CN102108234A - Colourful environmental-friendly synthesized polymer waterproof paint - Google Patents
Colourful environmental-friendly synthesized polymer waterproof paint Download PDFInfo
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- CN102108234A CN102108234A CN 201010600068 CN201010600068A CN102108234A CN 102108234 A CN102108234 A CN 102108234A CN 201010600068 CN201010600068 CN 201010600068 CN 201010600068 A CN201010600068 A CN 201010600068A CN 102108234 A CN102108234 A CN 102108234A
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Abstract
The invention relates to a colourful environmental-friendly synthesized polymer waterproof paint which comprises the following components in parts by weight: 3-7 parts of petroleum resin, 5-15 parts of styrene-ethylene-butylene-styrene (SEBS), 5-15 parts of styrene-butylene-styrene (SBS), 5-10 parts of thermoplastic polyurethane elastomer, 4-8 parts of terpene resin, 4-8 parts of poly-alpha-methyl styrene, 2-5 parts of tung oil, 10-15 parts of mica powder, 0.2-0.5 part of antiager D, 0.2-0.5 part of antioxidant 264, 0.2-0.5 part of defoaming agent, 0.3-0.5 part of ultraviolet absorber, 35-45 parts of 120 # solvent, 5-15 parts of butyl acetate and 1-3 parts of color paste. The paint has the characteristics of unique waterproof property, acid-base resistance, ultraviolet irradiation resistance, heat insulation, anti-aging property, high adhesion strength, water repellent, good leakage-resisting effect, heat resistance, frost resistance and good elongation; and the paint also has the advantages of wide application range, moderate price, environmental friendliness, durability and the like, and is convenient to use, thereby meeting the demand of people in a real life.
Description
Technical field:
The present invention relates to a kind of architectural waterproof material, relate to colorful environment-friendly synthetic macromolecular waterproof coating specifically.
Technical background:
At present, the kind of waterproof paint is a lot, but most of Material Physics poor mechanical property, work-ing life is short, and too big with the gap in work-ing life of buildings, range of application is narrow and small, and not necessarily environmental protection.Polyurethane water-proof paint is a waterproof paint comparatively high-grade in the present waterproof paint, its over-all properties will be significantly better than other waterproof paints, but medium-sized polyurethane water-proof paint is because its liquid filler that adopts (petroleum by-product) and solvent (toluene, dimethylbenzene etc.) all exist environmental issue, and its mechanical property still is apparent not enough.The high-strength polyurethane waterproof coating material of no-solvent type and Spray Polyurea Elastomer are the novel high-grade materials in the polyurethane water-proof paint family, but its synthetic and equal more complicated of construction technology, cost is higher, only uses to some extent in the high-speed railway bridge waterproof at present, is difficult to be accepted by the general user.That is to say, existing waterproof paint is difficult to accomplish to satisfy simultaneously that mechanical property is good, applied range, operation facility whether, price and the environmental protection composite request of aspect such as whether.Colorful environment-friendly synthetic macromolecular waterproof coating of the present invention is exactly in line with this actual requirement, has accomplished the comprehensive unification of these requirements, thereby satisfies people's actual demand.
Summary of the invention:
The purpose of this invention is to provide a kind of excellent performance, be widely used, easy to use, moderate, the competent colorful environment-friendly waterproof paint of environmental protection, to satisfy the needs of people's actual life.
In order to achieve the above object, technical scheme of the present invention is achieved in that a kind of colorful environment-friendly synthetic macromolecular waterproof coating, one-tenth by following weight part is grouped into: petroleum resin 3-7 part, SEBS 5-15 part, SBS 5-15 part, thermoplastic polyurethane elastomer 5-10 part, terpine resin 4-8 part, poly alpha methylstyrene 4-8 part, tung oil 2-5 part, mica powder 10-15 part, antioxidant D 0.2-0.5 part, antioxidant 264 0.2-0.5 part, defoamer 0.2-0.5 part, UV light absorber 0.3-0.5 part, 120# solvent 35-45 part, ethyl acetate 5-15 part, mill base 1-3 part.
Described each composition adopts following weight part: 5 parts of petroleum resin, 8 parts of SEBS, 8 parts of SBS, 7 parts of thermoplastic polyurethane elastomers, 6 parts of terpine resins, 6 parts of poly alpha methylstyrenes, 3 parts of tung oil, 10 parts of mica powders, 0.3 part of antioxidant D, 0.3 part of antioxidant 264,0.3 part of defoamer, 0.5 part of UV light absorber, 40 parts of 120# solvents, 10 parts of ethyl acetates, 2 parts of mill bases.
Described blending process: the liquid material is metered into unlatching stirring in the reactor by prescription, presses formula ratio again and add macromolecular materials such as SBS, SEBS, thermoplastic polyurethane elastomer; Open heating system, add material material such as petroleum resin, terpine resin, poly alpha methylstyrene resin more successively, be warming up to 70～80 ℃ and keep more than the 1h, treat that all solids material dissolves the back sampling fully and observes no macroscopic solid particulate and suspended substance, close heating system; Then in reactor, add auxiliary agents such as anti-aging agent, oxidation inhibitor, UV light absorber, defoamer successively and continue to stir, add filler mica powder, mill base more successively, stir and it is mixed behind the 1h and be cooled to 50～55 ℃, stop to stir; At last material is ground by colloidal mill, promptly make this coating after the grinding.
Described liquid material is No. 120 solvent oils, butylacetate, tung oil.
Advantage of the present invention and beneficial effect are: the present invention has adopted multiple synthetic macromolecule rubber and elastomerics, thereby has the over-all properties of these materials.The present invention has excellent physical and mechanical property, and tensile strength and elongation at break all far surpass like product, has excellent water-fast, oil resistant, acid and alkali-resistance, resistance to chemical attack, UV resistant, high and low temperature resistance simultaneously.Not only can do water-proof material, can also do impregnating material, have the dual-use function of water-tight corrosion-proof.The physical performance index of this coating meets the requirement of company standard Q/JD001-2009, and the physical and mechanical property index of this standard will be significantly higher than the technical indicator of similar waterproof paint.
The present invention has utilized the manufacturing technology of sizing agent, has adopted the tackifying resin material of multiple water-fast, acid and alkali-resistance, makes this coating and other material have excellent adhesiveproperties, compares approximately with existing water-proof material to be enhanced about more than once, and can keep for a long time.Thereby, can have waterproof and binding function, remarkable for the waterproof repairment effect.
Production technique of the present invention is simple, and product is single-component, spraying or brush all can, thereby constructing operation is simple, and is easy to use.In addition, starting material of the present invention are nontoxic ep-type material, thereby this coating is the environment-friendly type waterproof paint.The environmental-protecting performance index of this coating meets the requirement of GB 50325-2001 civil building engineering indoor environmental pollution control standard (version in 2006).
By above-mentioned technique means, make and have extraordinary tensile strength, elongation and cohesive strength behind the dried coating film of the present invention, and has unique water resistance, acid and alkali-resistance, UV resistant irradiation, heat insulation, anti-aging, its bonding strength is big, and waterproof, anti-leakage effect are good, heat-resisting freeze proof, good extending performance.Cold construction, directly spray is easy to operate.Now, be widely used in: between 1) bathe in various new, the roofings of old building, indoor moistureproof decoration, metope, terrace, lavatory, pond, swimming pool and other buildings; 2) various passages such as the interior exterior wall of underground structure, base plate, elevator hole, tunnel, viaduct, overpass, the pipeline of various athletic grounds, various industrial and mining enterprises, the inside and outside waterproof in acid, alkali, salt, wet goods pond; 3) large-scale waterproofing works such as the vault of Highrise buildings, people's air defense, subway, electric power, water conservancy oil, chemical mine, boats and ships, grain depot; 4) be used for amonang floor, asbestos tile, grouan, color steel watt; 5) various difficult antiseepages such as exterior wall leakage, doors and windows sealing, leakproof, protection against the tide and maintenance engineering.This product also can be modulated into any color, is complementary with working-yard surrounding environment color.Through a large amount of practical engineering application, material of the present invention is subjected to the consistent of each side in material property, construction with aspects such as application, cost performances and approves.
Embodiment:
Be embodiments of the invention below, described embodiment just is used for illustrating the present invention, and should not be considered as is limitation of the present invention.
Embodiment 1: the material of getting following weight is as raw material: 3 kilograms of petroleum resin, 5 kilograms of terpine resins, 5 kilograms of SEBS, 15 kilograms of SBS, 5 kilograms of thermoplastic polyurethane elastomers, 5 kilograms of poly alpha methylstyrenes, 2 kilograms of tung oil, 15 kilograms of mica powders, 0.3 kilogram of defoamer, 35 kilograms of 120# solvents, 10 kilograms of ethyl acetates, 1 kilogram of mill base.Present embodiment can be used for the lavatory non-waterproof that exposes the construction site of use such as between bathing.
Embodiment 2: the material of getting following weight is as raw material: 3 kilograms of petroleum resin, 7 kilograms of terpine resins, 15 kilograms of SEBS, 5 kilograms of SBS, 8 kilograms of thermoplastic polyurethane elastomers, 6 kilograms of poly alpha methylstyrenes, 4 kilograms of tung oil, 10 kilograms of mica powders, 0.3 kilogram of antioxidant D, 0.3 kilogram of defoamer, antioxidant 264: 0.5 kilogram, 0.5 kilogram of UV light absorber, 35 kilograms of 120# solvents, 15 kilograms of ethyl acetates, 2 kilograms of mill bases.Present embodiment can be used for the waterproof that roofing etc. exposes the ageing-resistant good construction site of service requirements.
Embodiment 3: the material of getting following weight is as raw material: 3 kilograms of petroleum resin, 7 kilograms of terpine resins, 10 kilograms of SEBS, 10 kilograms of SBS, 10 kilograms of thermoplastic polyurethane elastomers, 5 kilograms of poly alpha methylstyrenes, 2 kilograms of tung oil, 15 kilograms of mica powders, 0.3 kilogram of defoamer, 40 kilograms of 120# solvents, 15 kilograms of ethyl acetates, 1 kilogram of mill base.Present embodiment can be used for the waterproof that hypogee etc. has the construction site that certain acid and alkali-resistance and chemical corrosion require.
Liquid material among the embodiment 1-3 (No. 120 solvent oils, butylacetate, tung oil) is metered into reactor.Open and stir, macromolecular materials such as SBS, the SEBS of adding formula ratio, thermoplastic polyurethane elastomer.Open heating system, add materials such as petroleum resin, terpine resin, poly alpha methylstyrene resin more successively, be warming up to 70～80 ℃ and keep more than the 1h, treat that all solids material dissolves back (no macroscopic solid particulate and suspended substance are observed in sampling) fully, closes heating system.Then in reactor, add auxiliary agents such as anti-aging agent, oxidation inhibitor, UV light absorber, defoamer successively and continue to stir, add filler mica powder, mill base more successively, stir and it is mixed behind the 1h and be cooled to 50～55 ℃, stop to stir.At last material is ground by colloidal mill, promptly make colorful environment-friendly synthetic macromolecular waterproof coating after the grinding.
More than colorful environment-friendly synthetic macromolecular waterproof coating provided by the present invention is described in detail.Having used concrete case herein sets forth principle of the present invention and embodiment, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof, for one of ordinary skill in the art, foundation thought of the present invention, can change to some extent in specific embodiments and applications simultaneously.
Claims (4)
1. colorful environment-friendly synthetic macromolecular waterproof coating, it is characterized in that being grouped into: petroleum resin 3-7 part by the one-tenth of following weight part, SEBS 5-15 part, SBS 5-15 part, thermoplastic polyurethane elastomer 5-10 part, terpine resin 4-8 part, poly alpha methylstyrene 4-8 part, tung oil 2-5 part, mica powder 10-15 part, antioxidant D 0.2-0.5 part, antioxidant 264 0.2-0.5 part, defoamer 0.2-0.5 part, UV light absorber 0.3-0.5 part, 120# solvent 35-45 part, ethyl acetate 5-15 part, mill base 1-3 part.
2. colorful environment-friendly synthetic macromolecular waterproof coating according to claim 1 is characterized in that each composition adopts following weight part: 5 parts of petroleum resin, 8 parts of SEBS, 8 parts of SBS, 7 parts of thermoplastic polyurethane elastomers, 6 parts of terpine resins, 6 parts of poly alpha methylstyrenes, 3 parts of tung oil, 10 parts of mica powders, 0.3 part of antioxidant D, 0.3 part of antioxidant 264,0.3 part of defoamer, 0.5 part of UV light absorber, 40 parts of 120# solvents, 10 parts of ethyl acetates, 2 parts of mill bases.
3. colorful environmental protection synthetic macromolecular waterproof coating according to claim 1, it is characterized in that its blending process: the liquid material is metered into to open in the reactor by prescription stirs, press formula ratio again and add macromolecular materials such as SBS, SEBS, thermoplastic polyurethane elastomer; Open heating system, add material material such as petroleum resin, terpine resin, poly alpha methylstyrene resin more successively, be warming up to 70～80 ℃ and keep more than the 1h, treat that all solids material dissolves the back sampling fully and observes no macroscopic solid particulate and suspended substance, close heating system; Then in reactor, add auxiliary agents such as anti-aging agent, oxidation inhibitor, UV light absorber, defoamer successively and continue to stir, add filler mica powder, mill base more successively, stir and it is mixed behind the 1h and be cooled to 50～55 ℃, stop to stir; At last material is ground by colloidal mill, promptly make this coating after the grinding.
4. colorful environmental protection synthetic macromolecular waterproof coating according to claim 1 is characterized in that described liquid material is No. 120 solvent oils, butylacetate, tung oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201010600068 CN102108234A (en) | 2010-12-22 | 2010-12-22 | Colourful environmental-friendly synthesized polymer waterproof paint |
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| CN 201010600068 CN102108234A (en) | 2010-12-22 | 2010-12-22 | Colourful environmental-friendly synthesized polymer waterproof paint |
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| CN102108234A true CN102108234A (en) | 2011-06-29 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173088A (en) * | 2013-04-09 | 2013-06-26 | 中国建筑材料科学研究总院苏州防水研究院 | Reflective insulating fire-retardant coating for waterproof roll, and preparation method and use thereof |
| CN103305077A (en) * | 2013-05-28 | 2013-09-18 | 济宁恒泰机械有限公司 | Coating with protection and color alteration functions |
| CN103756494A (en) * | 2013-12-26 | 2014-04-30 | 嘉兴北大华丰新能源有限公司 | Manufacturing method for water-based simulated granite colorful environment-friendly heat-insulating coating |
| CN104744963A (en) * | 2015-04-13 | 2015-07-01 | 哈尔滨中建璟园科技开发有限公司 | Terrace and construction method thereof |
| CN105111802A (en) * | 2015-09-07 | 2015-12-02 | 无锡市嘉邦电力管道厂 | Multicolor environment-friendly high-polymer water-resistant paint, and preparation method and application thereof |
| CN105131726A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠南自仪表有限公司 | Thermoplastic heat-dissipating coating material and preparation method thereof |
| CN105219067A (en) * | 2015-10-26 | 2016-01-06 | 青岛喜乐途轮胎科技有限公司 | A kind of novel tire leakproof selfreparing macromolecular material |
| CN105985698A (en) * | 2015-02-09 | 2016-10-05 | 章道义 | Insulated waterproof paint and preparation method thereof |
| CN106380937A (en) * | 2016-08-31 | 2017-02-08 | 河南省治海建材有限公司 | Milk-white environment-friendly type synthesis polymer steel roofing paint |
| CN108250860A (en) * | 2018-02-27 | 2018-07-06 | 合肥尚涵装饰工程有限公司 | A kind of sun-proof exterior coating and preparation method thereof |
| CN111286251A (en) * | 2020-03-03 | 2020-06-16 | 华南理工大学 | Environment-friendly three-proofing paint based on synthetic rubber system and preparation method and application thereof |
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| CN1434089A (en) * | 2003-02-19 | 2003-08-06 | 江南大学 | Water-resistant corrosion-resistant paint or water-resistant factice produced by using industrial organic waste as raw material |
| CN1887990A (en) * | 2006-07-19 | 2007-01-03 | 李广臣 | Green waterproof milk white polymer paint |
| CN101074345A (en) * | 2007-06-22 | 2007-11-21 | 郑州大学 | Color SBS modified waterproof asphalt material |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103173088B (en) * | 2013-04-09 | 2015-05-13 | 中国建筑材料科学研究总院苏州防水研究院 | Reflective insulating fire-retardant coating for waterproof roll, and preparation method and use thereof |
| CN103173088A (en) * | 2013-04-09 | 2013-06-26 | 中国建筑材料科学研究总院苏州防水研究院 | Reflective insulating fire-retardant coating for waterproof roll, and preparation method and use thereof |
| CN103305077A (en) * | 2013-05-28 | 2013-09-18 | 济宁恒泰机械有限公司 | Coating with protection and color alteration functions |
| CN103756494B (en) * | 2013-12-26 | 2015-09-16 | 嘉兴北大华丰新能源有限公司 | The manufacture method of the colorful environmental protection heat insulating coatings of aqueousance artificial granite |
| CN103756494A (en) * | 2013-12-26 | 2014-04-30 | 嘉兴北大华丰新能源有限公司 | Manufacturing method for water-based simulated granite colorful environment-friendly heat-insulating coating |
| CN105985698A (en) * | 2015-02-09 | 2016-10-05 | 章道义 | Insulated waterproof paint and preparation method thereof |
| CN104744963A (en) * | 2015-04-13 | 2015-07-01 | 哈尔滨中建璟园科技开发有限公司 | Terrace and construction method thereof |
| CN105131726A (en) * | 2015-08-13 | 2015-12-09 | 蚌埠南自仪表有限公司 | Thermoplastic heat-dissipating coating material and preparation method thereof |
| CN105111802A (en) * | 2015-09-07 | 2015-12-02 | 无锡市嘉邦电力管道厂 | Multicolor environment-friendly high-polymer water-resistant paint, and preparation method and application thereof |
| CN105219067A (en) * | 2015-10-26 | 2016-01-06 | 青岛喜乐途轮胎科技有限公司 | A kind of novel tire leakproof selfreparing macromolecular material |
| CN106380937A (en) * | 2016-08-31 | 2017-02-08 | 河南省治海建材有限公司 | Milk-white environment-friendly type synthesis polymer steel roofing paint |
| CN108250860A (en) * | 2018-02-27 | 2018-07-06 | 合肥尚涵装饰工程有限公司 | A kind of sun-proof exterior coating and preparation method thereof |
| CN111286251A (en) * | 2020-03-03 | 2020-06-16 | 华南理工大学 | Environment-friendly three-proofing paint based on synthetic rubber system and preparation method and application thereof |
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Application publication date: 20110629 |