CN106047082A - Scratch-resistant coating for hair dryer and preparation method thereof - Google Patents
Scratch-resistant coating for hair dryer and preparation method thereof Download PDFInfo
- Publication number
- CN106047082A CN106047082A CN201610662859.8A CN201610662859A CN106047082A CN 106047082 A CN106047082 A CN 106047082A CN 201610662859 A CN201610662859 A CN 201610662859A CN 106047082 A CN106047082 A CN 106047082A
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- parts
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- hair dryer
- preparation
- resistant coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a scratch-resistant coating for a hair dryer. The scratch-resistant coating is prepared from the following raw materials: epoxy resin, pure acrylic emulsion, ethyl cellulose, polyacrylonitrile fiber, succinic acid, montmorillonite, propylene glycol, dihydric alcohol ether, a proper amount of water, a catalyst, a curing agent, nanometer silica, aliphatic polycarbonate and organic silica gel. The preparation method comprises the following successive steps: (1) preparing preliminarily mixed liquid; (2) preparing intermediate liquid; (3) preparing mixed liquid; and 4) adding the mixed liquid obtained in the step (3) into a ball mill for grinding and carrying out sieving so as to obtain the finished scratch-resistant coating. The preparation method is scientific and reasonable, improves the scratch resistance of the composition by using organic polymer materials with good performance and carrying out optimized combination, and is low in cost, short in production period and suitable for industrial mass production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of anti-scratch coating of hair dryer and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition
Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with
The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real
Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection
Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual
Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application
Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost
Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of anti-scratch coating of hair dryer and
Its preparation method, this coating products excellent performance, there are good anti-scratch performance, and energy-conserving and environment-protective, possess preferable economy
Benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of anti-scratch coating of hair dryer, is prepared by the raw materials in: epoxy resin 35～45 parts, silicone acrylic emulsion
10～15 parts, ethyl cellulose 2～5 parts, polyacrylonitrile fibre 5～12 parts, succinic acid 8～15 parts, montmorillonite powder 2～6 parts, third
Glycol 1～3 parts, glycol ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, firming agent 1.5～2.5 parts, nanometer titanium dioxide
Silicon 1～5 parts, fatty poly-ester carbonate 5～10 parts, organic silica gel 5～12 parts；
Its preparation method in turn includes the following steps:
(1) succinic acid, montmorillonite powder, propylene glycol, glycol ether, nano silicon and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of epoxy resin, silicone acrylic emulsion, ethyl cellulose, polyacrylonitrile fibre and fatty poly-ester carbonate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, firming agent and organic silica gel,
Mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described firming agent is pyridine.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized
Combination, improves the anti-scratch performance of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, gloss retention
Good, the index such as hot strength is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively
Low, it is achieved that making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrial mass raw
Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of anti-scratch coating of hair dryer, is prepared by the raw materials in: epoxy resin 35 parts, silicone acrylic emulsion 10
Part, ethyl cellulose 2 parts, polyacrylonitrile fibre 5 parts, succinic acid 8 parts, montmorillonite powder 2 parts, propylene glycol 1 part, glycol ether 6 parts,
Water is appropriate, catalyst 1.5 parts, 1.5 parts of firming agent, nano silicon 1 part, fatty poly-ester carbonate 5 parts, organic silica gel 5 parts；
Its preparation method in turn includes the following steps:
(1) succinic acid, montmorillonite powder, propylene glycol, glycol ether, nano silicon and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of epoxy resin, silicone acrylic emulsion, ethyl cellulose, polyacrylonitrile fibre and fatty poly-ester carbonate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, firming agent and organic silica gel,
Mix and blend 50 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of anti-scratch coating of hair dryer, is prepared by the raw materials in: epoxy resin 45 parts, silicone acrylic emulsion 15
Part, ethyl cellulose 5 parts, polyacrylonitrile fibre 12 parts, succinic acid 15 parts, montmorillonite powder 6 parts, propylene glycol 3 parts, glycol ether 12
Part, water is appropriate, catalyst 3 parts, 2.5 parts of firming agent, nano silicon 5 parts, fatty poly-ester carbonate 10 parts, organic silica gel 12
Part；
Its preparation method in turn includes the following steps:
(1) succinic acid, montmorillonite powder, propylene glycol, glycol ether, nano silicon and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of epoxy resin, silicone acrylic emulsion, ethyl cellulose, polyacrylonitrile fibre and fatty poly-ester carbonate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, firming agent and organic silica gel,
Mix and blend 80 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sulfonic acid zinc；
Described firming agent is pyridine.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The anti-scratch performance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength
Being superior to common coating etc. index, can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that money
Making full use of of source and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (3)
1. the anti-scratch coating of hair dryer, it is characterised in that be prepared by the raw materials in: epoxy resin 35～45
Part, silicone acrylic emulsion 10～15 parts, ethyl cellulose 2～5 parts, polyacrylonitrile fibre 5～12 parts, succinic acid 8～15 parts, montmorillonite
Powder 2～6 parts, propylene glycol 1～3 parts, glycol ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, firming agent 1.5～2.5 parts,
Nano silicon 1～5 parts, fatty poly-ester carbonate 5～10 parts, organic silica gel 5～12 parts；
Its preparation method in turn includes the following steps:
(1) succinic acid, montmorillonite powder, propylene glycol, glycol ether, nano silicon and suitable quantity of water are joined reaction vessel
In, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) epoxy resin, silicone acrylic emulsion, ethyl cellulose, polyacrylonitrile fibre and fatty poly-ester carbonate are mixed to join
In the first mixed liquid that step (1) obtains, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, firming agent and organic silica gel, mixing
Stir 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of anti-scratch coating of hair dryer the most according to claim 1, it is characterised in that described catalyst is sulfonic acid zinc.
A kind of anti-scratch coating of hair dryer the most according to claim 1, it is characterised in that described firming agent is pyridine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662859.8A CN106047082A (en) | 2016-08-12 | 2016-08-12 | Scratch-resistant coating for hair dryer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662859.8A CN106047082A (en) | 2016-08-12 | 2016-08-12 | Scratch-resistant coating for hair dryer and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106047082A true CN106047082A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610662859.8A Pending CN106047082A (en) | 2016-08-12 | 2016-08-12 | Scratch-resistant coating for hair dryer and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752678A (en) * | 2016-11-22 | 2017-05-31 | 南京悠谷知识产权服务有限公司 | A kind of refractory coating material and preparation method thereof |
| CN107502018A (en) * | 2017-09-22 | 2017-12-22 | 安徽慕曼德家具有限公司 | A kind of scratch resistant environmental protection paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263042A (en) * | 2014-09-16 | 2015-01-07 | 安徽明都电气有限公司 | Antiseptic antioxidant deodorizing green paint and preparation method thereof |
| CN104341999A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Whitening and anti-aging aqueous coating for glass sliding doors and preparation method of whitening and anti-aging aqueous coating |
| CN104449379A (en) * | 2014-09-15 | 2015-03-25 | 天长市巨龙车船涂料有限公司 | Multifunctional modified asphalt paint capable of improving weathering resistance and enhancing brightness of oil paint and preparation method of multifunctional modified asphalt paint |
| CN105199529A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Modified acrylic ester waterproof coating |
-
2016
- 2016-08-12 CN CN201610662859.8A patent/CN106047082A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449379A (en) * | 2014-09-15 | 2015-03-25 | 天长市巨龙车船涂料有限公司 | Multifunctional modified asphalt paint capable of improving weathering resistance and enhancing brightness of oil paint and preparation method of multifunctional modified asphalt paint |
| CN104263042A (en) * | 2014-09-16 | 2015-01-07 | 安徽明都电气有限公司 | Antiseptic antioxidant deodorizing green paint and preparation method thereof |
| CN104341999A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Whitening and anti-aging aqueous coating for glass sliding doors and preparation method of whitening and anti-aging aqueous coating |
| CN105199529A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Modified acrylic ester waterproof coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752678A (en) * | 2016-11-22 | 2017-05-31 | 南京悠谷知识产权服务有限公司 | A kind of refractory coating material and preparation method thereof |
| CN107502018A (en) * | 2017-09-22 | 2017-12-22 | 安徽慕曼德家具有限公司 | A kind of scratch resistant environmental protection paint |
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Application publication date: 20161026 |