CN106280793A - A kind of electric massager antistatic coating and preparation method thereof - Google Patents
A kind of electric massager antistatic coating and preparation method thereof Download PDFInfo
- Publication number
- CN106280793A CN106280793A CN201610665169.8A CN201610665169A CN106280793A CN 106280793 A CN106280793 A CN 106280793A CN 201610665169 A CN201610665169 A CN 201610665169A CN 106280793 A CN106280793 A CN 106280793A
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- parts
- antistatic
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- modified
- electric massager
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of electric massager antistatic coating, be made up of following raw materials according: be acrylic resin modified, pure-acrylic emulsion, polyanion cellulose, amino resins, maleic acid, ferrophosphorus powder, diethylene glycol, propylene-glycol ethyl ether, water appropriate, catalyst, antistatic auxiliary, nano zine oxide, butyl acetate, modified rosin resin；Its preparation method in turn includes the following steps: the most mixed liquid of (1) preparation；(2) intermediate liquid is prepared；(3) mixed liquor is prepared；(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves the antistatic property of compositions, and its cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric massager antistatic coating and preparation side thereof
Method.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition
Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with
The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real
Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection
Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual
Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application
Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost
Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric massager antistatic is coated with
Material and preparation method thereof, this coating products excellent performance, there are good antistatic property, and energy-conserving and environment-protective, possess preferably
Economic benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric massager antistatic coating, is prepared by the raw materials in: acrylic resin modified 35～45
Part, pure-acrylic emulsion 10～15 parts, polyanion cellulose 2～5 parts, amino resins 5～12 parts, maleic acid 8～15 parts, ferrophosphorus powder
2～6 parts, diethylene glycol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, antistatic auxiliary 1.5～
2.5 parts, nano zine oxide 1～5 parts, butyl acetate 5～10 parts, modified rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrophosphorus powder, diethylene glycol, propylene-glycol ethyl ether, nano zine oxide and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin modified, pure-acrylic emulsion, polyanion cellulose, amino resins and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and Colophonium
Modified resin, mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described antistatic auxiliary is alkyl quaternary ammonium salts.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized
Combination, improves the antistatic property of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, gloss retention
Good, the index such as hot strength is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively
Low, it is achieved that making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrial mass raw
Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric massager antistatic coating, is prepared by the raw materials in: acrylic resin modified 35 parts, pure
Acrylic emulsion 10 parts, polyanion cellulose 2 parts, 5 parts of amino resins, maleic acid 8 parts, 2 parts of ferrophosphorus powder, diethylene glycol 1 part, the third two
Alcohol ether 6 parts, water are appropriate, catalyst 1.5 parts, antistatic auxiliary 1.5 parts, nano zine oxide 1 part, butyl acetate 5 parts, Colophonium change
Property resin 5 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrophosphorus powder, diethylene glycol, propylene-glycol ethyl ether, nano zine oxide and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin modified, pure-acrylic emulsion, polyanion cellulose, amino resins and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and Colophonium
Modified resin, mix and blend 50 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric massager antistatic coating, is prepared by the raw materials in: acrylic resin modified 45 parts, pure
Acrylic emulsion 15 parts, polyanion cellulose 5 parts, 12 parts of amino resins, maleic acid 15 parts, 6 parts of ferrophosphorus powder, diethylene glycol 3 parts, third
Glycol ether 12 parts, water are appropriate, catalyst 3 parts, antistatic auxiliary 2.5 parts, nano zine oxide 5 parts, butyl acetate 10 parts, Colophonium
Modified resin 12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrophosphorus powder, diethylene glycol, propylene-glycol ethyl ether, nano zine oxide and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of acrylic resin modified, pure-acrylic emulsion, polyanion cellulose, amino resins and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and Colophonium
Modified resin, mix and blend 80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sulfonic acid zinc；
Described antistatic auxiliary is alkyl quaternary ammonium salts.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The antistatic property of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength
Being superior to common coating etc. index, can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that money
Making full use of of source and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (3)
1. an electric massager antistatic coating, it is characterised in that be prepared by the raw materials in: modified acroleic acid tree
Fat 35～45 parts, pure-acrylic emulsion 10～15 parts, polyanion cellulose 2～5 parts, amino resins 5～12 parts, maleic acid 8～15
Part, ferrophosphorus powder 2～6 parts, diethylene glycol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water is appropriate, catalyst 1.5～3 parts, antistatic
Auxiliary agent 1.5～2.5 parts, nano zine oxide 1～5 parts, butyl acetate 5～10 parts, modified rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrophosphorus powder, diethylene glycol, propylene-glycol ethyl ether, nano zine oxide and suitable quantity of water are joined reaction vessel
In, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) acrylic resin modified, pure-acrylic emulsion, polyanion cellulose, amino resins and butyl acetate are mixed to join
In the first mixed liquid that step (1) obtains, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and Abietyl modified
Resin, mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric massager antistatic coating the most according to claim 1, it is characterised in that described catalyst is sulfonic acid
Zinc.
A kind of electric massager antistatic coating the most according to claim 1, it is characterised in that described antistatic auxiliary is
Alkyl quaternary ammonium salts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610665169.8A CN106280793A (en) | 2016-08-12 | 2016-08-12 | A kind of electric massager antistatic coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610665169.8A CN106280793A (en) | 2016-08-12 | 2016-08-12 | A kind of electric massager antistatic coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106280793A true CN106280793A (en) | 2017-01-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610665169.8A Pending CN106280793A (en) | 2016-08-12 | 2016-08-12 | A kind of electric massager antistatic coating and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173107A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Washing-resistant antistatic coating and preparation method thereof |
| CN104293187A (en) * | 2014-09-16 | 2015-01-21 | 天长市银狐漆业有限公司 | Anti-aging and anti-static green paint for cabin and preparation method of paint |
| CN104877524A (en) * | 2015-06-28 | 2015-09-02 | 任碧龙 | High-temperature-resistant and antistatic coating |
| CN105647319A (en) * | 2016-01-20 | 2016-06-08 | 赵东星 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
-
2016
- 2016-08-12 CN CN201610665169.8A patent/CN106280793A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173107A (en) * | 2011-12-22 | 2013-06-26 | 深圳市百泉河实业有限公司 | Washing-resistant antistatic coating and preparation method thereof |
| CN104293187A (en) * | 2014-09-16 | 2015-01-21 | 天长市银狐漆业有限公司 | Anti-aging and anti-static green paint for cabin and preparation method of paint |
| CN104877524A (en) * | 2015-06-28 | 2015-09-02 | 任碧龙 | High-temperature-resistant and antistatic coating |
| CN105647319A (en) * | 2016-01-20 | 2016-06-08 | 赵东星 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
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Application publication date: 20170104 |