CN107286846A - A kind of glass-flake coating - Google Patents
A kind of glass-flake coating Download PDFInfo
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- CN107286846A CN107286846A CN201710424601.9A CN201710424601A CN107286846A CN 107286846 A CN107286846 A CN 107286846A CN 201710424601 A CN201710424601 A CN 201710424601A CN 107286846 A CN107286846 A CN 107286846A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D187/00—Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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Abstract
The present invention relates to a kind of glass-flake coating, belong to technical field of coatings.The present invention is soaked after crushing waste ceramic and kaolinite with oxalic acid, filter to obtain filter residue and compressing, voluminous powder is crushed to obtain after drying and calcining, added after glass flake powder is handled into surface with a variety of surfactants again in the suspension containing voluminous powder, and add paraffin, sediment and dry dried object are separated to obtain after ultrasonic disperse, by styrene, the material mixings such as acrylic acid obtain mix monomer, polymerisation is carried out in the presence of initiator, carry out cross-linking reaction with epoxy resin etc. again after reactant, anti-corrosion resin emulsion is obtained after reaction, and by anti-corrosion resin emulsion, dried object, the material mixings such as curing agent, glass-flake coating can be obtained.The coating toughness of glass-flake coating formation prepared by the present invention is big, and adhesive force is strong, is difficult to peel off, and with higher Corrosion Protection.
Description
Technical field
The present invention relates to a kind of glass-flake coating, belong to technical field of coatings.
Background technology
Glass-flake coating belongs to a kind of effective heavy-duty anticorrosive coating, because glass flake is parallel to each other inside film
And overlapping arrangement, coating is not only divided into many small spaces and the shrinkage stress and the coefficient of expansion of coating is greatly reduced,
And can be formed and prevent the barrier of Medium Diffusion, the roundabout infiltration of medium is forced, extension medium osmosis is diffused into the time of matrix, from
And increase the anti-permeability performance and mechanical strength of film, reach the purpose of extension matrix anti-corrosion time.Due to glass-flake coating
With anti-corrosion, thermal coefficient of expansion is small, and Googol motion controller is few, wear-resistant, easy construction, it is easy to repair, thus glass flake applies
Material has extensive application in industries such as chemical industry, metallurgy, chemical fibre, plating, buildings, particularly at various offshore engineering equipments, sea
Petroleum gas platform, bay harbour and marine vessel applications are more extensive.
Existing glass-flake coating is mostly solvent-borne type, and solvent volatilization causes coating voidage and shrinkage factor to increase, easily
Stress raisers are formed, make coating fragility big, adhesive force, permeability resistance and shock resistance reduction；When coating is thicker, solvent
Coat inside is easily trapped in, coating compactness is influenceed；And solvent is high, environmental pollution.Therefore, urgent one kind of finding can be formed
Toughness is larger, and adhesive force is high, the good glass-flake coating of shock resistance.
The content of the invention
The technical problems to be solved by the invention：Coating fragility for traditional glass-flake coating formation is big, attachment
The problem of power and low shock resistance, there is provided a kind of preparation method of glass-flake coating.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of glass-flake coating, is counted by weight, including 80~100 parts of resin emulsions, 15~25 parts of modified glass flakes
Mixture, 1~3 part of diethylenetriamine, 2~4 part of 200~220 mesh aluminium powder, 1~3 part of accelerator and 1~3 part of defoamer, 1~3
Part silane coupler and 2~5 parts of triethylene tetramines.
Described modified glass flakes mixture is to count by weight, choose respectively 10~15 parts of voluminous powders, 80~
100 parts of absolute ethyl alcohols, 20~40 parts of modified glass flakes powder and 5~7 parts of paraffin, filter after mixing, obtain filter cake, dry
.
Described modified glass flakes powder is to count by weight, choose respectively 70~100 parts of glass flake powder,
150~200 parts of isopropanols, 8~10 parts of lauryl sodium sulfate, 10~12 parts of Triton X-100s and 12~15 part ten
Dialkyl dimethyl amine oxide, centrifuges after stirring, obtains sediment, and drying, ball milling, sieve to obtain modified glass flakes powder.
The preparation method of described voluminous powder is：（1）In mass ratio 2:1, waste ceramic and kaolinite are weighed respectively, are mixed
Crushed after conjunction, sieve to obtain mixed-powder；（2）In mass ratio 1:Mixed-powder is added immersion in the oxalic acid solution of mass fraction 5% by 5,
Soak and filtered after 30~50min, collect filter residue and wash；（3）Filter residue after washing is put into cylindrical type mould, is pressed into
Type, obtains wet base substrate, is put into after drying in Muffle furnace, is warming up to cooling discharging after 900~1100 DEG C, 2~4h of calcining, must calcine
Thing, is crushed, and sieving obtains voluminous powder.
Described resin emulsion is that acrylic emulsion modified epoxy is obtained.
Described epoxy resin can also be modified by eleostearic acid and linoleic acid.
Described accelerator is BYK-4511, and described defoamer is BYK-066N.
Described silane coupler is one kind in KH-550, KH-560 and KH-570.
The present invention is compared with other method, and advantageous effects are：
（1）Tradition is added in resin emulsion without modified glass flake, and dispersiveness is poor, and glass flake is in resin emulsion
In orientations degree it is relatively low, there is no that relatively good overlap joint can be formed between scale, cause the structure of coat inside not
Homogeneous, coating fragility is big formed by, and adhesive force and shock resistance are low, and the present invention is that first glass flake is changed
Property, add surfactant and emulsifying agent carries out handling modified to glass flake surface, glass flake can be made uniformly to divide
It is dispersed in resin emulsion, orientations degree is good, and after mixing with silane coupler, can makes to form fine between scale
Overlap joint, structural arrangement is close, so that the impermeability of coating is improved, with excellent Corrosion Protection；
（2）The present invention is the end group in matrix, acrylic emulsion using the resin emulsion after acrylic emulsion modified epoxy
Functional group is reacted with the epoxy radicals in epoxy resin, generation grafting or block copolymer, can form the net for having moderate crosslinking
Shape system, eleostearic acid and linoleic acid can improve the film forming speed of epoxy resin, the coating mechanical property of formation to epoxy resin modification
And corrosion resistance and good, can for a long time it be used in corrosive environment；
（3）The present invention adds paraffin after being prepared into voluminous powder and glass flake mixing using waste ceramic and kaolinite, its mesh
Be that glass flake is loaded with the hole of voluminous powder, add in resin emulsion, can be tightly combined, hole is less, heap
Product is closely knit, and the compatibility with resin is good, constitutes anticorrosive paint, can significantly improve the compactness of film layer.
Embodiment
In mass ratio 2:1, waste ceramic and kaolinite are weighed respectively, adds in pulverizer and crushes, and are crossed after 80~100 mesh sieves
Mix to obtain mixed-powder, in mass ratio 1:5 will soak in the mixed-powder addition oxalic acid solution of mass fraction 5%, and immersion 30~
Filtered after 50min, collect filter residue, and filter residue is washed with deionized 2~4 times, collect the filter residue after washing；By the filter after washing
Slag is put into cylindrical type mould, and 5~7min is suppressed under 3~5MPa, the wet base substrate of shaping is put into baking oven, 110~120
6~8h is dried at DEG C, is put into after obtaining dry body body in Muffle furnace, is warming up to 900~1100 DEG C with 5~7 DEG C/min heating rates, forges
Cooling discharging after 2~4h is burnt, calcined material is obtained, calcined material is added in pulverizer and crushed, 40~50 mesh sieves are crossed after crushing, obtain porous
Powder；Count by weight, choose respectively 70~100 parts of glass flake powder, 150~200 parts of isopropanols, 8~10 part 12
Sodium alkyl sulfate, 10~12 parts of Triton X-100s and 12~15 parts of DDAOs, insulated and stirred 2
Added after~3h in centrifuge, centrifuged under 1000~1200r/min rotating speeds, obtain sediment, sediment is put into baking oven
In, 4~6h is dried at 80~100 DEG C, ball milling in ball mill is added after drying, 300~320 mesh sieves is crossed and obtains modified glass flakes
Powder；In mass ratio 1:1, eleostearic acid is weighed respectively and linoleic acid is added in three-necked flask, and three-necked flask is put into oil bath pan, and
150~170 DEG C are heated to, 5~6 times of epoxy resin E51 of eleostearic acid quality, 20~30min of insulated and stirred are added into three-necked flask
After be cooled to 100~110 DEG C, be cooled to after being subsequently added 6~7 times of acrylic emulsions of eleostearic acid quality, 30~40min of stirring reaction
40~50 DEG C, and the sodium hydroxide solution of 5~10% mass fraction of eleostearic acid quality 15% is added, add eleostearic acid after stirring 10~15min
20~30 times of deionized waters of quality, are stirred with 600~800r/min rotating speeds and are discharged after 30~40min, obtain resin emulsion；By weight
Number meter, takes 80~100 parts of resin emulsions, 15~25 parts of modified glass flakes mixtures, 1~3 part of diethylenetriamine, 2 respectively
~4 part of 200~220 mesh aluminium powder, 1~3 part of accelerant B YK-4511 and 1~3 part of defoamer BYK-066N, 1~3 part it is silane coupled
Agent, 2~5 parts of triethylene tetramines, are stirred with 300~400r/min rotating speeds and are discharged after 20~30min, you can obtain glass flake painting
Material.
One kind in described silane resin acceptor kh-550, KH-560 and KH-570.
Example 1
In mass ratio 2:1, waste ceramic and kaolinite are weighed respectively, adds in pulverizer and crushes, and are mixed and must be mixed after crossing 100 mesh sieves
Close powder, in mass ratio 1:Mixed-powder is added filtering after immersion in the oxalic acid solution of mass fraction 5%, immersion 50min by 5, is collected
Filter residue, and filter residue is washed with deionized 4 times, collect the filter residue after washing；Filter residue after washing is put into cylindrical type mould,
7min is suppressed under 5MPa, the wet base substrate of shaping is put into baking oven, 8h is dried at 120 DEG C, Muffle is put into after obtaining dry body body
In stove, cooling discharging after 1100 DEG C, calcining 4h is warming up to 7 DEG C/min heating rates, calcined material is obtained, calcined material is added and crushed
Crushed in machine, 50 mesh sieves are crossed after crushing, voluminous powder is obtained；Count by weight, 100 parts of glass flake powder, 200 are chosen respectively
Part isopropanol, 10 parts of lauryl sodium sulfate, 12 parts of Triton X-100s and 15 parts of DDAOs,
Added after insulated and stirred 3h in centrifuge, centrifuged under 1200r/min rotating speeds, obtain sediment, sediment is put into baking oven
In, 6h is dried at 100 DEG C, ball milling in ball mill is added after drying, 320 mesh sieves is crossed and obtains modified glass flakes powder；By weight
Number meter, chooses 15 parts of voluminous powders, 100 parts of absolute ethyl alcohols, 40 parts of modified glass flakes powder and 7 parts of paraffin, mixing respectively
After filter, obtain filter cake, modified glass flakes mixture can be obtained after drying；In mass ratio 1:1, eleostearic acid and linoleic acid are weighed respectively
Add in three-necked flask, three-necked flask is put into oil bath pan, and be heated to 170 DEG C, eleostearic acid quality 6 is added into three-necked flask
110 DEG C are cooled to after times epoxy resin E51, insulated and stirred 30min, 7 times of acrylic emulsions of eleostearic acid quality are subsequently added, stirring is anti-
Answer and 50 DEG C are cooled to after 40min, and add addition after the sodium hydroxide solution of 10% mass fraction of eleostearic acid quality 15%, stirring 15min
30 times of deionized waters of eleostearic acid quality, to be discharged after 800r/min rotating speeds stirring 40min, obtain resin emulsion；Count by weight, point
Do not take 100 parts of resin emulsions, 25 parts of modified glass flakes mixtures, 1~3 part of diethylenetriamine, 2~4 part of 220 mesh aluminium powder, 3 parts
Accelerant B YK-4511 and 3 parts of defoamer BYK-066N, 3 parts of silane resin acceptor kh-550s, 5 parts of triethylene tetramines, with 400r/
Discharged after min rotating speeds stirring 30min, you can obtain glass-flake coating.
Example 2
In mass ratio 2:1, waste ceramic and kaolinite are weighed respectively, adds in pulverizer and crushes, and are mixed and must be mixed after crossing 80 mesh sieves
Close powder, in mass ratio 1:Mixed-powder is added filtering after immersion in the oxalic acid solution of mass fraction 5%, immersion 30min by 5, is collected
Filter residue, and filter residue is washed with deionized 2 times, collect the filter residue after washing；Filter residue after washing is put into cylindrical type mould,
5min is suppressed under 3MPa, the wet base substrate of shaping is put into baking oven, 6h is dried at 110 DEG C, Muffle is put into after obtaining dry body body
In stove, cooling discharging after 900 DEG C, calcining 2h is warming up to 5 DEG C/min heating rates, calcined material is obtained, calcined material is added and crushed
Crushed in machine, 40 mesh sieves are crossed after crushing, voluminous powder is obtained；Count by weight, 70 parts of glass flake powder, 150 are chosen respectively
Part isopropanol, 8 parts of lauryl sodium sulfate, 10 parts of Triton X-100s and 12 parts of DDAOs,
Added after insulated and stirred 2h in centrifuge, centrifuged under 1000r/min rotating speeds, obtain sediment, sediment is put into baking oven
In, 4h is dried at 80 DEG C, ball milling in ball mill is added after drying, 300 mesh sieves is crossed and obtains modified glass flakes powder；In mass ratio
1:1, eleostearic acid and linoleic acid are weighed respectively and is added in three-necked flask, and three-necked flask is put into oil bath pan, and it is heated to 150 DEG C,
100 DEG C are cooled to after adding 5 times of epoxy resin E51 of eleostearic acid quality, insulated and stirred 20min into three-necked flask, paulownia is subsequently added
40 DEG C are cooled to after sour 6 times of acrylic emulsions of quality, stirring reaction 30min, and adds the hydrogen-oxygen of 5% mass fraction of eleostearic acid quality 15%
Eleostearic acid 20 times of deionized waters of quality are added after changing sodium solution, stirring 10min, to be discharged after 600r/min rotating speeds stirring 30min, are obtained
Resin emulsion；Count by weight, 80 parts of resin emulsions, 15 parts of modified glass flakes mixtures, 1 part of divinyl three are taken respectively
Amine, 2 part of 200 mesh aluminium powder, 1 part of accelerant B YK-4511 and 1 part of defoamer BYK-066N, 1 part of silane coupler KH-560,2 parts
Triethylene tetramine, to be discharged after 300r/min rotating speeds stirring 20min, you can obtain glass-flake coating.
Example 3
In mass ratio 2:1, waste ceramic and kaolinite are weighed respectively, adds in pulverizer and crushes, and are mixed and must be mixed after crossing 90 mesh sieves
Close powder, in mass ratio 1:Mixed-powder is added filtering after immersion in the oxalic acid solution of mass fraction 5%, immersion 40min by 5, is collected
Filter residue, and filter residue is washed with deionized 3 times, collect the filter residue after washing；Filter residue after washing is put into cylindrical type mould,
6min is suppressed under 4MPa, the wet base substrate of shaping is put into baking oven, 7h is dried at 115 DEG C, Muffle is put into after obtaining dry body body
In stove, cooling discharging after 950 DEG C, calcining 3h is warming up to 6 DEG C/min heating rates, calcined material is obtained, calcined material is added and crushed
Crushed in machine, 45 mesh sieves are crossed after crushing, voluminous powder is obtained；Count by weight, 90 parts of glass flake powder, 170 are chosen respectively
Part isopropanol, 9 parts of lauryl sodium sulfate, 11 parts of Triton X-100s and 13 parts of DDAOs,
Added after insulated and stirred 2h in centrifuge, centrifuged under 1100r/min rotating speeds, obtain sediment, sediment is put into baking oven
In, 5h is dried at 90 DEG C, ball milling in ball mill is added after drying, 310 mesh sieves is crossed and obtains modified glass flakes powder；In mass ratio
1:1, eleostearic acid and linoleic acid are weighed respectively and is added in three-necked flask, and three-necked flask is put into oil bath pan, and it is heated to 160 DEG C,
105 DEG C are cooled to after adding 5 times of epoxy resin E51 of eleostearic acid quality, insulated and stirred 25min into three-necked flask, paulownia is subsequently added
45 DEG C are cooled to after sour 7 times of acrylic emulsions of quality, stirring reaction 35min, and adds the hydrogen-oxygen of 7% mass fraction of eleostearic acid quality 15%
Eleostearic acid 25 times of deionized waters of quality are added after changing sodium solution, stirring 12min, to be discharged after 700r/min rotating speeds stirring 35min, are obtained
Resin emulsion；Count by weight, 90 parts of resin emulsions, 20 parts of modified glass flakes mixtures, 2 parts of divinyls three are taken respectively
Amine, 3 part of 210 mesh aluminium powder, 2 parts of accelerant B YK-4511 and 2 parts of defoamer BYK-066N, 2 parts of silane couplers, 3 parts of triethylenes
Tetramine, to be discharged after 350r/min rotating speeds stirring 25min, you can obtain glass-flake coating.
Example 1 to example 3 is painted on the steel substrate surface after cleaning, it is 0.4mm to control the thickness brushed, and waits to brush
After end, through drying, coating is obtained, and according to JB/T224-2007《Firm structural anticorrosion coating for building》Standard, detection apply
Layer.
（1）Water resistance test：Steel substrate after brushing is put into the beaker for filling running water, base material is immersed water
In, stand.
（2）Resistance to salt water is tested：Steel substrate after brushing is put into 5%NaCI solution, base material is immersed in solution,
It is placed under the conditions of 25 ± 2 DEG C, observes the aliquation of base material, bubble, come off, and record the time changed.
（3）Resistance to acids and bases is tested：Steel substrate after brushing is put into mass fraction is 5%H2SO4 or mass fraction is 5%
In NaOH solution, base material is immersed in solution, is placed under the conditions of 25 ± 2 DEG C, observed the aliquation of base material, bubble, come off, and record
The time changed.
According to the method described above, to the detection data such as table 1 of coating.
As can be seen from Table 1, the glass-flake coating physical property that prepared by the present invention is superior, and with preferable anticorrosion energy
Power.
Claims (8)
1. a kind of glass-flake coating, is counted by weight, including 80~100 parts of resin emulsions, 15~25 parts of modified glass squamas
Piece mixture, 1~3 part of diethylenetriamine, 2~4 part of 200~220 mesh aluminium powder, 1~3 part of accelerator and 1~3 part of defoamer, 1~
3 parts of silane couplers and 2~5 parts of triethylene tetramines.
It 2. is characterized in that：Described modified glass flakes mixture is to count by weight, and 10~15 parts of selection is porous respectively
Powder, 80~100 parts of absolute ethyl alcohols, 20~40 parts of modified glass flakes powder and 5~7 parts of paraffin, filter after mixing, must filter
Cake, drying can be obtained.
3. a kind of glass-flake coating according to claim 1, it is characterised in that：Described modified glass flakes powder is
Count by weight, 70~100 parts of glass flake powder, 150~200 parts of isopropanols, 8~10 parts of dodecyl sulphur are chosen respectively
Sour sodium, 10~12 parts of Triton X-100s and 12~15 parts of DDAOs, are centrifuged after stirring,
Sediment, drying, ball milling, sieve to obtain modified glass flakes powder.
4. a kind of glass-flake coating according to claim 1, it is characterised in that：The preparation method of described voluminous powder
For：（1）In mass ratio 2:1, weigh respectively crushed after waste ceramic and kaolinite, mixing, sieve to obtain mixed-powder；（2）By matter
Amount compares 1:Mixed-powder is added filtering after immersion in the oxalic acid solution of mass fraction 5%, 30~50min of immersion by 5, collects filter residue simultaneously
Washing；（3）Filter residue after washing is put into cylindrical type mould, it is compressing, wet base substrate is obtained, is put into after drying in Muffle furnace,
Cooling discharging after 900~1100 DEG C, 2~4h of calcining is warming up to, calcined material is obtained, crushes, sieving obtains voluminous powder.
5. a kind of glass-flake coating according to claim 1, it is characterised in that：Described resin emulsion is propylene yogurt
Liquid modified epoxy is obtained.
6. a kind of glass-flake coating according to claim 4, it is characterised in that：Described epoxy resin can also pass through
Eleostearic acid and linoleic acid are modified.
7. a kind of glass-flake coating according to claim 1, it is characterised in that：Described accelerator is BYK-4511,
Described defoamer is BYK-066N.
8. a kind of glass-flake coating according to claim 1, it is characterised in that：Described silane coupler is KH-
550th, one kind in KH-560 and KH-570.
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| CN109161276A (en) * | 2018-09-18 | 2019-01-08 | 浙江洋铭工贸有限公司 | Paint film and preparation method thereof in radiator |
| CN109554060A (en) * | 2018-12-10 | 2019-04-02 | 郑州艾比利特节能科技有限公司 | A kind of aqueous industrial metallic paint and preparation method thereof |
| CN110373103A (en) * | 2019-08-19 | 2019-10-25 | 蔡樟森 | A kind of anti-water supply line etching ground and preparation method thereof |
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| CN109161276A (en) * | 2018-09-18 | 2019-01-08 | 浙江洋铭工贸有限公司 | Paint film and preparation method thereof in radiator |
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| CN110373103A (en) * | 2019-08-19 | 2019-10-25 | 蔡樟森 | A kind of anti-water supply line etching ground and preparation method thereof |
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