CN101863640A - Environment-friendly colored fire-proof coating for tunnels - Google Patents

Environment-friendly colored fire-proof coating for tunnels Download PDF

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Publication number
CN101863640A
CN101863640A CN200910082115A CN200910082115A CN101863640A CN 101863640 A CN101863640 A CN 101863640A CN 200910082115 A CN200910082115 A CN 200910082115A CN 200910082115 A CN200910082115 A CN 200910082115A CN 101863640 A CN101863640 A CN 101863640A
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China
Prior art keywords
fire
parts
tunnels
environment
proof coating
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Pending
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CN200910082115A
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Chinese (zh)
Inventor
刘军辉
殷学智
仲晓林
史生军
陈夙
梁彦伟
杨力
苏舜
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MCC COMMUNICATION ENGINEERING TECHNOLOGY Co Ltd
China Jingye Engineering Corp Ltd
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MCC COMMUNICATION ENGINEERING TECHNOLOGY Co Ltd
China Jingye Engineering Corp Ltd
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Priority to CN200910082115A priority Critical patent/CN101863640A/en
Publication of CN101863640A publication Critical patent/CN101863640A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides an environment-friendly colored fire-proof coating for tunnels, comprising the following components in parts by mass: 10-50 parts of cement, 40-90 parts of expanded perlite, expanded vermiculite and precipitated calcium carbonate, 1-10 parts of inorganic mineral fibers, 5-30 parts of flame retardant systems, 0.1-5.0 parts of rubber powder, 0.5-3.0 parts of water reducing agents, air entraining agents and expanding agents and 0.5-2.0 parts of inorganic pigments. The coating has the following beneficial effects: (1) the requirements of different colors and daylighting can be satisfied and the cost of tunnel surface decoration can be lowered by adding the inorganic pigments to the fire-proof coating for tunnels; (2) the construction process is simplified and the construction procedure of finish is lessened; (3) the coating has the characteristics of high fire endurance and bond strength, good water resistance and the like, does not produce any toxic gas or waste in the construction processes and fire disasters and is safe and environment-friendly; and (4) the coating can be widely applicable to fire-proof protection of highways, railways and metro tunnel structures and to fire-proof walls in petrochemical engineering, etc.

Description

Environment-friendly colored fire-proof coating for tunnels
Technical field
The present invention relates to a kind of environment-friendly type fire-proof coating for tunnels, specifically a kind of environment-friendly colored fire-proof coating for tunnels that can be used for the different colours requirement.
Background technology
Along with high speed development of national economy, urban construction is accelerated, and the floating population increases sharply, and transport development reaches to improve and seems particularly important.And the tunnel is realized that target range is the shortest, floor space is minimum, physical environment and landscape destruction degree minimum, characteristics that cost is low has been subjected to planning construction person's favor with it.But tunnel structure generally is to be assembled by stone and Steel Concrete to form, and when temperature rose to 600 ℃, concrete strength was with a toll of more than 50%, and the yielding stress of steel drops under the normal temperature force-at-yield below 1/3.And during the tunnel presence of fire, temperature is generally more than 1000 ℃, the tunnel masonry is difficult to bear high temperature like this, serious part burns down easily, and it is airtight relatively to add tunnel environment, and people's flow density is big, in case presence of fire, the evacuation and the quite difficulty of putting out a fire to save life and property cause great loss of life and personal injury and property damage easily, and therefore the tunnel being prevented fires from handling seems very important.
Fire-proof coating for tunnels is just progressively to study and produce from late 1990s, mainly is made up of binding agent, inorganic fire resistant infilling, fire retardant and auxiliary agent.Its flameproof protection principle is: fire-resistantly do not fire by self, at high temperature form adamantine membrane sealing base material, secluding air, intercept flame and heat, thereby reach the purpose of fire protection flame retarding.Therefore fire-proof coating for tunnels is the fire endurance that improves the tunnel, prevents that the steel member from because of heating up rapidly one of effective safeguard procedures of deformation slump taking place in fire.Because the length in tunnel is different with design requirements, also more and more higher to the decoration requirement of inner surface of tunnel, present way is external coating or spraying finishing fire retardant paint or the Decorative Cover finish paint that arrives at fire-proof coating for tunnels.These finish paints are organism mostly, and cost is higher, discharge toxic gas in high temperature or fire easily, quicken flame transmission; And the easy variable color of organic coating, weather resisteant is poor.
Summary of the invention
At the defective of present fire-proof coating for tunnels, the invention provides different colours, fire endurance height and moderate environment-friendly colored fire-proof coating for tunnels.
Environment-friendly colored fire-proof coating for tunnels of the present invention comprises the content of following component and mass fraction:
Component 1: 10~50 parts of cement
Component 2: 40~90 parts of pearlstone, expanded vermiculite and light calcium carbonates
Component 3: 1~10 part of inorganic mineral fiber
Component 4: 5~30 parts of flame-retardant systems
Component 5: 0.1~5.0 part of rubber powder
Component 6: 0.5~3.0 part of water reducer, air entrapment agent and swelling agent
Component 7: 0.5~2.0 part of mineral dye.
Mix through the forced action type mixer and to get final product.
Described cement is ordinary Portland cement or quick hardening sulphoaluminate cement, and its strength mark is not less than 42.5; Flame-retardant system employing magnesium hydroxide and aluminium hydroxide are composite; Water reducer is poly carboxylic acid or naphthalene series high-efficiency water-reducing agent; Air entrapment agent is rosin based or alkylsulfonate system.
The mechanism of action of the present invention is: with ordinary Portland cement or high-alumina cement is jointing compound, with the gluing of various lightweight weighting agent together, adds fire retardant and various auxiliary agent simultaneously therein; The lightweight weighting agent can effectively reduce thermal conduction because transmissibility factor is less.Flame-retardant system can reduce the temperature of fire-proof coating for tunnels in fire, effectively protects base material.Water reducer, rubber powder then play remarkable improve workability, application property, close-burning effect.Mineral dye can be given the fire-proof coating for tunnels distinct colors.
During construction, the material that the present invention is prepared adds the water of (mass percent 1: 0.8~1: 1.5), adopts forced mixer to mix and stir into wet mortar, takes the mode of conventional spraying, sprays to treated structures surface and gets final product.When closing on initial set, optical processing is received on the surface.
Innovative point of the present invention and beneficial effect are: (1) adds mineral dye in fire-proof coating for tunnels, can satisfy the demand of different color and daylighting, can reduce the cost that tunnel surface is decorated.(2) simplify construction technology, reduced the operational procedure of finishing paint.(3) have characteristics such as fire endurance, cohesive strength height, water-tolerant, this fire-proof coating for tunnels does not produce any toxic gas and waste in construction process and the fire, safety and environmental protection.(4) this coating can be widely used in the flameproof protection of highway, railway, subway tunnel construction, also can be used for the fireproof brickwork of petrochemical industry project etc.
Embodiment
Come the present invention is described further below in conjunction with specific embodiment, following each embodiment only is used to the present invention is described but not limitation of the present invention.
Embodiment 1:
Choose: 10 kilograms of silicate cements, 60 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 0.1 kilogram of polycarboxylate water-reducer, 0.3 kilogram of rosin based air entrapment agent, 0.2 kilogram of swelling agent, 30 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 0.5 kilogram of mineral dye red iron oxide, 5 kilograms of rubber powders, 6 kilograms of inorganic mineral fibers.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 1 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Embodiment 2:
Choose: 30 kilograms of silicate cements, 40 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 1.0 kilograms of naphthalene series high-efficiency water-reducing agents, alkylsulfonate is 0.8 kilogram of an air entrapment agent, 1.2 kilograms of swelling agents, 20 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 2.0 kilograms of mineral dye barba hispanicas, 3 kilograms of rubber powders, 1 kilogram of inorganic mineral fiber.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 0.8 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Embodiment 3:
Choose: 50 kilograms of silicate cements, 90 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 0.5 kilogram of water reducer, 0.5 kilogram of air entrapment agent, 0.5 kilogram of swelling agent, 5 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 1.0 kilograms of mineral dye cadmium yellows, 0.1 kilogram of rubber powder, 10 kilograms of inorganic mineral fibers.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 1.5 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Embodiment 4:
Choose: 30 kilograms of quick hardening sulphoaluminate cements, 40 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 1.0 kilograms of naphthalene series high-efficiency water-reducing agents, alkylsulfonate is 0.8 kilogram of an air entrapment agent, 1.2 kilograms of swelling agents, 20 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 2.0 kilograms of mineral dye chromoxide greens, 3 kilograms of rubber powders, 1 kilogram of inorganic mineral fiber.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 1.2 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Embodiment 5:
Choose: 10 kilograms of quick hardening sulphoaluminate cements, 50 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 0.1 kilogram of polycarboxylate water-reducer, 0.3 kilogram of rosin based air entrapment agent, 0.2 kilogram of swelling agent, 30 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 0.5 kilogram of mineral dye chrome yellow, 5 kilograms of rubber powders, 6 kilograms of inorganic mineral fibers.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 1 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Embodiment 6:
Choose: 50 kilograms of quick hardening sulphoaluminate cements, 90 kilograms of pearlstone, expanded vermiculite and light calcium carbonates, 0.5 kilogram of water reducer, 0.5 kilogram of air entrapment agent, 0.5 kilogram of swelling agent, 5 kilograms of magnesium hydroxide and aluminium hydroxide flame-retardant systems, 1.0 kilograms of mineral dye ferrotitanium powder or titanium dioxides, 0.1 kilogram of rubber powder, 10 kilograms of inorganic mineral fibers.Above-mentioned starting material are dropped in the forced mixer, get final product after stirring.At the construction field (site), add entry at 1: 1.5 according to quality of materials per-cent, stir 15min with forced mixer, the mortar that mix becomes to have to wipe one's face the construction denseness is sprayed on the substrate surface of handling through suitably, and maintenance was tested after 28 days under the normal temperature.
Environment-friendly colored fire-proof coating for tunnels embodiment performance test results table
Figure B2009100821159D0000041
Annotate: People's Republic of China's Safety Industry standard is GA98-2005 " a concrete structure frie retardant coating "
Test result shows: the adding of pigment is less to the cohesive strength of fire-proof coating for tunnels and fire endurance influence, and therefore the color of allocating fire-proof coating for tunnels by mineral dye is feasible.

Claims (5)

1. an environment-friendly colored fire-proof coating for tunnels is characterized in that, comprises the content of following component and mass fraction:
Component 1: 10~50 parts of cement
Component 2: 40~90 parts of pearlstone, expanded vermiculite and light calcium carbonates
Component 3: 1~10 part of inorganic mineral fiber
Component 4: 5~30 parts of flame-retardant systems
Component 5: 0.1~5.0 part of rubber powder
Component 6: 0.5~3.0 part of water reducer, air entrapment agent and swelling agent
Component 7: 0.5~2.0 part of mineral dye.
2. environment-friendly colored fire-proof coating for tunnels according to claim 1 is characterized in that, described cement is ordinary Portland cement or quick hardening sulphoaluminate cement, and its strength mark is not less than 42.5.
3. environment-friendly colored fire-proof coating for tunnels according to claim 1 is characterized in that, described flame-retardant system employing magnesium hydroxide and aluminium hydroxide are composite.
4. environment-friendly colored fire-proof coating for tunnels according to claim 1 is characterized in that, described water reducer is poly carboxylic acid or naphthalene series high-efficiency water-reducing agent.
5. according to arbitrary described environment-friendly colored fire-proof coating for tunnels in the claim 1~4, it is characterized in that described air entrapment agent is rosin based or alkylsulfonate system.
CN200910082115A 2009-04-15 2009-04-15 Environment-friendly colored fire-proof coating for tunnels Pending CN101863640A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910082115A CN101863640A (en) 2009-04-15 2009-04-15 Environment-friendly colored fire-proof coating for tunnels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910082115A CN101863640A (en) 2009-04-15 2009-04-15 Environment-friendly colored fire-proof coating for tunnels

Publications (1)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173691A (en) * 2011-02-22 2011-09-07 山西省交通科学研究院 Single-component tunnel fire-retardant coating and preparation method thereof
CN102219438A (en) * 2011-03-21 2011-10-19 山西省交通科学研究院 Flame-retardant double-component adhesive used for color antiskid pavement layer of tunnel
CN103396068A (en) * 2013-08-22 2013-11-20 吴江市冰心文教用品有限公司 Tunnel fire prevention pigment
CN103964776A (en) * 2013-02-05 2014-08-06 保全研究与技术中心 Fire protection mortar
GB2525683A (en) * 2014-05-02 2015-11-04 Northern Chimney Lining System Improved concrete mix
RU2720540C1 (en) * 2019-08-02 2020-05-12 ООО "ПО Химцентр" Composition for making fireproof mortar
EP3896046A1 (en) 2020-04-16 2021-10-20 Hydro Building Systems Poland Sp. z o.o. Dry cement-based ceramic composition for preparing a cooling material for reinforcement insert or filling of aluminum systems, reinforcement filling for aluminum systems comprising it, method of providing fire protection of aluminum system and use of dry cement-based ceramic composition for preparing reinforcement filling or insert
RU2799677C1 (en) * 2023-03-10 2023-07-10 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Fire retardant plaster raw mix
CN116426151A (en) * 2023-03-10 2023-07-14 中国电建集团华东勘测设计研究院有限公司 Ultra-light UHDC fireproof protective coating for steel structure building and spraying device

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173691A (en) * 2011-02-22 2011-09-07 山西省交通科学研究院 Single-component tunnel fire-retardant coating and preparation method thereof
CN102219438A (en) * 2011-03-21 2011-10-19 山西省交通科学研究院 Flame-retardant double-component adhesive used for color antiskid pavement layer of tunnel
CN102219438B (en) * 2011-03-21 2012-12-05 山西省交通科学研究院 Flame-retardant double-component adhesive used for color antiskid pavement layer of tunnel
CN103964776B (en) * 2013-02-05 2016-07-06 保全研究与技术中心 fireproof mortar
CN103964776A (en) * 2013-02-05 2014-08-06 保全研究与技术中心 Fire protection mortar
WO2014122085A1 (en) 2013-02-05 2014-08-14 Promat Research and Technology Centre NV Fire protection mortar
US9034097B2 (en) 2013-02-05 2015-05-19 Promat Research and Technology Centre NV Fire protection mortar
AU2014200344B2 (en) * 2013-02-05 2017-03-02 Promat Research and Technology Centre NV Fire Protection Mortar
EA026204B1 (en) * 2013-02-05 2017-03-31 Промат Рисерч Энд Текнолоджи Сентр Н.В. Fire protection mortar
CN103396068A (en) * 2013-08-22 2013-11-20 吴江市冰心文教用品有限公司 Tunnel fire prevention pigment
GB2525683A (en) * 2014-05-02 2015-11-04 Northern Chimney Lining System Improved concrete mix
RU2720540C1 (en) * 2019-08-02 2020-05-12 ООО "ПО Химцентр" Composition for making fireproof mortar
EP3896046A1 (en) 2020-04-16 2021-10-20 Hydro Building Systems Poland Sp. z o.o. Dry cement-based ceramic composition for preparing a cooling material for reinforcement insert or filling of aluminum systems, reinforcement filling for aluminum systems comprising it, method of providing fire protection of aluminum system and use of dry cement-based ceramic composition for preparing reinforcement filling or insert
RU2799677C1 (en) * 2023-03-10 2023-07-10 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Fire retardant plaster raw mix
CN116426151A (en) * 2023-03-10 2023-07-14 中国电建集团华东勘测设计研究院有限公司 Ultra-light UHDC fireproof protective coating for steel structure building and spraying device
RU2811704C1 (en) * 2023-03-10 2024-01-16 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) Raw mixture for fire retardant plaster mortar

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Application publication date: 20101020