05-13 苏州爱得华塑化有限公司 Preparation process of flame-retardant material for cable protective sleeve of charging pile

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Inventor after: Guo Xiaojing

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Patentee before: LVBAO CABLE (Group) Co.,Ltd.

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Effective date of registration: 20190730

Address after: 214500 No. 1 Wei2 Road, Chengnan Park, Jingjiang City, Taizhou City, Jiangsu Province

Patentee after: Jiangsu Xiangyun Plastic Technology Co.,Ltd.

Address before: 300000 Wenyueyuan 2-4-301, South Side of Meishi Highway, Chenzui Town, Wuqing District, Tianjin

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Granted publication date: 20151230