CN103305077A - Coating with protection and color alteration functions - Google Patents
Coating with protection and color alteration functions Download PDFInfo
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- CN103305077A CN103305077A CN2013102041779A CN201310204177A CN103305077A CN 103305077 A CN103305077 A CN 103305077A CN 2013102041779 A CN2013102041779 A CN 2013102041779A CN 201310204177 A CN201310204177 A CN 201310204177A CN 103305077 A CN103305077 A CN 103305077A
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Abstract
The invention discloses a coating with protection and color alteration functions. The coating is prepared from the following components in parts by weight: 150-200 parts of thermoplastic butadiene styrene rubber A, 50-100 parts of thermoplastic butadiene styrene rubber B, 300-400 parts of sec-butyl acetate, 300-400 parts of 120# solvent naphtha, 300-400 parts of xylene, 30-50 parts of C9 petroleum resin, 5-10 parts of antioxidant, 5-10 parts of ultraviolet light absorber, 3-10 parts of light stabilizer, 12-25 parts of fumed silica, 3-6 parts of defoaming agent and 0 or 15-32 parts of pigment. Compared with a chloroprene rubber strippable coating, the coating with protection and color alteration functions, disclosed by the invention, belongs to an environment-friendly coating and is greatly improved on the aspects of elasticity and toughness such as tensile strength, stretching strength, resilience coefficient, surface hardness, adhesive force and the like.
Description
Technical field
The present invention relates to a kind of coating with protection and the function of changing colour.
Background technology
In the prior art; chloroprene rubber strippable paint (chlorinated rubber paint) is widely used in the parcel plating; the insulation protection of facing as milling aluminium alloy, stainless steel, titanium alloy; automobile is coated with lacquer protection outward and changes colour, and automobile coats with lacquer repairing outward, top layer and the electrical equipment protection of article such as instrument, equipment in the sea-freight process; the sealing of mine anti-explosion case; the subsea equipment sealing protection, the instrument insulation is soaked and is moulded industry etc.But there is following shortcoming in the chloroprene rubber strippable paint, has limited it and has promoted on a large scale:
1. contain poisonous class materials such as a large amount of toluene, 2-butanone in the chloroprene rubber strippable paint, chronic poisoning or acute poisoning can appear in long term operation staff under this environment.
2. environment there is serious harm, can causes severe contamination to air, water surrounding and water source.
3. in parcel plating during as insulation protection coating, after the plating, oxide on surface can make coating adhesion too high, causes divesting difficulty, has a strong impact on working efficiency.
4. in parcel plating, occur erosion and coating shedding, disqualification rate height occurring leaking because adhesive force of coatings is low through regular meeting.
5. because the chloroprene rubber color is darker, as paint the time, can only do the darker paint of color or priming paint.
6. in the construction process, time of drying is slow excessively, influences working efficiency.
Summary of the invention
At above-mentioned prior art, the invention provides a kind of coating with protection and the function of changing colour, it does not contain a large amount of toxic substances, can not pollute environment, and resistance to acids and bases is strong, difficult drop-off and corrosion, color can be adjusted arbitrarily according to demand.
The present invention is achieved by the following technical solutions:
A kind of have protection and the coating of the function of changing colour, and is to be made by the component of following weight part: thermoplastic styrene butadiene rubber A:150~200 part, thermoplastic styrene butadiene rubber B:50~100 part; 300~400 parts of 2-butyl acetates; 300~400 parts of 120# solvent oils, 300~400 parts of dimethylbenzene, 30~50 parts of C9 petroleum resin; 5~10 parts of antioxidants; 5~10 parts of UV light absorber, 3~10 parts of photostabilizers, 12~25 parts of aerosils; 3~6 parts of defoamers, pigment 0 or 15~32 parts.
It preferably, is to be made by the component of following weight part: thermoplastic styrene butadiene rubber A SBS792:200 part, thermoplastic styrene butadiene rubber B SEBS501:100 part, 400 parts of 2-butyl acetates, 400 parts of 120# solvent oils, 400 parts of dimethylbenzene, 50 parts of C9 petroleum resin, 8 parts of antioxidants, 8 parts of UV light absorber, 7 parts of photostabilizers, 18 parts of aerosils, 5 parts of defoamers, 0 part or 32 parts of pigment.
Described thermoplastic styrene butadiene rubber A preferred thermoplastic styrene-butadiene rubber(SBR) SBS792.
The described thermoplastic styrene butadiene rubber B SEBS501 Ba Ling of preferred China Petrochemical Industry petrochemical industry YH-501.
The preferred Qilu Petrochemical of described C9 petroleum resin is produced the C9 petroleum resin.
Kelamayi, the preferred Xinjiang of described naphthenic oil petrochemical industry is produced the KN4006 solvent oil.
The bright Sheng BHT antioxidant of the preferred Germany of described antioxidant.
The THUV-328 of the preferred Taiwan of described UV light absorber photochemistry limited-liability company production forever.
The HS-508 (292) that the preferred Qingdao of described photostabilizer Xing Nuoxin Fine Chemical Co., Ltd produces.
Described aerosil preference card is won special product TS720, or Cabot M-5.
The LT-203 that the preferred Shanghai of described defoamer upright strange auxiliary chemicals company limited produces.
The environment-friendly type pigment that the huge Fa Science Co., Ltd in described pigment optimization Hunan produces, the color of pigment can be determined according to purposes.When not adding pigment, the coating that mixes is the translucent coating of little yellow, and when adding pigment, the painting color that mixes is consistent with pigment color.
Described preparation method with coating of protection and the function of changing colour is:
(1) heat-obtaining plasticity styrene-butadiene rubber(SBR) A SBS792, SEBS YH-501 adds naphthenic oil, stirs 5 minutes with rotating speed 〉=1000 commentaries on classics/min with high speed dispersor, pours reactor then into;
(2) add 2-butyl acetate, D30 solvent oil and dimethylbenzene, stir 45 minutes to all dissolving with rotating speed 〉=1000 commentaries on classics/min;
(3) add C9 petroleum resin, antioxidant, UV light absorber, photostabilizer, aerosil, defoamer and pigment, disperseed 30 minutes with linear velocity 20m/s, enter shredder and be ground to more than 1000 orders, namely; During concrete production, can adopt 120# solvent oil or 2-butyl acetate or dimethylbenzene dilution (because 2-butyl acetate, the 120# solvent oil, which kind of thinner is dimethylbenzene evaporation rate speed difference should select for use according to purposes), impurity screening then, can in sprinkling irrigation or iron sheet barrel certainly, print the date manufactured of lasting after, pack, the finished product warehouse-in, schema as shown in Figure 1.
Coating with protection and the function of changing colour of the present invention, preparation principle is as follows:
The SBS792 that buying is come chemically examines, and Butadiene content is 40/60, and styrene content is too high, and elasticity is relatively poor, and it is relatively poor that toughness appears in the too high meeting of butadiene content, therefore selects a moderate raw material extremely important; Its viscosity of paint thermoplastic styrene butadiene rubber is higher, and is mobile relatively poor, in order to reduce its viscosity, strengthens flowability, selects for use the naphthenic oil of environment-protecting asepsis homogenizer oil-filled (SBS is relatively good with the consistency of naphthenic oil, in order to accelerate oil suction, can suitably heat); Because every over-all properties of styrene-butadiene rubber(SBR) also is not very desirable, need to use SEBS501, with elasticity, toughness, the tensile strength of reinforcement thermoplastic elastomer, decide body intensity, tear strength; Enter high speed dispersor, add the mixed type solvent then, solvent is considered its time of drying, environmental protection, economic a large amount of 2-butyl acetates and 120# solvent oil and a spot of dimethylbenzene therefore selected for use; Be stirred to translucent liquid at homogenizer solid is all melted, dispersing speed gets final product about 1000r/min; Add antioxidant, UV light absorber, photostabilizer, to improve weather-proof, the resistance to oxidation of coating, add C9 petroleum resin or other artificial synthetic resins to strengthen the coating surface hardness, add aerosil, to improve pigment stability, make colo(u)rant dispersion effective, thickening, anti-sedimentation help the effect of grade of flowing; To stir after adding these additives or properties-correcting agent; After stirring, because granules of pigments is bigger, enters shredder and grind; Grinding finishes and wants impurity screening; Pack warehouse-in at last.
Described using method with coating of protection and the function of changing colour is: can use hairbrush, brush 1~3 layer at the workpiece surface that needs apply, brush the about 0.2mm of thickness; Also can use spray gun, spray 3~6 layers, the about 0.15mm of coating thickness; Be 15 minutes every layer of time of drying, 15 minutes after fixing film forming.
Of the present invention have protection and the coating of the function of changing colour, and the chloroprene rubber strippable paint belongs to environment-friendly type coating relatively, possess that production technique is simple, easy construction, to characteristics such as operator's Health hazard are little; Because adopt SBS thermoplastic elastomer and properties-correcting agent, its performance improves greatly, no matter is elasticity or toughness, comprise that tensile strength, tensile modulus, rebound degree, surface hardness, sticking power etc. all improve greatly; Liquid color is shallow, can mix colours arbitrarily, makes color more extensive, has increased practical purposes greatly, can be used on automobile decoration, decoration industries such as home decoration.Effect can be removed owing to possess, the colour match weak effect needn't be worried fully in use, construction problems such as jet flow, going wrong to remove sprays again again.
Coating with protection and the function of changing colour of the present invention has following beneficial effect:
1. at the shortcoming 1 of prior art, do not re-use noxious solvents such as toluene, 2-butanone, adopt 2-butyl acetate, D30 (30#) solvent oil, reach a small amount of 120# solvent oil, dimethylbenzene.Thinner uses 2-butyl acetate.Reduce toxicity greatly.
2. at the shortcoming 2 of prior art, because 2-butyl acetate and D30 all are environment-friendly type solvents, therefore can not pollute environment, the relative toluene toxicity of dimethylbenzene reaches environmental hazard is also reduced greatly simultaneously.
3. at the shortcoming 3,4 of prior art, adopted thermoplasticity SBS (styrene-butadiene-styrene multipolymer, its molecular weight is at the linear structure of 8-12 ten thousand), because it possesses excellent acid alkali and weathering resistance can finely solve.
4. at the shortcoming 5 of prior art, SBS styrene-butadiene rubber(SBR) solution is colourless, translucent, can add pigment arbitrarily, selects pigment according to demand.
Description of drawings
Fig. 1 is preparation method's schema of the present invention.
Fig. 2 is for the paint spay-coating effect of embodiment 1 and can remove the effect synoptic diagram, wherein A: the spraying effect synoptic diagram; B: can remove effect synoptic diagram one; C: can remove effect synoptic diagram two; D: can remove effect synoptic diagram three.
Embodiment
The present invention is described further below in conjunction with embodiment.
Its raw material source of the present invention is:
Thermoplastic styrene butadiene rubber A is thermoplastic styrene butadiene rubber SBS792.
Thermoplastic styrene butadiene rubber B SEBS501 is the Ba Ling of China Petrochemical Industry petrochemical industry YH-501.
The C9 petroleum resin are that Qilu Petrochemical is produced the C9 petroleum resin.
Naphthenic oil is that Kelamayi, Xinjiang petrochemical industry is produced the KN4006 solvent oil.
Antioxidant is the bright Sheng BHT antioxidant of Germany.
UV light absorber is the THUV-328 of Taiwan photochemistry limited-liability company production forever.
Photostabilizer is the HS-508 (292) that Qingdao Xing Nuoxin Fine Chemical Co., Ltd produces.
Aerosil is that Cabot produces TS720, or Cabot M-5.
Defoamer is the LT-203 that Shanghai upright strange auxiliary chemicals company limited produces.
Pigment is the environment-friendly type pigment that the huge Fa Science Co., Ltd in Hunan produces, and the color of pigment can be determined according to purposes.
Embodiment 1 preparation coating
Prescription is: thermoplastic styrene butadiene rubber A SBS792:200 kilogram, thermoplastic styrene butadiene rubber B SEBS501:100 kilogram, 400 kilograms of 2-butyl acetates, 400 kilograms of 120# solvent oils, 400 kilograms of dimethylbenzene, 50 kilograms of C9 petroleum resin, 8 kilograms of antioxidants, 8 kilograms of UV light absorber, 7 kilograms of photostabilizers, 18 kilograms of aerosils, 5 kilograms of defoamers.
The preparation method is: (flow process as shown in Figure 1)
(1) heat-obtaining plasticity styrene-butadiene rubber(SBR) A SBS792, SEBS YH-501 adds naphthenic oil, stirs 5 minutes with rotating speed 〉=1000 commentaries on classics/min with high speed dispersor, pours reactor then into;
(2) add 2-butyl acetate, D30 solvent oil and dimethylbenzene, stir 45 minutes to all dissolving with rotating speed 〉=1000 commentaries on classics/min;
(3) add C9 petroleum resin, antioxidant, UV light absorber, photostabilizer, aerosil and defoamer, disperseed 30 minutes with linear velocity 20m/s, entering shredder is ground to more than 1000 orders, adopt the dilution of 120# solvent oil, dilution standard is coated with-4 glasss and measures 18-20 second for adopting, impurity screening then, and can is in iron sheet barrel, that is, be the translucent coating of little yellow.
Using method is: use hairbrush, brush 3 layers at the workpiece surface that needs apply, brush the about 0.2mm of thickness; Be 15 minutes every layer of time of drying, and 15 minutes after fixing film forming are shown in Fig. 2 A.Performance perameter after the film forming is as shown in table 1:
Table 1
As shown in Table 1, the coating with protection and the function of changing colour of the present invention, relative chloroprene rubber strippable paint, tensile strength, tensile modulus, rebound degree, surface hardness, sticking power etc. all are improved.
Of the present invention have protection and the coating of the function of changing colour, and possesses to remove effect (shown in Fig. 2 B, C, D), needn't worry the colour match weak effect fully in use, construction problems such as jet flow, and going wrong to remove sprays again again.
Embodiment 2 preparation coating
Prescription is: thermoplastic styrene butadiene rubber A SBS792:200 kilogram, thermoplastic styrene butadiene rubber B SEBS501:100 kilogram, 400 kilograms of 2-butyl acetates, 400 kilograms of 120# solvent oils, 400 kilograms of dimethylbenzene, 50 kilograms of C9 petroleum resin, 8 kilograms of antioxidants, 8 kilograms of UV light absorber, 7 kilograms of photostabilizers, 18 kilograms of aerosils, 5 kilograms of defoamers, 32 kilograms of pigment (pigment color is black).
The preparation method is:
(1) heat-obtaining plasticity styrene-butadiene rubber(SBR) A SBS792, SEBS YH-501 adds naphthenic oil, stirs 5 minutes with rotating speed 〉=1000 commentaries on classics/min with high speed dispersor, pours reactor then into;
(2) add 2-butyl acetate, D30 solvent oil and dimethylbenzene, stir 45 minutes to all dissolving with rotating speed 〉=1000 commentaries on classics/min;
(3) add C9 petroleum resin, antioxidant, UV light absorber, photostabilizer, aerosil, defoamer and pigment, disperseed 30 minutes with linear velocity 20m/s, entering shredder is ground to more than 1000 orders, the dilution of employing dimethylbenzene, dilution standard is measured 18-20 second for employing is coated with-4 glasss, impurity screening then, can is in iron sheet barrel, namely.
Claims (2)
1. one kind has protection and the coating of the function of changing colour; it is characterized in that: be to be made by the component of following weight part: thermoplastic styrene butadiene rubber A:150~200 part; thermoplastic styrene butadiene rubber B:50~100 part; 300~400 parts of 2-butyl acetates; 300~400 parts of 120# solvent oils; 300~400 parts of dimethylbenzene; 30~50 parts of C9 petroleum resin; 5~10 parts of antioxidants; 5~10 parts of UV light absorber, 3~10 parts of photostabilizers, 12~25 parts of aerosils; 3~6 parts of defoamers, pigment 0 or 15~32 parts.
2. the described preparation method with protection and coating of the function of changing colour of claim 1, it is characterized in that: step is as follows:
(1) heat-obtaining plasticity styrene-butadiene rubber(SBR) A SBS792, SEBS YH-501 adds naphthenic oil, stirs 5 minutes with rotating speed 〉=1000 commentaries on classics/min with high speed dispersor, pours reactor then into;
(2) add 2-butyl acetate, D30 solvent oil and dimethylbenzene, stir 45 minutes to all dissolving with rotating speed 〉=1000 commentaries on classics/min;
(3) add C9 petroleum resin, antioxidant, UV light absorber, photostabilizer, aerosil, defoamer and pigment, disperseed 30 minutes with linear velocity 20m/s, enter shredder and be ground to more than 1000 orders, namely.
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103738812A (en) * | 2013-12-13 | 2014-04-23 | 广东升达电梯有限公司 | Production process for novel lift car with changeable colors |
CN104372347A (en) * | 2014-10-22 | 2015-02-25 | 深圳市鹰达行实业有限公司 | Peelable rust inhibitor, and preparation method and application method thereof |
CN105820669A (en) * | 2016-06-06 | 2016-08-03 | 广东莱雅化工有限公司 | Tearable spray film and preparation method thereof |
CN106280728A (en) * | 2016-08-08 | 2017-01-04 | 北京天山新材料技术有限公司 | A kind of coating composition comprising butadiene-styrene rubber and preparation method and application |
CN106675139A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Peelable spray membrane and preparation method thereof |
CN109401522A (en) * | 2016-09-30 | 2019-03-01 | 中国航发商用航空发动机有限责任公司 | A kind of surface protection process of photocuring increasing material manufacturing resin product |
WO2019084622A1 (en) * | 2017-11-02 | 2019-05-09 | Griffith University | Cell culture system |
CN110194915A (en) * | 2019-07-01 | 2019-09-03 | 山东领辉智能科技有限公司 | A kind of petrochemical equipment spray film paint and preparation method thereof |
CN111286251A (en) * | 2020-03-03 | 2020-06-16 | 华南理工大学 | Environment-friendly three-proofing paint based on synthetic rubber system and preparation method and application thereof |
CN114163876A (en) * | 2021-12-13 | 2022-03-11 | 中昊北方涂料工业研究设计院有限公司 | Quick-drying repair adhesive for chemical milling and preparation method thereof |
CN115216184A (en) * | 2022-03-21 | 2022-10-21 | 芜湖伦比轴承有限公司 | Strippable protective adhesive for bearing phosphating shielding and preparation method thereof |
CN115975468A (en) * | 2022-12-09 | 2023-04-18 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004013238A1 (en) * | 2002-08-06 | 2004-02-12 | Environment Leading Technology Co., Ltd. | Coating composition using rubber compound, preferably scrap tire, and method of producing the same |
CN101104775A (en) * | 2007-08-15 | 2008-01-16 | 李国树 | Elastomer silicon rubber waterproofing paint |
CN102108234A (en) * | 2010-12-22 | 2011-06-29 | 白铁林 | Colourful environmental-friendly synthesized polymer waterproof paint |
CN102443322A (en) * | 2010-10-12 | 2012-05-09 | 3M创新有限公司 | Paint composition and coating product prepared from same |
-
2013
- 2013-05-28 CN CN2013102041779A patent/CN103305077A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004013238A1 (en) * | 2002-08-06 | 2004-02-12 | Environment Leading Technology Co., Ltd. | Coating composition using rubber compound, preferably scrap tire, and method of producing the same |
CN101104775A (en) * | 2007-08-15 | 2008-01-16 | 李国树 | Elastomer silicon rubber waterproofing paint |
CN102443322A (en) * | 2010-10-12 | 2012-05-09 | 3M创新有限公司 | Paint composition and coating product prepared from same |
CN102108234A (en) * | 2010-12-22 | 2011-06-29 | 白铁林 | Colourful environmental-friendly synthesized polymer waterproof paint |
Non-Patent Citations (1)
Title |
---|
赵鹏飞等: "双环戊二烯石油树脂对丁苯橡胶性能的影响", 《特种橡胶制品》 * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103738812A (en) * | 2013-12-13 | 2014-04-23 | 广东升达电梯有限公司 | Production process for novel lift car with changeable colors |
CN104372347A (en) * | 2014-10-22 | 2015-02-25 | 深圳市鹰达行实业有限公司 | Peelable rust inhibitor, and preparation method and application method thereof |
CN105820669A (en) * | 2016-06-06 | 2016-08-03 | 广东莱雅化工有限公司 | Tearable spray film and preparation method thereof |
CN106280728B (en) * | 2016-08-08 | 2018-07-06 | 北京天山新材料技术有限公司 | A kind of coating composition comprising butadiene-styrene rubber and preparation method and application |
CN106280728A (en) * | 2016-08-08 | 2017-01-04 | 北京天山新材料技术有限公司 | A kind of coating composition comprising butadiene-styrene rubber and preparation method and application |
CN109401522A (en) * | 2016-09-30 | 2019-03-01 | 中国航发商用航空发动机有限责任公司 | A kind of surface protection process of photocuring increasing material manufacturing resin product |
CN106675139A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Peelable spray membrane and preparation method thereof |
WO2019084622A1 (en) * | 2017-11-02 | 2019-05-09 | Griffith University | Cell culture system |
CN110194915A (en) * | 2019-07-01 | 2019-09-03 | 山东领辉智能科技有限公司 | A kind of petrochemical equipment spray film paint and preparation method thereof |
CN111286251A (en) * | 2020-03-03 | 2020-06-16 | 华南理工大学 | Environment-friendly three-proofing paint based on synthetic rubber system and preparation method and application thereof |
CN114163876A (en) * | 2021-12-13 | 2022-03-11 | 中昊北方涂料工业研究设计院有限公司 | Quick-drying repair adhesive for chemical milling and preparation method thereof |
CN115216184A (en) * | 2022-03-21 | 2022-10-21 | 芜湖伦比轴承有限公司 | Strippable protective adhesive for bearing phosphating shielding and preparation method thereof |
CN115975468A (en) * | 2022-12-09 | 2023-04-18 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
CN115975468B (en) * | 2022-12-09 | 2023-10-31 | 山东高速交通科技有限公司 | Durable hot-melt marking paint and preparation method thereof |
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