CN103351549B - A kind of EPDM and PVC composite cable material and preparation method thereof - Google Patents
A kind of EPDM and PVC composite cable material and preparation method thereof Download PDFInfo
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- CN103351549B CN103351549B CN201310243344.0A CN201310243344A CN103351549B CN 103351549 B CN103351549 B CN 103351549B CN 201310243344 A CN201310243344 A CN 201310243344A CN 103351549 B CN103351549 B CN 103351549B
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- epdm
- cable material
- carbon black
- composite cable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
A kind of EPDM and PVC composite cable material and preparation method thereof, it is characterized in that being made up of the raw material of following weight part: terpolymer EP rubber 5-9, SG-3PVC45-48, polyisobutene 8-12, 3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, Microcrystalline Wax 3-4, propionate 5-6, octyl epoxy stearate 1-2, epoxidation tri-glyceride 6-8, Zinc Stearate 1-2, dibasic lead phosphite 1-2, fast extrusion carbon black N660? 30-35, carbon black N220? 13-16, titanate coupling agent TMC-TTS? 2-3, zinc oxide 1-2, Na-22? 1-2, vulkacit D TDM? 1-2, 2-thiol group benzimidazolyl 1-2, modification infusorial earth 6-8.The material that the present invention produces, except the performance of the PVC cable material of inheriting tradition, also has more soft characteristic, simplifies production process, reduce production cost, breach the limitation of traditional sulfuration process.
Description
Technical field
The invention belongs to CABLE MATERIALS technical field, more particularly, relate to a kind of EPDM and PVC composite cable material and preparation method thereof.
Background technology
Wire cable material, be mixed primarily of resin material, stopping composition, softening agent, anti-aging agent, fire retardant, oxidation inhibitor etc., formula material mainly concentrates on some conventional compositions, cause the not high or high in cost of production problem of CABLE MATERIALS technical indicator thus, such as volume specific resistance is on the low side, high temperature resistant, low temperature resistant, flame retardant resistance, insulativity etc. can not meet the requirement of cable producer to insulation-grade sheath material more high electrical performance.
Summary of the invention
The object of this invention is to provide a kind of EPDM and PVC composite cable material and preparation method thereof, the present invention
The technical solution adopted in the present invention is:
A kind of EPDM and PVC composite cable material, is characterized in that being made up of the raw material of following weight part:
Terpolymer EP rubber 5-9, SG-3PVC45-48, polyisobutene 8-12, 3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, Microcrystalline Wax 3-4, propionate 5-6, octyl epoxy stearate 1-2, epoxidation tri-glyceride 6-8, Zinc Stearate 1-2, dibasic lead phosphite 1-2, fast extrusion carbon black N66030-35, carbon black N22013-16, titanate coupling agent TMC-TTS2-3, zinc oxide 1-2, Na-221-2, vulkacit D TDM1-2, 2-thiol group benzimidazolyl 1-2, modification infusorial earth 6-8.
Described modification infusorial earth is obtained by following methods:
Calcine 3-4 hour at diatomite being put into 460-480 DEG C, take out, cooling, puts into 10-12% sodium hydroxide solution and soaks 2-3 hour, takes out, and cleans with pure water, dries grinding powder; Add the aluminium nitride, the ferrocene of 3-4%, the Zirconium tetrafluoride of 2-3%, the zinc oxide of 3-4%, the promotor PZ of 5-6% that are equivalent to diatomite weight 35-40% again, mixed grinding 30-40 minute, and then spray into the sec.-propyl distearyl acyloxy Aluminate being equivalent to diatomite weight 6-8%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
The preparation method of described EPDM and PVC composite cable material, it is characterized in that comprising the following steps: terpolymer EP rubber, PTMG, Microcrystalline Wax, propionate, octyl epoxy stearate, epoxidation tri-glyceride, Zinc Stearate, vulkacit D TDM, 2-thiol group benzimidazolyl, modification infusorial earth are mixed 12-16 minute at 80-95 DEG C, obtains compound A; By other mixing of materials, at 125-140 DEG C, mix 12-16 minute, obtain compound B; Compound A, B are deposited after 18-24 hour and mix, at 120-135 DEG C, mix 10-15 minute, send into twin screw extruder extruding pelletization at 125-145 DEG C, to obtain final product.
The material that the present invention produces, except the performance of the PVC cable material of inheriting tradition, also has more soft characteristic, simplifies production process, reduce production cost, breach the limitation of traditional sulfuration process.
Embodiment
A kind of EPDM and PVC composite cable material, be made up of the raw material of following weight part (kilogram):
Terpolymer EP rubber 9, SG-3PVC48, polyisobutene 12,3-aminopropyl trimethoxysilane 3, PTMG 3, Microcrystalline Wax 4, propionate 5, octyl epoxy stearate 2, epoxidation tri-glyceride 6, Zinc Stearate 2, dibasic lead phosphite 2, fast extrusion carbon black N66035, carbon black N22016, titanate coupling agent TMC-TTS3, zinc oxide 2, Na-222, vulkacit D TDM2,2-thiol group benzimidazolyl 2, modification infusorial earth 8.
Described modification infusorial earth is obtained by following methods:
Calcine 3-4 hour at diatomite being put into 460-480 DEG C, take out, cooling, puts into 10-12% sodium hydroxide solution and soaks 2-3 hour, takes out, and cleans with pure water, dries grinding powder; Add the aluminium nitride, the ferrocene of 4%, Zirconium tetrafluoride, the zinc oxide of 4%, the promotor PZ of 6% of 3% that are equivalent to diatomite weight 40% again, mixed grinding 30-40 minute, and then spray into the sec.-propyl distearyl acyloxy Aluminate being equivalent to diatomite weight 8%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
The preparation of EPDM and PVC composite cable material, comprise the following steps: terpolymer EP rubber, PTMG, Microcrystalline Wax, propionate, octyl epoxy stearate, epoxidation tri-glyceride, Zinc Stearate, vulkacit D TDM, 2-thiol group benzimidazolyl, modification infusorial earth are mixed 12-16 minute at 80-95 DEG C, obtains compound A; By other mixing of materials, at 125-140 DEG C, mix 12-16 minute, obtain compound B; Compound A, B are deposited after 18-24 hour and mix, at 120-135 DEG C, mix 10-15 minute, send into twin screw extruder extruding pelletization at 125-145 DEG C, to obtain final product.
CABLE MATERIALS performance of the present invention:
| Project | Unit | CABLE MATERIALS of the present invention |
| Green tensile intensity | MPa is not less than | 21.00 |
| Original broken elongation | % is not less than | 560 |
| After resistance to 158 DEG C × 168h is aging | ||
| Breaking tenacity | MPa is not less than | 19 |
| Elongation at break | % is not less than | 520 |
| 20 DEG C of volume specific resistances | Ω·m | 1.0×1015 |
| 200 DEG C of heat-stable times | Min | 50 |
Claims (2)
1. an EPDM and PVC composite cable material, it is characterized in that being made up of the raw material of following weight part: terpolymer EP rubber 5-9, SG-3PVC45-48, polyisobutene 8-12, 3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, Microcrystalline Wax 3-4, propionate 5-6, octyl epoxy stearate 1-2, epoxidation tri-glyceride 6-8, Zinic stearas 1-2, dibasic lead phosphite 1-2, fast extrusion carbon black N66030-35, carbon black N22013-16, titanate coupling agent TMC-TTS2-3, zinc oxide 1-2, Na-221-2, vulkacit D TDM1-2, 2 mercapto benzimidazole 1-2, modification infusorial earth 6-8, described modification infusorial earth is obtained by following methods: calcine 3-4 hour at diatomite being put into 460-480 DEG C, takes out, and cooling, puts into 10-12% sodium hydroxide solution and soak 2-3 hour, takes out, and cleans with pure water, dries grinding powder, add the aluminium nitride, the ferrocene of 3-4%, the Zirconium tetrafluoride of 2-3%, the zinc oxide of 3-4%, the promotor PZ of 5-6% that are equivalent to diatomite weight 35-40% again, mixed grinding 30-40 minute, and then spray into the sec.-propyl distearyl acyloxy Aluminate being equivalent to diatomite weight 6-8%, under 13000-16000 rev/min, stir 60-70 minute, to obtain final product.
2. the preparation method of EPDM and PVC composite cable material according to claim 1, it is characterized in that comprising the following steps: terpolymer EP rubber, PTMG, Microcrystalline Wax, propionate, octyl epoxy stearate, epoxidation tri-glyceride, Zinic stearas, vulkacit D TDM, 2 mercapto benzimidazole, modification infusorial earth are mixed 12-16 minute at 80-95 DEG C, obtains compound A; By other mixing of materials, at 125-140 DEG C, mix 12-16 minute, obtain compound B; Compound A, B are deposited after 18-24 hour and mix, at 120-135 DEG C, mix 10-15 minute, send into twin screw extruder extruding pelletization at 125-145 DEG C, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310243344.0A CN103351549B (en) | 2013-06-19 | 2013-06-19 | A kind of EPDM and PVC composite cable material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310243344.0A CN103351549B (en) | 2013-06-19 | 2013-06-19 | A kind of EPDM and PVC composite cable material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103351549A CN103351549A (en) | 2013-10-16 |
| CN103351549B true CN103351549B (en) | 2016-01-20 |
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| CN103865210A (en) * | 2014-03-26 | 2014-06-18 | 马鞍山市佳源环保科技有限公司 | Flexible wear-resisting polyvinyl chloride cable material and preparation method thereof |
| CN104817794A (en) * | 2015-05-22 | 2015-08-05 | 罗满清 | Corrosion-resistant PVC (polyvinyl chloride) tube for drainage and preparation method thereof |
| CN105131437A (en) * | 2015-08-14 | 2015-12-09 | 烟台顺隆化工科技有限公司 | Ethylene-propylene rubber cable insulation material |
| CN106098233A (en) * | 2016-06-24 | 2016-11-09 | 浙江英美达电缆科技有限公司 | A kind of aluminium alloy power cable of fire-retardant anti-long-term ultraviolet ageing |
| CN105906992A (en) * | 2016-06-24 | 2016-08-31 | 浙江英美达电缆科技有限公司 | Flame retardant long-term ultraviolet aging resistant steel-tape armoured aluminium alloy power cable |
| CN106128618A (en) * | 2016-06-24 | 2016-11-16 | 浙江英美达电缆科技有限公司 | A kind of aluminum alloy wire of anti-long-term ultraviolet ageing |
| CN105924855A (en) * | 2016-06-24 | 2016-09-07 | 浙江英美达电缆科技有限公司 | Aluminum alloy electric wire resistant to ultraviolet aging |
| CN106188931A (en) * | 2016-06-24 | 2016-12-07 | 浙江英美达电缆科技有限公司 | A kind of aluminium alloy power cable of ultraviolet aging resistance |
| CN106046601A (en) * | 2016-06-24 | 2016-10-26 | 浙江英美达电缆科技有限公司 | Flame-retardant long-term ultraviolet aging resistant lapped aluminum alloy power cable |
| CN106065138A (en) * | 2016-06-24 | 2016-11-02 | 浙江英美达电缆科技有限公司 | A kind of steel-tape armouring aluminium alloy power cable of anti-long-term ultraviolet ageing |
| CN105885303A (en) * | 2016-06-24 | 2016-08-24 | 浙江英美达电缆科技有限公司 | Anti-ultraviolet ageing steel-tape armouring aluminium alloy power cable |
| CN106098234A (en) * | 2016-06-24 | 2016-11-09 | 浙江英美达电缆科技有限公司 | A kind of aluminium alloy power cable of anti-long-term ultraviolet ageing |
| CN105895190A (en) * | 2016-06-24 | 2016-08-24 | 浙江英美达电缆科技有限公司 | Long-term ultraviolet aging resistant wrapped aluminium alloy power cable |
| CN106117869A (en) * | 2016-06-24 | 2016-11-16 | 浙江英美达电缆科技有限公司 | A kind of wrapped aluminium alloy power cable of ultraviolet aging resistance |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080060752A (en) * | 2006-12-27 | 2008-07-02 | 주식회사 엘지화학 | Plasticizer composition, preparation method thereof and vinyl chloride resin composition for tape of vehicle cable containing the same |
| CN102504436A (en) * | 2011-10-18 | 2012-06-20 | 池州灵芝化建材料科技有限公司 | Flame-retardant cable filler and preparation method thereof |
| CN102827438A (en) * | 2012-09-20 | 2012-12-19 | 江苏上上电缆集团有限公司 | Cable filler composition |
| CN102964697A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-wollastonite powder modified ethylene propylene diene copolymer cable material |
| CN102993598A (en) * | 2012-10-22 | 2013-03-27 | 江苏晨电太阳能光电科技有限公司 | Flame-resistant polyvinyl chloride cable material |
-
2013
- 2013-06-19 CN CN201310243344.0A patent/CN103351549B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080060752A (en) * | 2006-12-27 | 2008-07-02 | 주식회사 엘지화학 | Plasticizer composition, preparation method thereof and vinyl chloride resin composition for tape of vehicle cable containing the same |
| CN102504436A (en) * | 2011-10-18 | 2012-06-20 | 池州灵芝化建材料科技有限公司 | Flame-retardant cable filler and preparation method thereof |
| CN102827438A (en) * | 2012-09-20 | 2012-12-19 | 江苏上上电缆集团有限公司 | Cable filler composition |
| CN102993598A (en) * | 2012-10-22 | 2013-03-27 | 江苏晨电太阳能光电科技有限公司 | Flame-resistant polyvinyl chloride cable material |
| CN102964697A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-wollastonite powder modified ethylene propylene diene copolymer cable material |
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| CN103351549A (en) | 2013-10-16 |
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Address after: 239300 Anhui city of Chuzhou province Tianchang Qin LAN Zhen Shou Chang Lu No. 6 Patentee after: Anhui Star Cable Technology Co. Ltd. Address before: 239341 Anhui city of Chuzhou province Tianchang Qin LAN Zhen Shou Chang Lu Patentee before: Anhui Tianxing Optical Fiber Communication Equipment Co., Ltd. |
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