CN107384048A - A kind of preparation method of oceanographic equipment nano-antirust coating - Google Patents
A kind of preparation method of oceanographic equipment nano-antirust coating Download PDFInfo
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- CN107384048A CN107384048A CN201710754382.0A CN201710754382A CN107384048A CN 107384048 A CN107384048 A CN 107384048A CN 201710754382 A CN201710754382 A CN 201710754382A CN 107384048 A CN107384048 A CN 107384048A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of preparation method of oceanographic equipment nano-antirust coating,Chlorinated rubber,Styrene,The modified nano materials of Na LTA/SSZ 13,Acrylic resin,Modified sodium silicate sand,Methyl methacrylate,Alkoxyl silicone acetoacetic ester,Phosphate ester monomer,Methacrylic acid,N methyl pyrrolidones,Polypropylene glycol is primary raw material,By the way that the nano materials of Na LTA/SSZ 13 are carried out into oxidation modification,It is compound with acrylic resin and modified sodium silicate sand again,Add chlorinated rubber and the acrylate copolymer of styrene one prepares the severe antirusting paint of excellent performance,The present invention by the nano materials of Na LTA/SSZ 13 by that will carry out oxidation modification,It is compound with acrylic resin and modified sodium silicate sand again,Adding severe antirusting paint prepared by chlorinated rubber and the acrylate copolymer of styrene one has excellent weatherability and corrosion resistance.
Description
Technical field
Invention is related to a kind of preparation method of oceanographic equipment nano-antirust coating, belongs to paint field.
Background technology
Marine paint be used for protecting ship, marine drilling and producing platform and harbour piling bar etc. not by seawater or marine biological polution or
The coating of corrosion, the different parts of ship have different requirements to coating, and hull bottom long period of soaking is that full ship corrosion is most tight in seawater
The position of weight, ship bottom paint generally comprise antirust paint and top layer antifouling paint, and it is excellent that antirust paint should have following performance to possess
Water resistance, rust-preventing characteristic, paint film must have excellent adhesive force in steel surface, stand prolonged seawater immersion and water
Stream impact, paint film are not susceptible to bubbling, obscission.Easily there is precipitation, caking etc. in storage process in existing antirust paint
Phenomenon, bin stability is poor, and the adhesive force of paint film is not ideal enough.
The content of the invention
It is an object of the invention to provide a kind of oceanographic equipment nano-antirust coating and preparation method thereof, pass through party's legal system
Standby material has excellent rust-proof effect.
A kind of preparation method of oceanographic equipment nano-antirust coating, it is characterised in that this method comprises the following steps:
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Described modification Na-LTA/SSZ-13 preparation method of nano material is as follows:
Step 1, ice bath cool down and stir under conditions of, into the 69ml concentrated sulfuric acids addition 1.5g sodium nitrate(Grind), wait nitric acid
After sodium is completely dissolved in the concentrated sulfuric acid, 3g SSZ-13 and 6gNa-LTA molecular sieve are added thereto while stirring;
Step 2,9g potassium permanganate is then slowly added into, adds speed and strictly control, to ensure that temperature is less than 20 DEG C, then removed
Ice bath, using water-bath and maintain the temperature at 35 DEG C or so, be incubated 2 hours, 137ml deionized waters are slowly initially added under stirring,
System is fiercely warming up to 98 DEG C, rear to be kept for 15 minutes with 98 DEG C of water-baths;
Step 3 and then 420ml is diluted further to 60 DEG C of deionized waters of warm, then adds excessive 30% hydrogen peroxide with also
Remaining potassium permanganate and be manganese dioxide in substance system, obtains bright orange color system and filters while hot, is 1 with volume ratio:10 salt
Acid solution wash once, is washed three times, 45 DEG C of dryings in an oven.
Step 4, the oxidation composite molecular screen grind into powder by above-mentioned preparation, to ensure abundant expanded by heating, progressively rise
Temperature loads in tube furnace to 200 DEG C, heats and is sealed at the mouth of pipe, and thermocouple is contacted to ensure that thermometric is accurate with heating bottom of the tube.Heat
After expansion terminates, modified oxidized Na-LTA/SSZ-13 nano materials are obtained.
Described modified sodium silicate sand preparation method is as follows:
Step 1,500g water-glass sands are added in roaster, high-temperature roasting 2 hours at 200 DEG C, by the waterglass after heating
Sand is added in rotary grinding device while hot, and surface treating adhesive is sloughed by the grinding of 1500r/min high-speed stirreds;
Step 2, the water-glass sand is added to sonic oscillation 3 hours in Sufficient purified water again, is washed with water to neutrality and dries, then added
Enter 85g sepiolites, 20g carbon blacks and 35g alumina laps to 500 mesh fine powders, it is equal to add 10g tetrabutyl titanate mixed grindings
It is even.
Beneficial effect:Oceanographic equipment nano-antirust coating prepared by the present invention, Na-LTA/SSZ-13 nano materials are carried out
Oxidation modification, then it is compound with acrylic resin and modified sodium silicate sand, add chlorinated rubber and the acrylic ester copolymer of styrene one
Thing improves the corrosion resistance and weatherability of coating, and modified Na-LTA/SSZ-13 nano materials have small-size effect, can
Prevented in the hole of anticorrosive coating and defect to be filled into and delay small molecule corrosive medium to enter metallic matrix, effectively increased
The physical isolation effect of strong anticorrosion film.In addition the alkyl silicic acids ethyl ester with chain hydrophobic carries out two-phase with acrylate monomer
Semi-continuous emulsion polymerizing, the acrylate copolymer emulsion of styrene one of nano hybridization is directly obtained, wherein unhydrolysed silica
Key further crosslinks during emulsion film forming between base material, pigment, emulsion particle, improves the compactness of paint film, increases
The resistance to saltfog energy of strong paint film, so as to further increase the rust-resisting property of coating.
Embodiment
A kind of preparation method of oceanographic equipment nano-antirust coating of embodiment 1, comprises the following steps:
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Described modification Na-LTA/SSZ-13 preparation method of nano material is as follows:
Step 1, ice bath cool down and stir under conditions of, into the 69ml concentrated sulfuric acids addition 1.5g sodium nitrate(Grind), wait nitric acid
After sodium is completely dissolved in the concentrated sulfuric acid, 3g SSZ-13 and 6gNa-LTA molecular sieve are added thereto while stirring;
Step 2,9g potassium permanganate is then slowly added into, adds speed and strictly control, to ensure that temperature is less than 20 DEG C, then removed
Ice bath, using water-bath and maintain the temperature at 35 DEG C or so, be incubated 2 hours, 137ml deionized waters are slowly initially added under stirring,
System is fiercely warming up to 98 DEG C, rear to be kept for 15 minutes with 98 DEG C of water-baths;
Step 3 and then 420ml is diluted further to 60 DEG C of deionized waters of warm, then adds excessive 30% hydrogen peroxide with also
Remaining potassium permanganate and be manganese dioxide in substance system, obtains bright orange color system and filters while hot, is 1 with volume ratio:10 salt
Acid solution wash once, is washed three times, 45 DEG C of dryings in an oven.
Step 4, the oxidation composite molecular screen grind into powder by above-mentioned preparation, to ensure abundant expanded by heating, progressively rise
Temperature loads in tube furnace to 200 DEG C, heats and is sealed at the mouth of pipe, and thermocouple is contacted to ensure that thermometric is accurate with heating bottom of the tube.Heat
After expansion terminates, modified oxidized Na-LTA/SSZ-13 nano materials are obtained.
Described modified sodium silicate sand preparation method is as follows:
Step 1,500g water-glass sands are added in roaster, high-temperature roasting 2 hours at 200 DEG C, by the waterglass after heating
Sand is added in rotary grinding device while hot, and surface treating adhesive is sloughed by the grinding of 1500r/min high-speed stirreds;
Step 2, the water-glass sand is added to sonic oscillation 3 hours in Sufficient purified water again, is washed with water to neutrality and dries, then added
Enter 85g sepiolites, 20g carbon blacks and 35g alumina laps to 500 mesh fine powders, it is uniform to add 10g tetrabutyl titanate mixed grindings
.
Embodiment 2
Step 1, by 6 parts of chlorinated rubbers, 10 parts of styrene, 23 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid trees
Stirred in fat input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 3
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 13 parts of modified Na-LTA/SSZ-13 nano materials, 5 parts of acrylic acid trees
Stirred in fat input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 4
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 16 parts of modified sodium silicate sands, 14 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 5
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 6 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 18 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 18 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 6
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 12 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 2 parts of phosphate ester monomers, 1.7 parts of methacrylic acids stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1 part of polypropylene glycol and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
It is uniform that material is added to grinding distribution in sand mill, and is stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 7
Step 1, by 11 parts of chlorinated rubbers, 18 parts of styrene, 43 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 8
Step 1, by 13 parts of chlorinated rubbers, 5 parts of styrene, 3 parts of modified Na-LTA/SSZ-13 nano materials, 3 parts of acrylic resins
Stirred in input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 9
Step 1, by 23 parts of chlorinated rubbers, 25 parts of styrene, 15 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 10
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 20 parts of modified sodium silicate sands, 9 parts of methyl methacrylates, 3 parts of acrylic acid fourths are added under identical rotating speed
Ester, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add again
Enter 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, after scattered
Material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Remaining is prepared and embodiment 1 is identical.
Embodiment 11
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2., 13 parts of modified sodium silicate sands, 13 parts of modified bauxites, 4 parts of methyl methacrylates are added under identical rotating speed
Ester, 8 parts of butyl acrylates, 22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes,
It is cooled to 60 DEG C and adds 8 parts of 1-METHYLPYRROLIDONEs, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor,
It is scattered, will it is scattered after material to be added to grinding distribution in sand mill uniform, and stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
Described modification bauxite preparation method is as follows:
25 parts of bauxites are put into the liquor alumini chloridi of mass fraction 8% at 90 DEG C and stirred 5 hours, filters, washs to neutrality,
Drying, is dispersed in the deionized water solution of ethanol one, adds 18 parts of octadecylamines in 60 DEG C of stirred in water bath 4 hours, ultrasound
It is scattered 30 minutes, filter, washing, be dried under vacuum to constant weight, grind, sieve and produce modified Nano bauxite.
Reference examples 1
It is with the difference of embodiment 1:In step 1 prepared by modified Na-LTA/SSZ-13 nano materials, toward the 69ml concentrated sulfuric acids
Middle addition 3g sodium nitrate(Grind), after waiting sodium nitrate to be completely dissolved in the concentrated sulfuric acid, 12gNa-LTA molecular sieves side is added thereto,
Remaining step is identical with embodiment 1.
Reference examples 2
It is with the difference of embodiment 1:In step 1 prepared by modified Na-LTA/SSZ-13 nano materials, toward the 69ml concentrated sulfuric acids
Middle addition 1.5g sodium nitrate(Grind), after waiting sodium nitrate to be completely dissolved in the concentrated sulfuric acid, by 12g SSZ-13 molecular sieves while stirring
It is added thereto, remaining step is identical with embodiment 1.
Reference examples 3
It is with the difference of embodiment 1:In step 2 prepared by modified Na-LTA/SSZ-13 nano materials, 18g height is slowly added to
Potassium manganate, remaining step are identical with embodiment 1.
Reference examples 4
It is with the difference of embodiment 1:In step 2 prepared by modified Na-LTA/SSZ-13 nano materials, 3g Gao Meng are slowly added to
Sour potassium, remaining step are identical with embodiment 1.
Reference examples 5
It is with the difference of embodiment 1:It is 5 with volume ratio in step 3 prepared by modified Na-LTA/SSZ-13 nano materials:1
Hydrochloric acid solution washed once, remaining step is identical with embodiment 1.
Reference examples 6
It is with the difference of embodiment 1:In step 3 prepared by modified Na-LTA/SSZ-13 nano materials, with 30% concentration
NaCl solution washed once, and remaining step is identical with embodiment 1, and remaining step is identical with embodiment 1.
Reference examples 7
It is with the difference of embodiment 1:In step 2 prepared by modified sodium silicate sand, 15g sepiolites, 30g carbon blacks and 8g oxygen are added
Change aluminium and be ground to 500 mesh fine powders, remaining step is identical with embodiment 1.
Reference examples 8
It is with the difference of embodiment 1:In step 2 prepared by modified sodium silicate sand, 45g sepiolites, 10g carbon blacks and 15g are added
Alumina lap is identical with embodiment 1 to 500 mesh fine powders, remaining step.
Reference examples 9
It is with the difference of embodiment 1:In step 2 prepared by modified sodium silicate sand, 10g sepiolites, 45g carbon blacks and 5g oxygen are added
Change aluminium and be ground to 500 mesh fine powders, remaining step is identical with embodiment 1.
Reference examples 10
It is with the difference of embodiment 1:In step 2 prepared by modified sodium silicate sand, 30g tetrabutyl titanates, remaining step are added
It is identical with embodiment 1.
Choose the oceanographic equipment nano-antirust coating being prepared and carry out performance detection respectively,
Rustless property is tested, and using monolithic rust prevention test method, experiment is with reference to GB/6144-55 methods;
Water-resistant coating is tested, by GB/T1733-1993 standard testings;
Coating resistance to salt water is tested, and is tested by GB/1763-1989 standard first method.
Test result
Test result indicates that oceanographic equipment nano-antirust coating provided by the invention has good rust-proof effect, coating is in country
Under standard test condition, saline sook concentration is certain, and the stainless time is longer, illustrates that rust-proof effect is better, conversely, effect is poorer;
Embodiment 1 arrives embodiment 10, and the stainless time more than 25 days, changes matching somebody with somebody for each raw material composition in severe antirusting paint respectively
Than having different degrees of influence to the rustless property of material, in modified Na-LTA/SSZ-13 nano materials, acrylic resin
It is 3 with modified sodium silicate sand quality proportioning:1:2, when other dispensing dosages are fixed, rust-proof effect is best;It is it is worth noting that real
Apply example 11 and add modified bauxite, rust-proof effect is greatly improved, reached 125 days, illustrates modified bauxite to filling-material structure
Rustless property have more preferable optimization function;Reference examples 1 to reference examples 4 change modified Na-LTA/SSZ-13 nano materials and prepared
Sodium nitrate and molecular sieve proportioning and oxidant potassium permanganate dosage, rust-proof effect is decreased obviously, and illustrates sodium nitrate and oxidant
Dosage produces material impact to the modified of molecular screen material;Reference examples 5 change the acid concentration of composite molecular screen washing to reference examples 6
And component, effect is also bad, illustrates that cleaning solution acidity is modified to molecular screen material and plays an important role;Reference examples 7 and example 9 change
The proportioning of water glass sand modified raw material, insulation effect substantially reduce, and illustrate sepiolite, carbon black and aluminum oxide dosage to filling-material structure
Composite modified influence it is very big;To example 10, the dosage of tetrabutyl titanate is increased, effect is still bad, illustrates tetrabutyl titanate
The rust-preventing characteristic of coating can excessively be influenceed;Therefore the forms poisoning antirusting paint prepared using the present invention has good antirust to imitate
Fruit.
Claims (3)
1. a kind of preparation method of oceanographic equipment nano-antirust coating, it is characterised in that this method comprises the following steps:
Step 1, by 13 parts of chlorinated rubbers, 15 parts of styrene, 33 parts of modified Na-LTA/SSZ-13 nano materials, 13 parts of acrylic acid
Stirred in resin input reactor, reaction temperature is controlled at 250 DEG C, to stir 2 hours under 800 revs/min;
Step 2, under identical rotating speed add 26 parts of modified sodium silicate sands, 4 parts of methyl methacrylates, 8 parts of butyl acrylates,
22 parts of alkoxyl silicone acetoacetic esters, 7 parts of phosphate ester monomers, 0.7 part of methacrylic acid stir 50 minutes, are cooled to 60 DEG C and add 8
Part 1-METHYLPYRROLIDONE, 1.8 parts of polypropylene glycols and 30 parts of deionized waters, stirred in reactor, be scattered, the thing after disperseing
It is uniform that material is added to grinding distribution in sand mill, and is stirred 30 minutes under 1400 revs/min;
Step 3, finely dispersed material is added in filter and filtered, the material that fineness is 50 μm is obtained after filtering, will
Material packaging after filtering.
A kind of 2. preparation method of oceanographic equipment nano-antirust coating according to claim 1, it is characterised in that it is described,
Described modification Na-LTA/SSZ-13 preparation method of nano material is as follows:
Step 1, ice bath cool down and stir under conditions of, into the 69ml concentrated sulfuric acids addition 1.5g sodium nitrate(Grind), wait nitric acid
After sodium is completely dissolved in the concentrated sulfuric acid, 3g SSZ-13 and 6gNa-LTA molecular sieve are added thereto while stirring;
Step 2,9g potassium permanganate is then slowly added into, adds speed and strictly control, to ensure that temperature is less than 20 DEG C, then removed
Ice bath, using water-bath and maintain the temperature at 35 DEG C or so, be incubated 2 hours, 137ml deionized waters are slowly initially added under stirring,
System is fiercely warming up to 98 DEG C, rear to be kept for 15 minutes with 98 DEG C of water-baths;
Step 3 and then 420ml is diluted further to 60 DEG C of deionized waters of warm, then adds excessive 30% hydrogen peroxide with also
Remaining potassium permanganate and be manganese dioxide in substance system, obtains bright orange color system and filters while hot, is 1 with volume ratio:10 salt
Acid solution wash once, is washed three times, 45 DEG C of dryings in an oven;
Step 4, the oxidation composite molecular screen grind into powder by above-mentioned preparation, to ensure abundant expanded by heating, are progressively warming up to
200 DEG C, load in tube furnace, heat and sealed at the mouth of pipe, thermocouple is contacted to ensure that thermometric is accurate with heating bottom of the tube;
After thermal expansion terminates, modified oxidized Na-LTA/SSZ-13 nano materials are obtained.
3. a kind of preparation method of oceanographic equipment nano-antirust coating according to claim 1, it is characterised in that described changes
Property water-glass sand preparation method is as follows:
Step 1,500g water-glass sands are added in roaster, high-temperature roasting 2 hours at 200 DEG C, by the waterglass after heating
Sand is added in rotary grinding device while hot, and surface treating adhesive is sloughed by the grinding of 1500r/min high-speed stirreds;
Step 2, the water-glass sand is added to sonic oscillation 3 hours in Sufficient purified water again, is washed with water to neutrality and dries, then added
Enter 85g sepiolites, 20g carbon blacks and 35g alumina laps to 500 mesh fine powders, it is uniform to add 10g tetrabutyl titanate mixed grindings
.
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