CN105647319A - Anti-static nano water-based anticorrosive paint and preparation method thereof - Google Patents
Anti-static nano water-based anticorrosive paint and preparation method thereof Download PDFInfo
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- CN105647319A CN105647319A CN201610034484.0A CN201610034484A CN105647319A CN 105647319 A CN105647319 A CN 105647319A CN 201610034484 A CN201610034484 A CN 201610034484A CN 105647319 A CN105647319 A CN 105647319A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses anti-static nano water-based anticorrosive paint and a preparation method thereof. The paint is prepared from pure acrylic emulsion, polyurethane emulsion, hydroxy propyl cellulose, nanosilicon dioxide, isothiazolone, mica powder, talcum powder, sodium dodecyl sulfate, fluoroethylene carbonate, heptadecanoic acide, glass fibers and brominated epoxy resin. The preparation method comprises the steps of weighing all raw materials according to the compounding ratio, dissolving the raw materials into water, conducting stirring so that the raw materials can be mixed uniformly, conducting grinding, adding slurry obtained after grinding to the pure acrylic emulsion and the polyurethane emulsion, conducting mixing uniformly, continuing with grinding and dispersion in a grinder, and leaving the mixture standing still at the room temperature, so that the anti-static nano water-based anticorrosive paint is obtained. The paint is large in surface resistance, good anti-static capability is displayed, the raw materials are low in cost and easy to obtain, and the paint is suitable for being used widely; the paint is good in water resistance and acid resistance, excellent in anticorrosive property, long in actual service life, stable, safe, environmentally friendly, excellent in performance and wide in application.
Description
Technical field
The present invention relates to chemistry painting industry field, specifically a kind of anti-electrostatic nano water-based anticorrosive paint and preparation method thereof.
Background technology
In numerous safeguard procedures, application is one of the most simple and efficient effective safeguard procedures. Application is that coating is coated on device product surface, can play insulating effect to reduce the external environment corrosion to device product, the service life of extension device, reduces use cost. Along with people are more and more higher to the requirement of living environment, increasingly attaching importance to environmental protection problem. But most anticorrosive paints contain volatile organic solvent on the market at present, some volatile matters are poisonous even can be carcinogenic, drastically influence the health of people; Additionally, popularizing along with electronic product, the electromagnetic wave signal of surrounding is increasingly stronger, and radiation interference is also increasingly severe, thus the antistatic effect of device product be it is also proposed higher requirement. Therefore existing coating must be improved, to meet the needs of modern social development.
Summary of the invention
It is an object of the invention to provide a kind of anti-electrostatic nano water-based anticorrosive paint and preparation method thereof, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of anti-electrostatic nano water-based anticorrosive paint, is prepared from by the raw material of following weight portion: pure-acrylic emulsion 30��40 parts, polyaminoester emulsion 25��35 parts, hydroxypropyl cellulose 18��22 parts, nano silicon 19��21 parts, isothiazolone 8��10 parts, mica powder 12��14 parts, Pulvis Talci 11��13 parts, dodecyl sodium sulfate 15��17 parts, fluorinated ethylene carbonate 7��9 parts, heptadecanoic acid 13��15 parts, glass fibre 17��19 parts, brominated epoxy resin 16��18 parts.
A kind of preparation method of described anti-electrostatic nano water-based anticorrosive paint, concrete preparation process is as follows:
(1) each raw material is weighed by proportioning, standby
(2) raw material hydroxypropyl cellulose, nano silicon, isothiazolone, mica powder, Pulvis Talci, dodecyl sodium sulfate, fluorinated ethylene carbonate, heptadecanoic acid, glass fibre and brominated epoxy resin are dissolved in the water, stirring 3��4h, mix homogeneously, is ground to 1400��1600 orders by slurry;
(3) pure-acrylic emulsion, polyaminoester emulsion are added the slurry after grinding, mix homogeneously, grinder continues grinding distribution 2��3h, left at room temperature 8��10h, to obtain final product.
Compared with prior art, the invention has the beneficial effects as follows:
The sheet resistance of coating of the present invention is big, shows good antistatic effect, and cost of material is low and is easy to get, and is suitable for widely using; Coating of the present invention has good resistance to water and acid resistance, has an outstanding antiseptic property, actual life length and stable, safety and environmental protection, excellent performance, use extensively.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments. Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment 1
Anti-electrostatic nano water-based anticorrosive paint, is prepared from by the raw material of following weight portion: pure-acrylic emulsion 30 parts, polyaminoester emulsion 35 parts, hydroxypropyl cellulose 18 parts, nano silicon 21 parts, isothiazolone 8 parts, mica powder 14 parts, Pulvis Talci 11 parts, dodecyl sodium sulfate 17 parts, fluorinated ethylene carbonate 7 parts, heptadecanoic acid 15 parts, glass fibre 17 parts, brominated epoxy resin 18 parts.
In above-described embodiment, the preparation process of anti-electrostatic nano water-based anticorrosive paint is as follows:
(1) each raw material is weighed by proportioning, standby
(2) raw material hydroxypropyl cellulose, nano silicon, isothiazolone, mica powder, Pulvis Talci, dodecyl sodium sulfate, fluorinated ethylene carbonate, heptadecanoic acid, glass fibre and brominated epoxy resin are dissolved in the water, stirring 3h, mix homogeneously, is ground to 1400 orders by slurry;
(3) pure-acrylic emulsion, polyaminoester emulsion are added the slurry after grinding, mix homogeneously, grinder continues grinding distribution 2h, left at room temperature 8h, to obtain final product.
Embodiment 2
Anti-electrostatic nano water-based anticorrosive paint, is prepared from by the raw material of following weight portion: pure-acrylic emulsion 35 parts, polyaminoester emulsion 30 parts, hydroxypropyl cellulose 20 parts, nano silicon 20 parts, isothiazolone 9 parts, mica powder 13 parts, Pulvis Talci 12 parts, dodecyl sodium sulfate 16 parts, fluorinated ethylene carbonate 8 parts, heptadecanoic acid 14 parts, glass fibre 18 parts, brominated epoxy resin 17 parts.
In above-described embodiment, the preparation process of anti-electrostatic nano water-based anticorrosive paint is as follows:
(1) each raw material is weighed by proportioning, standby
(2) raw material hydroxypropyl cellulose, nano silicon, isothiazolone, mica powder, Pulvis Talci, dodecyl sodium sulfate, fluorinated ethylene carbonate, heptadecanoic acid, glass fibre and brominated epoxy resin are dissolved in the water, stirring 3.5h, mix homogeneously, is ground to 1500 orders by slurry;
(3) pure-acrylic emulsion, polyaminoester emulsion are added the slurry after grinding, mix homogeneously, grinder continues grinding distribution 2.5h, left at room temperature 9h, to obtain final product.
Embodiment 3
Anti-electrostatic nano water-based anticorrosive paint, is prepared from by the raw material of following weight portion: pure-acrylic emulsion 40 parts, polyaminoester emulsion 25 parts, hydroxypropyl cellulose 22 parts, nano silicon 19 parts, isothiazolone 10 parts, mica powder 12 parts, Pulvis Talci 13 parts, dodecyl sodium sulfate 15 parts, fluorinated ethylene carbonate 9 parts, heptadecanoic acid 13 parts, glass fibre 19 parts, brominated epoxy resin 16 parts.
In above-described embodiment, the preparation process of anti-electrostatic nano water-based anticorrosive paint is as follows:
(1) each raw material is weighed by proportioning, standby
(2) raw material hydroxypropyl cellulose, nano silicon, isothiazolone, mica powder, Pulvis Talci, dodecyl sodium sulfate, fluorinated ethylene carbonate, heptadecanoic acid, glass fibre and brominated epoxy resin are dissolved in the water, stirring 4h, mix homogeneously, is ground to 1600 orders by slurry;
(3) pure-acrylic emulsion, polyaminoester emulsion are added the slurry after grinding, mix homogeneously, grinder continues grinding distribution 3h, left at room temperature 10h, to obtain final product.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when without departing substantially from the spirit of the present invention or basic feature, it is possible to realize the present invention in other specific forms. Therefore, no matter from which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the invention rather than described above limits, it is intended that all changes in the implication of the equivalency dropping on claim and scope included in the present invention.
Claims (2)
1. an anti-electrostatic nano water-based anticorrosive paint, it is characterised in that be prepared from by the raw material of following weight portion: pure-acrylic emulsion 30��40 parts, polyaminoester emulsion 25��35 parts, hydroxypropyl cellulose 18��22 parts, nano silicon 19��21 parts, isothiazolone 8��10 parts, mica powder 12��14 parts, Pulvis Talci 11��13 parts, dodecyl sodium sulfate 15��17 parts, fluorinated ethylene carbonate 7��9 parts, heptadecanoic acid 13��15 parts, glass fibre 17��19 parts, brominated epoxy resin 16��18 parts.
2. the preparation method of an anti-electrostatic nano water-based anticorrosive paint as claimed in claim 1, it is characterised in that concrete preparation process is as follows:
(1) each raw material is weighed by proportioning, standby
(2) raw material hydroxypropyl cellulose, nano silicon, isothiazolone, mica powder, Pulvis Talci, dodecyl sodium sulfate, fluorinated ethylene carbonate, heptadecanoic acid, glass fibre and brominated epoxy resin are dissolved in the water, stirring 3��4h, mix homogeneously, is ground to 1400��1600 orders by slurry;
(3) pure-acrylic emulsion, polyaminoester emulsion are added the slurry after grinding, mix homogeneously, grinder continues grinding distribution 2��3h, left at room temperature 8��10h, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610034484.0A CN105647319A (en) | 2016-01-20 | 2016-01-20 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610034484.0A CN105647319A (en) | 2016-01-20 | 2016-01-20 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
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| CN105647319A true CN105647319A (en) | 2016-06-08 |
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| CN201610034484.0A Pending CN105647319A (en) | 2016-01-20 | 2016-01-20 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010156A (en) * | 2016-08-12 | 2016-10-12 | 安庆市七仙女电器制造有限公司 | Electric iron antistatic paint and preparation method thereof |
| CN106147547A (en) * | 2016-08-12 | 2016-11-23 | 安庆市七仙女电器制造有限公司 | A kind of electric massager anticorrosive coating and preparation method thereof |
| CN106243996A (en) * | 2016-08-12 | 2016-12-21 | 安庆市七仙女电器制造有限公司 | A kind of desk lamp antistatic coating and preparation method thereof |
| CN106243954A (en) * | 2016-08-01 | 2016-12-21 | 安庆瑞泰化工有限公司 | A kind of Antistatic type water paint and preparation method thereof |
| CN106280793A (en) * | 2016-08-12 | 2017-01-04 | 安庆市七仙女电器制造有限公司 | A kind of electric massager antistatic coating and preparation method thereof |
| CN106590103A (en) * | 2016-12-15 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Water-borne anti-corrosion coating and preparing method thereof |
| CN107880317A (en) * | 2017-11-13 | 2018-04-06 | 郑州诚合信息技术有限公司 | A kind of anti-fog thin film and preparation method thereof |
| CN108102533A (en) * | 2017-12-26 | 2018-06-01 | 龙口德源高分子科技有限公司 | A kind of high performance water proof anti-corrosive paint and preparation method thereof |
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| CN102352171A (en) * | 2011-09-16 | 2012-02-15 | 中华制漆（深圳）有限公司 | Novel environment-friendly coating with superhigh marine environment corrosion resistance and preparation method and application thereof |
| CN105199582A (en) * | 2015-10-27 | 2015-12-30 | 苏州宽温电子科技有限公司 | Environment-friendly anti-static polyurethane anticorrosion paint and preparation method thereof |
-
2016
- 2016-01-20 CN CN201610034484.0A patent/CN105647319A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352171A (en) * | 2011-09-16 | 2012-02-15 | 中华制漆（深圳）有限公司 | Novel environment-friendly coating with superhigh marine environment corrosion resistance and preparation method and application thereof |
| CN105199582A (en) * | 2015-10-27 | 2015-12-30 | 苏州宽温电子科技有限公司 | Environment-friendly anti-static polyurethane anticorrosion paint and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243954A (en) * | 2016-08-01 | 2016-12-21 | 安庆瑞泰化工有限公司 | A kind of Antistatic type water paint and preparation method thereof |
| CN106010156A (en) * | 2016-08-12 | 2016-10-12 | 安庆市七仙女电器制造有限公司 | Electric iron antistatic paint and preparation method thereof |
| CN106147547A (en) * | 2016-08-12 | 2016-11-23 | 安庆市七仙女电器制造有限公司 | A kind of electric massager anticorrosive coating and preparation method thereof |
| CN106243996A (en) * | 2016-08-12 | 2016-12-21 | 安庆市七仙女电器制造有限公司 | A kind of desk lamp antistatic coating and preparation method thereof |
| CN106280793A (en) * | 2016-08-12 | 2017-01-04 | 安庆市七仙女电器制造有限公司 | A kind of electric massager antistatic coating and preparation method thereof |
| CN106590103A (en) * | 2016-12-15 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Water-borne anti-corrosion coating and preparing method thereof |
| CN107880317A (en) * | 2017-11-13 | 2018-04-06 | 郑州诚合信息技术有限公司 | A kind of anti-fog thin film and preparation method thereof |
| CN108102533A (en) * | 2017-12-26 | 2018-06-01 | 龙口德源高分子科技有限公司 | A kind of high performance water proof anti-corrosive paint and preparation method thereof |
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Application publication date: 20160608 |
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