CN106046947A - Electric iron antibacterial coating and preparation method thereof - Google Patents
Electric iron antibacterial coating and preparation method thereof Download PDFInfo
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- CN106046947A CN106046947A CN201610668023.9A CN201610668023A CN106046947A CN 106046947 A CN106046947 A CN 106046947A CN 201610668023 A CN201610668023 A CN 201610668023A CN 106046947 A CN106046947 A CN 106046947A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses an electric iron antibacterial coating prepared from the following raw materials: cellulose resin, a pure acrylic emulsion, polymethyl methacrylate, epoxy resin, aliphatic dicarboxylic acid, wollastonite in powder, ethanol, propylene glycol ether, a proper amount of water, a catalyst, an antibacterial agent, nano zinc oxide, propylene glycol methyl ether acetate and an epoxy adhesive. A preparation method successively comprises the following steps: (1) preparing a primary mixture; (2) preparing an intermediate liquid; (3) preparing a mixed liquid; and (4) putting the mixed liquid obtained in the step (3) into a ball mill, carrying out grinding treatment, and sieving to obtain the finished product. The preparation method is scientific and reasonable, the organic polymer materials having relatively excellent comprehensive performance are adopted for optimal combination, and the antibacterial property of the composition is improved; and the coating has the advantages of relatively low cost and short production cycle, and is suitable for industrialized mass production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric iron antibiotic paint and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition
Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with
The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real
Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection
Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual
Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application
Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost
Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric iron antibiotic paint and
Preparation method, this coating products excellent performance, there are good anti-microbial property, and energy-conserving and environment-protective, possess preferable economic benefit
And social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric iron antibiotic paint, is prepared by the raw materials in: celluosic resin 35～45 parts, pure-acrylic emulsion
10～15 parts, polymethyl methacrylate 2～5 parts, epoxy resin 5～12 parts, aliphatic dicarboxylic acid 8～15 parts, wollastonite in powder 2
～6 parts, ethanol 1～3 parts, propylene glycol monomethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, antibacterial 1.5～2.5 parts, receive
Rice zinc oxide 1～5 parts, propylene glycol methyl ether acetate 5～10 parts, epoxy glue 5～12 parts；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, wollastonite in powder, ethanol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined instead
Answer in container, be heated to 50～65 DEG C, stir 20～30 minutes under 900～1200 revs/min, obtain the most mixed after mix homogeneously
Liquid；
(2) by celluosic resin, pure-acrylic emulsion, polymethyl methacrylate, epoxy resin and propylene glycol methyl ether acetate
It is mixed to join in the first mixed liquid that step (1) obtains, is heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed
Close stirring 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sodium sulfonate.
Preferably, described antibacterial is copper oxide.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized
Combination, improves the anti-microbial property of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good,
The indexs such as hot strength are superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low,
Achieving making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production,
Possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric iron antibiotic paint, is prepared by the raw materials in: celluosic resin 35 parts, pure-acrylic emulsion 10
Part, polymethyl methacrylate 2 parts, epoxy resin 5 parts, aliphatic dicarboxylic acid 8 parts, wollastonite in powder 2 parts, ethanol 1 part, propylene glycol
Methyl ether 6 parts, water are appropriate, catalyst 1.5 parts, antibacterial 1.5 parts, nano zine oxide 1 part, propylene glycol methyl ether acetate 5 parts, epoxy
5 parts of glue；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, wollastonite in powder, ethanol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined instead
Answer in container, be heated to 50～65 DEG C, stir 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) by celluosic resin, pure-acrylic emulsion, polymethyl methacrylate, epoxy resin and propylene glycol methyl ether acetate
It is mixed to join in the first mixed liquid that step (1) obtains, is heated to 65～80 DEG C, continue stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed
Close stirring 50 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric iron antibiotic paint, is prepared by the raw materials in: celluosic resin 45 parts, pure-acrylic emulsion 15
Part, polymethyl methacrylate 5 parts, epoxy resin 12 parts, aliphatic dicarboxylic acid 15 parts, wollastonite in powder 6 parts, ethanol 3 parts, the third two
Alcohol methyl ether 12 parts, water are appropriate, catalyst 3 parts, antibacterial 2.5 parts, nano zine oxide 5 parts, propylene glycol methyl ether acetate 10 parts, ring
12 parts of oxygen glue；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, wollastonite in powder, ethanol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined instead
Answer in container, be heated to 50～65 DEG C, stir 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) by celluosic resin, pure-acrylic emulsion, polymethyl methacrylate, epoxy resin and propylene glycol methyl ether acetate
It is mixed to join in the first mixed liquid that step (1) obtains, is heated to 65～80 DEG C, continue stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed
Close stirring 80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sodium sulfonate；
Described antibacterial is copper oxide.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The anti-microbial property of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength etc.
Index is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that resource
With making full use of of the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (3)
1. an electric iron antibiotic paint, it is characterised in that be prepared by the raw materials in: celluosic resin 35～45
Part, pure-acrylic emulsion 10～15 parts, polymethyl methacrylate 2～5 parts, epoxy resin 5～12 parts, aliphatic dicarboxylic acid 8～15
Part, wollastonite in powder 2～6 parts, ethanol 1～3 parts, propylene glycol monomethyl ether 6～12 parts, water is appropriate, catalyst 1.5～3 parts, antibacterial
1.5～2.5 parts, nano zine oxide 1～5 parts, propylene glycol methyl ether acetate 5～10 parts, epoxy glue 5～12 parts；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, wollastonite in powder, ethanol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water join reaction to hold
In device, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) celluosic resin, pure-acrylic emulsion, polymethyl methacrylate, epoxy resin and propylene glycol methyl ether acetate are mixed
Join in the first mixed liquid that step (1) obtains, be heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains being cooled to 40～50 DEG C, add catalyst, antibacterial and epoxy glue, mixing is stirred
Mix 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric iron antibiotic paint the most according to claim 1, it is characterised in that described catalyst is sodium sulfonate.
A kind of electric iron antibiotic paint the most according to claim 1, it is characterised in that described antibacterial is copper oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610668023.9A CN106046947A (en) | 2016-08-12 | 2016-08-12 | Electric iron antibacterial coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610668023.9A CN106046947A (en) | 2016-08-12 | 2016-08-12 | Electric iron antibacterial coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046947A true CN106046947A (en) | 2016-10-26 |
Family
ID=57480862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610668023.9A Pending CN106046947A (en) | 2016-08-12 | 2016-08-12 | Electric iron antibacterial coating and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106046947A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157813A (en) * | 2007-09-12 | 2008-04-09 | 深圳市广田环保涂料有限公司 | Electroplating effect imitated plastic paint and preparation method, diluent and process of using same |
| CN102585681A (en) * | 2012-02-08 | 2012-07-18 | 上海三恩化工有限公司 | Coating for automobile sealing strip and preparation method thereof |
| CN104031425A (en) * | 2014-05-12 | 2014-09-10 | 谷屿 | Modified nanometer titanium dioxide with bacteriostatic and antibacterial effects and preparation method thereof |
| CN105062262A (en) * | 2015-08-05 | 2015-11-18 | 天长市开林化工有限公司 | Building interior wall special-purpose antibacterial mildew-resistant emulsion paint |
-
2016
- 2016-08-12 CN CN201610668023.9A patent/CN106046947A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157813A (en) * | 2007-09-12 | 2008-04-09 | 深圳市广田环保涂料有限公司 | Electroplating effect imitated plastic paint and preparation method, diluent and process of using same |
| CN102585681A (en) * | 2012-02-08 | 2012-07-18 | 上海三恩化工有限公司 | Coating for automobile sealing strip and preparation method thereof |
| CN104031425A (en) * | 2014-05-12 | 2014-09-10 | 谷屿 | Modified nanometer titanium dioxide with bacteriostatic and antibacterial effects and preparation method thereof |
| CN105062262A (en) * | 2015-08-05 | 2015-11-18 | 天长市开林化工有限公司 | Building interior wall special-purpose antibacterial mildew-resistant emulsion paint |
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Application publication date: 20161026 |
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