CN106047109A - Antibacterial coating for electric massager and preparation method thereof - Google Patents

Antibacterial coating for electric massager and preparation method thereof Download PDF

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Publication number
CN106047109A
CN106047109A CN201610665238.5A CN201610665238A CN106047109A CN 106047109 A CN106047109 A CN 106047109A CN 201610665238 A CN201610665238 A CN 201610665238A CN 106047109 A CN106047109 A CN 106047109A
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CN
China
Prior art keywords
parts
antibacterial
preparation
electric massager
mixed liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610665238.5A
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Chinese (zh)
Inventor
韩梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing Seven Fairy Electric Appliance Manufacturing Co Ltd
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Anqing Seven Fairy Electric Appliance Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anqing Seven Fairy Electric Appliance Manufacturing Co Ltd filed Critical Anqing Seven Fairy Electric Appliance Manufacturing Co Ltd
Priority to CN201610665238.5A priority Critical patent/CN106047109A/en
Publication of CN106047109A publication Critical patent/CN106047109A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antibacterial coating for an electric massager. The antibacterial coating is prepared from the following raw materials: alkyd resin, silicone-acrylic emulsion, polymethyl methacrylate, polyurethane resin, aliphatic dicarboxylic acid, jade powder, polyester diol, propylene glycol methyl ether, a proper amount of water, a catalyst, an antibacterial agent, nanometer zinc oxide, dimethyl carbonate and epoxy glue. The preparation method comprises the following successive steps: (1) preparing preliminarily mixed liquid; (2) preparing intermediate liquid; (3) preparing mixed liquid; and (4) adding the mixed liquid obtained in the step (3) into a ball mill for grinding and carrying out sieving so as to obtain the finished antibacterial coating. The preparation method is scientific and reasonable, improves the antibacterial resistance of the composition by using organic polymer materials with good performance and carrying out optimized combination, and is low in cost, short in production period and suitable for industrial mass production.

Description

A kind of electric massager antibiotic paint and preparation method thereof
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric massager antibiotic paint and preparation side thereof Method.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric massager antibiotic paint And preparation method thereof, this coating products excellent performance, there are good anti-microbial property, and energy-conserving and environment-protective, possess preferable economy Benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric massager antibiotic paint, is prepared by the raw materials in: alkyd resin 35~45 parts, silicon the third breast Liquid 10~15 parts, polymethyl methacrylate 2~5 parts, polyurethane resin 5~12 parts, aliphatic dicarboxylic acid 8~15 parts, jade Powder 2~6 parts, polyester-diol 1~3 parts, propylene glycol monomethyl ether 6~12 parts, water are appropriate, catalyst 1.5~3 parts, antibacterial 1.5~ 2.5 parts, nano zine oxide 1~5 parts, dimethyl carbonate 5~10 parts, epoxy glue 5~12 parts;
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, jade powder, polyester-diol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined In reaction vessel, it is heated to 50~65 DEG C, stirs 20~30 minutes under 900~1200 revs/min, obtain the most mixed after mix homogeneously Liquid;
(2) mixing of alkyd resin, silicone acrylic emulsion, polymethyl methacrylate, polyurethane resin and dimethyl carbonate is added Enter to step (1) in the first mixed liquid obtained, be heated to 65~80 DEG C, continue stirring 30~40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed Close stirring 50~80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sodium sulfonate.
Preferably, described antibacterial is ammonium dihydrogen phosphate.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized Combination, improves the anti-microbial property of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, The indexs such as hot strength are superior to common coating, and can meet coated-body the most comprehensively uses requirement;Cost of the present invention is relatively low, Achieving making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production, Possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric massager antibiotic paint, is prepared by the raw materials in: alkyd resin 35 parts, silicone acrylic emulsion 10 Part, polymethyl methacrylate 2 parts, polyurethane resin 5 parts, aliphatic dicarboxylic acid 8 parts, jade powder 2 parts, polyester-diol 1 part, third Glycol methyl ether 6 parts, water are appropriate, catalyst 1.5 parts, antibacterial 1.5 parts, nano zine oxide 1 part, dimethyl carbonate 5 parts, epoxy glue 5 parts;
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, jade powder, polyester-diol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined In reaction vessel, it is heated to 50~65 DEG C, stirs 20 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) mixing of alkyd resin, silicone acrylic emulsion, polymethyl methacrylate, polyurethane resin and dimethyl carbonate is added Enter to step (1) in the first mixed liquid obtained, be heated to 65~80 DEG C, continue stirring 30 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed Close stirring 50 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric massager antibiotic paint, is prepared by the raw materials in: alkyd resin 45 parts, silicone acrylic emulsion 15 Part, polymethyl methacrylate 5 parts, polyurethane resin 12 parts, aliphatic dicarboxylic acid 15 parts, jade powder 6 parts, polyester-diol 3 parts, Propylene glycol monomethyl ether 12 parts, water are appropriate, catalyst 3 parts, antibacterial 2.5 parts, nano zine oxide 5 parts, dimethyl carbonate 10 parts, epoxy 12 parts of glue;
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, jade powder, polyester-diol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined In reaction vessel, it is heated to 50~65 DEG C, stirs 30 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) mixing of alkyd resin, silicone acrylic emulsion, polymethyl methacrylate, polyurethane resin and dimethyl carbonate is added Enter to step (1) in the first mixed liquid obtained, be heated to 65~80 DEG C, continue stirring 40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains is cooled to 40~50 DEG C, adds catalyst, antibacterial and epoxy glue, mixed Close stirring 80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sodium sulfonate;
Described antibacterial is ammonium dihydrogen phosphate.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve The anti-microbial property of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength etc. Index is superior to common coating, and can meet coated-body the most comprehensively uses requirement;Cost of the present invention is relatively low, it is achieved that resource With making full use of of the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (3)

1. an electric massager antibiotic paint, it is characterised in that be prepared by the raw materials in: alkyd resin 35~45 Part, silicone acrylic emulsion 10~15 parts, polymethyl methacrylate 2~5 parts, polyurethane resin 5~12 parts, aliphatic dicarboxylic acid 8~ 15 parts, jade powder 2~6 parts, polyester-diol 1~3 parts, propylene glycol monomethyl ether 6~12 parts, water are appropriate, catalyst 1.5~3 parts, antibacterial Agent 1.5~2.5 parts, nano zine oxide 1~5 parts, dimethyl carbonate 5~10 parts, epoxy glue 5~12 parts;
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, jade powder, polyester-diol, propylene glycol monomethyl ether, nano zine oxide and suitable quantity of water are joined reaction In container, it is heated to 50~65 DEG C, stirs 20~30 minutes under 900~1200 revs/min, after mix homogeneously, obtain the most mixed liquid;
(2) alkyd resin, silicone acrylic emulsion, polymethyl methacrylate, polyurethane resin and dimethyl carbonate are mixed to join In the first mixed liquid that step (1) obtains, it is heated to 65~80 DEG C, continues stirring 30~40 minutes, obtain intermediate liquid;
(3) intermediate liquid that step (2) obtains being cooled to 40~50 DEG C, add catalyst, antibacterial and epoxy glue, mixing is stirred Mix 50~80 minutes, obtain mixed liquor;
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric massager antibiotic paint the most according to claim 1, it is characterised in that described catalyst is sulfonic acid Sodium.
A kind of electric massager antibiotic paint the most according to claim 1, it is characterised in that described antibacterial is di(2-ethylhexyl)phosphate Hydrogen ammonium.
CN201610665238.5A 2016-08-12 2016-08-12 Antibacterial coating for electric massager and preparation method thereof Pending CN106047109A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610665238.5A CN106047109A (en) 2016-08-12 2016-08-12 Antibacterial coating for electric massager and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610665238.5A CN106047109A (en) 2016-08-12 2016-08-12 Antibacterial coating for electric massager and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106047109A true CN106047109A (en) 2016-10-26

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486863A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly waterborne paint and preparation thereof
CN102702889A (en) * 2012-06-01 2012-10-03 安徽省金盾涂料有限责任公司 Anti-bacterial water-based paint and preparation method thereof
CN104403455A (en) * 2014-11-28 2015-03-11 安徽省金盾涂料有限责任公司 Safe, environment-friendly, heat-resisting and antibacterial water-based paint
CN103937360B (en) * 2013-01-17 2016-06-22 深圳市莱莉雅环保科技有限公司 A kind of preparation method of low-temperature setting Water-based glass baking paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486863A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly waterborne paint and preparation thereof
CN102702889A (en) * 2012-06-01 2012-10-03 安徽省金盾涂料有限责任公司 Anti-bacterial water-based paint and preparation method thereof
CN103937360B (en) * 2013-01-17 2016-06-22 深圳市莱莉雅环保科技有限公司 A kind of preparation method of low-temperature setting Water-based glass baking paint
CN104403455A (en) * 2014-11-28 2015-03-11 安徽省金盾涂料有限责任公司 Safe, environment-friendly, heat-resisting and antibacterial water-based paint

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Application publication date: 20161026