CN106189708A - A kind of hair dryer aging resistant coating and preparation method thereof - Google Patents
A kind of hair dryer aging resistant coating and preparation method thereof Download PDFInfo
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- CN106189708A CN106189708A CN201610662365.XA CN201610662365A CN106189708A CN 106189708 A CN106189708 A CN 106189708A CN 201610662365 A CN201610662365 A CN 201610662365A CN 106189708 A CN106189708 A CN 106189708A
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- hair dryer
- resistant coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of hair dryer aging resistant coating, be made up of following raw materials according: epoxy resin, acrylate and vinyl acetate emulsion, butadiene-styrene rubber, polyimides, aliphatic dicarboxylic acid, Kaolin, isobutanol, propylene-glycol ethyl ether, water are appropriate, catalyst, antioxidant, nano silicon, urethane acrylate, rosin resin；Its preparation method in turn includes the following steps: the most mixed liquid of (1) preparation；(2) intermediate liquid is prepared；(3) mixed liquor is prepared；(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves the ageing-resistant performance of compositions, and its cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of hair dryer aging resistant coating and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition
Green economy globalization overall situation under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with
The environmental protection such as newly " environmental law " promulgates, country " environmental protection, beautiful China " advocate the most no longer to stay on slogan, but real
Execute execution, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water of environmental protection
Property coating etc. substitute, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, more environmentally friendly, more individual
Property has become as the pursuit direction of household electrical appliances coating.Before the market demand huge in the face of household electrical appliances coating and ever-increasing application
Scape, strengthens research and development capabilities, and updates and improving product performance, accelerates product quality upgrading, develops technically, cost
Above, the household electrical appliances coating more showing powerful competitive advantage in performance has the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of hair dryer aging resistant coating and
Its preparation method, this coating products excellent performance, there are good ageing-resistant performance, and energy-conserving and environment-protective, possess preferable economy
Benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of hair dryer aging resistant coating, is prepared by the raw materials in: epoxy resin 35～45 parts, acrylate and vinyl acetate emulsion
10～15 parts, butadiene-styrene rubber 2～5 parts, polyimides 5～12 parts, aliphatic dicarboxylic acid 8～15 parts, Kaolin 2～6 parts, isobutyl
Alcohol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, antioxidant 1.5～2.5 parts, nanometer titanium dioxide
Silicon 1～5 parts, urethane acrylate 5～10 parts, rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, Kaolin, isobutanol, propylene-glycol ethyl ether, nano silicon and suitable quantity of water are joined
In reaction vessel, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, obtain the most mixed after mix homogeneously
Liquid；
(2) epoxy resin, acrylate and vinyl acetate emulsion, butadiene-styrene rubber, polyimides and urethane acrylate are mixed to join step
Suddenly in the first mixed liquid that (1) obtains, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antioxidant and rosin resin,
Mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sodium sulfonate.
Preferably, described antioxidant is dihydroquinoline.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and being optimized
Combination, improves the ageing-resistant performance of compositions, and the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, gloss retention
Good, the index such as hot strength is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively
Low, it is achieved that making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrial mass raw
Produce, possess preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of hair dryer aging resistant coating, is prepared by the raw materials in: epoxy resin 35 parts, acrylate and vinyl acetate emulsion 10
Part, 2 parts of butadiene-styrene rubber, polyimides 5 parts, aliphatic dicarboxylic acid 8 parts, Kaolin 2 parts, isobutanol 1 part, propylene-glycol ethyl ether 6 parts,
Water is appropriate, catalyst 1.5 parts, 1.5 parts of antioxidant, nano silicon 1 part, urethane acrylate 5 parts, rosin resin 5 parts；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, Kaolin, isobutanol, propylene-glycol ethyl ether, nano silicon and suitable quantity of water are joined
In reaction vessel, it is heated to 50～65 DEG C, stirs 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) epoxy resin, acrylate and vinyl acetate emulsion, butadiene-styrene rubber, polyimides and urethane acrylate are mixed to join step
Suddenly in the first mixed liquid that (1) obtains, it is heated to 65～80 DEG C, continues stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antioxidant and rosin resin,
Mix and blend 50 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of hair dryer aging resistant coating, is prepared by the raw materials in: epoxy resin 45 parts, acrylate and vinyl acetate emulsion 15
Part, 5 parts of butadiene-styrene rubber, polyimides 12 parts, aliphatic dicarboxylic acid 15 parts, Kaolin 6 parts, isobutanol 3 parts, propylene-glycol ethyl ether 12
Part, water is appropriate, catalyst 3 parts, 2.5 parts of antioxidant, nano silicon 5 parts, urethane acrylate 10 parts, rosin resin 12
Part；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, Kaolin, isobutanol, propylene-glycol ethyl ether, nano silicon and suitable quantity of water are joined
In reaction vessel, it is heated to 50～65 DEG C, stirs 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) epoxy resin, acrylate and vinyl acetate emulsion, butadiene-styrene rubber, polyimides and urethane acrylate are mixed to join step
Suddenly in the first mixed liquid that (1) obtains, it is heated to 65～80 DEG C, continues stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antioxidant and rosin resin,
Mix and blend 80 minutes, obtains mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sodium sulfonate；
Described antioxidant is dihydroquinoline.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The ageing-resistant performance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength
Being superior to common coating etc. index, can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that money
Making full use of of source and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (3)
1. a hair dryer aging resistant coating, it is characterised in that be prepared by the raw materials in: epoxy resin 35～45
Part, acrylate and vinyl acetate emulsion 10～15 parts, butadiene-styrene rubber 2～5 parts, polyimides 5～12 parts, aliphatic dicarboxylic acid 8～15 parts, Kaolin
2～6 parts, isobutanol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, antioxidant 1.5～2.5 parts,
Nano silicon 1～5 parts, urethane acrylate 5～10 parts, rosin resin 5～12 parts；
Its preparation method in turn includes the following steps:
(1) aliphatic dicarboxylic acid, Kaolin, isobutanol, propylene-glycol ethyl ether, nano silicon and suitable quantity of water are joined reaction
In container, it is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) epoxy resin, acrylate and vinyl acetate emulsion, butadiene-styrene rubber, polyimides and urethane acrylate are mixed to join step (1)
In the first mixed liquid obtained, it is heated to 65～80 DEG C, continues stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antioxidant and rosin resin, mixing
Stir 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of hair dryer aging resistant coating the most according to claim 1, it is characterised in that described catalyst is sodium sulfonate.
A kind of hair dryer aging resistant coating the most according to claim 1, it is characterised in that described antioxidant is dihydro quinoline
Quinoline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662365.XA CN106189708A (en) | 2016-08-12 | 2016-08-12 | A kind of hair dryer aging resistant coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662365.XA CN106189708A (en) | 2016-08-12 | 2016-08-12 | A kind of hair dryer aging resistant coating and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106189708A true CN106189708A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610662365.XA Pending CN106189708A (en) | 2016-08-12 | 2016-08-12 | A kind of hair dryer aging resistant coating and preparation method thereof |
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| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131268A (en) * | 2011-11-23 | 2013-06-05 | 天津市新丽华色材有限责任公司 | Exterior wall painting paint and preparation method thereof |
| CN104073041A (en) * | 2014-07-24 | 2014-10-01 | 周彩球 | Steel surface treatment paint |
| CN104073044A (en) * | 2014-07-24 | 2014-10-01 | 梁胜光 | Rust-removing and corrosion-resisting polymer paint |
| CN104610872A (en) * | 2015-01-28 | 2015-05-13 | 芜湖县双宝建材有限公司 | Water-tolerant and ageing-resistant waterborne polyurethane coating |
-
2016
- 2016-08-12 CN CN201610662365.XA patent/CN106189708A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131268A (en) * | 2011-11-23 | 2013-06-05 | 天津市新丽华色材有限责任公司 | Exterior wall painting paint and preparation method thereof |
| CN104073041A (en) * | 2014-07-24 | 2014-10-01 | 周彩球 | Steel surface treatment paint |
| CN104073044A (en) * | 2014-07-24 | 2014-10-01 | 梁胜光 | Rust-removing and corrosion-resisting polymer paint |
| CN104610872A (en) * | 2015-01-28 | 2015-05-13 | 芜湖县双宝建材有限公司 | Water-tolerant and ageing-resistant waterborne polyurethane coating |
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Application publication date: 20161207 |