CN106380937A - Milk-white environment-friendly type synthesis polymer steel roofing paint - Google Patents

Milk-white environment-friendly type synthesis polymer steel roofing paint Download PDF

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Publication number
CN106380937A
CN106380937A CN201610774359.3A CN201610774359A CN106380937A CN 106380937 A CN106380937 A CN 106380937A CN 201610774359 A CN201610774359 A CN 201610774359A CN 106380937 A CN106380937 A CN 106380937A
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China
Prior art keywords
parts
solvent naphtha
steel roofing
paint
antioxidant
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Pending
Application number
CN201610774359.3A
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Chinese (zh)
Inventor
王丽莉
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Henan Province Hai Hai Building Materials Co Ltd
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Henan Province Hai Hai Building Materials Co Ltd
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Priority to CN201610774359.3A priority Critical patent/CN106380937A/en
Publication of CN106380937A publication Critical patent/CN106380937A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an environment-friendly type synthesis polymer steel roofing paint, which belongs to the field of waterproof construction. The paint comprises the following components: 8-20 parts of a polyolefin thermoplastic elastomer, 4-8 parts of aldehyde ketone resin, 2-12 parts of styrene resin, 1-5 parts of silicon powder, 1-10 parts of mica powder, 1-5 parts of rutile titanium dioxide, 0.3-1 part of an antioxidant 1010, 0.3-1 part of an antioxidant 1076, 0.3-1 part of an anti-oxidant 531, 0.5-2.5 parts of an antifoaming agent, 0.3-1 part of an ultraviolet ray absorber, 5-30 parts of D40 solvent naphtha, and 5-30 parts of butyiate solvent naphtha. The milk-white steel roofing waterproof paint has the characteristics of no toxicity, no harm, no pollution, no containing of noxious materials and harmful components such as pitch and benzene, and realization of free toning. The product performance is stable, the material service life can reach 30 years or more, and has the characteristics of strong adhesion stress, good penetration performance and good elongation percentage.

Description

Milky environment-friendly synthetic macromolecular steel roofing special coating
Technical field
The present invention relates to a kind of architectural waterproof material is and in particular to a kind of milky environment-friendly synthetic macromolecular steel roofing is special Use coating.
Background technology
Buildings waterproof is by preventing water from the infiltration at some positions of building is taken from construction material and on construction Measure.Using in roofing, hypogee, the under ground portion of building and the interior room needing waterproof and water storage structures more than waterproof Deng.The measure taken by it and the difference of means, are divided into material waterproofing and constructional waterproofing two big class.Involved in the present invention is main It is a kind of material waterproofing, the problem of the always one waterproof headache of protruding parts of steel structural roof, waterproof on the market at present The material such as coating such as silica gel, APP, construction is complicated, is difficult that toning, decorative effect are poor, and permeability, cohesive force are poor, and properties of product are not Stable, service life is short, containing multiple harmful chemicals preparations, and all can not solve the leakage problems of roofing well.And apply for Artificially solve the above problems, applied for that in 2006 patent name is " green waterproof milk white polymer paint ", specially Profit number for " 200610099088.2 " patent of invention although possess nontoxic, pollution-free, UV resistant irradiate, heat-insulated, anti-ageing Change, direct brushing, construction are simple, and the features such as color-adjustable, but, after years of research and found that, this coating is permissible for interior, For during outdoor steel roof waterproof, because outdoor environment is changeable, use environment is poor:Wind scrape drench with rain, the extraneous dirty spies such as many Point, in outdoor UV resistant, loss of properties on aging, properties of product are not very stable to this coating, have more than is needed several years, properties of product It is easily broken and water leakage situation occurs again, therefore be badly in need of improving.
Content of the invention
It is an object of the invention to overcoming the technology that in prior art, water-repellent paint exists in outdoor steel roof waterproof to ask Topic, provides a kind of environment-friendly synthetic macromolecular steel roofing special coating, and this coating is steel roofing waterproof paint specially, ageing-resistant, UV resistant performance is good, and properties of product are stable, and service life was up to 30 years as long as.
Technical scheme:A kind of environment-friendly synthetic macromolecular steel roofing special coating, this coating is made up of following components:Polyene Hydrocarbon thermoplastic elastomer (TPE) 8-20 part, aldehyde ketone resin 4-8 part, styrene resin 2-12 part, silica flour 1-5 part, mica powder 1-10 part, gold Red stone-type titanium dioxide 1-5 part, age resistor 1010 0.3-1 part, age resistor 1076 0.3-1 part, antioxidant 531 0.3-1 part, disappear Infusion 0.5-2.5 part, UV absorbent 327 0.3-1 part, D40 solvent naphtha 5-30 part, butyl ester solvent naphtha 5-30 part.
Based on technique scheme, the steel roofing special coating of the present invention is made up of following components:Polylefin thermoplatic bullet 15 parts of gonosome, 6 parts of aldehyde ketone resin, 8 parts of styrene resin, 3 parts of silica flour, 5 parts of mica powder, 3 parts of Rutile type titanium dioxide, age resistor 1010 0.7 parts, 1,076 0.6 parts of age resistor, 531 0.8 parts of antioxidant, 1 part of defoamer, 327 0.8 parts of UV absorbent, 20 parts of D40 solvent naphtha, 15 parts of butyl ester solvent naphtha.
Main component in technique scheme is:TPO, aldehyde ketone resin and styrene resin, its Middle TPO is a kind of High performance polyolefin product, at normal temperatures become caoutchouc elasticity, have density little, bending Greatly, low-temperature impact resistance height, easy processing, reusable the features such as.Aldehyde ketone resin refers to by ketone and aldehydes through polycondensation reaction Polymer, also referred to as aldehyde ketone resin or polyketone resin.The chemical constitution of aldehyde ketone resin gives its very special quality and spy Property, resin defines the circulus of saturation so as to have high glaze, hardness, anti-degraded and weatherability feature in the condensation phase.By Do not contain ester bond in the structure in this resin, thus have preferable resistance to water, major key contains a lot of cyclohexyls so as to have Thermostability.In addition, the polarity of ketone groups and hydroxyl groups makes it have extensive dissolubility intermiscibility, therefore, polyketone resin both may be used The compound larger with polarity is compatible, again can be compatible with the less compound of polarity, is suitable for most of ink, coating and adhesive System.Styrene resin is engineering thermoplasties, has very high impact strength and toughness, can improve as coating additive UV resistant performance and heat stability, anti-flammability and antistatic property.After triplicity, product genus paint property of the present invention is polynary poly- Compound, becomes a kind of continuous closing rubber-like elastic body, has superpower cohesive force, may penetrate into cement after product curing of coating 2-3 millimeter, is integrated with cement basic layer completely, has high tensile, can effectively resist because of building basic unit uneven settlement, The face coat crack performance that structural cracking caused by four seasons difference variation causes occurs.
The present invention has the advantages that:1. the present invention is milky steel roofing waterproof paint specially, the product five poisonous creatures: scorpion, viper, centipede, house lizard, toad, Harmless, pollution-free, the not noxious substance harmful components such as bituminous, benzene, the health of environment and personnel is all had no adverse effects, product For milky, can achieve and freely mix colours, color and luster is attractive in appearance, product can need to match colors according to design requirement and user, has splendid Heat-insulation and heat-preservation and decoration effect.
2. stable performance, stable performance in the presence of ultraviolet, light, heat and oxygen, the materials'use life-span reaches in external enwergy More than 30 years, under protective layer, service life was identical with cement.
3. cohesive force is extremely strong, adhesion strength 1.8MPa, does not peel off under external force, not stratified, can form stable preventing Water is overall, because cohesive force is excellent, filled up China can only downstream waterproof it is impossible to the technological gap of waterproof against the current.
4th, permeance property is good, because the permeance property of material is good, applies brush material and can penetrate into cement basic layer basic material Space in, plug penetrating passage, good water-proof effect, permeable cement basic unit 2-3mm, combine together with cement basic layer completely
5. elongation percentage is high, product waterproof, antistatic, anti-fracture, elongation percentage height after solidification, because elongation percentage is high, after basic unit's deformation, prevents Water layer and basic unit are without departing from the blank of waterproof material no fracture when solving basic unit's differential settlement.
6. high and low temperature resistance is good, and product is high temperature resistant to trickle up to 130 degree of portions, low temperature 40 degrees below zero not embrittlement, and subzero 35 Degree more than can normal construction, product by roof coated with high reflectance white material, can by sunlight reflectance bring up to 60% with On, and roof painted white can make a building energy conservation 20%.
Specific embodiment
With reference to specific embodiment, the present invention will be further described, to be better understood from technical solution of the present invention.
Embodiment 1:Environment-friendly synthetic macromolecular steel roofing special coating, this coating is weighed by following parts by weight when making Raw material:8 parts of TPO, 4 parts of aldehyde ketone resin, 2 parts of styrene resin, 1 part of silica flour, 1 part of mica powder, rutile 5 parts of type titanium dioxide, 1,010 1 parts of age resistor, 1,076 0.3 parts of age resistor, 531 1 parts of antioxidant, 0.5 part of defoamer, ultraviolet 327 1 parts of absorbent, 5 parts of D40 solvent naphtha, 30 parts of butyl ester solvent naphtha.
Embodiment 2:Environment-friendly synthetic macromolecular steel roofing special coating, this coating is weighed by following parts by weight when making Raw material:15 parts of TPO, 6 parts of aldehyde ketone resin, 8 parts of styrene resin, 3 parts of silica flour, 5 parts of mica powder, golden red 3 parts of stone-type titanium dioxide, 1,010 0.7 parts of age resistor, 1,076 0.6 parts of age resistor, 531 0.8 parts of antioxidant, 1 part of defoamer is purple 327 0.8 parts of ultraviolet absorbers, 20 parts of D40 solvent naphtha, 15 parts of butyl ester solvent naphtha.
Embodiment 3:Environment-friendly synthetic macromolecular steel roofing special coating, this coating is weighed by following parts by weight when making Raw material:
20 parts of TPO, 8 parts of aldehyde ketone resin, 12 parts of styrene resin, 5 parts of silica flour, 10 parts of mica powder, 1 part of Rutile type titanium dioxide, 1,010 0.3 parts of age resistor, 1,076 1 parts of age resistor, 531 0.3 parts of antioxidant, defoamer 2.5 Part, 327 0.3 parts of UV absorbent, D40 solvent naphtha 5-30 part, butyl ester solvent naphtha 5-30 part.
Environment-friendly synthetic macromolecular steel roofing special coating in above-described embodiment, for the use characteristic of steel roof waterproof, Steel construction color steel roof causes drainage especially severe due to reasons such as installation, roofing elastic deformation, roofing vibrations, and And, water-repellent paint exposed for a long time outside it is easy to being aging, corroding, and then reduce water resistance, cause water-repellent paint ftracture, Drainage occurs.Therefore steel roofing waterproof paint need to have superpower tensile strength, uvioresistant, aging resistance, resisting fatigue, Low temperature flexibility, corrosion-free, stay in grade feature, above-described embodiment is in the documents of Patent No. " 200610099088.2 " On the basis of, component is improved, TPO and aldehyde ketone resin, styrene resin is effectively combined, Instead of SEBS, the SBS in documents, and eliminate the fractions in documents, from specific antioxidant, prevent always Agent, UV absorbent and solvent naphtha, and a kind of milky steel roofing waterproof paint specially made, have superpower gluing Knot power, may penetrate into cement 2-3 millimeter, is integrated with cement basic layer completely, can effectively resist and sink not because of building basic unit Even, the face coat crack performance that the structural cracking caused by four seasons difference variation causes occurs.High-low temperature resistant, corrosion-resistant, Antioxygenic property is extremely strong, and properties of product are stable, service life up to 30 years, highly promotion and implementation.

Claims (2)

1. a kind of environment-friendly synthetic macromolecular steel roofing special coating, is characterized in that:This coating is made up of following components:Polyolefin Thermoplastic elastomer (TPE) 8-20 part, aldehyde ketone resin 4-8 part, styrene resin 2-12 part, silica flour 1-5 part, mica powder 1-10 part, golden red Stone-type titanium dioxide 1-5 part, age resistor 1010 0.3-1 part, age resistor 1076 0.3-1 part, antioxidant 531 0.3-1 part, froth breaking Agent 0.5-2.5 part, UV absorbent 327 0.3-1 part, D40 solvent naphtha 5-30 part, butyl ester solvent naphtha 5-30 part.
2. environment-friendly synthetic macromolecular steel roofing special coating according to claim 1, is characterized in that:This coating is by following Component is made:15 parts of TPO, 6 parts of aldehyde ketone resin, 8 parts of styrene resin, 3 parts of silica flour, 5 parts of mica powder, 3 parts of Rutile type titanium dioxide, 1,010 0.7 parts of age resistor, 1,076 0.6 parts of age resistor, 531 0.8 parts of antioxidant, defoamer 1 Part, 327 0.8 parts of UV absorbent, 20 parts of D40 solvent naphtha, 15 parts of butyl ester solvent naphtha.
CN201610774359.3A 2016-08-31 2016-08-31 Milk-white environment-friendly type synthesis polymer steel roofing paint Pending CN106380937A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108627455A (en) * 2018-04-25 2018-10-09 郑州中原思蓝德高科股份有限公司 A kind of test method of thermoplasticity spacer bar and outer course glue sticking performance

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CN102912941A (en) * 2012-11-13 2013-02-06 天津市禹红建筑防水材料有限公司 Roofing polyolefin polymer waterproof coiled material with anti-aging layer
CN103333302A (en) * 2013-06-25 2013-10-02 华南理工大学 Preparation method and application of mild reaction type aldehyde ketone resin
CN103773016A (en) * 2014-01-20 2014-05-07 南通东南公路工程有限公司 Asphalt polyolefin waterproof material
CN103834240A (en) * 2014-03-19 2014-06-04 王勇 TPE (Thermoplastic Polyolefin) rubber waterproof coating film and preparation method thereof
CN104559707A (en) * 2015-01-20 2015-04-29 芜湖县双宝建材有限公司 High-adhesion high-performance corrosion-resistant decontaminable paint
CN104927372A (en) * 2015-06-23 2015-09-23 深圳中佳和化工有限公司 Asphalt size used for producing APP plastic body modified asphalt waterproofing material and preparation method and application thereof
CN105885693A (en) * 2016-03-14 2016-08-24 北京东方雨虹防水技术股份有限公司 Non-curable rubber asphalt waterproof coating and preparation method and composite waterproof roll material thereof

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Publication number Priority date Publication date Assignee Title
CN102108234A (en) * 2010-12-22 2011-06-29 白铁林 Colourful environmental-friendly synthesized polymer waterproof paint
CN102912941A (en) * 2012-11-13 2013-02-06 天津市禹红建筑防水材料有限公司 Roofing polyolefin polymer waterproof coiled material with anti-aging layer
CN103333302A (en) * 2013-06-25 2013-10-02 华南理工大学 Preparation method and application of mild reaction type aldehyde ketone resin
CN103773016A (en) * 2014-01-20 2014-05-07 南通东南公路工程有限公司 Asphalt polyolefin waterproof material
CN103834240A (en) * 2014-03-19 2014-06-04 王勇 TPE (Thermoplastic Polyolefin) rubber waterproof coating film and preparation method thereof
CN104559707A (en) * 2015-01-20 2015-04-29 芜湖县双宝建材有限公司 High-adhesion high-performance corrosion-resistant decontaminable paint
CN104927372A (en) * 2015-06-23 2015-09-23 深圳中佳和化工有限公司 Asphalt size used for producing APP plastic body modified asphalt waterproofing material and preparation method and application thereof
CN105885693A (en) * 2016-03-14 2016-08-24 北京东方雨虹防水技术股份有限公司 Non-curable rubber asphalt waterproof coating and preparation method and composite waterproof roll material thereof

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Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108627455A (en) * 2018-04-25 2018-10-09 郑州中原思蓝德高科股份有限公司 A kind of test method of thermoplasticity spacer bar and outer course glue sticking performance

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Application publication date: 20170208