CN105908572A - Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof - Google Patents

Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof Download PDF

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Publication number
CN105908572A
CN105908572A CN201610253103.8A CN201610253103A CN105908572A CN 105908572 A CN105908572 A CN 105908572A CN 201610253103 A CN201610253103 A CN 201610253103A CN 105908572 A CN105908572 A CN 105908572A
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CN
China
Prior art keywords
hour
raw paper
flame
paper
wallpaper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610253103.8A
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Chinese (zh)
Inventor
李华令
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Suoya Decorative Materials Co Ltd
Original Assignee
Anhui Suoya Decorative Materials Co Ltd
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Publication date
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Priority to CN201610253103.8A priority Critical patent/CN105908572A/en
Publication of CN105908572A publication Critical patent/CN105908572A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00—Methods of beating or refining; Beaters of the Hollander type
    • D21D1/02—Methods of beating; Beaters of the Hollander type
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00—Wet end of machines for making continuous webs of paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00—Press section of machines for making continuous webs of paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F5/00—Dryer section of machines for making continuous webs of paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/60—Waxes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants

Abstract

The invention discloses a flame retardation wallpaper raw paper with ultraviolet ray absorption performance. Present technologies and present formulas are improved, meerschaum powder-antimony oxide-chlorinated paraffin is adopted as a flame retardant and is modified, H. and OH. free radicals in the chain reaction and for keeping combustion in a paper combustion reaction gas phase are captured to change the reaction mode in the gas phase, the heat release amount of the reaction is reduced to quench flame, and nanometer cerium oxide is added to raw materials after being organically modified to improve the brush ability of raw paper and make the raw paper be closely combined with a decoration layer and not shed. The flame retardation performance of the flame retardation wallpaper raw paper meets GB/T14656-93 requirements, the tearability, the folding strength, the ring crush strength and the tensile strength are improved, and wallpaper made by using the raw paper has the advantages of beautifulness, flatness, good embossing effect, and realization of good ultraviolet ray absorption performance, mild resistance, moisture resistance and air permeability without other treatments.

Description

A kind of have flame wallpaper body paper absorbing ultraviolet performance and preparation method thereof
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of flame wallpaper body paper with absorption ultraviolet performance and preparation method thereof.
Background technology
Wallpaper, also known as wallpaper, is with paper, non-weaving cloth or woven cloths as base material, adds decorative layer, be widely used in the decoration of some metopes or wall.Although wallpaper is not requisite to the decoration function of building, but it has been to build room style, atmosphere and the important means of color.No matter the especially wallpaper with paper as base material, enjoy the favor of people from properties of product or environmental requirement.
Paper is requisite article during people live.All many-sides such as packaging material, construction material, industrial or agricultural and daily living article it are widely used in along with socioeconomic development, paper and paper products.The burning-point of paper is at 130～230 DEG C, and oxygen index (OI), between 15%～20%, is the most incendive article.It is often rendered as the material or promote the medium that advances rapidly of the intensity of a fire of igniting of fire.And the wallpaper with paper as base material, once breaking out of fire, flame easily spreads along wallpaper, causes the intensity of a fire to expand rapidly, thus is the important means of the fire-retardant research of wallpaper to the fire-retardant research of paper.The fire-retardant way of tradition is mostly to decorative layer in addition flame treatment, but the decorative layer having used wallpaper surface of long duration and covering easily weares and teares to come off or affected by other external environments and causes the anti-flammability of wallpaper to reduce, it is clear that wallpaper base material body paper is carried out flame treatment particularly important.
" development of sepiolite powder fire retardant papers " literary composition describes the preparation method of fire retardant papers, is studied for the flame-retardant system of host inorganic additive with sepiolite powder.Result shows, time merely with sepiolite powder for additive, addition reaches more than 70% just preferable anti-flammability；Add a certain amount of chlorinated paraffin-antimony oxide and can be greatly improved the fire resistance of paper.The proportioning being obtained mixing fire retardant by screening is 7: 1: 2, and addition is 30%, and the fire resistance of paper reaches GB/T14656-93 requirement, and its tensile strength, tearability, folding strength, ring crush intensity have reached preferable level.
The anti-flammability of body paper is only analyzed by literary composition, but current wallpaper is usually present easy laying dust dirty, meets the problems such as water is the wettest, soundproof effect is poor, function singleness, it is coated with and functions only as decoration function on the wall, do not reach people's technical specification to indoor environment high request, and can be mouldy at sough or wet climates especially south plum rain season, it being difficult to preserve, service life is shorter, wallpaper often changed by so needs, relatively costly.Therefore, the present invention improves existing production technology and formula, prepares the wallpaper composite flame-proof body paper of diverse in function.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of have flame wallpaper body paper absorbing ultraviolet performance and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of have the flame wallpaper body paper absorbing ultraviolet performance, is prepared by the raw materials in: bamboo pulp 57-59, walnut parting 10-12, Pericarpium Citri tangerinae 8-9, cotton fiber 4-6, polyethylene fibre 3-5, sepiolite powder 16-18, chlorinated paraffin 2.1-2.5, antimony oxide 5.2-5.5, Graphene 1.2-1.4, ultraviolet absorbent UV-531 0.1-0.2, alkyl polyglucoside 6-8, Borax 0.2-0.4, nano-cerium oxide 0.3-0.5.
Described a kind of manufacture method with the flame wallpaper body paper absorbing ultraviolet performance, comprises the following steps:
(1) under nitrogen protection by alkyl polyglucoside heated and boiled; add nano-cerium oxide, polyethylene fibre keeps temperature magnetic agitation 1-2 hour; filter, washing is ground 30-40 minute after drying, and freezing 3-5 hour at subzero 15-20 DEG C prepares organic modified nano cerium oxide；
(2) sepiolite powder, Graphene are put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour at 735-745 DEG C to neutral vacuum drying, add after condensation ultraviolet absorbent UV-531, chlorinated paraffin, step (1) material ultrasonic grinding 30-40 minute organically-modified sepiolite powder；
(3) add water pulping by walnut parting, Pericarpium Citri tangerinae, adds cotton fiber and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry；
(4) bamboo pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
The invention have the advantage that the present invention improves existing technique and formula with sepiolite powder-antimony oxide-chlorinated paraffin for fire retardant in addition modified, by catching H and the OH free radical of the chain reaction maintaining burning in burning paper reaction gas phase, and then the reaction pattern in change gas phase, reduce exothermic heat of reaction amount and make flame cancellation, the most also add in raw material after organically-modified for nano-cerium oxide, improve the brushability of body paper, being tightly combined difficult drop-off with decorative layer, the flame wallpaper body paper firing resistance utilizing the present invention to prepare reaches GB/T14656-93 requirement, its tearability, folding strength, ring crush intensity, tensile strength are improved, and wallpaper prepared by this body paper, attractive in appearance smooth, embossing effects is good, it is not necessary to other process i.e. possess that good absorption is imparted, mildew resistance, moisture resistance and breathability.
Detailed description of the invention
A kind of have the flame wallpaper body paper absorbing ultraviolet performance, is prepared by the raw materials in: bamboo pulp 57, walnut parting 10, Pericarpium Citri tangerinae 8, cotton fiber 4, polyethylene fibre 3, sepiolite powder 16, chlorinated paraffin 2.1, antimony oxide 5.2, Graphene 1.2, ultraviolet absorbent UV-531 0.1, alkyl polyglucoside 6, Borax 0.2, nano-cerium oxide 0.3.
Described a kind of manufacture method with the flame wallpaper body paper absorbing ultraviolet performance, comprises the following steps:
(1) under nitrogen protection by alkyl polyglucoside heated and boiled; add nano-cerium oxide, polyethylene fibre keeps temperature magnetic agitation 1-2 hour; filter, washing is ground 30-40 minute after drying, and freezing 3-5 hour at subzero 15-20 DEG C prepares organic modified nano cerium oxide；
(2) sepiolite powder, Graphene are put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour at 735-745 DEG C to neutral vacuum drying, add after condensation ultraviolet absorbent UV-531, chlorinated paraffin, step (1) material ultrasonic grinding 30-40 minute organically-modified sepiolite powder；
(3) add water pulping by walnut parting, Pericarpium Citri tangerinae, adds cotton fiber and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry；
(4) bamboo pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
The flame wallpaper body paper utilizing the present invention to prepare has a following technical specification:
Tensile strength/kN m–1: 3.43；
Tearability/mN:433；
Folding strength/and time: 55；
Ring crush intensity/kN m–1: 2.73.

Claims (2)

1. one kind has the flame wallpaper body paper absorbing ultraviolet performance, it is characterized in that, be prepared by the raw materials in: bamboo pulp 57-59, walnut parting 10-12, Pericarpium Citri tangerinae 8-9, cotton fiber 4-6, polyethylene fibre 3-5, sepiolite powder 16-18, chlorinated paraffin 2.1-2.5, antimony oxide 5.2-5.5, Graphene 1.2-1.4, ultraviolet absorbent UV-531 0.1-0.2, alkyl polyglucoside 6-8, Borax 0.2-0.4, nano-cerium oxide 0.3-0.5.
A kind of manufacture method with the flame wallpaper body paper absorbing ultraviolet performance the most according to claim 1, it is characterised in that comprise the following steps:
(1) under nitrogen protection by alkyl polyglucoside heated and boiled; add nano-cerium oxide, polyethylene fibre keeps temperature magnetic agitation 1-2 hour; filter, washing is ground 30-40 minute after drying, and freezing 3-5 hour at subzero 15-20 DEG C prepares organic modified nano cerium oxide；
(2) sepiolite powder, Graphene are put in the hydrochloric acid solution that concentration is 3-5mol/L continuous magnetic agitation 2-3 hour in 30-60 DEG C of water bath with thermostatic control, filter, washing adds antimony oxide roasting 1-2 hour at 735-745 DEG C to neutral vacuum drying, add after condensation ultraviolet absorbent UV-531, chlorinated paraffin, step (1) material ultrasonic grinding 30-40 minute organically-modified sepiolite powder；
(3) add water pulping by walnut parting, Pericarpium Citri tangerinae, adds cotton fiber and sodium hydrate aqueous solution steaming and decocting that appropriate mass concentration is 1-2% 5-8 hour, uses flowing water rinsed clean, grind to form antibacterial slurry；
(4) bamboo pulp, step (3) material are added in beater, add suitable quantity of water making beating, it is subsequently adding step (2) material and other residual components stirring and evenly mixings, is heated to 50-55 DEG C and keeps temperature magnetic agitation 1-2 hour, finally mixing starched through copy paper, squeeze, dry, crimp discharging.
CN201610253103.8A 2016-04-22 2016-04-22 Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof Pending CN105908572A (en)

Priority Applications (1)

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CN201610253103.8A CN105908572A (en) 2016-04-22 2016-04-22 Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610253103.8A CN105908572A (en) 2016-04-22 2016-04-22 Flame retardation wallpaper raw paper with ultraviolet ray absorption performance, and making method thereof

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Publication Number Publication Date
CN105908572A true CN105908572A (en) 2016-08-31

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08100389A (en) * 1994-09-28 1996-04-16 New Oji Paper Co Ltd Flame retardant paper for backing vinyl wallpaper
CN103044756A (en) * 2012-11-25 2013-04-17 安徽六方重联机械股份有限公司 Preparation method of packaging plastic base material film containing modified calcined fluorite powder
CN103059696A (en) * 2012-12-12 2013-04-24 滁州市宏源喷涂有限公司 Powder coating containing modified sepiolite powder and preparing method thereof
CN103756094A (en) * 2014-01-10 2014-04-30 安徽瑞升电气科技有限公司 Halogen-free flame-retardant polyphenyl ether cable material
CN105220557A (en) * 2015-09-11 2016-01-06 姚志宏 Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof
CN105256643A (en) * 2015-09-11 2016-01-20 姚志宏 Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08100389A (en) * 1994-09-28 1996-04-16 New Oji Paper Co Ltd Flame retardant paper for backing vinyl wallpaper
CN103044756A (en) * 2012-11-25 2013-04-17 安徽六方重联机械股份有限公司 Preparation method of packaging plastic base material film containing modified calcined fluorite powder
CN103059696A (en) * 2012-12-12 2013-04-24 滁州市宏源喷涂有限公司 Powder coating containing modified sepiolite powder and preparing method thereof
CN103756094A (en) * 2014-01-10 2014-04-30 安徽瑞升电气科技有限公司 Halogen-free flame-retardant polyphenyl ether cable material
CN105220557A (en) * 2015-09-11 2016-01-06 姚志宏 Flyash superfine fibre composite base paper that a kind of intensity is high and preparation method thereof
CN105256643A (en) * 2015-09-11 2016-01-20 姚志宏 Stellera chamaejasme flower rhizome mothproof base paper and preparation method therefor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨守生: ""壁纸阻燃基纸的研制"", 《新型建筑材料》 *

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Application publication date: 20160831

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